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Keywords = upscaled experimental study

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43 pages, 12675 KB  
Article
Intelligent Water Quality Assessment and Prediction System for Public Networks: A Comparative Analysis of ML Algorithms and Rule-Based Recommender Techniques
by Camelia Paliuc, Paul Banu-Taran, Sebastian-Ioan Petruc, Razvan Bogdan and Mircea Popa
Sensors 2026, 26(4), 1392; https://doi.org/10.3390/s26041392 - 23 Feb 2026
Viewed by 329
Abstract
An assessment and prediction system for the quality of public water networks was developed, using Timișoara, Romania, as a case study. This was implemented on a Google Firebase cloud storage system and comprised twelve ML algorithms applied to test samples for drinkability and [...] Read more.
An assessment and prediction system for the quality of public water networks was developed, using Timișoara, Romania, as a case study. This was implemented on a Google Firebase cloud storage system and comprised twelve ML algorithms applied to test samples for drinkability and used in predictions of upcoming samples. The system compares 17 water quality parameters to the World Health Organization and public reports of Timișoara drinking water standards for 804 samples. The system provides real-time data storage, drinkability prediction for the reservoir water system, and rule-based critical water recommendations for elementary treatment in samples. The most accurate and best-calibrated against random forest, gradient boosting, and Logistic Regression algorithms was the decision tree algorithm of the ML models. The experimental findings also determine the regions of the worst and best water quality and propose respective treatment. In contrast to previous research and structures, the paper demonstrates an approved stable solution for smart water monitoring, correlating practical deployment with sophisticated data-based conclusions. The results contribute to enhancing public health, enhancing water management measures, and upscaling the system for larger-scale applications. Full article
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24 pages, 5058 KB  
Article
Influence of Rainfall on Urban Non-Point Source Pollution in Rivers from an Event-Based Perspective in Taihu Basin
by Ye Pan, Qiqi Yuan, Jiaxun Guo, Haigang Jia and Lachun Wang
Environments 2026, 13(2), 104; https://doi.org/10.3390/environments13020104 - 13 Feb 2026
Viewed by 412
Abstract
Urban point source pollution has been effectively controlled in recent years; however, rainfall-driven non-point source (NPS) pollution has become a major contributor to the deterioration of urban water environments. This study focuses on the plain river network region of Wuxi City in the [...] Read more.
Urban point source pollution has been effectively controlled in recent years; however, rainfall-driven non-point source (NPS) pollution has become a major contributor to the deterioration of urban water environments. This study focuses on the plain river network region of Wuxi City in the Taihu Basin, China. By integrating field monitoring with coupled model simulations, this study upscaled results from the experimental plot to the urban-scale river network, enabling analysis of the full processes of pollutant inflow and transport and evaluation of the role of rainfall in regulating these dynamics. Field monitoring in the experimental plot demonstrated a strong correlation between the temporal dynamics of NPS pollutant inflows and rainfall characteristics. Further analysis using model simulations in the river network area revealed that rainfall, maximum 1 h rainfall, and rainfall duration were identified as the primary drivers of pollutant inflows, while early drought duration, rainfall intensity, and variance between rainfall per unit time exerted non-linear effects. Specifically, when early drought duration was approximately 6–7 days or when rainfall intensity ranged from 2.1 to 2.6 mm/h, riverine nitrogen (N) and phosphorus (P) concentrations and pollutant loadings reached their peaks. In addition, when the deviation of unit-time rainfall from the event mean was between 1.8 and 2 mm, the duration of increase in pollutants entering the river was the longest. This study provides quantitative evidence highlighting the influence of rainfall characteristics on nitrogen and phosphorus dynamics in plain river network urban rivers. The findings offer valuable insights into the remediation of urban black-odor water bodies. Full article
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21 pages, 4347 KB  
Article
Microwave-Assisted Bio-Based Chemical Recycling of Fiber-Reinforced Composites from Construction and Demolition Waste
by Gonzalo Murillo-Ciordia and Cecilia Chaine
Polymers 2026, 18(3), 362; https://doi.org/10.3390/polym18030362 - 29 Jan 2026
Viewed by 570
Abstract
Fiber-reinforced polymer composites (FRPCs) are increasingly used in construction due to their high performance and low environmental footprint. However, their widespread adoption has raised concerns over end-of-life management, particularly under European regulations mandating high recycling rates for construction and demolition waste (CDW). This [...] Read more.
