Search Results (14)

Tyre wear particles (TWPs), generated from tyre-road abrasion, are a pervasive and under-regulated environmental pollutant, accounting for a significant share of global microplastic contamination. Recent estimates indicate that 1.3 million metric tons of TWPs are released annually in Europe, dispersing via atmospheric transport, stormwater runoff, and sedimentation to contaminate air, water, and soil. TWPs are composed of synthetic rubber polymers, reinforcing fillers, and chemical additives, including heavy metals such as zinc (Zn) and copper (Cu) and organic compounds like polycyclic aromatic hydrocarbons (PAHs) and N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine (6PPD). These constituents confer persistence and bioaccumulative potential. While TWP toxicity in aquatic systems is well-documented, its ecological impacts on terrestrial environments, particularly in agricultural soils, remain less understood despite global soil loading rates exceeding 6.1 million metric tons annually. This review synthesizes global research on TWP sources, environmental fate, and ecotoxicological effects, with a focus on soil–plant systems. TWPs have been shown to alter key soil properties, including a 25% reduction in porosity and a 20–35% decrease in organic matter decomposition, disrupt microbial communities (with a 40–60% reduction in nitrogen-fixing bacteria), and induce phytotoxicity through both physical blockage of roots and Zn-induced oxidative stress. Human exposure occurs through inhalation (estimated at 3200 particles per day in urban areas), ingestion, and dermal contact, with epidemiological evidence linking TWPs to increased risks of respiratory, cardiovascular, and developmental disorders. Emerging remediation strategies are critically evaluated across three tiers: (1) source reduction using advanced tyre materials (up to 40% wear reduction in laboratory tests); (2) environmental interception through bioengineered filtration systems (60–80% capture efficiency in pilot trials); and (3) contaminant degradation via novel bioremediation techniques (up to 85% removal in recent studies). Key research gaps remain, including the need for long-term field studies, standardized mitigation protocols, and integrated risk assessments. This review emphasizes the importance of interdisciplinary collaboration in addressing TWP pollution and offers guidance on sustainable solutions to protect ecosystems and public health through science-driven policy recommendations. Full article

Polychlorinated biphenyls (PCBs) are synthetic organic compounds that were widely used in industrial applications throughout the 20th century. Due to their chemical stability, resistance to degradation and ability to bioaccumulate and biomagnify through food chains, PCBs pose long-term environmental and health risks. Due to these characteristics, PCBs have been globally regulated as persistent organic pollutants (POPs), despite being banned from production in most countries decades ago. This study investigates temporal trends in PCB contamination in urban soils of Bucharest over a 20-year period (2002–2022), focusing on six principal congeners (PCB 28, 52, 101, 138, 153, and 180) sampled from 13 locations, including roadsides and urban parks. Gas chromatography and spatial analysis using inverse distance weighting (IDW) revealed a marked reduction in Σ6PCB concentrations, declining from 0.0159 mg/kg in 2002 to 0.0065 mg/kg in 2022, with statistically significant differences confirmed by Kruskal–Wallis analysis (p < 0.05). This decline is primarily attributed to reduced emissions, source control measures, and natural attenuation. However, the persistence of PCBs in localized hotspots is influenced by secondary dispersion mechanisms, such as atmospheric deposition and surface runoff, which redistribute contaminants rather than eliminate them. Health risk assessments via ingestion, dermal absorption, and inhalation routes confirmed negligible carcinogenic risk for both adults and children. Although measurable progress has been achieved, the persistence of localized contamination underscores the need for targeted remediation strategies and sustained environmental monitoring to protect vulnerable urban areas from recontamination. Full article

