Search Results (23)

In this paper, a new approach is proposed to improve the performance of the LNG regasification process in a geothermal-transcritical CO₂–LNG cycle by using thermoelectric generators. Energy and exergy analyses were applied to the proposed system and the plant’s performance is compared with the conventional CO₂–LNG cycle. To achieve the optimal solution for the system, a multi-objective optimization technique based on a genetic algorithm is used. This study’s findings revealed that in the conventional CO₂–LNG cycle, the highest exergy destruction occurs in the preheater. However, integrating a thermoelectric generator allows a portion of this destroyed exergy to be converted into power. The proposed system demonstrated 2% less exergy destruction compared to the conventional system. Moreover, the TEG contributes additional power, increasing the net output power of the system by 24%. This improvement ultimately enhances the overall exergy efficiency of the system. The analysis also concluded that, although a lower LNG mass flow rate reduces the system’s net power output, it improves the exergy efficiency. Overall, the proposed system exhibits an 8.37% higher exergy efficiency and a 24.22% greater net output power compared to the conventional CO₂–LNG cycle. Full article

The study introduces an innovative three-stage nested power generation system that enables the cascading utilization of LNG cold energy. It makes the most of wasted energy by using ship jacket cooling water (JCW) and exhaust gas (EG) as heat sources, a trans-critical carbon dioxide cycle as internal circulation, and utilizing the pressure exergy of LNG. We choose two azeotrope mixing fluids that match the requirements and create four cases for the outer and middle cycle working fluids in the three-stage nested system. To discover the ideal system performance from the perspectives of exergy (E), economy (E), and environment (E), four cases were subjected to multi-objective optimization using the multi-objective particle swarm optimization technique (MOPSO). Finally, the optimal solution was found by applying the TOPSIS decision-making method. Through comparative analysis, the optimal system is selected among the four optimization results. R170 (22.66%) and R1150 (77.34%) are used as the outer circulating working medium, while R170 (90.86%) and R1270 (9.14%) are utilized as the inter-cycle working fluid. The net output work is 575.75 kW, the optimal exergy efficiency is 46.09%, the optimal electricity production cost is $0.04009 per kWh, the carbon dioxide emissions can be reduced by 36,910 tons, and the payback period is 2.548 years. After optimization, a more energy-efficient and environmentally friendly power generation system is obtained. Full article

Carbon dioxide (CO₂) has been recognized as one of the potential working fluids to operate power generation cycles, either in supercritical or transcritical configuration. However, a small concentration of some of the additives to CO₂ have shown promising improvements in the overall performance of the cycle. The current study is motivated by the newly proposed additive silicon tetrachloride (SiCl₄), and so we perform a detailed investigation of SiCl₄ along with a few well-known additives to CO₂-based binary mixtures as a working fluid in transcritical organic Rankine cycle setup with internal heat regeneration. The additives selected for the study are pentane, cyclopentane, cyclohexane, and silicon tetrachloride (SiCl₄). A comprehensive study on the energy and exergy performance of the cycle for warm regions is conducted at a turbine inlet temperature of 250 °C. The performance of the heat recovery unit is also assessed to highlight its importance in comparison to a simple configuration of the cycle. This study shows that the cycle operating with binary mixtures performs significantly better than with pure CO₂, which is mainly due to its better heat recovery in the heat recovery unit. The results show that the optimal molar concentration of the additives is in between 20% and 25%. Besides having better thermal stability, SiCl₄ shows an improvement in the cycle thermal efficiency by 6% points which is comparable to cyclopentane (7.3% points) and cyclohexane (7.8% points). The optimal cycle pressure ratio for SiCl₄ is also relatively lower than for other additives. The energy efficiency of the cycle with pure CO₂ is around 45% which is also increased to 58%, 63%, 64%, 60% with pentane, cyclopentane, cyclohexane, and SiCl₄, respectively. These results suggest that additives like SiCl₄ could make CO₂-based cycles more viable for power generation in warm regions. Full article