Fiber-reinforced polymer composites (FRPCs) are increasingly used in construction due to their high performance and low environmental footprint. However, their widespread adoption has raised concerns over end-of-life management, particularly under European regulations mandating high recycling rates for construction and demolition waste (CDW). This study evaluates different systems for the chemical recycling of FRPCs through microwave (MW)-assisted solvolysis using green solvents, including deep eutectic solvents (DESs) and biobased acetic acid. The process targets thermoset resin depolymerization while preserving fiber integrity, operating at reduced temperatures (≤230 °C) and lower energy demand than conventional techniques, such as pyrolysis. A systematic experimental design was applied to CDW-derived polyester composites and extended to industrial epoxy and vinyl ester composites. Among the tested solvents, glacial acetic acid + ZnCl2 (5 wt.%), achieved the highest degradation efficiency, exceeding 94% in small-scale trials and maintaining over 78% upon upscaling. Recovered fibers showed moderate property retention, with tensile strength and elongation losses of ~30% and ~45% for infusion-based epoxy composites, while those from pultrusion-based epoxy composites exhibited 16–19% and retained similar properties to the virgin material, respectively. The method facilitates fiber recovery with limited degradation and aligns with circular economy principles through solvent reuse and minimizing environmental impact. Full article
(This article belongs to the Special Issue Chemical Recycling of Polymers, 2nd Edition)
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25 pages, 8350 KB  
Article
A Meso-Scale Modeling Framework Using the Discrete Element Method (DEM) for Uniaxial and Flexural Response of Ultra-High Performance Concrete (UHPC)
by Pu Yang, Aashay Arora, Christian G. Hoover, Barzin Mobasher and Narayanan Neithalath
Appl. Sci. 2026, 16(3), 1230; https://doi.org/10.3390/app16031230 - 25 Jan 2026
Viewed by 257
Abstract
This study addresses a key limitation in meso-scale discrete element modeling (DEM) of ultra-high performance concrete (UHPC). Most existing DEM frameworks rely on extensive macroscopic calibration and do not provide a clear, transferable pathway to derive contact law parameters from measurable micro-scale properties, [...] Read more.
This study addresses a key limitation in meso-scale discrete element modeling (DEM) of ultra-high performance concrete (UHPC). Most existing DEM frameworks rely on extensive macroscopic calibration and do not provide a clear, transferable pathway to derive contact law parameters from measurable micro-scale properties, limiting reproducibility and physical interpretability. To bridge this gap, we develop and validate a micro-indentation-informed, poromechanics-consistent calibration framework that links UHPC phase-level micromechanical measurements to a flat-joint DEM contact model for predicting uniaxial compression, direct tension, and flexural response. Elastic moduli and Poisson’s ratios of the constituent phases are obtained from micro-indentation and homogenization relations, while cohesion (c) and friction angle (α) are inferred through a statistical treatment of the indentation modulus and hardness distributions. The tensile strength limit (σₜ) is identified by matching the simulated flexural stress–strain peak and post-peak trends using a parametric set of (c, α, σₜ) combinations. The resulting DEM model reproduces the measured UHPC responses with strong agreement, capturing (i) compressive stress–strain response, (ii) flexural stress–strain response, and (iii) tensile stress–strain response, while also recovering the experimentally observed failure modes and damage localization patterns. These results demonstrate that physically grounded micro-scale measurements can be systematically upscaled to meso-scale DEM parameters, providing a more efficient and interpretable route for simulating UHPC and other porous cementitious composites from indentation-based inputs. Full article
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13 pages, 4480 KB  
Article
Optimization of Fracture Parameters and Turning Angle of Temporary Plugging Refracturing in the Triassic Chang 6 Reservoir
by Zengli Xiao, Ziang Zhu, Yifan Cao and Hao Tan
Processes 2025, 13(12), 3805; https://doi.org/10.3390/pr13123805 - 25 Nov 2025
Viewed by 310
Abstract
The Triassic Chang 6 reservoir in the Suijing Oilfield is characterized by poor reservoir quality, pronounced heterogeneity, well-developed fractures, and suboptimal well pattern configuration, which collectively impede the establishment of an efficient displacement system. During the initial development phase, low production rates and [...] Read more.