Water pollution, resulting from industrial effluents, agricultural runoff, and pharmaceutical residues, poses serious threats to ecosystems and human health, highlighting the need for innovative approaches to effective remediation, particularly for non-biodegradable emerging pollutants. This research work explores the influence of shape-controlled nanocrystalline titanium dioxide (TiO₂ NC), synthesized by a simple hydrothermal method, on the photodegradation efficiency of three different classes of emerging environmental pollutants: phenol, pesticides (methomyl), and drugs (sodium diclofenac). Experiments were conducted to assess the influence of the water matrix on treatment efficiency by using ultrapure water and stormwater (basic) collected from an urban drainage system as matrices. The size and shape of the nano-cuboids were accurately controlled during synthesis to assess their impact on photoactivity and selectivity. Regarding total organic carbon removal using TiO₂ nano-cuboids in basic environments, the results were particularly remarkable. TiO₂ nano-cuboids and truncated bipyramids synthesized in the 200–250 °C temperature range showed an enhanced photocatalytic efficiency when compared to alternative formulations. Diclofenac, methomyl, and phenol were fully mineralized from ultrapure water and basic stormwater. The TiO₂ nano-cuboids/nano-bipyramids demonstrated better selectivity and photoactivity in comparison to irregular TiO₂ nanoparticles. The differences in photoactivity and selectivity are explained in terms of charge carrier separation and trapping on the different crystal facets. Their performance demonstrates their potential as sustainable materials for the photodegradation of emerging pollutants in various water matrices. Full article

Heavy metals originating from industrial runoff, agricultural practices, urbanization, and natural geological processes persist in coastal sediments due to their low degradation rates and high stability. Their cycling is influenced by sediment dynamics, water circulation, and complex interactions with biological and chemical factors. Heavy metal pollution demonstrates serious risks to coastal biota, including fish, shellfish, algae, and marine mammals through mechanisms such as bioaccumulation and biomagnification. These processes lead to biodiversity loss, habitat degradation, and reduced ecosystem functionality. Current mitigation strategies for pollution control regulations and remediation techniques show promise but face challenges in implementation. Emerging technologies such as nanotechnology and bioremediation offer innovative solutions but require further validation. Knowledge gaps persist in understanding the long-term ecological impacts of heavy metal contamination and optimizing management strategies for diverse coastal ecosystems. Coastal ecosystems are vital for supporting biodiversity and providing essential ecosystem services, but they are increasingly threatened by heavy metal pollution—a pervasive environmental challenge that demands urgent attention. This review investigates the sources, characteristics, pathways, ecological impacts, and management strategies associated with heavy metal contamination in coastal environments. The review synthesizes findings from recent literature, employing a systematic approach to analyze natural and anthropogenic sources, contamination pathways, and the biogeochemical processes governing heavy metal cycling. Future research should focus on addressing these gaps through interdisciplinary approaches, integrating advanced modeling techniques, stakeholder engagement, and sustainable management practices. By prioritizing these efforts, we can safeguard coastal ecosystems and their essential services from the escalating threats of heavy metal pollution. Full article

Being tidal-sensitive, the river channel in the Longjin Yangqi area of Cangshan, Fuzhou City, is challenged further because of rapid urbanization. Thus, resultant remediation efforts are crucial. This study aims analyzes hydrodynamic characteristics of the area and, secondly, proposes an ecological dispatch solution with evaluation of its effectiveness through the Storm Water Management Model (SWMM). The chief tasks cover imitating rainfall runoff, optimizing sluice gate activities, reorganizing pump management, and reshaping river morphology to bolster flood control and water quality. Improvements were shown through ecological dispatch strategies, which suggested increasing the channel width for the river and deepening the riverbed, thereby increasing the flood duration, lowering water levels, and less frequent flood occurrences. Optimizing sluice gate settings improved efficiency in the regulation of water flow and reduced scour or siltation problems. Various adjustments to pumping operations scattered over various times were based on live-data analysis, therefore enhancing water flow and the self-purification capacity of the water body. The SWMM was directly applied in this tidal river for urban water resource management with data processing from over 100,000 points in simulations. Wherever needed, changes to model parameters were made to improve its capability and enhance its appropriate use in future urban settings. As a whole, this study presents a plan for sustainable water resource management paired with environmental conditions for the benefit of over 500,000 urban residents in the Longjin Yangqi area. Full article