The thermodynamic analysis of an increasing-pressure endothermic power cycle (IPEPC) integrated with closed-loop geothermal energy extraction (CLGEE) in a geothermal well at a depth from 2 km to 5 km has been carried out in this study. Using CLGEE can avoid some typical problems associated with traditional EGS technology, such as water contamination and seismic-induced risk. Simultaneous optimization has been conducted for the structural parameters of the downhole heat exchanger (DHE), the CO₂ mixture working fluid type, and the IPEPC operating parameters. The CO₂-R32 mixture has been selected as the optimal working fluid for the IPEPC based on the highest net power output obtained. It has been found that, when the DHE length is 4 km, the thermosiphon effect is capable of compensating for 53.8% of the pump power consumption. As long as the DHE inlet pressure is higher than the critical pressure, a lower DHE inlet pressure results in more power production. The power generation performance of the IPEPC has been compared with that of the organic Rankine cycle (ORC), trans-critical carbon dioxide cycle (t-CO₂), and single-flash (SF) systems. The comparison shows that the IPEPC has more net power output than other systems in the case that the DHE length is less than 3 km, along with a DHE outer diameter of 0.155 m. When the DHE outer diameter is increased to 0.22 m, the IPEPC has the highest net power output for the DHE length ranging from 2 km to 5 km. The application scopes obtained in this study for different power generation systems are of engineering-guiding significance for geothermal industries. Full article

Supercritical carbon dioxide (sCO₂) can be mixed with dopants such as titanium tetrachloride (TiCl₄), hexafluoro-benzene (C₆F₆), and sulphur dioxide (SO₂) to raise the critical temperature of the working fluid, allowing it to condense at ambient temperatures in dry solar field locations. The resulting transcritical power cycles have lower compression work and higher thermal efficiency. This paper presents the aerodynamic flow path design of a utility-scale axial turbine operating with an 80–20% molar mix of CO₂ and SO₂. The preliminary design is obtained using a mean line turbine design method based on the Aungier loss model, which considers both mechanical and rotor dynamic criteria. Furthermore, steady-state 3D computational fluid dynamic (CFD) simulations are set up using the k-ω SST turbulence model, and blade shape optimisation is carried out to improve the preliminary design while maintaining acceptable stress levels. It was found that increasing the number of stages from 4 to 14 increased the total-to-total efficiency by 6.3% due to the higher blade aspect ratio, which reduced the influence of secondary flow losses, as well as the smaller tip diameter, which minimised the tip clearance losses. The final turbine design had a total-to-total efficiency of 92.9%, as predicted by the CFD results, with a maximum stress of less than 260 MPa and a mass flow rate within 1% of the intended cycle’s mass flow rate. Optimum aerodynamic performance was achieved with a 14-stage design where the hub radius and the flow path length are 310 mm and 1800 mm, respectively. Off-design analysis showed that the turbine could operate down to 88% of the design reduced mass flow rate with a total-to-total efficiency of 80%. Full article

In this paper, a transcritical carbon dioxide power generation system based on a vortex tube is studied, which has the advantage of the self-condensation of carbon dioxide. The thermodynamic performance of the system was investigated by establishing a mathematical model. The results showed that under fundamental working conditions, the system could output a net power of 271.72 kW, and the thermal efficiency as well as the exergy efficiency of the system could reach 7.38% and 27.09%, respectively. Exergy analysis showed that the turbine had the greatest exergy loss among the system’s components, followed by the vortex tube, pump, heater and cooler. Parameter analysis showed that increasing the outlet pressure and inlet temperature of the vortex tube can improve the thermal efficiency and exergy efficiency of the system. In addition, the improvement in the turbine component’s efficiency is the most beneficial to the system’s performance, among which the turbine’s efficiency has the greatest impact. Carbon dioxide can be effectively liquified by expanding it in the vortex tube, and its liquefaction ratio increases with the decrease in the vortex tube’s inlet temperature and the increase in the vortex tube’s inlet pressure. Full article

This paper used the energy, exergy, and economic analysis of a carbon dioxide (CO₂) transcritical two-stage compression system based on organic Rankine cycle (ORC) waste heat recovery technology. When the intermediate pressure and high-pressure compressor outlet pressure were changed, respectively, this study simulated the change in system energy efficiency by adding the ORC for waste heat recovery, calculated the ratio of exergy loss of each component, and performed an economic analysis of the coupled system. The results show that adding waste heat recovery can effectively increase the energy efficiency of the system, and among all components, the heat exchanger had the largest exergy loss, while the evaporator had the highest capital investment and maintenance costs. Full article