The Triassic Chang 6 reservoir in the Suijing Oilfield is characterized by poor reservoir quality, pronounced heterogeneity, well-developed fractures, and suboptimal well pattern configuration, which collectively impede the establishment of an efficient displacement system. During the initial development phase, low production rates and delayed lateral response were observed, prompting a tight-spacing infill drilling pilot in the central low-productivity zone. However, conventional fracturing with upscaled stimulation volumes yielded limited fluid production uplift, rapid water cut escalation, and marginal incremental oil recovery. To address these challenges, a dual strategy integrating legacy fracture modification and new fracture generation was developed. Key fracturing parameters influencing reservoir drainage efficiency were systematically investigated, and an orthogonal experimental design was employed to optimize these parameters. The following conclusions were drawn: Stimulation timing should be postponed until water cut stabilizes below 20% in high-productivity zones; the optimal fracture half-length was determined to be 190 m; post-fracturing conductivity was optimized to 30 μm2·cm; and the turning angle for corner wells was set at 23°. For low-productivity zones with impaired reservoir properties that lead to retarded waterfront advancement, refracturing is recommended to be deferred until the water cut reaches 20–40%. The findings of this study provide a theoretical foundation for optimizing on-site refracturing processes and offer valuable guidance for addressing the optimization of fracturing parameters in low-permeability tight sandstone reservoirs. Full article
(This article belongs to the Section Chemical Processes and Systems)
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20 pages, 2261 KB  
Article
Stress-Based Optimization of Components and Supports for Sinter-Based Additive Manufacturing
by David Stachg, Jaco Beckmann and Jens Telgkamp
Appl. Sci. 2025, 15(22), 12198; https://doi.org/10.3390/app152212198 - 17 Nov 2025
Viewed by 723
Abstract
Sinter-based additive manufacturing (SBAM) processes, such as Cold Metal Fusion (CMF), combine the geometric freedom of additive manufacturing with the scalability of powder metallurgy, but part distortion and collapse during debinding and sintering remain critical design challenges. This study presents a revised stress-based [...] Read more.
Sinter-based additive manufacturing (SBAM) processes, such as Cold Metal Fusion (CMF), combine the geometric freedom of additive manufacturing with the scalability of powder metallurgy, but part distortion and collapse during debinding and sintering remain critical design challenges. This study presents a revised stress-based optimization framework to address these issues by integrating sintering-specific load cases into topology optimization. In contrast to earlier approaches, the revised workflow applies all load cases to the upscaled green-part geometry. This adjustment mitigates the non-linear scaling effects of dead load-induced stresses. A Case study, including a steering bracket for a Formula Student racing car, demonstrates that the revised method improves not only sinterability but also application-related performance compared to earlier approaches. In addition, a semi-automated procedure for generating sinter supports is introduced, allowing stable processing of geometries without planar bearing surfaces. Experimental validation confirms that optimized supports effectively prevent part failure during post-processing, though challenges remain in separating complex freeform geometries. Finally, the influence of stiffness on sintering-induced deformations is investigated, showing that higher stiffness configurations significantly reduce dimensional errors. Together, these results highlight stress- and stiffness-based optimization as tools to enhance the reliability, efficiency, and design freedom of SBAM. Full article
(This article belongs to the Section Additive Manufacturing Technologies)
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19 pages, 3240 KB  
Article
AI-Based Downscaling of MODIS LST Using SRDA-Net Model for High-Resolution Data Generation
by Hongxia Ma, Kebiao Mao, Zijin Yuan, Longhao Xu, Jiancheng Shi, Zhonghua Guo and Zhihao Qin
Remote Sens. 2025, 17(21), 3510; https://doi.org/10.3390/rs17213510 - 22 Oct 2025
Viewed by 790
Abstract
Land surface temperature (LST) is a critical parameter in agricultural drought monitoring, crop growth analysis, and climate change research. However, the challenge of acquiring high-resolution LST data with both fine spatial and temporal scales remains a significant obstacle in remote sensing applications. Despite [...] Read more.
