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25 pages, 10097 KiB  
Article
Biocrusts Alter the Pore Structure and Water Infiltration in the Top Layer of Rammed Soils at Weiyuan Section of the Great Wall in China
by Xiaoju Yang, Fasi Wu, Long Li, Ruihua Shang, Dandan Li, Lina Xu, Jing Cui and Xueyong Zhao
Coatings 2025, 15(8), 908; https://doi.org/10.3390/coatings15080908 (registering DOI) - 3 Aug 2025
Viewed by 93
Abstract
The surface of the Great Wall harbors a large number of non-vascular plants dominated by cyanobacteria, lichens and mosses as well as microorganisms, and form biocrusts by cementing with the soils and greatly alters the pore structure of the soil and the ecohydrological [...] Read more.
The surface of the Great Wall harbors a large number of non-vascular plants dominated by cyanobacteria, lichens and mosses as well as microorganisms, and form biocrusts by cementing with the soils and greatly alters the pore structure of the soil and the ecohydrological processes associated with the soil pore space, and thus influences the soil resistance to erosion. However, the microscopic role of the biocrusts in influencing the pore structure of the surface of the Great Wall is not clear. This study chose the Warring States Qin Great Wall in Weiyuan, Gansu Province, China, as research site to quantify thepore structure characteristics of the three-dimensional of bare soil, cyanobacterial-lichen crusts, and moss crusts at the depth of 0–50 mm, by using optical microscopy, scanning electron microscopy, and X-ray computed tomography and image analysis, and the precipitation infiltration process. The results showed that the moss crust layer was dominated by large pores with long extension and good connectivity, which provided preferential seepage channels for precipitation infiltration, while the connectivity between the cyanobacterial-lichen crust voids was poor; The porosity of the cyanobacterial-lichen crust and the moss crust was 500% and 903.27% higher than that of the bare soil, respectively. The porosity of the subsurface layer of cyanobacterial-lichen crust and moss crust was significantly lower than that of the biocrusts layer by 92.54% and 97.96%, respectively, and the porosity of the moss crust was significantly higher than that of the cyanobacterial-lichen crust in the same layer; Cyanobacterial-lichen crusts increased the degree of anisotropy, mean tortuosity, moss crust reduced the degree of anisotropy, mean tortuosity. Biocrusts increased the fractal dimension and Euler number of pores. Compared with bare soil, moss crust and cyanobacterial-lichen crust increased the isolated porosity by 2555% and 4085%, respectively; Biocrusts increased the complexity of the pore network models; The initial infiltration rate, stable infiltration rate, average infiltration rate, and the total amount of infiltration of moss crusted soil was 2.26 and 3.12 times, 1.07 and 1.63 times, respectively, higher than that of the cyanobacterial-lichen crusts and the bare soil, by 1.53 and 2.33 times, and 1.13 and 2.08 times, respectively; CT porosity and clay content are significantly positively correlated with initial soil infiltration rate (|r| ≥ 0.85), while soil type and organic matter content are negatively correlated with initial soil infiltration rate. The soil type and bulk density are directly positively and negatively correlated with CT porosity, respectively (|r| ≥ 0.52). There is a significant negative correlation between soil clay content and porosity (|r| = 0.15, p < 0.001). Biocrusts alter the erosion resistance of rammed earth walls by affecting the soil microstructure of the earth’s great wall, altering precipitation infiltration, and promoting vascular plant colonisation, which in turn alters the erosion resistance of the wall. The research results have important reference for the development of disposal plans for biocrusts on the surface of archaeological sites. Full article
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11 pages, 1936 KiB  
Communication
Diffusion of C-O-H Fluids in a Sub-Nanometer Pore Network: Role of Pore Surface Area and Its Ratio with Pore Volume
by Siddharth Gautam and David Cole
C 2025, 11(3), 57; https://doi.org/10.3390/c11030057 - 1 Aug 2025
Viewed by 175
Abstract
Porous materials are characterized by the pore surface area (S) and volume (V) accessible to a confined fluid. For mesoporous materials NMR measurements of diffusion are used to assess the S/V ratio, because at short times, only [...] Read more.
