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Search Results (1,417)

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Keywords = two-dimensional optics

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20 pages, 6694 KiB  
Article
Spatiotemporal Assessment of Benzene Exposure Characteristics in a Petrochemical Industrial Area Using Mobile-Extraction Differential Optical Absorption Spectroscopy (Me-DOAS)
by Dong keun Lee, Jung-min Park, Jong-hee Jang, Joon-sig Jung, Min-kyeong Kim, Jaeseok Heo and Duckshin Park
Toxics 2025, 13(8), 655; https://doi.org/10.3390/toxics13080655 (registering DOI) - 31 Jul 2025
Abstract
Petrochemical complexes are spatially expansive and host diverse emission sources, making accurate monitoring of volatile organic compounds (VOCs) challenging using conventional two-dimensional methods. This study introduces Mobile-extraction Differential Optical Absorption Spectroscopy (Me-DOAS), a real-time, three-dimensional remote sensing technique for assessing benzene emissions in [...] Read more.
Petrochemical complexes are spatially expansive and host diverse emission sources, making accurate monitoring of volatile organic compounds (VOCs) challenging using conventional two-dimensional methods. This study introduces Mobile-extraction Differential Optical Absorption Spectroscopy (Me-DOAS), a real-time, three-dimensional remote sensing technique for assessing benzene emissions in the Ulsan petrochemical complex, South Korea. A vehicle-mounted Me-DOAS system conducted monthly measurements throughout 2024, capturing data during four daily intervals to evaluate diurnal variation. Routes included perimeter loops and grid-based transects within core industrial zones. The highest benzene concentrations were observed in February (mean: 64.28 ± 194.69 µg/m3; geometric mean: 5.13 µg/m3), with exceedances of the national annual standard (5 µg/m3) in several months. Notably, nighttime and early morning sessions showed elevated levels, suggesting contributions from nocturnal operations and meteorological conditions such as atmospheric inversion. A total of 179 exceedances (≥30 µg/m3) were identified, predominantly in zones with benzene-handling activities. Correlation analysis revealed a significant relationship between high concentrations and specific emission sources. These results demonstrate the utility of Me-DOAS in capturing spatiotemporal emission dynamics and support its application in exposure risk assessment and industrial emission control. The findings provide a robust framework for targeted management strategies and call for integration with source apportionment and dispersion modeling tools. Full article
(This article belongs to the Section Air Pollution and Health)
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15 pages, 3113 KiB  
Article
Dark Soliton Dynamics for the Resonant Nonlinear Schrödinger Equation with Third- and Fourth-Order Dispersions
by Weiqian Zhao, Yuan Wang, Ziye Wang and Ying Wang
Photonics 2025, 12(8), 773; https://doi.org/10.3390/photonics12080773 (registering DOI) - 31 Jul 2025
Abstract
Optical solitons have emerged as a highly active research domain in nonlinear fiber optics, driving significant advancements and enabling a wide range of practical applications. This study investigates the dynamics of dark solitons in systems governed by the resonant nonlinear Schrödinger equation (RNLSE). [...] Read more.
Optical solitons have emerged as a highly active research domain in nonlinear fiber optics, driving significant advancements and enabling a wide range of practical applications. This study investigates the dynamics of dark solitons in systems governed by the resonant nonlinear Schrödinger equation (RNLSE). For the RNLSE with third-order (3OD) and fourth-order (4OD) dispersions, the dark soliton solution of the equation in the (1+1)-dimensional case is derived using the F-expansion method, and the analytical study is extended to the (2+1)-dimensional case via the self-similar method. Subsequently, the nonlinear equation incorporating perturbation terms is further studied, with particular attention given to the dark soliton solutions in both one and two dimensions. The soliton dynamics are illustrated through graphical representations to elucidate their propagation characteristics. Finally, modulation instability analysis is conducted to evaluate the stability of the nonlinear system. These theoretical findings provide a solid foundation for experimental investigations of dark solitons within the systems governed by the RNLSE model. Full article
(This article belongs to the Section Optoelectronics and Optical Materials)
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21 pages, 2926 KiB  
Article
Exact Solutions and Soliton Transmission in Relativistic Wave Phenomena of Klein–Fock–Gordon Equation via Subsequent Sine-Gordon Equation Method
by Muhammad Uzair, Ali H. Tedjani, Irfan Mahmood and Ejaz Hussain
Axioms 2025, 14(8), 590; https://doi.org/10.3390/axioms14080590 - 29 Jul 2025
Viewed by 208
Abstract
This study explores the (1+1)-dimensional Klein–Fock–Gordon equation, a distinct third-order nonlinear differential equation of significant theoretical interest. The Klein–Fock–Gordon equation (KFGE) plays a pivotal role in theoretical physics, modeling high-energy particles and providing a fundamental framework for simulating relativistic wave phenomena. To find [...] Read more.