Land surface temperature (LST) is a critical parameter in agricultural drought monitoring, crop growth analysis, and climate change research. However, the challenge of acquiring high-resolution LST data with both fine spatial and temporal scales remains a significant obstacle in remote sensing applications. Despite the high temporal resolution afforded by daily MODIS LST observations, the coarse (1 km) spatial scale of these data restricts their applicability for studies demanding finer spatial resolution. To address this challenge, a novel deep learning-based approach is proposed for LST downscaling: the spatial resolution downscaling attention network (SRDA-Net). The model is designed to upscale the resolution of MODIS LST from 1000 m to 250 m, overcoming the shortcomings of traditional interpolation techniques in reconstructing spatial details, as well as reducing the reliance on linear models and multi-source high-temporal LST data typical of conventional fusion approaches. SRDA-Net captures the feature interaction between MODIS LST and auxiliary data through global resolution attention to address spatial heterogeneity. It further enhances the feature representation ability under heterogeneous surface conditions by optimizing multi-source features to handle heterogeneous data. Additionally, it strengthens the model of spatial dependency relationships through a multi-level feature refinement module. Moreover, this study constructs a composite loss function system that integrates physical mechanisms and data characteristics, ensuring the improvement of reconstruction details while maintaining numerical accuracy and model interpret-ability through a triple collaborative constraint mechanism. Experimental results show that the proposed model performs excellently in the simulation experiment (from 2000 m to 1000 m), with an MAE of 0.928 K and an R2 of 0.95. In farmland areas, the model performs particularly well (MAE = 0.615 K, R2 = 0.96, RMSE = 0.823 K), effectively supporting irrigation scheduling and crop health monitoring. It also maintains good vegetation heterogeneity expression ability in grassland areas, making it suitable for drought monitoring tasks. In the target downscaling experiment (from 1000 m to 500 m and 250 m), the model achieved an RMSE of 1.804 K, an MAE of 1.587 K, and an R2 of 0.915, confirming its stable generalization ability across multiple scales. This study supports agricultural drought warning and precise irrigation and provides data support for interdisciplinary applications such as climate change research and ecological monitoring, while offering a new approach to generating high spatio-temporal resolution LST. Full article
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25 pages, 11642 KB  
Article
Non-Invasive Estimation of Crop Water Stress Index and Irrigation Management with Upscaling from Field to Regional Level Using Remote Sensing and Agrometeorological Data
by Emmanouil Psomiadis, Panos I. Philippopoulos and George Kakaletris
Remote Sens. 2025, 17(14), 2522; https://doi.org/10.3390/rs17142522 - 20 Jul 2025
Cited by 1 | Viewed by 3177
Abstract
Precision irrigation plays a crucial role in managing crop production in a sustainable and environmentally friendly manner. This study builds on the results of the GreenWaterDrone project, aiming to estimate, in real time, the actual water requirements of crop fields using the crop [...] Read more.
