Search Results (14)

The widespread phase-out of long-chain per- and poly-fluoroalkyl substances (PFASs) has created an urgent need for durable, fluorine-free water-repellent finishes that match the performance of legacy chemistries while minimising environmental impact. Here, the performance of an eco-friendly hybrid organic–inorganic treatment obtained by the in situ hydrolysis–condensation of triethoxy(octyl)silane (OS) in an amino-terminated polydimethylsiloxane (APT-PDMS) aqueous dispersion was investigated. The sol was applied to plain-weave cotton and polyester by a pad-dry-cure process and benchmarked against a commercial fluorinated finish. Morphology and chemistry were characterised by SEM–EDS, ATR-FTIR, and Raman spectroscopy; wettability was assessed by static contact angle, ISO 4920 spray ratings, and AATCC 193 water/alcohol repellence; and durability, handle, and breathability were evaluated through repeated laundering, bending stiffness, and water-vapour transmission rate measurements. The silica/PDMS coating formed a uniform, strongly adherent nanostructured layer conferring static contact angles of 130° on cotton and 145° on polyester. After five ISO 105-C10 wash cycles, the treated fabrics still displayed a spray rating of 5/5 and AATCC 193 grade 7, outperforming or equalling the fluorinated control, while causing ≤5% loss of water-vapour permeability and only a marginal increase in bending stiffness. These results demonstrate that the proposed one-step, water-borne sol–gel process affords a sustainable, industrially scalable route to high-performance, durable, water-repellent finishes for both natural and synthetic textiles, offering a viable alternative to PFAS-based chemistry for outdoor apparel and technical applications. Full article

This study investigates the optimization of the Material Extrusion (MEX) process for producing polylactic acid (PLA) patterns used in investment casting moulds, specifically targeting the casting of non-ferrous alloys such as brass. Key MEX process parameters—layer thickness, wall thickness, infill density, and post-processing with dichloromethane vapour for surface enhancement—were systematically analyzed for their impact on mould quality. Results indicate that an optimized combination of MEX parameters yields moulds with high dimensional accuracy, low surface roughness, and minimal pattern residue within the mould cavity. These optimized moulds were subsequently used in brass casting, with the final cast parts evaluated for dimensional precision and surface finish. The study concludes that PLA patterns manufactured via optimized MEX parameters provide a precise, cost-effective, and easy-to-implement solution for industry applications. Additionally, this process is environmentally friendly and presents clear advantages over other pattern-making methods, offering a sustainable alternative for producing complex metal parts with reduced environmental impact. The findings underscore the significant role of post-processing in enhancing mould quality and, consequently, the quality of the cast parts. Full article

The work deals with the influence of the reach of the applied tool holder on the edge wear, dimensional accuracy and surface quality defined by the topography as well as the roughness of the machined surface. The research has been conducted on specimens made of Inconel 718 in the configuration of sleeves, within the scope of finish turning with constant cutting parameters, v_c = 85 m/min; f = 0.14 mm/rev; a_p = 0.2 mm. The material under machining has undergone heat treatment procedures such as solution treatment and precipitation hardening, resulting in a hardness of 45 ± 2 HRC. Two kinds of turning holders have been used with the reaches of 120 mm and 700 mm. The tools are intended for turning external and internal surfaces, respectively. The tests have been conducted using V-shaped cutting inserts manufactured by different producers, made of fine-grained carbide with coatings applied by the PVD (Physical Vapour Deposition) and CVD (Chemical Vapour Deposition) methods. The edge wear has been evaluated. The value of the achieved diameter dimensions has also been assessed in relation to the set ones, as well as the recorded values of surface roughness and the surface topography parameters have also been assessed. It has been determined that the quality of the manufactured surface evaluated by the 2D and 3D roughness parameters, as well as the dimensional quality are influenced by the kind of the applied tool holder. The influence is also visible considering the edge wear. The smallest values of the deviations from the nominal dimensions have been obtained for the coated inserts of the range of higher abrasion resistance (taking into account information from the producers). The obtained results show that in predicting the dimensional accuracy in the process of turning Inconel 718 alloy with long-overhang tools, one should consider the necessity of correction of the tool path. Taking into account the achieved surface roughness, it should be pointed out that not only the kind of the tool coating but also the character of its wear has a great influence, particularly, when a long cutting distance is required. Full article