Hybrid solar thermal power plants using the Brayton cycle are currently of great interest as they have proven to be technically feasible. This study evaluates mechanisms to reduce fuel consumption and increase the power generated, improving plant efficiency. An energy and exergy model for the hybrid solar plant is developed using an estimation model for the solar resource to determine the plant operation under specific environmental conditions. The effect of using different working fluids in the Brayton cycle, such as air, and helium in transcritical conditions and carbon dioxide in subcritical and supercritical conditions, is evaluated. Additionally, the plant’s exergy destruction and exergy efficiency are evaluated. In those, it can be highlighted that the helium cycle in the same operating conditions compared to other working fluids can increase the power by 160%, increasing fuel consumption by more than 390%. Full article

Carbon dioxide trans-critical refrigeration systems have been deeply investigated over the last years, with the aim to improve their performance by using several possible technical solutions. However, most of them lead to a more complex and expensive system, and therefore a trade-off is always needed to identify the best viable solution. Therefore, many efforts have also been focused on the study of a critical component of the basic carbon dioxide trans-critical cycle, which is the gas cooler, especially by numerical simulations. This work shows a new flexible approach to numerically model an air-cooled finned-tube CO₂ trans-critical gas cooler integrating a Top-Down methodology with a Finite Difference Method to solve the governing equation of the thermodynamic processes involved. The model was developed to reproduce the behavior of an experimental CO₂ refrigeration system, which provided the experimental data used for its validation. In detail, the model showed a good agreement with the experimental data, with average deviations of 1 K (0.3%), 0.9 bar (1%) and 0.15 kW (2.8%) regarding the refrigerant outlet temperature, the refrigerant outlet pressure and the rejected heat, respectively. The Top-Down numerical approach slightly outperformed the performance of previous numerical models available in the literature. Furthermore, the analysis of the refrigerant temperature and pressure along the tubes and rows also shows that the model can reproduce their behavior consistently and accordingly to data reported in the literature. The proposed approach can be used for detailed thermo-economic analysis of the whole refrigeration system, with the aim to optimize the design of the gas cooler. Full article

The urgent energy transition needs a better penetration of renewable energy in the world’s energy mix. The intermittency of renewables requires the use of longer-term storage. The present system uses water displacement, in a lined rock cavern or in an aerial pressurised vessel, as the virtual piston of compressor and expander functions in a carbon dioxide heat pump cycle (HPC) and in an organic transcritical cycle (OTC). Within an impermeable membrane, carbon dioxide is compressed and expanded by filling and emptying pumped-hydro water. Carbon dioxide exchanges heat with two atmospheric thermal storage pits. The hot fluid and ice pits are charged by the HPC when renewable energy becomes available and discharged by the OTC when electricity is needed. A numerical model was built to replicate the system’s losses and to calculate its round-trip efficiency (RTE). A subsequent parametric study highlights key parameters for sizing and optimisation. With an expected RTE of around 70%, this CO₂ PHES (pumped-hydro electricity storage) coupled with PTES (pumped thermal energy storage) could become a game-changer by allowing the efficient storage of intermittent renewable energy and by integrating with district heating and cooling networks, as required by cities and industry in the future. Full article

New guidelines set by international organizations for refrigeration companies cause that natural working fluids such as carbon dioxide are increasingly used in new refrigeration systems. Carbon dioxide (R-744) is used in freezing, cooling, or air conditioning installations, in which the cooling load fluctuates hourly. To adapt the cooling capacity of the evaporator to the current cooling load of the cooled space, a number of control elements are used. The paper proposes a new method of regulating the cooling capacity for a one-stage refrigeration cycle with the R-744 refrigerant and an internal heat exchanger (IHX). The proposed method involves using an additional evaporator and combines the possibility of regulating the cooling capacity with the possibility of energy efficiency ratio (EER) improvement. The energy analysis of the proposed method of regulating the cooling capacity was performed and the results were compared with the control method. The control method was using the compressor hot gas bypass valve which allows the flow of hot vapor refrigerant to the suction side. The energy analysis was carried out for both subcritical and supercritical cycles using the energy equations. For each of the considered methods, the characteristics of the change in the EER as a function of the reduction of the cooling capacity in both supercritical and subcritical cycles were determined. It was found that when the cooling capacity decreased by 50%, the hot gas bypass regulating method was around 30% less efficient compared to the proposed additional evaporator regulating method. Full article