Precision irrigation plays a crucial role in managing crop production in a sustainable and environmentally friendly manner. This study builds on the results of the GreenWaterDrone project, aiming to estimate, in real time, the actual water requirements of crop fields using the crop water stress index, integrating infrared canopy temperature, air temperature, relative humidity, and thermal and near-infrared imagery. To achieve this, a state-of-the-art aerial micrometeorological station (AMMS), equipped with an infrared thermal sensor, temperature–humidity sensor, and advanced multispectral and thermal cameras is mounted on an unmanned aerial system (UAS), thus minimizing crop field intervention and permanently installed equipment maintenance. Additionally, data from satellite systems and ground micrometeorological stations (GMMS) are integrated to enhance and upscale system results from the local field to the regional level. The research was conducted over two years of pilot testing in the municipality of Trifilia (Peloponnese, Greece) on pilot potato and watermelon crops, which are primary cultivations in the region. Results revealed that empirical irrigation applied to the rhizosphere significantly exceeded crop water needs, with over-irrigation exceeding by 390% the maximum requirement in the case of potato. Furthermore, correlations between high-resolution remote and proximal sensors were strong, while associations with coarser Landsat 8 satellite data, to upscale the local pilot field experimental results, were moderate. By applying a comprehensive model for upscaling pilot field results, to the overall Trifilia region, project findings proved adequate for supporting sustainable irrigation planning through simulation scenarios. The results of this study, in the context of the overall services introduced by the project, provide valuable insights for farmers, agricultural scientists, and local/regional authorities and stakeholders, facilitating improved regional water management and sustainable agricultural policies. Full article
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22 pages, 11772 KB  
Article
Effect of Slide Valve Gap Surface Roughness on Particle Transport Properties
by Jin Zhang, Ranheng Du, Pengpeng Dong, Kuohang Zhang, Shengrong Wang, Ying Li and Kuo Zhang
Aerospace 2025, 12(7), 608; https://doi.org/10.3390/aerospace12070608 - 5 Jul 2025
Cited by 1 | Viewed by 654
Abstract
Fuel electro-hydraulic servo valves are core components in the fuel control system of aero-engines, and their performance directly affects thrust regulation and power output precision. Due to the combustibility of the working medium in fuel systems and the lack of effective circulation filtration, [...] Read more.
Fuel electro-hydraulic servo valves are core components in the fuel control system of aero-engines, and their performance directly affects thrust regulation and power output precision. Due to the combustibility of the working medium in fuel systems and the lack of effective circulation filtration, the retention of micron-sized particles within the valve gap can lead to valve spool jamming, which is a critical reliability issue. This study, based on fractal theory and the liquid–solid two-phase flow model, proposes a parametric model for non-ideal surface valve gaps and analyzes the dynamics of particles subjected to drag, lift, and buoyant forces on rough surfaces. By numerically analyzing flow field models with different roughness levels and comparing them with an ideal smooth gap model, the migration characteristics of particles were studied. To verify the accuracy of the model, an upscaled experimental setup was built based on similarity theory, and PIV experiments were conducted for validation. Experimental results show that the particle release position and valve surface roughness significantly affect particle migration time. The weight of the release position on particle migration time is 63%, while the impact of valve surface roughness is 37%. In models with different roughness levels, the particle migration time increases more rapidly for roughness values greater than Ra0.4, while for values less than Ra0.4, the increase in migration time is slower. Furthermore, the study reveals that particle migration trajectories are independent of flow velocity, with velocity only affecting particle migration time. This research provides theoretical support for enhancing the reliability of fuel electro-hydraulic servo valves and offers a new perspective for the design of highly reliable hydraulic components. Full article
(This article belongs to the Section Aeronautics)
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20 pages, 3339 KB  
Article
Experimental Dielectric Properties and Temperature Measurement Analysis to Assess the Thermal Distribution of a Multimode Microwave-Assisted Susceptor Fixed-Bed Reactor
by Alejandro Fresneda-Cruz, Gonzalo Murillo-Ciordia and Ignacio Julian
Processes 2025, 13(3), 774; https://doi.org/10.3390/pr13030774 - 7 Mar 2025
Cited by 2 | Viewed by 2053
Abstract
In this study, the integration of microwave-assisted technology into fixed-bed configuration processes is explored aiming to characterize and address its challenges with a customized multimodal microwave cavity. This research focuses on evaluating the uncertainty in contactless temperature measurement methods as spectral thermographic cameras [...] Read more.