The long-term endurance of building stones must be assured since their longevity has repercussions for their economic and social value. Frequently, slabs for flooring and cladding are installed with polished finishing in outdoor environments for technical and ornamental purposes in cultural heritage sites and modern civil architecture. Compared to any other finishing, glossy surfaces are rather vulnerable to wear, particularly when they interact with slightly acidic rainwater. Several hydrophobic treatments are applied to prevent this damage by preventing contact between rain and stone; such treatments are efficient but sometimes non-durable. Stakeholders and conservation scientists need better methods to anticipate the future behaviour of this building material and hydrophobic solutions. Complying with this demand, a comparison is made between outdoor natural ageing and artificial weathering, reproduced by UVA radiation, moisture and spray accelerated weathering. Artificial weathering is applied to predict the behaviour of stones over time in the real environment. Data obtained through the measurement of gloss and colour parameters, the detection of micro-textures through SEM, and the calculation of micro-roughness using a digital rugosimeter demonstrate that weakly acidic rainwater is the main cause of superficial decay of stone finishing over just six months of outdoor exposure. This period corresponds to 7–14 days of artificial weathering. Furthermore, the loss of efficiency and durability of the hydrophobic coatings is detected by measuring the static contact angle. This highlights that even if a protective treatment was proficient, it could easily deteriorate in normal weathering conditions if applied on polished, low-porosity stone. Additionally, water vapour permeability indicates variations of regular vapour transmission through the stones due to ageing. The first solution to threats is the prevention of pathologies, including aesthetic ones. A careful choice of the most suitable lithotype finish and an environmental study represent an existing solution to the problem. It must be highlighted that aesthetic requirements should not be prioritised to detriment of the technical requirements of architectural quality, performance, durability, and safety. Full article

Due to their variety, specific activity, and mild reaction conditions, enzymes have a wide application in beam house processes such as soaking, dehairing, bating, and de-greasing. Recently, due to improvements in biotechnology, re-bating after chroming has received increased attention. The aim of this work was to investigate the application of enzyme preparation in the re-bating process and its effect on the semifinished and finished product, as well as its influence on post-tanning operations. The enzymatic treatment of chromed semifinished leather (wet blue) led to a higher shrinkage temperature (1–6 °C), greater water vapour absorption (0.3–5.5%), better chromium compounds exhaustion during re-chroming (4–21%), and better dye penetration. Moreover, collagen was affected during the enzymatic process; the results showed a greater concentration influence in the operation compared to the process time. On the other hand, no effect on the physical and mechanical properties and fat-liquoring process was observed. Overall, these results indicate that some properties and processes are improved; however, before use for re-bating, every enzyme should be carefully investigated. Full article

Current trends towards saving energy and designing sustainable buildings result in most designers focusing on achieving the best thermal parameters, thereby neglecting a careful moisture analysis. Excessive moisture content in building partitions degrades the mechanical properties of materials, reduces thermal insulation properties (which leads to an increase in the demand for thermal energy) and worsens the microclimate in rooms. Modern digital solutions help create appropriate models of partitions that work for many years in good environmental conditions. According to the analysis of air parameters, 1 m³ of air at 20 °C contains approx. 17.3 g of water. When the temperature of the air reaches the dew point temperature, water vapour condenses. The dew point depends on air temperature and relative air humidity; for instance, at the same air temperature of 20 °C, the dew point temperature at 40% relative air humidity is 6 °C, whereas at 90% relative humidity, it is over 18 °C. This means that the higher the value of relative humidity in the room at a certain temperature, the lower the temperature that will cause condensation. The article presents a numerical analysis of the insulation work of flexible materials within the layers of ventilated partitions in an 8-year simulated period of varying environmental conditions. The aim of the article is to analyze different models and variants of ventilated partition operation with respect to the advisability of using a vapour barrier to avoid the problem of destruction of thermal insulation and finishing layers of a ventilated roof. Full article