This study explores the (1+1)-dimensional Klein–Fock–Gordon equation, a distinct third-order nonlinear differential equation of significant theoretical interest. The Klein–Fock–Gordon equation (KFGE) plays a pivotal role in theoretical physics, modeling high-energy particles and providing a fundamental framework for simulating relativistic wave phenomena. To find the exact solution of the proposed model, for this purpose, we utilized two effective techniques, including the sine-Gordon equation method and a new extended direct algebraic method. The novelty of these approaches lies in the form of different solutions such as hyperbolic, trigonometric, and rational functions, and their graphical representations demonstrate the different form of solitons like kink solitons, bright solitons, dark solitons, and periodic waves. To illustrate the characteristics of these solutions, we provide two-dimensional, three-dimensional, and contour plots that visualize the magnitude of the (1+1)-dimensional Klein–Fock–Gordon equation. By selecting suitable values for physical parameters, we demonstrate the diversity of soliton structures and their behaviors. The results highlighted the effectiveness and versatility of the sine-Gordon equation method and a new extended direct algebraic method, providing analytical solutions that deepen our insight into the dynamics of nonlinear models. These results contribute to the advancement of soliton theory in nonlinear optics and mathematical physics. Full article
(This article belongs to the Special Issue Applied Nonlinear Dynamical Systems in Mathematical Physics)
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13 pages, 5624 KiB  
Article
Identification of Hexagonal Boron Nitride Thickness on SiO2/Si Substrates by Colorimetry and Contrast
by Elena Blundo, Niklas H. T. Schmidt, Andreas V. Stier and Jonathan J. Finley
Appl. Sci. 2025, 15(15), 8400; https://doi.org/10.3390/app15158400 - 29 Jul 2025
Viewed by 102
Abstract
Hexagonal boron nitride (hBN) is a layered material with a wide variety of excellent properties for emergent applications in quantum photonics using atomically thin materials. For example, it hosts single-photon emitters that operate up to room-temperature, it can be exploited for atomically flat [...] Read more.
Hexagonal boron nitride (hBN) is a layered material with a wide variety of excellent properties for emergent applications in quantum photonics using atomically thin materials. For example, it hosts single-photon emitters that operate up to room-temperature, it can be exploited for atomically flat tunnel barriers, and it can be used to form high finesse photonic nanocavities. Moreover, it is an ideal encapsulating dielectric for two-dimensional (2D) materials and heterostructures, with highly beneficial effects on their electronic and optical properties. Depending on the use case, the thickness of hBN is a critical parameter and needs to be carefully controlled from the monolayer to hundreds of layers. This calls for quick and non-invasive methods to unambiguously identify the thickness of exfoliated flakes. Here, we show that the apparent color of hBN flakes on different SiO2/Si substrates can be made to be highly indicative of the flake thickness, providing a simple method to infer the hBN thickness. Using experimental determination of the colour of hBN flakes and calculating the optical contrast, we derived the optimal substrates for the most reliable hBN thickness identification for flakes with thickness ranging from a few layers towards bulk-like hBN. Our results offer a practical guide for the determination of hBN flake thickness for widespread applications using 2D materials and heterostructures. Full article
(This article belongs to the Section Materials Science and Engineering)
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13 pages, 1220 KiB  
Article
Uncertainty Evaluation of Two-Dimensional Horizontal Distributed Photometric Sensor Based on MCM for Illuminance Measurement Task
by Jianguo Sun, Yueyao Wang, Yinbao Cheng, Guanghu Zhu, Jianwen Shao and Yuebing Sha
Sensors 2025, 25(15), 4648; https://doi.org/10.3390/s25154648 - 27 Jul 2025
Viewed by 176
Abstract
In response to the demand for precise measurement of illuminance distribution in the quality control of LED monitoring fill light products and the iterative direction of secondary optical design, distributed photometric sensors have shown advantages, but their measurement uncertainty assessment faces challenges. This [...] Read more.
