Search Results (49)

Pyrolysis technology currently serves as a significant method for recycling and reducing waste tires. In this paper, in order to improve the heat transfer efficiency during the pyrolysis of waste tires in a horizontal rotary furnace and the yield of pyrolysis oil, the effect laws of tire particle size, rotary furnace rotation speed, enhanced heat transfer materials, and adding spiral fins on heat transfer performance and pyrolysis product distribution were studied, respectively. The innovation lies in two aspects: first, aiming at the problems of slow heat transfer and low pyrolysis efficiency in horizontal rotary furnaces, we identified technical measures through experiments to enhance heat transfer, thereby accelerating pyrolysis and reducing energy consumption; second, with the goal of increasing high-value pyrolysis oil yield, we determined optimal operating parameters to improve economic and sustainability outcomes. The results showed that powdered particles of waste tires were heated more evenly during the pyrolysis process, which increased the overall heat transfer coefficient and the proportion of liquid products. When the rotational speed of the rotary pyrolysis furnace exceeded 2 rpm, there was sufficient contact between the material and the furnace wall, which was beneficial to the improvement of heat transfer performance. Adding heat transfer enhancement materials such as carborundum and white alundum could improve the heat transfer performance between the pyrolysis furnace and the material. Notably, a rotational speed of 3 rpm and carborundum were used as a heat transfer enhancement material with powdered waste tire particles during the pyrolysis process; the overall heat transfer coefficient was the highest, which was 16.89 W/(m²·K), and the proportion of pyrolysis oil products was 46.1%. When spiral fins were installed, the comprehensive heat transfer coefficient was increased from 12.78 W/(m²·K) to 16.32 W/(m²·K). The experimental results show that by increasing the speed of the pyrolysis furnace, adding heat transfer enhancing materials with high thermal conductivity to waste tires, and appropriate particle size, the heat transfer performance and pyrolysis rate can be improved, and energy consumption can be reduced. Full article

This paper presents the results of naturally aspirated compression ignition (CI) internal combustion engine (ICE) bench tests of fuels in the form of a blend of diesel oil with recycled oil (RF) in the form of tire pyrolysis oil (TPO) as an admixture with the content of pyrolytic oil with the blend being 10% m/m (D90+RF10). The results relate to reference conditions in which the engine is fed with pure diesel oil (D100). The experiment included the evaluation of engine performance and the determination of the content of selected substances in the exhaust gas for brake-set engine loads equal to 5 Nm, 10 Nm, 15 Nm, and 20 Nm. For each load, engine operating parameters and emissions of selected exhaust components were recorded at preset speeds in the range of 1400–2400 rpm for each engine load. The hourly fuel consumption and exhaust gas temperature were determined. The contents of CO₂, CO, and HC in the exhaust gas were measured. The consumption of D90+RF10 increased by 56%, and CO₂ emissions were 21.7% higher at low loads. The addition of sulfur-containing pyrolytic oil as an admixture to diesel oil resulted in SO_x emissions. The results show the suitability of pyrolytic oil and the possibility of using it as an admixture to fossil fuels. In order to meet SO_x emission levels in land-based installations and for vehicle propulsion, it is necessary to desulfurize fuel or desulfurize deSO_x exhaust gas systems. The CO and HC emission levels in the exhaust gases from the engine powered by the D90+RF10 fuel meet current requirements for motor vehicle exhaust composition. Full article

The aim of the article is to present the impact of blending diesel fuel with tire pyrolysis (TPO) oil on the changes in the fuel’s rheological properties and to evaluate these changes in the context of meeting legal requirements for various types of fuels. This research presents the impact of normative D100 diesel oil with TPO as an admixture on the rheological properties of the blends. Measurements are made for the content of TPO in the blend equal to 5, 7, 10, 15, and 20% m/m. In addition, the reference measurements are made for pure diesel oil and pure pyrolytic oil. Kinematic viscosity density, dynamic viscosity, viscosity index, pour point, cloud point, and cold filter plugging point are determined. The density of each sample is found at 15, 20, 30, 40, 50, 60, 70, 80, 90, and 100 °C. Viscosity is determined at the reference temperatures of 20, 40, and 100 °C, which are typically used as reference temperatures for petroleum products. Approximating models are built for all the analyzed parameters, which can be used in future studies. The fit of each model to empirical data is evaluated using the coefficient of determination R². At the same time, the individual values of the analyzed indicators are compared to the limit values specified in selected standards and regulations, thus allowing us to assess the usefulness of individual fuels in terms of compliance with effective and reliable engine operation requirements. The fuels under study fulfill the normative requirements for the parameters for marine distillate fuels for blends with a pyrolysis oil content of 0–20% m/m and the requirements for standard-grade diesel oils indicated in the Regulation of the Minister of Economy of Poland for blends with a pyrolysis oil content of 0–7% m/m. Full article

This article considers modern approaches to obtaining synthetic oil from unconventional hydrocarbon feedstocks, including plastic waste, tires, biomass, coal, and extra-heavy oil. Particular attention is paid to multi-stage technologies, such as pyrolysis, catalytic depolymerization, gasification followed by Fischer–Tropsch synthesis, and hydrocracking of heavy residues. The important role of catalysts in increasing the selectivity and economic efficiency of processes is noted: nanostructured, bifunctional, and pollution-resistant systems are increasingly used. Economic factors influencing the competitiveness of this industry are considered, including the volatility of prices for traditional oil, government support measures, and the development of waste logistics infrastructure. It is emphasized that the strengthening of the position of synthetic oil is associated with the growth of environmental requirements stimulating the recycling of plastics, tires, and biomass; at the same time, compliance with high environmental standards and transparency of emission control play a critical role in the social aspects of projects. In addition to improving the environmental situation, the development of synthetic oil contributes to the creation of jobs, the resolution of problems of shortage of classical oil fields, and the increase of energy security. It is concluded that further improvement of technologies and integration into industrial clusters can turn this sphere into a significant component of the future energy sector. Full article