With the rapid development of industrialization and urbanization, the issue of soil environmental pollution is becoming more and more prominent, especially concerning heavy metal contamination, which has garnered significant scholarly attention. The surface watershed formed by waterline is influenced by various factors such as topography, industrial emissions, and agricultural runoff, resulting in a complex process of migration and accumulation of heavy metal elements from multiple sources. In this study, the pollution characteristics and sources of heavy metal elements Hg, As, Pb, Ni, Cd, Cr, Cu and Zn in 165 surface soil samples from the Manghe River watershed in Jiyuan City were comprehensively analyzed using a variety of methods, including statistics, geostatistics, enriched factor analysis and the Positive Matrix Factorization Model (PMF). The results showed that the concentrations of Hg, Cd, As, Cu, Pb and Zn exceeded their corresponding background values with varying degrees of enrichment. Notably, the average contents of Cd, Hg and Pb were 26.70 times, 3.69 times and 4.49 times higher than those in Chinese soils on average, respectively, showing obvious enrichment characteristics. Moreover, there were distinct spatial distribution patterns for each heavy metal element; Ni and Cr exhibited similar trends mainly controlled by the parent material, while human activities significantly affect the other six elements forming high-value areas around mining and related industries. It is noteworthy that Cu, Hg and Zn were influenced by dominant wind direction in autumn and winter, forming sub-high-value zones in southern forested areas; meanwhile, Cu and Zn were also influenced by agricultural fertilizer application as well as surface runoff, leading to secondary high-value areas in the dryland areas. Further analysis revealed a significant positive correlation among these heavy metal elements, suggesting that they may share common sources. Through the PMF Model, four main factors were identified, with factor 2 (36.25%), factor 1 (23.00%), factor 3 (21.20%) and factor 4 (19.55%) ranked in descending order of contribution rate. The heavy metal pollution in the study area was attributed to anthropogenic activities and natural factors, accounting for 63.75% and 36.25%, respectively. Coal mining, chemical industry smelting, vehicle emissions and excessive use of agrochemicals were identified as the main sources of heavy metal pollution. These pollutants entered the soil through direct emissions, atmospheric deposition, transportation and agricultural activities, exerting a significant impact on the soil environment. Therefore, delving into the spatial distribution pattern of soil heavy metal pollution and precise analysis of its sources are of great importance for effective treatment and remediation of soil heavy metal pollution in small watersheds, maintaining healthy soil ecology and safeguarding human health. Full article

The intensification of anthropogenic activities (agriculture, industry, and exploitation of water resources) during urbanization has posed significant challenges to the aquatic environment, particularly in karst regions. Karst aquifers are highly susceptible to surface contaminants and exhibit minimal natural remediation capabilities. Our understanding of the anthropogenic activities involved in these sensitive karst systems remains limited. To address this gap, we conducted a comprehensive study, collecting 285 groundwater samples in Feicheng, northern China, from 1996 to 2015. The overexploitation of karst groundwater has resulted in several concerns. The whole dataset was classified into four groups according to land use. Water quality assessments revealed a yearly decline, particularly in industrial and agricultural areas. The water chemistry transitioned from Ca-Mg-HCO₃ to Ca-Mg-HCO₃-SO₄. Such evolution was attributed to natural hydrogeochemical processes, atmospheric precipitation, and anthropogenic inputs. Natural factors included water-rock interactions (the mineral dissolution) and ion exchange. Absolute principal component scores with multiple linear regression (APCS-MLR) were used to quantitatively estimate the sources of pollution. The results showed that hydrogeological settings (recharge, runoff, and discharge) were crucial in the hydrochemistry evolution of karst groundwater systems. In agricultural areas, it is recognized that much of the NO₃⁻ accumulation in aquifers came from upstream inputs in the groundwater system, not just irrigation and fertilization. Urban areas were affected by Cl⁻ pollution, primarily due to domestic waste. Industrial regions of recharge zones were more susceptible to atmospheric precipitation and industrial waste, with pollutants infiltrating through rainfall and degrading water quality. Mining areas exhibit higher SO₄²⁻ and lower pH due to the oxidation of sulfur-containing minerals. Therefore, the rapid response and low self-purification capacity of groundwater in karst regions necessitate caution in urban planning to mitigate impacts on these fragile systems. Full article