Porous materials are characterized by the pore surface area (S) and volume (V) accessible to a confined fluid. For mesoporous materials NMR measurements of diffusion are used to assess the S/V ratio, because at short times, only the diffusivity of molecules in the adsorbed layer is affected by confinement and the fractional population of these molecules is proportional to the S/V ratio. For materials with sub-nanometer pores, this might not be true, as the adsorbed layer can encompass the entire pore volume. Here, using molecular simulations, we explore the role played by S and S/V in determining the dynamical behavior of two carbon-bearing fluids—CO2 and ethane—confined in sub-nanometer pores of silica. S and V in a silicalite model representing a sub-nanometer porous material are varied by selectively blocking a part of the pore network by immobile methane molecules. Three classes of adsorbents were thus obtained with either all of the straight (labeled ‘S-major’) or zigzag channels (‘Z-major’) remaining open or a mix of a fraction of both types of channel blocked, resulting in half of the total pore volume being blocked (‘Half’). While the adsorption layers from opposite surfaces overlap, encompassing the entire pore volume for all pores except the intersections, the diffusion coefficient is still found to be reduced at high S/V, especially for CO2, albeit not so strongly as would be expected in the case of wider pores. This is because of the presence of channel intersections that provide a wider pore space with non-overlapping adsorption layers. Full article
(This article belongs to the Section Carbon Cycle, Capture and Storage)
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17 pages, 13918 KiB  
Article
Occurrence State and Controlling Factors of Methane in Deep Marine Shale: A Case Study from Silurian Longmaxi Formation in Sichuan Basin, SW China
by Junwei Pu, Tongtong Luo, Yalan Li, Hongwei Jiang and Lin Qi
Minerals 2025, 15(8), 820; https://doi.org/10.3390/min15080820 - 1 Aug 2025
Viewed by 140
Abstract
Deep marine shale is the primary carrier of shale gas resources in Southwestern China. Because the occurrence and gas content of methane vary with burial conditions, understanding the microscopic mechanism of methane occurrence in deep marine shale is critical for effective shale gas [...] Read more.
Deep marine shale is the primary carrier of shale gas resources in Southwestern China. Because the occurrence and gas content of methane vary with burial conditions, understanding the microscopic mechanism of methane occurrence in deep marine shale is critical for effective shale gas exploitation. The temperature and pressure conditions in deep shale exceed the operating limits of experimental equipment; thus, few studies have discussed the microscopic occurrence mechanism of shale gas in deep marine shale. This study applies molecular simulation technology to reveal the methane’s microscopic occurrence mechanism, particularly the main controlling factor of adsorbed methane in deep marine shale. Two types of simulation models are also proposed. The Grand Canonical Monte Carlo (GCMC) method is used to simulate the adsorption behavior of methane molecules in these two models. The results indicate that the isosteric adsorption heat of methane in both models is below 42 kJ/mol, suggesting that methane adsorption in deep shale is physical adsorption. Adsorbed methane concentrates on the pore wall surface and forms a double-layer adsorption. Furthermore, adsorbed methane can transition to single-layer adsorption if the pore size is less than 1.6 nm. The total adsorption capacity increases with rising pressure, although the growth rate decreases. Excess adsorption capacity is highly sensitive to pressure and can become negative at high pressures. Methane adsorption capacity is determined by pore size and adsorption potential, while accommodation space and adsorption potential are influenced by pore size and mineral type. Under deep marine shale reservoir burial conditions, with burial depth deepening, the effect of temperature on shale gas occurrence is weaker than pressure. Higher temperatures inhibit shale gas occurrence, and high pressure enhances shale gas preservation. Smaller pores facilitate the occurrence of adsorbed methane, and larger pores have larger total methane adsorption capacity. Deep marine shale with high formation pressure and high clay mineral content is conducive to the microscopic accumulation of shale gas in deep marine shale reservoirs. This study discusses the microscopic occurrence state of deep marine shale gas and provides a reference for the exploration and development of deep shale gas. Full article
(This article belongs to the Special Issue Element Enrichment and Gas Accumulation in Black Rock Series)
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26 pages, 9458 KiB  
Article
Wettability Characteristics of Mixed Sedimentary Shale Reservoirs in Saline Lacustrine Basins and Their Impacts on Shale Oil Energy Replenishment: Insights from Alternating Imbibition Experiments
by Lei Bai, Shenglai Yang, Dianshi Xiao, Hongyu Wang, Jian Wang, Jin Liu and Zhuo Li
Energies 2025, 18(14), 3887; https://doi.org/10.3390/en18143887 - 21 Jul 2025
Viewed by 328
Abstract
Due to the complex mineral composition, low clay content, and strong heterogeneity of the mixed sedimentary shale in the Xinjiang Salt Lake Basin, the wettability characteristics of the reservoir and their influencing factors are not yet clear, which restricts the evaluation of oil-bearing [...] Read more.