Liquid crystal polymer (LCP) has gained wide interest in the electronics industry largely due to its flexibility, stable insulation and dielectric properties and chip integration capabilities. Recently, LCP has also been investigated as a biocompatible substrate for the fabrication of multielectrode arrays. Realizing a fully implantable LCP-based bioelectronic device, however, still necessitates a low form factor packaging solution to protect the electronics in the body. In this work, we investigate two promising encapsulation coatings based on thin-film technology as the main packaging for LCP-based electronics. Specifically, a HfO₂–based nanolaminate ceramic (TFE1) deposited via atomic layer deposition (ALD), and a hybrid Parylene C-ALD multilayer stack (TFE2), both with a silicone finish, were investigated and compared to a reference LCP coating. T-peel, water-vapour transmission rate (WVTR) and long-term electrochemical impedance spectrometry (EIS) tests were performed to evaluate adhesion, barrier properties and overall encapsulation performance of the coatings. Both TFE materials showed stable impedance characteristics while submerged in 60 °C saline, with TFE1-silicone lasting more than 16 months under a continuous 14V DC bias (experiment is ongoing). The results presented in this work show that WVTR is not the main factor in determining lifetime, but the adhesion of the coating to the substrate materials plays a key role in maintaining a stable interface and thus longer lifetimes. Full article

For the aluminium alloys produced by the hot extrusion process, the profile is shaped according to the bearing at the exit of the extrusion die. The tribological process has significant effects on the die service life, profile dimensional tolerances, and profile surface finish. Recently, new technologies have been introduced to the hot extrusion die, such as cemented carbide insert die and surface coating. However, under hot extrusion working conditions, quantitative studies on their friction and wear performances are lacking. In this work, the friction and wear performances of three typical extrusion die materials, traditional hot tool steel (H13), cemented carbide (YG8), and chemical vapour deposition (CVD) coating, were studied. Macro and nano hardness tests, Pin-on-disk friction and wear tests, optical profiler and SEM observations, and experiments and simulations of hot extrusion were conducted. The results show that the coefficients of friction of CVD coatings and H13 hot work tool steel specimens were smaller under the hot extrusion condition than at room temperature. The wear mechanisms of H13, YG8, and CVD coatings at 500 °C are adhesion, abrasive, and fatigue, respectively. Moreover, the tribology results were validated by the extrusion experiments and the finite element analysis of hot extrusion. The conclusion of this manuscript is useful not only for the numerical simulation of the hot extrusion process but also for the surface finishing of the extrusion profile. Full article

This paper deals with the influence of the type of transparent surface finish on the change of colour of the surfaces of native wood, and thermally treated wood, with saturated water vapour. In the experiment, alder, European beech, Paper birch, and Norway maple wood were thermally treated at a temperature of 135 °C under saturated water vapour for six hours. Three various types of surface finishes (acrylic-polyurethane, polyacrylic and aldehyde resin, and alkyd resin) were applied onto the wood surfaces. The colours of the surfaces in the system, CIE L*a*b* (lightness, coordinates a* and b*, chroma and hue angle), were measured during finishing and natural ageing behind glass windows in an interior, over a period of 60 days. The results show that the changes in the yellowness index, and the total colour differences after the application of individual surface finishes to wood species, changed because of sunlight exposure. Moreover, it is clear that different wood finishes behaved differently on all of the wood species. An analysis is presented in this paper. Full article

Plasters have covered wide surface areas of buildings since antiquity, with a main purpose of indoor protection of the substrate on which they are applied. When no longer functional, they might require substitution with solutions that can combine compatibility with the substrate with the current need to mitigate building emissions. Indeed, plasters can contribute to lowering buildings’ energy demands while improving indoor air quality and the comfort of buildings’ users, as plasters can be used as passive regulators of relative humidity (RH). Hence, this study presents the relative-humidity-dependent properties of different plastering mortars based on clay, air lime, and natural hydraulic lime, and plastering finishing pastes based on gypsum and gypsum–air lime, in all cases tested using small size specimens. A cement-based plaster is also analysed for comparison. The clay-based plaster was the most promising material for RH passive regulation, and could be applied to repair and replace plasters in different types of buildings. Pastes based on air lime–gypsum could be applied as finishing layers, specifically on traditional porous walls. The sorption behaviour of cement plaster appeared interesting; however, its water vapour permeability was as expected, found to be the lowest, discouraging its application on historic walls. Full article