In this study, the integration of microwave-assisted technology into fixed-bed configuration processes is explored aiming to characterize and address its challenges with a customized multimodal microwave cavity. This research focuses on evaluating the uncertainty in contactless temperature measurement methods as spectral thermographic cameras and infrared pyrometers, microwave heating performance, and the thermal homogeneity within fixed beds containing microwave–susceptor materials, including the temperature-dependent dielectric characterization of such materials, having different geometry and size (from 120 to 5000 microns). The thermal inhomogeneities along different bed configurations were quantified, assessing the most appropriate fixed-bed arrangement and size limitation at the employed irradiation frequency (2.45 GHz) to tackle microwave-assisted gas–solid chemical conversions. An increased temperature heterogeneity along the axial profile was found for finer susceptor particles, while the higher microwave susceptibility of coarser grades led to increased temperature gradients, ΔT > 300 °C. Moreover, results evidenced that the temperature measurement on the fixed-bed quartz reactor surface by a punctual infrared pyrometer entails a major error regarding the real temperature on the microwave susceptor surface within the tubular quartz reactor (up to 230% deviation). The experimental findings pave the way to assess the characteristics that microwave susceptors and fixed beds must perform to minimize thermal inhomogeneities and optimize the microwave-assisted coupling with solid–gas-phase reactor design and process upscaling using such multimode cavities. Full article
(This article belongs to the Special Issue Heat and Mass Transfer Phenomena in Energy Systems)
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14 pages, 3330 KB  
Article
Scaling Torsional Drilling Vibrations: A Simulation-Based Comparison of Downscale and Upscale Drill Strings Under Varying Torque Conditions
by Chinedu Ejike, Khizar Abid and Catalin Teodoriu
Appl. Sci. 2025, 15(5), 2399; https://doi.org/10.3390/app15052399 - 24 Feb 2025
Cited by 4 | Viewed by 1943
Abstract
Torsional vibrations pose a serious challenge in drilling operations and can lead to effects such as stick-slip phenomena, tool wear, and reduced drilling efficiency. While previous research has been conducted on torsional vibrations, there is a notable gap in comparative studies that assess [...] Read more.
Torsional vibrations pose a serious challenge in drilling operations and can lead to effects such as stick-slip phenomena, tool wear, and reduced drilling efficiency. While previous research has been conducted on torsional vibrations, there is a notable gap in comparative studies that assess the scalability of downscale models to real-world drilling conditions. This study fills this gap by systematically comparing torsional vibrations in downscale and upscale drill strings under different torque conditions at three different depths, shedding light on scaling effects in drilling vibrations. Numerical simulation was carried out taking into account non-linear interactions, damping effects, and torque variations. The laboratory set-up was for a well length of 15 m and was geometrically scaled to represent an upscale well of 450 m. Certain operational parameters such as rotation speed, torque, density, and friction coefficients were modified to keep realistic dynamic behavior, and all models were run at an identical speed of rotation to enforce consistency. The results show that both the upscale and downscale models exhibited stick-slip behavior, but differences in vibration intensity and stabilization trends point out how scaling affects torsional dynamics. Notably, the upscale bit first faced higher torsional oscillation than the set rotation speed after overcoming stick-slip before stabilizing, whereas the downscale bit went through prolonged stick-slip instability before synchronization. This study enhances the understanding of scaling effects in torsional drilling vibrations, offering a foundation for optimizing experimental setups and improving predictive modeling in drilling operations. Full article
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20 pages, 7061 KB  
Article
Research on High-Resolution Modeling of Satellite-Derived Marine Environmental Parameters Based on Adaptive Global Attention
by Ruochu Cui, Liwen Ma, Yaning Hu, Jiaji Wu and Haiying Li
Remote Sens. 2025, 17(4), 709; https://doi.org/10.3390/rs17040709 - 19 Feb 2025
Cited by 4 | Viewed by 1419
Abstract
The analysis of marine environmental parameters plays an important role in areas such as sea surface simulation modeling, analysis of sea clutter characteristics, and environmental monitoring. However, ocean observation remote sensing satellites typically deliver large volumes of data with limited spatial resolution, which [...] Read more.