Due to the complex mineral composition, low clay content, and strong heterogeneity of the mixed sedimentary shale in the Xinjiang Salt Lake Basin, the wettability characteristics of the reservoir and their influencing factors are not yet clear, which restricts the evaluation of oil-bearing properties and the identification of sweet spots. This paper analyzed mixed sedimentary shale samples from the Lucaogou Formation of the Jimsar Sag and the Fengcheng Formation of the Mahu Sag. Methods such as petrographic thin sections, X-ray diffraction, organic matter content analysis, and argon ion polishing scanning electron microscopy were used to examine the lithological and mineralogical characteristics, geochemical characteristics, and pore space characteristics of the mixed sedimentary shale reservoir. Alternating imbibition and nuclear magnetic resonance were employed to quantitatively characterize the wettability of the reservoir and to discuss the effects of compositional factors, lamina types, and pore structure on wettability. Research findings indicate that the total porosity, measured by the alternate imbibition method, reached 72% of the core porosity volume, confirming the effectiveness of alternate imbibition in filling open pores. The Lucaogou Formation exhibits moderate to strong oil-wet wettability, with oil-wet pores predominating and well-developed storage spaces; the Fengcheng Formation has a wide range of wettability, with a higher proportion of mixed-wet pores, strong heterogeneity, and weaker oil-wet properties compared to the Lucaogou Formation. TOC content has a two-segment relationship with wettability, where oil-wet properties increase with TOC content at low TOC levels, while at high TOC levels, the influence of minerals such as carbonates dominates; carbonate content shows an “L” type response to wettability, enhancing oil-wet properties at low levels (<20%), but reducing it due to the continuous weakening effect of minerals when excessive. Lamina types in the Fengcheng Formation significantly affect wettability differentiation, with carbonate-shale laminae dominating oil pores, siliceous laminae contributing to water pores, and carbonate–feldspathic laminae forming mixed pores; the Lucaogou Formation lacks significant laminae, and wettability is controlled by the synergistic effects of minerals, organic matter, and pore structure. Increased porosity strengthens oil-wet properties, with micropores promoting oil adsorption through their high specific surface area, while macropores dominate in terms of storage capacity. Wettability is the result of the synergistic effects of multiple factors, including TOC, minerals, lamina types, and pore structure. Based on the characteristic that oil-wet pores account for up to 74% in shale reservoirs (mixed-wet 12%, water-wet 14%), a wettability-targeted regulation strategy is implemented during actual shale development. Surfactants are used to modify oil-wet pores, while the natural state of water-wet and mixed-wet pores is maintained to avoid interference and preserve spontaneous imbibition advantages. The soaking period is thus compressed from 30 days to 3–5 days, thereby enhancing matrix displacement efficiency. Full article
(This article belongs to the Special Issue Sustainable Development of Unconventional Geo-Energy)
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17 pages, 2951 KiB  
Article
Long-Term Rainfall–Runoff Relationships During Fallow Seasons in a Humid Region
by Rui Peng, Gary Feng, Ying Ouyang, Guihong Bi and John Brooks
Climate 2025, 13(7), 149; https://doi.org/10.3390/cli13070149 - 16 Jul 2025
Viewed by 674
Abstract
The hydrological processes of agricultural fields during the fallow season in east-central Mississippi remain poorly understood, due to the region’s unique rainfall patterns. This study utilized long-term rainfall records from 1924 to 2023 to evaluate runoff characteristics and the runoff response to various [...] Read more.
The hydrological processes of agricultural fields during the fallow season in east-central Mississippi remain poorly understood, due to the region’s unique rainfall patterns. This study utilized long-term rainfall records from 1924 to 2023 to evaluate runoff characteristics and the runoff response to various rainfall events during fallow seasons in Mississippi by applying the DRAINMOD model. The analysis revealed that the average rainfall during the fallow season was 760 mm over the past 100 years, accounting for 65% of the annual total. In dry, normal, and wet fallow seasons, the average rainfall was 528, 751, and 1010 mm, respectively, corresponding to runoff of 227, 388, and 602 mm. Runoff frequency increased with wetter weather conditions, rising from 16 events in dry seasons to 23 in normal seasons and 30 in wet seasons. Over the past century, runoff dynamics were predominantly regulated by high-intensity rainfall events during the fallow season. Very heavy rainfall events (mean frequency = 11 events) generated 215 mm of runoff and accounted for 53% of the total runoff, while extreme rainfall events (mean frequency = 2 events) contributed 135 mm of runoff, making up 34% of the total runoff. Water table depth played a critical role in shaping spring runoff dynamics. As the water table decreased from 46 mm in March to 80 mm in May, the soil pore space increased from 5 mm in March to 14 mm in May. This increased soil infiltration and water storage capacity, leading to a steady decline in runoff. The study found that the mean daily runoff frequency dropped from 13.5% in March to 7.6% in May, while monthly runoff decreased from 74 to 38 mm. Increased extreme rainfall (R95p) in April contributed over 45% of the total runoff and resulted in the highest daily mean runoff of 20 mm, compared to 18 mm in March and 16 mm in May. The results from this century-long historical weather data could be used to enhance field-scale water resource management, predict potential runoff risks, and optimize planting windows in the humid east-central Mississippi. Full article
(This article belongs to the Section Weather, Events and Impacts)
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15 pages, 2434 KiB  
Article
Proteomic Responses of the Springtail Folsomia candida to Drought
by Yang Wang, Stine Slotsbo, Steffen Y. Bak, Christopher J. Martyniuk and Martin Holmstrup
Insects 2025, 16(7), 707; https://doi.org/10.3390/insects16070707 - 9 Jul 2025
Viewed by 405
Abstract
Springtails are adapted to life in the pore space of soil, where humidity in moist soil is close to saturation. Drought is the most important limiting factor for springtails; however, their molecular and physiological adaptations to low humidity are not well understood. The [...] Read more.