In response to the demand for precise measurement of illuminance distribution in the quality control of LED monitoring fill light products and the iterative direction of secondary optical design, distributed photometric sensors have shown advantages, but their measurement uncertainty assessment faces challenges. This paper addresses the problem of uncertainty evaluation in photometric parameter measurement with a two-dimensional horizontal distributed photometric sensor and proposes an uncertainty evaluation framework for this task. We have established an uncertainty analysis model for the measurement system and provided two uncertainty synthesis methods, The Guide to the Expression of Uncertainty in Measurement and the Monte Carlo method. This study designed illuminance measurement experiments to validate the feasibility of the proposed uncertainty evaluation method. The results demonstrate that the actual probability distribution of the measurement data follows a trapezoidal distribution. Furthermore, the expanded uncertainty calculated using the GUM method was 21.1% higher than that obtained by the MCM. This work effectively addresses the uncertainty evaluation challenge for illuminance measurement tasks using a two-dimensional horizontal distributed photometric sensor. The findings offer valuable reference for the uncertainty assessment of other high-precision optical instruments and possess significant engineering value in enhancing the reliability of optical metrology systems. Full article
(This article belongs to the Special Issue Optical Sensors for Industrial Applications)
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10 pages, 1873 KiB  
Article
Stacking Order-Dependent Electronic and Optical Properties of h-BP/Borophosphene Van Der Waals Heterostructures
by Kejing Ren, Quan Zhang, Shengli Zhang and Yang Zhang
Nanomaterials 2025, 15(15), 1155; https://doi.org/10.3390/nano15151155 - 25 Jul 2025
Viewed by 154
Abstract
Van der Waals (vdW) heterostructures, typically composed of two-dimensional (2D) atomic layers, have attracted significant attention over the past few decades. Their performance is closely dependent on their composition and interlayer interactions. In this study, we constructed four types of 2D hexagonal BP [...] Read more.
Van der Waals (vdW) heterostructures, typically composed of two-dimensional (2D) atomic layers, have attracted significant attention over the past few decades. Their performance is closely dependent on their composition and interlayer interactions. In this study, we constructed four types of 2D hexagonal BP monolayer (h-BP)/borophosphene vdW heterostructures with different stacking orders: (i) B-B stacking, (ii) P-P stacking, (iii) moire-I, and (iv) moire-II. Their structural stability and their electronic and optical properties were explored by using first-principles calculations. The results show that h-BP/borophosphene heterostructures can maintain their configurations with good structural stability and minimal lattice mismatch. All vdW heterostructures exhibit semiconducting characteristics, and their band gaps are highly dependent on interlayer stacking orders. Due to the regular atomic arrangement and enhanced interlayer dipole interactions, the B-B stacking bilayer opens a relatively large band gap of 0.157 eV, while the moire-II bilayer exhibits a very small band gap of 0.045 eV because of its irregular atom arrangements. By calculating the complex dielectric function, optical absorption spectra of B-B and P-P stacking bilayers were discussed. This study suggests that h-BP/borophosphene heterostructures have desirable optical properties, broadening the potential applications of the constituent monolayers. Full article
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9 pages, 3392 KiB  
Article
Validating Pseudo-Free-Space Conditions in a Planar Waveguide Using Phase Retrieval from Fresnel Diffraction Patterns
by Varis Karitans, Mattias Hammar, Martins Zubkins, Edvins Letko, Maris Ozolinsh and Sergejs Fomins
Photonics 2025, 12(8), 740; https://doi.org/10.3390/photonics12080740 - 22 Jul 2025
Viewed by 215
Abstract
In this study, we address the question of whether a waveguide with absorbing sidewalls can be considered pseudo free space and if the free-space transfer function is valid in such a medium. We test this hypothesis by applying a phase retrieval algorithm based [...] Read more.