Even though the common acknowledgment that vacant urban lands (VUL) can play a positive role in improving stormwater management, little synthesized literature is focused on understanding how VUL can take advantage of different stormwater control measures (SCMs) to advance urban water quality. The project aims to provide urban planners with information on the remediation of vacant lands using urban runoff pollutant removal techniques. To find the most effective removal method, relevant scholarly papers and case studies are reviewed to see what types of vacant land have many urban runoff pollutants and how to effectively remove contaminants from stormwater runoff in the city by SCMs. The results show that previously developed/used land (but now vacant) has been identified as contaminated sites, including prior residential, commercial, industrial, and parking lot land use from urban areas. SCMs are effective management approaches to reduce nonpoint source pollution problems runoff. It is an umbrella concept that can be used to capture nature-based, cost-effective, and eco-friendly treatment technologies and redevelopment strategies that are socially inclusive, economically viable, and with good public acceptance. Among these removal techniques, a bioretention system tends to be effective for removing dissolved and particulate components of heavy metals and phosphorus. Using different plant species and increasing filter media depth has identified the effectiveness of eliminating nitrate nitrogen (NO₃-N). A medium with a high hydraulic conductivity covers an existing medium with low hydraulic conductivity, and the result will be a higher and more effective decrease for phosphorus (P) pollutants. In addition, wet ponds were found to be highly effective at removing polycyclic aromatic hydrocarbons, with removal rates as high as 99%. For the removal of perfluoroalkyl acid (PFAA) pollutants, despite the implementation of SCMs in urban areas to remove PFAAs and particulate-related contaminants in stormwater runoff, the current literature has little information on SCMs’ removal of PFAAs. Studies have also found that VUL’s size, shape, and connectivity are significantly inversely correlated with the reduction in stormwater runoff. This paper will help planners and landscape designers make efficient decisions around removing pollutants from VUL stormwater runoff, leading to better use of these spaces. Full article

An in-depth study of the temporal and spatial distribution of pollution loads can assist in the development of water pollution remediation. The research scope of this paper was the highly developed Wuhu City located south of the Yangtze River. Chemical oxygen demand (COD), NH₃-H, and total phosphorus (TP) were chosen as the pollutant research objects of this study. Then, by combining the natural and social conditions within the scope of the study, a balanced system of pollution load generation and migration was described. A pollution load model of Wuhu City based on Load Calculator, MIKE 11, and ArcGIS was established. The results indicate that, in terms of the time distribution, the changes in the influx of the different pollutants were consistent. In terms of the spatial distribution, the major contributions to the annual pollution load were domestic pollution, urban surface runoff pollution, and poultry breeding pollution. The major contributors to the annual pollution load into the river were domestic pollution, urban surface runoff pollution, and sewage plant tail water pollution. This analysis provides references for the comprehensive management of local water environments. Full article

The sediment pollution index acts as a useful indicator for assessing anthropogenic pollution within river drainage basins. An industrialized urban river, Fengshan River in Kaohsiung City, southern Taiwan has been suffering heavy metal pollution from surrounding factories. In this study, spatial and seasonal variations in heavy metals in sediments from seven sampling sites of Fengshan River were determined to assess sediment pollution status and potential ecological risk using multiple sediment pollution indices. Results showed that the heavy metal concentrations displayed large spatial variations. Severe contamination of heavy metals, especially for Cr, Hg, and Zn in the lower reaches of Fengshan River, may attribute to wastewater discharges from leather processing and metal finishing factories along the river drainage basin. An increase in metal concentrations from upstream to downstream indicated that heavy metals tend to accumulate in tidal reaches, probably as a result of the flocculation effect. Frequent heavy rainfall in the wet season can enhance surface runoff to discharge metal pollutants from non-point sources (scattered factories) into the river. Assessment of multiple pollution indices showed moderately polluted (mCd = 3.9, PLI = 2.6) and considerable ecological risk (RI = 540, mERM_Q = 0.55), indicating Fengshan River sediments, particularly in the lower reaches, are considered toxic and can cause adverse effects to benthic organisms. Organic matters showed a good correlation with heavy metals, which play an important role in the spatiotemporal variations in heavy metal pollutants in the Fengshan River sediments. This study can provide valuable information for river pollution remediation, and urban planning and management. Full article