Springtails are adapted to life in the pore space of soil, where humidity in moist soil is close to saturation. Drought is the most important limiting factor for springtails; however, their molecular and physiological adaptations to low humidity are not well understood. The present study explored the global proteomic drought response of the springtail, Folsomia candida (Isotomidae, Collembola). In relatively dry soil (−360 kPa), adult springtails initially lost body water but re-established the normal body water content over the following two weeks. Nano LC–MS/MS analysis identified a total of 1729 unique proteins. Proteomic analysis and pathway enrichment found that the proteome generally did not show a dramatic induction of proteins in response to drought stress. After an initial down-regulation of pathways related to metabolism and growth, these pathways gradually returned to the same levels as in moist soil. Other pathways such as the cytoskeleton pathway, which is important in cell proliferation and differentiation, were predominantly down-regulated throughout the experiment in drought-exposed animals, which correlated with essentially no somatic growth of the springtails in dry soil. This study facilitates the understanding of the consequences of climate change on soil functioning and fertility. Full article
(This article belongs to the Special Issue Research on Insect Molecular Biology)
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15 pages, 3155 KiB  
Article
Study on Bearing Characteristics of DMJ Group Pile Composite Foundation Under Embankment Loading
by Haining Wang, Yuhe Zhang, Yang Wang, Weizhe Feng, Jie Li, Kaixing Zhang, Yu Rong, Zhanyong Yao and Kai Yao
CivilEng 2025, 6(3), 35; https://doi.org/10.3390/civileng6030035 - 30 Jun 2025
Viewed by 294
Abstract
The Deep Cement Mixing Integrated Drilling, Mixing, and Jetting (DMJ) technique was innovatively developed by incorporating high-pressure jetting apertures into the mixing blades to enhance the bearing capacity of deep cement-mixed piles. In this study, the bearing characteristics of DMJ pile composite foundations [...] Read more.
The Deep Cement Mixing Integrated Drilling, Mixing, and Jetting (DMJ) technique was innovatively developed by incorporating high-pressure jetting apertures into the mixing blades to enhance the bearing capacity of deep cement-mixed piles. In this study, the bearing characteristics of DMJ pile composite foundations under embankment loading are investigated using numerical simulation. Through comparative simulations involving various pile configurations, the results demonstrate that DMJ pile composite foundations exhibit significantly enhanced settlement control compared to conventional deep mixing piles. Notably, under identical area replacement ratios, the use of DMJ piles reduces total foundation settlement by approximately 30%. Furthermore, the findings indicate that larger pile diameters and smaller spacing are particularly effective in minimizing settlement. In terms of load transfer efficiency, DMJ piles are capable of transmitting embankment loads to depths of up to 15 m, surpassing the 10 m transfer depth observed in conventional pile systems. An analysis of excess pore water pressure further reveals that DMJ piles promote more effective dissipation, highlighting their superior performance in maintaining foundation stability under embankment loading. Full article
(This article belongs to the Section Geotechnical, Geological and Environmental Engineering)
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23 pages, 8674 KiB  
Article
Characterization of Matrix Pore Structure of a Deep Coal-Rock Gas Reservoir in the Benxi Formation, NQ Block, ED Basin
by Guangfeng Liu, Dianyu Wang, Xiang Peng, Qingjiu Zhang, Bofeng Liu, Zhoujun Luo, Zeyu Zhang and Daoyong Yang
Eng 2025, 6(7), 142; https://doi.org/10.3390/eng6070142 - 30 Jun 2025
Viewed by 285
Abstract
In this study, a comprehensive experimental framework was developed to quantitatively characterize the pore structure of a deep coal-rock (DCR; reservoirs below [3000 m]) gas reservoir. Experimentally, petrological and mineral characteristics were determined by performing proximate analysis and scanning electron microscopy (SEM) as [...] Read more.