In this study, we address the question of whether a waveguide with absorbing sidewalls can be considered pseudo free space and if the free-space transfer function is valid in such a medium. We test this hypothesis by applying a phase retrieval algorithm based on the free-space transfer function. First, optical measurements are carried out to measure the optical properties of a stack of thin films and select the parameters of simulations. Next, the propagation of light in a waveguide was simulated in COMSOL, and the phase of a wave was retrieved in MATLAB. Analysis was performed both for free-space conditions, and for a waveguide with absorbing sidewalls. The cross-correlation between the distributions of intensity under both conditions was about 0.40. The RMS error of the wave retrieved under free-space conditions was 0.378 rad, while that in the case of absorbing sidewalls was 0.323 rad, indicating successful retrieval. The successfully recovered phase of the input wave suggests that a waveguide with absorbing sidewalls can be approximated as pseudo free space and the free-space transfer function may be valid. These results may be used in future studies on how to shorten the phase retrieval of two-dimensional objects. Full article
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13 pages, 7300 KiB  
Article
Strain and Layer Modulations of Optical Absorbance and Complex Photoconductivity of Two-Dimensional InSe: A Study Based on GW0+BSE Calculations
by Chuanghua Yang, Yuan Jiang, Wendeng Huang and Feng Pan
Crystals 2025, 15(7), 666; https://doi.org/10.3390/cryst15070666 - 21 Jul 2025
Viewed by 233
Abstract
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and [...] Read more.
Since the definitions of the two-dimensional (2D) optical absorption coefficient and photoconductivity are independent of the thickness of 2D materials, they are more suitable than the dielectric function to describe the optical properties of 2D materials. Based on the many-body GW method and the Bethe–Salpeter equation, we calculated the quasiparticle electronic structure, optical absorbance, and complex photoconductivity of 2D InSe from a single layer (1L) to three layers (3L). The calculation results show that the energy difference between the direct and indirect band gaps in 1L, 2L, and 3L InSe is so small that strain can readily tune its electronic structure. The 2D optical absorbance results calculated taking into account exciton effects show that light absorption increases rapidly near the band gap. Strain modulation of 1L InSe shows that it transforms from an indirect bandgap semiconductor to a direct bandgap semiconductor in the biaxial compressive strain range of −1.66 to −3.60%. The biaxial compressive strain causes a slight blueshift in the energy positions of the first and second absorption peaks in monolayer InSe while inducing a measurable redshift in the energy positions of the third and fourth absorption peaks. Full article
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13 pages, 9483 KiB  
Article
Abnormal Angle-Dependent Multi-Channel Filtering in Photonic Crystals Containing Hyperbolic Metamaterials
by Mingyan Xie, Yuanda Huang, Haoyuan Qin and Guiqiang Du
Nanomaterials 2025, 15(14), 1122; https://doi.org/10.3390/nano15141122 - 19 Jul 2025
Viewed by 363
Abstract
Tunneling modes in all-dielectric one-dimensional photonic crystals can be utilized for multi-channel filtering. However, these tunneling modes generally blue shift upon increasing the incident angle. When hyperbolic metamaterials are introduced into one-dimensional photonic crystals, the competition between the propagation phase shifts in the [...] Read more.
Tunneling modes in all-dielectric one-dimensional photonic crystals can be utilized for multi-channel filtering. However, these tunneling modes generally blue shift upon increasing the incident angle. When hyperbolic metamaterials are introduced into one-dimensional photonic crystals, the competition between the propagation phase shifts in the dielectric materials and hyperbolic metamaterials can result in different angle dependencies, including blue shift, abnormal zero shift, and abnormal red shift. When the reduction in the propagation phase in the dielectric layer exceeds the increment in the propagation phase in the hyperbolic metamaterial, the tunneling modes are blue-shifted; conversely, when the phase increment in the hyperbolic metamaterial exceeds the phase reduction in the dielectric layer, the tunneling modes are abnormally red-shifted. When the phase changes in the two materials are the same, the tunneling modes are angle independent. In this study, we investigated the multiple filtering effects of one-dimensional photonic structures composed of hyperbolic metamaterials. These composed structures exhibited multiple tunneling modes based on one-, two-, or three-angle dependencies and can be applied in novel optical devices with different angle-dependence requirements. Full article
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19 pages, 2875 KiB  
Review
Streamlining ICI Transformed as a Nonnegative System
by David Hyland
Photonics 2025, 12(7), 733; https://doi.org/10.3390/photonics12070733 - 18 Jul 2025
Viewed by 113
Abstract
More than seventy-five years ago, R. Hanbury Brown and R. Q. Twiss performed the first experiments in quantum optics. At the outset, their results showed great promise for the field of astronomical science, featuring inexpensive hardware, immunity to atmospheric turbulence, and enormous interferometry [...] Read more.