The analysis of marine environmental parameters plays an important role in areas such as sea surface simulation modeling, analysis of sea clutter characteristics, and environmental monitoring. However, ocean observation remote sensing satellites typically deliver large volumes of data with limited spatial resolution, which often does not meet the precision requirements of practical applications. To overcome challenges in constructing high-resolution marine environmental parameters, this study conducts a systematic comparison of various interpolation techniques and deep learning models, aiming to develop a highly effective and efficient model optimized for enhancing the resolution of marine applications. Specifically, we incorporated adaptive global attention (AGA) mechanisms and a spatial gating unit (SGU) into the model. The AGA mechanism dynamically adjusts the weights of different regions in feature maps, enabling the model to focus more on critical spatial features and channel features. The SGU optimizes the utilization of spatial information by controlling the information transmission pathways. The experimental results indicate that for four types of marine environmental parameters from ERA5, our model achieves an overall PSNR of 44.0705, an SSIM of 0.9947, and an MAE of 0.2606 when the resolution is increased by a upscale factor of 2, as well as an overall PSNR of 35.5215, an SSIM of 0.9732, and an MAE of 0.8330 when the resolution is increased by an upscale factor of 4. These experiments demonstrate the model’s effectiveness in enhancing the spatial resolution of satellite-derived marine environmental parameters and its ability to be applied to any marine region, providing data support for many subsequent oceanic studies. Full article
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20 pages, 7939 KB  
Article
Plastic Devolatilisation Kinetics During Isothermal High-Temperature Pyrolysis: Focus on Solid Products (Part I)
by Ieva Kiminaitė, Sebastian Wilhelm, Lukas Martetschläger, Clara Leonie Brigitte Eckert, Marcos Berenguer Casco, Nerijus Striūgas and Sebastian Fendt
Polymers 2025, 17(4), 525; https://doi.org/10.3390/polym17040525 - 18 Feb 2025
Cited by 3 | Viewed by 2936
Abstract
Incineration remains Europe’s main practice for plastic packaging waste treatment, primarily due to the limitations of mechanical recycling technology. Consequently, research and development of more sustainable and flexible approaches are of high importance. Thermochemical conversion of polypropylene, polystyrene, and municipal plastic packaging mix [...] Read more.
Incineration remains Europe’s main practice for plastic packaging waste treatment, primarily due to the limitations of mechanical recycling technology. Consequently, research and development of more sustainable and flexible approaches are of high importance. Thermochemical conversion of polypropylene, polystyrene, and municipal plastic packaging mix via high-temperature flash pyrolysis (1000 °C/s) is studied in this research, focusing on the kinetics and yields of the devolatilisation stage. The primary stage results in the formation of volatile organic compounds considered intermediate products for carbon black production. The experiments were conducted in a pressurised wire mesh reactor, investigating the influence of temperature (600–1200 °C), residence time (0.5–10 s), and pressure (1–25 bar). The positive effect of temperature on the volatile yield was observed up to 2–5 s. The devolatilisation stage was completed within a maximum of 5 s at temperatures ranging from 800 to 1200 °C. The pressure was determined to be a kinetically limiting factor of the process to up to 800 °C, and the effect was not present at ≥1000 °C. Raman spectroscopy measurements revealed that pyrolytic carbon deposited on the post-experimental meshes is structurally similar to the industrially produced carbon black. The kinetic data and developed model can be further applied in the upscale reactor design. Full article
(This article belongs to the Section Circular and Green Sustainable Polymer Science)
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20 pages, 10254 KB  
Article
Discernible Orientation for Tortuosity During Oxidative Precipitation of Fe(II) in Porous Media: Laboratory Experiment and Micro-CT Imaging
by Wenran Cao, Ekaterina Strounina, Harald Hofmann and Alexander Scheuermann
Minerals 2025, 15(1), 91; https://doi.org/10.3390/min15010091 - 19 Jan 2025
Cited by 3 | Viewed by 1970
Abstract
In the mixing zone, where submarine groundwater carrying ferrous iron [Fe(II)] meets seawater with dissolved oxygen (DO), the oxidative precipitation of Fe(II) occurs at the pore scale (nm~μm), and the resulting Fe precipitation significantly influences the seepage properties at the Darcy scale (cm~m). [...] Read more.