In this study, a comprehensive experimental framework was developed to quantitatively characterize the pore structure of a deep coal-rock (DCR; reservoirs below [3000 m]) gas reservoir. Experimentally, petrological and mineral characteristics were determined by performing proximate analysis and scanning electron microscopy (SEM) as well as by measuring vitrinite reflectance and maceral components. Additionally, physisorption and high-pressure mercury injection (HPMI) tests were conducted to quantitatively characterize the nano- to micron-scale pores in the DCR gas reservoir at multiple scales. The DCR in the NQ Block is predominantly composed of vitrinite, accounting for approximately 77.75%, followed by inertinite. The pore space is predominantly characterized by cellular pores, but porosity development is relatively limited as most of such pores are extensively filled with clay minerals. The isothermal adsorption curves of CO2 and N2 in the NQ Block and the DJ Block exhibit very similar variation patterns. The pore types and morphologies of the DCR reservoir are relatively consistent, with a significant development of nanoscale pores in both blocks. Notably, micropore metrics per unit mass (pore volume (PV): 0.0242 cm3/g; and specific surface area (SSA): 77.7545 m2/g) indicate 50% lower gas adsorption potential in the DJ Block. In contrast, the PV and SSA of the mesopores per unit mass in the NQ Block are relatively consistent with those in the DJ and SF Blocks. Additionally, the peak mercury intake in the NQ Block occurs within the pore diameter < 20 nm, with nearly 60% of the mercury beginning to enter in large quantities only when the pore size exceeds 20 nm. This indicates that nanoscale pores are predominantly developed in the DCR of the NQ block, which aligns with the findings from physical adsorption experiments and SEM analyses. Overall, the development characteristics of multi-scale pores in the DCR formations of the NQ Block and the eastern part of the Basin are relatively similar, with both total PV and total SSA showing an L-shaped distribution. Due to the disparity in micropore SSA, however, the total SSA of the DJ Block is approximately twice that of the NQ Block. This discovery has established a robust foundation for the subsequent exploitation of natural gas resources in DCR formations within the NQ Block. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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17 pages, 4654 KiB  
Article
Pore Structure and Fractal Characteristics of the Permian Shales in Northeastern Sichuan Basin, China
by Guanping Wang, Qian Zhang, Baojian Shen, Pengwei Wang, Wei Du, Lu Wang, Min Li and Chengxiang Wan
Minerals 2025, 15(7), 684; https://doi.org/10.3390/min15070684 - 27 Jun 2025
Viewed by 326
Abstract
The complexity of the pore system hindered our understanding of the storage and transport properties of organic-rich shales, which in turn brought challenges to the efficient exploration and development of shale oil and gas. This study, based on elemental, mineralogical, petrographic, and petrophysical [...] Read more.
The complexity of the pore system hindered our understanding of the storage and transport properties of organic-rich shales, which in turn brought challenges to the efficient exploration and development of shale oil and gas. This study, based on elemental, mineralogical, petrographic, and petrophysical approaches, attempts to reveal the pore structure and fractal characteristics of a suite of Permian shales collected from the northeastern Sichuan Basin, China. The results showed that meso-pores make up the main proportion of the total pore volume in the Permian shale in this study; most of the pore size distribution patterns for micro pores and meso-macropores are bimodal. Pores related to clay minerals, organic matter pores, and intragranular dissolution pores are the main storage spaces in these shales. In these samples, ink-bottle pores dominate, with some slit and wedge-shaped ones developed. The morphology of the pores in the studied shales is mainly ink-bottle pores, with some slit-shaped and wedge-shaped pores. The fractal dimension D2 is greater than D1, indicating that the homogeneity of pore space is stronger than that of the specific surface area. Quartz in Permian shales inhibits the development of macro- and mesopore spaces and enhances pore heterogeneity, while clay minerals facilitate the development of macro- and mesopore spaces and attenuate pore heterogeneity. The organic matter content shows a negative impact on the macropore volume due to the stripped occurrence and matrix filling. This study has a vital significance for current exploration and development of shale gas in Permian strata in the Sichuan Basin and offers insights for Permian shales in other basins all over the world. Full article
(This article belongs to the Section Mineral Exploration Methods and Applications)
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19 pages, 5474 KiB  
Article
Structure and Fractal Characteristics of Organic Matter Pores in Wufeng–Lower Longmaxi Formations in Southern Sichuan Basin, China
by Quanzhong Guan, Dazhong Dong, Bin Deng, Cheng Chen, Chongda Li, Kun Jiao, Yuehao Ye, Haoran Liang and Huiwen Yue
Fractal Fract. 2025, 9(7), 410; https://doi.org/10.3390/fractalfract9070410 - 25 Jun 2025
Viewed by 611
Abstract
Organic matter pores constitute a significant storage space in shale gas reservoirs, contributing to approximately 50% of the total porosity. This study employed a comprehensive approach, utilizing scanning electron microscopy, low-pressure N2 adsorption, thermal analysis, image statistics, and fractal theory, to quantitatively [...] Read more.