More than seventy-five years ago, R. Hanbury Brown and R. Q. Twiss performed the first experiments in quantum optics. At the outset, their results showed great promise for the field of astronomical science, featuring inexpensive hardware, immunity to atmospheric turbulence, and enormous interferometry baselines. This was put to good use for the determination of stellar diameters up to the present time. However, for two-dimensional imaging with faint objects, the integration times are prohibitive. Recently, in a sequence of papers, the present author developed a stochastic search algorithm to remove this roadblock, reducing millions of hours to minutes or seconds. Also, the author’s paper entitled “The Rise of the Brown-Twiss Effect” summarized the search algorithm and emphasized the mathematical proofs of the algorithm. The current algorithm is a sequence of six lines of code. The goal of the present article is to streamline the algorithm in the form of a discrete-time dynamic system and to reduce the size of the state space. The previous algorithm used initial conditions that were randomly assorted pixel intensities. The intensities were mutually statistically independent and uniformly distributed over the range 0,δ, where δ is a (very small) positive constant. The present formulation employs a transformation requiring the uniformly distributed phase of the fast Fourier transform of the cross correlations of the data as initial conditions. We shall see that this strategy results in the simplest discrete-time dynamic system capable for exploring the alternate features and benefits of compartmental nonnegative dynamic systems. Full article
(This article belongs to the Special Issue Optical Imaging and Measurements: 2nd Edition)
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12 pages, 2335 KiB  
Article
Ultrawide-Field Optical Coherence Tomography Angiography-Guided Navigated Laser Therapy of Non-Perfused Areas in Branch Retinal Vein Occlusion
by Yao Zhou, Peng Peng, Jiaojiao Wei, Jian Yu and Min Wang
J. Clin. Med. 2025, 14(14), 5014; https://doi.org/10.3390/jcm14145014 - 15 Jul 2025
Viewed by 218
Abstract
Background/Objectives: This study evaluates whether ultrawide-field optical coherence tomography angiography (UWF-OCTA) can guide navigated laser therapy for non-perfused areas (NPAs) in branch retinal vein occlusion (BRVO). It further explores whether the laser spots can be accurately placed according to plan, considering that [...] Read more.
Background/Objectives: This study evaluates whether ultrawide-field optical coherence tomography angiography (UWF-OCTA) can guide navigated laser therapy for non-perfused areas (NPAs) in branch retinal vein occlusion (BRVO). It further explores whether the laser spots can be accurately placed according to plan, considering that the retina is three-dimensional (3D), while UWF-OCTA provides two-dimensional (2D) images. Methods: UWF-OCTA images from three devices—VG200, Xephilio OCT-S1, and Bmizar—guided the treatments. These images were superimposed onto NAVILAS® system images to guide NPA treatments. Pre-treatment planning was strategically designed to avoid normal and collateral vessels, with immediate post-laser OCTA and en face images assessing the efficacy of the laser spots in avoiding these vessels as planned. The accuracy of navigated laser therapy was further analyzed by comparing the intended laser locations with the actual spots. Results: All montaged OCTA images from the three devices were seamlessly integrated into the navigated laser system without registration errors. All patients received treatments targeting the NPAs as planned. However, not all collateral or normal vessels were successfully avoided by the laser spots. A further analysis revealed that the actual locations of the laser spots deviated slightly from the planned locations, particularly in the mid-periphery areas. Conclusions: UWF-OCTA-guided navigated laser photocoagulation is feasible and precise for treating NPAs in BRVO. Nonetheless, minor deviations between planned and actual locations were observed. This discrepancy, particularly important when treating diseases of the macular area, should be carefully considered when employing OCTA-guided navigated laser photocoagulation. Full article
(This article belongs to the Section Ophthalmology)
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17 pages, 2381 KiB  
Review
From Na2Cl to CaCl: Progress in the 2D Crystals of Unconventional Stoichiometries in Ambient Conditions
by Mengjiao Wu, Xiaoling Lei and Haiping Fang
Solids 2025, 6(3), 38; https://doi.org/10.3390/solids6030038 - 15 Jul 2025
Viewed by 263
Abstract
Two-dimensional (2D) crystals which present unconventional stoichiometries on graphene surfaces in ambient conditions, such as Na2Cl, Na3Cl, and CaCl, have attracted significant attention in recent years due to their electronic structures and abnormal cation–anion ratios, which differ from those [...] Read more.