In the mixing zone, where submarine groundwater carrying ferrous iron [Fe(II)] meets seawater with dissolved oxygen (DO), the oxidative precipitation of Fe(II) occurs at the pore scale (nm~μm), and the resulting Fe precipitation significantly influences the seepage properties at the Darcy scale (cm~m). Previous studies have presented a challenge in upscaling fluid dynamics from a small scale to a large scale, thereby constraining our understanding of the spatiotemporal variations in flow paths as porous media evolve. To address this limitation, this study simulated subsurface mixing by injecting Fe(II)-rich freshwater into a DO-rich saltwater flow within a custom-designed syringe packed with glass beads. Micro-computed tomography imaging at the representative elementary volume scale was utilized to track the development of Fe precipitates over time and space. Experimental observations revealed three distinct stages of Fe hydroxides and their effects on the flow dynamics. Initially, hydrous Fe precipitates were characterized by a low density and exhibited mobility, allowing temporarily clogged pathways to intermittently reopen. As precipitation progressed, the Fe precipitates accumulated, forming interparticle bonding structures that redirected the flow to bypass clogged pores and facilitated precipitate flushing near the syringe wall. In the final stage, a notable reduction in the macroscopic capillary number from 3.0 to 0.05 indicated a transition from a viscous- to capillary-dominated flow, which led to the construction of ramified, tortuous flow channels. This study highlights the critical role of high-resolution imaging techniques in bridging the gap between pore-scale and continuum-scale analyses of multiphase flows in hydrogeochemical processes, offering valuable insights into the complex groundwater–seawater mixing. Full article
(This article belongs to the Special Issue Mineral Dissolution and Precipitation in Geologic Porous Media)
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15 pages, 10531 KB  
Article
Mechanical Characterization of Main Minerals in Carbonate Rock at the Micro Scale Based on Nanoindentation
by Ting Deng, Junliang Zhao, Hongchuan Yin, Qiang Xie and Ling Gou
Processes 2024, 12(12), 2727; https://doi.org/10.3390/pr12122727 - 2 Dec 2024
Cited by 2 | Viewed by 1807
Abstract
The mechanical characterization of carbonate rock is crucial for the development of a hydrocarbon reservoir and underground gas storage. As a kind of natural composite material, the mechanical properties of carbonate rock exhibit multiscale characteristics. The macroscopic mechanical properties of carbonate rock are [...] Read more.
The mechanical characterization of carbonate rock is crucial for the development of a hydrocarbon reservoir and underground gas storage. As a kind of natural composite material, the mechanical properties of carbonate rock exhibit multiscale characteristics. The macroscopic mechanical properties of carbonate rock are determined by the mineral composition and structure at the micro scale. To achieve a mechanical investigation at the micro scale, this study designed a scheme for micromechanical characterization of carbonate rock. First, scanning electron microscope observation and energy dispersive spectroscopy analysis were combined to select the appropriate micromechanical test areas and to identify the mineral types in each area. Second, the selected test area was positioned in the nanoindentation instrument through the comparison of different-type microscopic images. Finally, quasi-static nanoindentation was carried out on the surface of different minerals in the selected test area to obtain quantitative mechanical evaluation results. A typical carbonate rock sample from the Huangcaoxia gas storage was investigated in this study. The experimental results indicated apparent micromechanical heterogeneity in the carbonate rock. The Young’s modulus of pyrite was over 200 GPa, while that of clay minerals was only approximately 50 GPa. In addition, the proposed micromechanical characterization scheme was discussed based on experimental results. For minerals with an unknown Poisson’s ratio, the maximum error introduced by the 0.25 assumption was lower than 15%. To discuss the effectiveness of the nanoindentation results, the characterization abilities constituted by lateral spatial resolution and elastic response depth were analyzed. The analysis results revealed that the nanoindentation measurement of clay was more susceptible to influence by the surrounding environment as compared to other kinds of minerals with the experimental setup in this study. The micromechanical characterization scheme for clay minerals can be optimized in future research. The mechanical data obtained at the micro scale can be used for the interpretation of the macroscopic mechanical features of carbonate rock for the parameter input and validation of mineral-related simulation and for the construction of a mechanical upscaling model. Full article
(This article belongs to the Special Issue Advances in Enhancing Unconventional Oil/Gas Recovery, 2nd Edition)
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