This paper presents a distributed mathematical model for a carbon dioxide direct expansion solar-assisted heat pump used to heat bath water. The main components are a gas cooler, a needle valve, an evaporator/collector, and a compressor. To develop the heat exchange models, mass, energy, and momentum balances were used. The model was validated for transient as well as steady state conditions using experimental data. A reasonably good agreement was observed between the predicted temperatures and experimental data. The simulations showed that the time step required to demonstrate the behavior of the heat pump in the transient regime is greater than the time step required for the steady state. The results obtained with the mathematical model revealed that a reduction in the water mass flow rate results in an increase in the water outlet temperature. In addition, when the carbon dioxide mass flow rate is reduced, the compressor inlet and outlet temperatures increase as well as the water outlet temperature. Full article

The energy-saving potential of heat pump technology is widely recognized in the building sector. In retrofit applications, especially in old and historic buildings, it may be difficult to replace the existing distribution and high-temperature emission systems. Often, historical buildings, especially the listed ones, cannot be thermally insulated; this leads to high temperatures of the heat carrier fluid for heating. In these cases, the main limits are related, on the one hand, to the reaching of the required temperatures, and on the other hand, to the obtaining of good performance even at high temperatures. To address these problems, a suitable solution can be a two-stage heat pump. In this work, a novel concept of a two-stage heat pump is proposed, based on a transcritical cycle that uses the natural fluid R744 (carbon dioxide) with an ejector system. The second refrigerant present in the heat pump and used for the high-temperature stage is the R1234ze, which is an HFO (hydrofluoro-olefin) fluid. This work aims to present the effective energy performance based on real data obtained in operating conditions in a monitoring campaign. The heat pump prototype used in this application is part of the H2020 Cheap-GSHP project, which was concluded in 2019. Full article

This study aims to provide a thermodynamic comparison between supercritical CO₂ cycles and ORC cycles utilizing flue gases as waste heat source. Moreover, the possibility of using CO₂ mixtures as working fluids in transcritical cycles to enhance the performance of the thermodynamic cycle is explored. ORCs operating with pure working fluids show higher cyclic thermal and total efficiencies compared to supercritical CO₂ cycles; thus, they represent a better option for high-temperature waste heat recovery provided that the thermal stability at a higher temperature has been assessed. Based on the improved global thermodynamic performance and good thermal stability of R134a, CO₂-R134a is investigated as an illustrative, promising working fluid mixture for transcritical power cycles. The results show that a total efficiency of 0.1476 is obtained for the CO₂-R134a mixture (0.3 mole fraction of R134a) at a maximum cycle pressure of 200 bars, which is 15.86% higher than the supercritical carbon dioxide cycle efficiency of 0.1274, obtained at the comparatively high maximum pressure of 300 bars. Steam cycles, owing to their larger number of required turbine stages and lower power output, did not prove to be a suitable option in this application. Full article

This paper provides an assessment of the expected Levelised Cost of Electricity enabled by Concentrated Solar Power plants based on Supercritical Carbon Dioxide (sCO ${}_2$ ) technology. A global approach is presented, relying on previous results by the authors in order to ascertain whether these innovative power cycles have the potential to achieve the very low costs of electricity reported in the literature. From a previous thermodynamic analysis of sCO ${}_2$ cycles, three layouts are shortlisted and their installation costs are compared prior to assessing the corresponding cost of electricity. Amongst them, the Transcritical layout is then discarded due to the virtually impossible implementation in locations with high ambient temperature. The remaining layouts, Allam and Partial Cooling are then modelled and their Levelised Cost of Electricity is calculated for a number of cases and two different locations in North America. Each case is characterised by a different dispatch control scheme and set of financial assumptions. A Concentrated Solar Power plant based on steam turbine technology is also added to the assessment for the sake of comparison. The analysis yields electricity costs varying in the range from 8 to over 11 ¢/kWh, which is near but definitely not below the 6 ¢/kWh target set forth by different administrations. Nevertheless, in spite of the results, a review of the conservative assumptions adopted in the analysis suggests that attaining costs substantially lower than this is very likely. In other words, the results presented in this paper can be taken as an upper limit of the economic performance attainable by Supercritical Carbon Dioxide in Concentrated Solar Power applications. Full article