Two-dimensional (2D) crystals which present unconventional stoichiometries on graphene surfaces in ambient conditions, such as Na2Cl, Na3Cl, and CaCl, have attracted significant attention in recent years due to their electronic structures and abnormal cation–anion ratios, which differ from those of conventional three-dimensional crystals. This unconventional crystallization is attributed to the cation–π interaction between ions and the π-conjugated system of the graphene surface. Consequently, their physical and chemical properties—including their electrical, optical, magnetic, and mechanical characteristics—often differ markedly from those of conventional crystals. This review summarizes the recent progress made in the fabrication and analysis of the structures, distinctive features, and applications of these 2D unconventional stoichiometry crystals on graphene surfaces in ambient conditions. Their special properties, including their piezoelectricity, metallicity, heterojunction, and room-temperature ferromagnetism, are given particularly close attention. Finally, some significant prospects and further developments in this exciting interdisciplinary field are proposed. Full article
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13 pages, 3647 KiB  
Article
Near-Infrared Synaptic Responses of WSe2 Artificial Synapse Based on Upconversion Luminescence from Lanthanide Doped Nanoparticles
by Yaxian Lu, Chuanwen Chen, Qi Sun, Ni Zhang, Kun Lv, Zhiling Chen, Yuelan He, Haowen Tang and Ping Chen
Inorganics 2025, 13(7), 236; https://doi.org/10.3390/inorganics13070236 - 10 Jul 2025
Viewed by 355
Abstract
Near-infrared (NIR) photoelectric synaptic devices show great potential in studying NIR artificial visual systems integrating excellent optical characteristics and bionic synaptic plasticity. However, NIR synapses based on transition metal dichalcogenides (TMDCs) suffer from low stability and poor environmental performance. Thus, an environmentally friendly [...] Read more.
Near-infrared (NIR) photoelectric synaptic devices show great potential in studying NIR artificial visual systems integrating excellent optical characteristics and bionic synaptic plasticity. However, NIR synapses based on transition metal dichalcogenides (TMDCs) suffer from low stability and poor environmental performance. Thus, an environmentally friendly NIR synapse was fabricated based on lanthanide-doped upconversion nanoparticles (UCNPs) and two-dimensional (2D) WSe2 via solution spin coating technology. Biological synaptic functions were simulated successfully through 975 nm laser regulation, including paired-pulse facilitation (PPF), spike rate-dependent plasticity, and spike timing-dependent plasticity. Handwritten digital images were also recognized by an artificial neural network based on device characteristics with a high accuracy of 97.24%. In addition, human and animal identification in foggy and low-visibility surroundings was proposed by the synaptic response of the device combined with an NIR laser and visible simulation. These findings might provide promising strategies for developing a 24/7 visual response of humanoid robots. Full article
(This article belongs to the Section Inorganic Materials)
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17 pages, 1876 KiB  
Article
Three-Dimensional Modeling of Condensing and Superimposing Deltamethrin Droplets on Strawberry Leaf Surface from Dynamic Wetting Process Monitoring Data
by Jun Lu, Zichao Wen, Xueying Wang and Xumin Ding
Processes 2025, 13(7), 2181; https://doi.org/10.3390/pr13072181 - 8 Jul 2025
Viewed by 222
Abstract
It is imperative to investigate the behavior of the droplet superimposed condensation of deltamethrin reagent on strawberry leaf surface, as well as the dynamic variation rule of its contact angle. A microinjector was utilized to conduct the experiment of droplet superposition and condensation. [...] Read more.