Organic matter pores constitute a significant storage space in shale gas reservoirs, contributing to approximately 50% of the total porosity. This study employed a comprehensive approach, utilizing scanning electron microscopy, low-pressure N2 adsorption, thermal analysis, image statistics, and fractal theory, to quantitatively characterize the structure and complexity of organic matter pores in the Wufeng–lower Longmaxi Formations (WLLFs). The WLLFs exhibit a high organic matter content, averaging 3.20%. Organic matter pores are typically well-developed, predominantly observed within organic matter clusters, organic matter–clay mineral complexes, and the internal organic matter of pyrite framboid. The morphology of these pores is generally elliptical and spindle-shaped, with the primary pore diameter displaying a bimodal distribution at 10~40 nm and 100~160 nm, potentially influenced by the observational limit of scanning electron microscopy. Shales from greater burial depths within the same gas well contain more organic matter pores; however, the development of organic matter pores in deep gas wells is roughly equivalent to that in medium and shallow gas wells. Fractal dimension values can be utilized to characterize the complexity of organic matter pores, with organic matter macropores (D>50) being more complex than organic matter mesopores (D2–50), which in turn are more complex than organic matter micropores (D<2). The development of macropores and mesopores is a key factor in the heterogeneity of organic matter pores. The complexity of organic matter pores in the same well increases gradually with the burial depth of the shale, and the complexity of organic matter pores in deep gas wells is roughly equivalent to that in medium and shallow gas wells. The structure and fractal characteristics of organic matter pores in shale are primarily controlled by components, diagenesis, tectonism, etc. The lower Longmaxi shale exhibit a high biogenic quartz content and robust hydrocarbon generation from organic matter. This composition effectively shields organic matter pores from multi-directional extrusion, leading to the formation of macropores and mesopores without specific orientation. High-quality shale sections (one and two sublayers) have relatively high fractal dimension D2–50 and D>50 values of organic matter pores and gas content. Consequently, the quality parameters of shale and fractal dimension characteristics can be comprehensively evaluated to identify high-quality shale sections. Full article
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25 pages, 5001 KiB  
Article
Mixed Compost Application: A Sustainable Tool for Improving Soil Carbon Dynamics in a Peach Orchard Under Mediterranean Conditions
by Maria Roberta Bruno, Mariagrazia Piarulli, Carolina Vitti, Marcello Mastrangelo, Alessandro Azzolini, Alessandro Ciurlia, Gianfranco Rana and Rossana Monica Ferrara
Sustainability 2025, 17(12), 5613; https://doi.org/10.3390/su17125613 - 18 Jun 2025
Viewed by 355
Abstract
This study investigated carbon dynamics in a peach orchard subjected to three treatments with a mixed compost amendment (MCA, 35% organic content): a control with no amendment (A0), a full dose (A1, 10 t ha−1), and a half dose (A2, 5 [...] Read more.
This study investigated carbon dynamics in a peach orchard subjected to three treatments with a mixed compost amendment (MCA, 35% organic content): a control with no amendment (A0), a full dose (A1, 10 t ha−1), and a half dose (A2, 5 t ha−1). The sustainability of MCA was assessed in terms of (i) potential and (ii) actual soil respiration, (iii) soil carbon and physical properties and (iv) fruit quality and yield. Carbon dioxide (CO2) emissions were measured both in the laboratory, by incubating soil samples without root removal, and in the field using static chambers. Observations spanned three growing seasons (2021–2023). A correlation was found between actual and potential soil respiration, with emission peaks occurring near the time of MCA application. Cumulative actual CO2 emissions amounted to 5.6, 12.0 and 9.4 t CO2 ha−1 for A0, A1 and A2, respectively. MCA application (i) increased microbial respiration, (ii) reduced soil physical characteristics, such as bulk density and water-filled pore space, and (iii) slightly improved fruit quality, although the yield was not significantly affected. Furthermore, the MCA enhanced soil organic carbon and total nitrogen content compared to the control. These results suggest that high organic content amendments, such as MCA, could represent a strategy to maintain or increase soil organic matter in a sustainable way, although MCA does not improve carbon emission efficiency. Full article
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33 pages, 6095 KiB  
Article
Pore Structure Influence on Properties of Air-Entrained Concrete
by Kamil Zalegowski
Materials 2025, 18(12), 2885; https://doi.org/10.3390/ma18122885 - 18 Jun 2025
Cited by 1 | Viewed by 446
Abstract
The study investigates the influence of an air-entraining admixture on the properties and pore structure of ordinary concrete. The aim was to examine how modifications to the concrete mix affect compressive strength, ultrasonic pulse velocity, and resistance to freeze–thaw cycles. Concrete samples with [...] Read more.