The Stationary Shoulder Friction Stir Welding (SS-FSW) technique benefits from reduced heat input, improved mechanical properties and surface finish of the weld, avoiding the need for post weld processing. Coatings on the tool probe and the shoulder for welding of aggressive Aluminium alloys have rarely been successful. Such coatings must be well adherent and inert. In this study, coated tools were used for SS-FSW of AA6082-T6 alloy. Performance of a nanoscale multilayer TiAlN/VN coating deposited by High Power Impulse Magnetron Sputtering (HIPIMS) technology was compared with amorphous Diamond Like Carbon (a-C:H) by Plasma Assisted Chemical Vapour Deposition (PACVD), AlTiN deposited by arc evaporation and TiBCN along with TiB₂ produced by Chemical Vapour Deposition (CVD) methods. The TiAlN/VN coating was found to have low affinity to aluminium, acceptable coefficient of friction and provided excellent weld quality by inhibiting intermixing between the tool and workpiece materials resulting in a significant reduction in tool wear. Full article

Despite several additive manufacturing techniques are commercially available in market, Fused Deposition Modeling (FDM) is increasingly used by researchers and engineers for new product development. FDM is an established process with a plethora of advantages, but the visible surface roughness (SR), being an intrinsic limitation, is major barrier against utilization of fabricated parts for practical applications. In the present study, the chemical finishing method, using vapour of acetone mixed with heated air, is being used. The combined impact of orientation angle, finishing temperature and finishing time has been studied using Taguchi and ANOVA, whereas multi-criteria optimization is performed using the Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS). The surface finish was highly responsive to increase in temperature while orientation angle of 0° yielded maximum strength; increase in finishing time led to weight gain of FDM parts. As the temperature increases, the percentage change in surface roughness increases as higher temperature assists the melt down process. On the other hand, anisotropic behaviour plays a major role during tensile testing. The Signal-to-noise (S/N) ratio plots, and ANOVA results indicated that surface finish is directly proportionate to finishing time because a longer exposure results in complete layer reflowing and settlement. Full article

The properties of polymer-based nanocomposites strongly depend on the fillers added and their dispersion on the matrix. Proposing a simple method that can control these variables is essential to obtain nanocomposites with enhanced properties. In this study, cellulose triacetate based nanocomposites modified with sol-gel synthesised vanadium oxide nanoparticles (V₂O₅) and poly(ethylene oxide-b-propylene oxide-b-ethylene oxide) (PEO-b-PPO-b-PEO or EPE) triblock copolymer were obtained by two methods: solvent casting (SC, drying at ambient conditions) and solvent vapour annealing (SVA, drying under solvent vapour atmosphere). Nanocomposites were characterised by Fourier-transform infrared spectroscopy (FTIR) and UV-vis spectroscopy. Nanocomposites presented green colour and high transparency, improving the SVA method the surface finish of the films. Moreover, V₂O₅ nanoparticles provided switchable photochromic properties, changing the film colour from green to pale blue when exposed to UV radiation. Nanocomposites with EPE triblock copolymer presented a more noticeable colour change. As for the speed of the recovery process to the initial state, it increased with the addition of EPE and the sol-gel content. Thus, it was proved that the SVA preparation method was more appropriate that the SC, as well as corroborate that the EPE triblock copolymer and the sol-gel content affected the properties of developed CTA nanocomposites. Full article

Owing to their high hardness, fracture toughness and oxidation resistance, tungsten carbide (WC) coatings are extensively deposited on parts that operate in demanding applications, necessitating wear, erosion, and corrosion resistance. The application of thick and hard WC coatings has an inevitable effect on the original dimensions of the parts, affecting the geometrical tolerances and surface roughness. The capability of achieving a sub-micron surface finish and adhere to tight geometrical tolerances accurately and repeatably is an important requirement, particularly with components that operate in high-precision sliding motion. Meeting such requirements through conventional surface finishing methods, however, can be challenging due to the superior mechanical and tribological properties of WC coatings. A brief review into the synthesis techniques of cemented and binderless WC coatings is presented together with a comprehensive review into the available techniques which are used to surface finish WC-based coatings with reference to their fundamental mechanisms and capabilities to process parts with intricate and internal features. The binderless WC/W coating considered in this work is deposited through chemical vapour deposition (CVD) and unlike traditional cemented carbide coatings, it has a homogenous coating structure. This distinctive characteristic has the potential of eliminating key issues commonly encountered with machining and finishing of WC-based coatings. Here, six contact and non-contact surface finishing techniques, include diamond turning, precision grinding, superfinishing, vibratory polishing, electrical discharge machining, and electropolishing are discussed along with their current use in industry and limitations. Key challenges in the field are highlighted and potential directions for future investigation, particularly on binderless WC coatings, are proposed herein. Full article