It is imperative to investigate the behavior of the droplet superimposed condensation of deltamethrin reagent on strawberry leaf surface, as well as the dynamic variation rule of its contact angle. A microinjector was utilized to conduct the experiment of droplet superposition and condensation. The surface tension of deltamethrin droplets was measured by means of an optical contact angle meter, and the wetting parameters, such as contact angle, volume, and spreading diameter, were obtained by observing the leaf surfaces of various parts of strawberries during the dynamic process of superimposed condensation. A model was constructed by establishing the relationship between the contact angle and the coordinates of the observation point and time through the spatial fitting interpolation method. This model is a three-dimensional dynamic trend surface model of contact angle for droplet superposition and condensation. The findings indicated that the surface tension of the deltamethrin drop was 28.92 ± 0.2 mN·m−1. The interval between the superposition of two droplets and the subsequent condensation of a new droplet was found to be within 0.5 s. The time taken for a new droplet to form was found to be between 0.0356 and 0.0476 s. The change in contact angle during the processes of superposition and coalescence can be broadly categorized into three distinct stages: namely, sharp oscillation, slight decrease, and gentle stabilization. The volume of the new droplet formed by the superposition and condensation was found to be 1.05 to 1.93 times that of a lying droplet. The maximum increase in the spreading diameter of the superimposed and condensed droplets was 40.29%. The three-dimensional dynamic trend surface model can reflect the overall spatial–temporal change trend of the contact angle in the process of superposition and coalescence. The model successfully passed the overall significance F-test and each coefficient of the statistical t-test, and demonstrated a satisfactory time interpolation effect. The experimental verification demonstrates that the predicted contact angle value of the model is consistent with the measured value. Full article
(This article belongs to the Section Process Control and Monitoring)
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16 pages, 9957 KiB  
Article
Analysis and Optimization of Rotationally Symmetric Au-Ag Alloy Nanoparticles for Refractive Index Sensing Properties Using T-Matrix Method
by Long Cheng, Shuhong Gong and Paerhatijiang Tuersun
Nanomaterials 2025, 15(13), 1052; https://doi.org/10.3390/nano15131052 - 6 Jul 2025
Viewed by 356
Abstract
Previous investigations devoted to non-spherical nanoparticles for biosensing have primarily addressed two hot topics, namely, finding nanoparticles with the best shape for refractive index sensing properties and the optimization of size parameters. In this study, based on these hot topics, Au-Ag alloy nanoparticles [...] Read more.
Previous investigations devoted to non-spherical nanoparticles for biosensing have primarily addressed two hot topics, namely, finding nanoparticles with the best shape for refractive index sensing properties and the optimization of size parameters. In this study, based on these hot topics, Au-Ag alloy nanoparticles with excellent optical properties were selected as the research object. Targeting rotationally symmetric Au-Ag alloy nanoparticles for biosensing applications, the complex media function correction model and T-matrix approach were used to systematically analyze the variation patterns of extinction properties, refractive index sensitivity, full width at half maximum, and figure of merit of three rotationally symmetric Au-Ag alloy nanoparticles with respect to the size of the particles and the Au molar fraction. In addition, we optimized the figure of merit to obtain the best size parameters and Au molar fractions for the three rotationally symmetric Au-Ag alloy nanoparticles. Finally, the range of dimensional parameters corresponding to a figure of merit greater than 98% of its maximum value was calculated. The results show that the optimized Au-Ag alloy nanorods exhibit a refractive index sensitivity of 395.2 nm/RIU, a figure of merit of 7.16, and a wide range of size parameters. Therefore, the optimized Au-Ag alloy nanorods can be used as high-performance biosensors. Furthermore, this study provides theoretical guidance for the application and preparation of rotationally symmetric Au-Ag alloy nanoparticles in biosensing. Full article
(This article belongs to the Special Issue Theoretical Calculation Study of Nanomaterials: 2nd Edition)
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