The study investigates the influence of an air-entraining admixture on the properties and pore structure of ordinary concrete. The aim was to examine how modifications to the concrete mix affect compressive strength, ultrasonic pulse velocity, and resistance to freeze–thaw cycles. Concrete samples with varying admixture dosages (0.00–1.50% of cement mass) were tested for mechanical properties and pore structure. Freeze–thaw resistance was assessed using both direct (PN-B-06265) and indirect methods (EN 480-11), while pore characteristics were evaluated via computer-aided image analysis. Results show that increasing the admixture dosage enhances freeze–thaw resistance by refining the pore structure—particularly by increasing the content of micropores below 0.3 mm—while simultaneously reducing compressive strength and ultrasonic velocity. Statistical analysis revealed that pore parameters such as total air content, specific surface area, and spacing factor significantly correlate with concrete performance. The regression models confirmed that compressive strength and ultrasonic velocity are negatively impacted by increased pore volume, while freeze–thaw resistance improves due to a more favorable pore size distribution. The findings demonstrate that optimizing the admixture dosage can effectively balance durability and mechanical performance, and that quantitative stereological parameters provide a valuable basis for predicting the behavior of air-entrained concrete. Full article
(This article belongs to the Collection Concrete and Building Materials)
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19 pages, 7532 KiB  
Article
Controls on the Hydrocarbon Production in Shale Gas Condensate Reservoirs of Rift Lake Basins
by Yaohua Li, Caiqin Bi, Chao Fu, Yinbo Xu, Yuan Yuan, Lihua Tong, Yue Tang and Qianyou Wang
Processes 2025, 13(6), 1868; https://doi.org/10.3390/pr13061868 - 13 Jun 2025
Viewed by 493
Abstract
The production of gas and condensate from liquid-rich shale reservoirs, particularly within heterogeneous lacustrine systems, remains a critical challenge in unconventional hydrocarbon exploration due to intricate multiphase hydrocarbon partitioning, including gases (C1–C2), volatile liquids (C3–C7), [...] Read more.
The production of gas and condensate from liquid-rich shale reservoirs, particularly within heterogeneous lacustrine systems, remains a critical challenge in unconventional hydrocarbon exploration due to intricate multiphase hydrocarbon partitioning, including gases (C1–C2), volatile liquids (C3–C7), and heavier liquids (C7+). This study investigates a 120-meter-thick interval dominated by lacustrine deposits from the Lower Cretaceous Shahezi Formation (K1sh) in the Songliao Basin. This interval, characterized by high clay mineral content and silicate–pyrite laminations, was examined to identify the factors controlling hybrid shale gas condensate systems. We proposed the Hybrid Shale Condensate Index (HSCI), defined as the molar ratios of (C1–C7)/C7+, to categorize fluid phases and address shortcomings in traditional GOR/API ratios. Over 1000 samples were treated by geochemical pyrolysis logging, X-ray fluorescence (XRF) spectrum element logging, SEM-based automated mineralogy, and in situ gas desorption, revealing four primary controls: (1) Thermal maturity thresholds. Mature to highly mature shales exhibit peak condensate production and the highest total gas content (TGC), with maximum gaseous and liquid hydrocarbons at Tmax = 490 °C. (2) Lithofacies assemblage. Argillaceous shales rich in mixed carbonate and clay minerals exhibit an intergranular porosity of 4.8 ± 1.2% and store 83 ± 7% of gas in intercrystalline pore spaces. (3) Paleoenvironmental settings. Conditions such as humid climate, saline water geochemistry, anoxic bottom waters, and significant input of volcanic materials promoted organic carbon accumulation (TOC reaching up to 5.2 wt%) and the preservation of organic-rich lamination. (4) Laminae and fracture systems. Silicate laminae account for 78% of total pore space, and pyrite laminations form interconnected pore networks conducive to gas storage. These findings delineate the “sweet spots” for unconventional hydrocarbon reservoirs, thereby enhancing exploration for gas condensate in lacustrine shale systems. Full article
(This article belongs to the Special Issue Recent Advances in Hydrocarbon Production Processes from Geoenergy)
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29 pages, 21376 KiB  
Article
Numerical Simulation of Fracture Failure Propagation in Water-Saturated Sandstone with Pore Defects Under Non-Uniform Loading Effects
by Gang Liu, Yonglong Zan, Dongwei Wang, Shengxuan Wang, Zhitao Yang, Yao Zeng, Guoqing Wei and Xiang Shi
Water 2025, 17(12), 1725; https://doi.org/10.3390/w17121725 - 7 Jun 2025
Cited by 1 | Viewed by 521
Abstract
The instability of mine roadways is significantly influenced by the coupled effects of groundwater seepage and non-uniform loading. These interactions often induce localized plastic deformation and progressive failure, particularly in the roof and sidewall regions. Seepage elevates pore water pressure and deteriorates the [...] Read more.