Stormwater runoff management is challenging in a highly urbanised tropical environment due to the unique space constraints and tropical climate conditions. A modular bioretention tree (MBT) with a small footprint and a reduced on-site installation time was explored for application in a tropical environment. Tree species used in the pilot studies were Talipariti tiliaceum (TT1) and Sterculia macrophylla (TT2). Both of the MBTs could effectively remove total suspended solids (TSS), total phosphorus (TP), zinc, copper, cadmium, and lead with removal efficiencies of greater than 90%. Total nitrogen (TN) removal was noted to be significantly higher in the wet period compared to the dry period (p < 0.05). Variation in TN removal between TT1 and TT2 were attributed to the nitrogen uptake and the root formation of the trees species. A field study MBT using Talipariti tiliaceum had a very clean effluent quality, with average TSS, TP, and TN effluent EMC of 4.8 mg/L, 0.04 mg/L, and 0.27 mg/L, respectively. Key environmental factors were also investigated to study their impact on the performance of BMT. It was found that the initial pollutant concentration, the dissolved fraction of influent pollutants, and soil moisture affect the performance of the MBT. Based on the results from this study, the MBT demonstrates good capability in the improvement of stormwater runoff quality. Full article

Poor soil health is a critical problem in many urban landscapes. Degraded soil restricts plant growth and microorganism activity, limiting the ability of urban landscapes to perform much needed ecosystem services. Incorporation of approximately 33% compost by volume into degraded soil has been proven to improve soil health and structure over time while avoiding the financial and environmental costs of importing soil mixes from elsewhere. However, additions of high volumes of compost could potentially increase the risk of nutrient loss through leaching and runoff. The objective of our study was to consider the effects of different compost amendments on soil health, plant health and susceptibility to nutrient leaching in order to identify ranges of acceptable compost characteristics that could be used for soil remediation in the urban landscape. A bioassay was conducted with Phaseolus vulgaris (Bush Bean) to measure the effect of nine composts from different feedstocks on various plant health parameters. Leachate was collected prior to planting to measure nutrient loss from each treatment. All compost amendments were found to improve soil health. Nutrient-rich, manure-based composts produced the greatest plant growth, but also leached high concentrations of nitrate and phosphorus. Some treatments provided sufficient nutrients for plant growth without excess nutrient loss. When incorporating as much as 33% compost by volume into a landscape bed, the optimal compost will generally have a C:N ratio of 10–20, P-content <1.0% and a soluble salt content between 1.0 and 3.5 mmhos/cm. These recommendations should ensure optimal plant and soil health and minimize nutrient leaching. Full article

Constructed wetlands (CWs) are used to remediate runoff from a variety of agricultural, industrial, and urban sources. CW remediation performance is often evaluated at the laboratory scale over durations less than one year. The purpose of this study was to characterize the effect of CW design (cell depth) and residence time on nitrogen (N) speciation and fate across season and years in two free water surface wetlands receiving runoff from irrigated plant production areas at an ornamental plant nursery. Water quality (mg·L⁻¹ of nitrate, nitrite, and ammonium, dissolved oxygen and oxidation reduction potential) was monitored at five sites within each of two CWs each month over four years. Nitrate-N was the dominant form of ionic N present in both CWs. Within CW1, a deep cell to shallow cell design, nitrate comprised 86% of ionic N in effluent. Within CW2, designed with three sequential deep cells, nitrate comprised only 66% of total N and ammonium comprised 27% of total N in CW2 effluent. Differences in ionic N removal efficacies and shifts in N speciation in CW1 and CW2 were controlled by constructed wetland design (depth and hydraulic retention time), the concentration of nutrients entering the CW, and plant species richness. Full article

A three-step method for the identification of the main sources of fecal coliforms (FC) in urban waters and for the analysis of remedial actions is proposed. The method is based on (1) The statistical analysis of the relationship between rainfall and FC concentrations in urban rivers; (2) The simulation of hydrology and hydraulics; and (3) Scenario analysis. The proposed method was applied to the Beauport River watershed, in Canada, covering an area of 28.7 km². FC loads and concentrations in the river, during and following rainfall events, were computed using the Storm Water Management Model (SWMM) hydrological/hydraulic simulation model combined with event mean concentrations. It was found that combined sewer overflows (CSOs) are the main FC sources, and that FC from stormwater runoff could still impair recreational activities in the Beauport River even if retention tanks were built to contain CSOs. Thus, intervention measures should be applied in order to reduce the concentration of FC in stormwater outfalls. The proposed method could be applied to water quality components other than FC, provided that they are present in stormwater runoff and/or CSOs, and that the time of concentration of the watershed is significantly lower than their persistence in urban waters. Full article