The instability of mine roadways is significantly influenced by the coupled effects of groundwater seepage and non-uniform loading. These interactions often induce localized plastic deformation and progressive failure, particularly in the roof and sidewall regions. Seepage elevates pore water pressure and deteriorates the mechanical properties of the rock mass, while non-uniform loading leads to stress concentration. The combined effect facilitates the propagation of microcracks and the formation of shear zones, ultimately resulting in localized instability. This initial damage disrupts the mechanical equilibrium and can evolve into severe geohazards, including roof collapse, water inrush, and rockburst. Therefore, understanding the damage and failure mechanisms of mine roadways at the mesoscale, under the combined influence of stress heterogeneity and hydraulic weakening, is of critical importance based on laboratory experiments and numerical simulations. However, the large scale of in situ roadway structures imposes significant constraints on full-scale physical modeling due to limitations in laboratory space and loading capacity. To address these challenges, a straight-wall circular arch roadway was adopted as the geometric prototype, with a total height of 4 m (2 m for the straight wall and 2 m for the arch), a base width of 4 m, and an arch radius of 2 m. Scaled physical models were fabricated based on geometric similarity principles, using defect-bearing sandstone specimens with dimensions of 100 mm × 30 mm × 100 mm (length × width × height) and pore-type defects measuring 40 mm × 20 mm × 20 mm (base × wall height × arch radius), to replicate the stress distribution and deformation behavior of the prototype. Uniaxial compression tests on water-saturated sandstone specimens were performed using a TAW-2000 electro-hydraulic servo testing system. The failure process was continuously monitored through acoustic emission (AE) techniques and static strain acquisition systems. Concurrently, FLAC3D 6.0 numerical simulations were employed to analyze the evolution of internal stress fields and the spatial distribution of plastic zones in saturated sandstone containing pore defects. Experimental results indicate that under non-uniform loading, the stress–strain curves of saturated sandstone with pore-type defects typically exhibit four distinct deformation stages. The extent of crack initiation, propagation, and coalescence is strongly correlated with the magnitude and heterogeneity of localized stress concentrations. AE parameters, including ringing counts and peak frequencies, reveal pronounced spatial partitioning. The internal stress field exhibits an overall banded pattern, with localized variations induced by stress anisotropy. Numerical simulation results further show that shear failure zones tend to cluster regionally, while tensile failure zones are more evenly distributed. Additionally, the stress field configuration at the specimen crown significantly influences the dispersion characteristics of the stress–strain response. These findings offer valuable theoretical insights and practical guidance for surrounding rock control, early warning systems, and reinforcement strategies in water-infiltrated mine roadways subjected to non-uniform loading conditions. Full article
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21 pages, 15103 KiB  
Article
Analysis of Waterflooding Oil Recovery Efficiency and Influencing Factors in the Tight Oil Reservoirs of Jilin Oilfield
by Jie Cao, Zhou Liu, Zhipeng Zhang, Yuezhi Wang and Liangliang Wang
Processes 2025, 13(5), 1490; https://doi.org/10.3390/pr13051490 - 13 May 2025
Viewed by 673
Abstract
During the waterflooding recovery process, water is injected into the hydrocarbon reservoirs and displaces a portion of the oil and gas, thereby improving oil and gas recovery rates and extending the production life of the reservoir. The macro benefits of waterflooding technology are [...] Read more.
During the waterflooding recovery process, water is injected into the hydrocarbon reservoirs and displaces a portion of the oil and gas, thereby improving oil and gas recovery rates and extending the production life of the reservoir. The macro benefits of waterflooding technology are widely recognized; however, the micro-scale effects of water on the reservoir’s pore structure and fluid distribution during the injection process remain underexplored. Therefore, this study aims to analyze the micro-distribution characteristics of fluids in the reservoir during the oil–water displacement process. To further investigate the micro-mechanisms of waterflooding recovery and the factors influencing recovery efficiency, the study focuses on the impact of permeability, pressure gradient, injection volume, and reverse displacement on oil recovery efficiency. A combined qualitative and quantitative analysis approach was employed, using techniques such as nuclear magnetic resonance (NMR), CT scanning, and fluid distribution tomography to comprehensively analyze the fluid evolution patterns within the reservoir. The results show the following: (1) The movable fluids in the oilfield are primarily distributed within pores ranging from 0.1 to 40 μm; the remaining oil is mainly distributed within pores of 0.1 to 10 μm, accounting for over 85% of the total distribution, and these pores serve as the main space for extracting remaining oil in later stages. (2) Increasing the injection volume significantly improves the oil recovery efficiency in pores ranging from 0.1 to 10 μm. Increasing the displacement pressure gradient effectively reduces remaining oil in pores of 0.1 to 5 μm. However, for reservoirs with permeability greater than 10 mD, once the injection volume exceeds 1 PV or the displacement pressure gradient exceeds 1.8 MPa/m, the increase in oil recovery efficiency becomes marginal. (3) With increasing water injection multiples, the oil displacement efficiency of cores with varying permeability levels shows an overall upward trend. However, the extent of improvement varies significantly, with low-permeability cores exhibiting a markedly greater enhancement in displacement efficiency compared to high-permeability cores. (4) Reverse displacement can reduce the remaining oil in pores ranging from 0.1 to 10 μm, and the increase in oil recovery efficiency is more significant in cores with lower permeability than in those with higher permeability. Therefore, increased production cannot solely rely on improving the production pressure differential to develop remaining oil. Full article
(This article belongs to the Special Issue Recent Developments in Enhanced Oil Recovery (EOR) Processes)
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