This research presents the impact of diesel blends with tire pyrolysis oil (TPO) as an additive for minimizing the wear and tear of engine components. This study investigates the blends of normative diesel oil with TPO content ranging from 5% m/m to 20% m/m. Reference measurements are made for pure diesel oil (D100) and pure TPO. This investigation included an evaluation of the corrosion effect and the effect of the fuels tested on abrasive wear. For each fuel, the sulfur content, water content, lubricity (which is defined as the corrected average diameter of the wear trace during the high-frequency reciprocating rig (HFRR) test), and impurity content are determined. Impurities are assessed using indicators such as ash residue, coking residue from 10% distillation residue, determination of wear metals and contaminants, insoluble impurity content, and total sediment by hot filtration. All parameters are determined using recognized methods described in international standards. Approximation models are built for all the analyzed parameters, which can be used in future studies. At the same time, the individual values of the analyzed factors are compared with the threshold values specified in selected standards and regulations. Consequently, it is possible to assess the usefulness of individual fuels in terms of meeting the requirements for minimum wear of engine components. The results show the suitability of pyrolysis oil and the potential for its use as an additive to fossil fuels in terms of meeting most factors. Some of the fuels tested did not meet the standards for acceptable sulfur content. However, in terms of sulfur content, all of the analyzed fuels can be used to power watercraft and land-based power and thermal power plants equipped with flue gas desulphurization systems. A second indicator for not meeting the standards is the ash residue value, which indicates the high content of non-combustible, mainly metallic, substances in the pyrolysis oil used for the tests. Post-recycled oils must, therefore, undergo appropriate purification before being used as an additive to diesel fuels for internal combustion engines. Once the post-recycling oil has been subjected to desulfurization and advanced filtration, it can be used as a fuel additive for land vehicles, which fits in with closed-loop economies and sustainable development strategies. Full article

The results of testing the ignition properties of fuels in the form of blends of diesel oil with pyrolysis oil produced from tires, used as an additive at concentrations of 0, 5, 7, 10, 15, and 20% m/m, are presented in this paper. The experiment included the preparation of distillation curves and the determination of the flash points, derived cetane number, and calculated cetane ratios. The results are related to the limits indicated in selected standards and regulations on requirements for marine- and land-based compression ignition engine fuels. The obtained results show the suitability of pyrolysis oil and the possibility of its use as an additive to fossil fuels, which fits in with the requirements of the policies currently being developed for reducing the use of fossil fuels and building a circular economy. Full article

Stockpiled end-of-life tires (ELTs) pose a serious environmental concern. In the current investigation, ELT pyrolysis oil (i.e., pyro-oil) was studied as a potential additive to conventional motor oil. The pyro-oil samples were mixed in different concentrations of 10 to 50 wt.% with commercial virgin motor oil to obtain a lubricant mixture. Chemical analyses were performed for the tire-recycled derivative material, as a potential route to utilize pyro-oils, valorize ELT waste, and reduce production costs of motor oil lubricants. Rheological examinations were performed to explore the impact of the pyro-oil on the rheological properties of the motor oil under several shearing rates and temperatures. Tribological analyses of the lubricant mixtures and the pure motor oil were accomplished to study the influence of the pyro-oil additive on the tribological behavior of motor oils. Lastly, thermal stability and wettability examinations were executed to assess the thermal and wetting properties of lubricant mixtures. The obtained results showed that adding a low concentration of the pyro-oil (≤10%) will sustain the motor oil’s chemical, wettability, thermal stability, rheological, and tribological properties, signifying a viable application of recycled ELTs and helping to reduce their environmental and economic impact. These findings offer a feasible route of use in the future to obtain low-cost oils with market specifications, utilizing pyro-oil as a sustainable and environmental oil additive. Full article

This research examines the possibility of palm oil and oil palm trunk biochar (OPTB) from pyrolysis effectively serving as alternative processing oils and fillers, substituting petroleum-based counterparts in natural rubber (NR) composites. Chemical, elemental, surface and morphological analyses were used to characterize both carbon black (CB) and OPTB, by using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) gas porosimetry, and scanning electron microscopy (SEM). The influences of OPTB contents from 0 to 100 parts per hundred rubber (phr) on thermal, dielectric, dynamic mechanical, and cure characteristics, and the key mechanical properties of particulate NR-composites were investigated. OPTB enhanced the characteristics of the composites, as demonstrated by a rise in dielectric constant, thermal stability, storage modulus, glass transition temperature (T_g), hardness and modulus at 300% elongation, along with a decrease in the loss tangent (tan δ). Tear strength exhibited an increase with OPTB content up to a specific threshold, whereas tensile strength and elongation at break declined. This implies a compromise between the various mechanical properties when incorporating OPTB as a filler. This work supports the potential application of OPTB as a renewable substitute for CB in the rubber industry, particularly in tire production and other industrial rubber applications, which would also bring environmental, sustainability, and economic benefits for the palm oil-related industry. Full article

The energy crisis and environmental degradation are pressing challenges, intensified by population growth and the excessive generation of solid waste. Converting waste into energy, especially through pyrolysis, is a viable and sustainable alternative. This thermal process transforms waste such as banana peels and used tires into high-value products, such as gas, char, and bio-oil. This study aims to evaluate the production of bio-oil from the pyrolysis and co-pyrolysis of these materials, considering different proportions and temperatures, as well as using an Artificial Neural Network (ANN) to predict the composition of the bio-oils. The pyrolysis tests with 100% banana peel and 75% banana peel mixed with 25% tire showed a decrease in bio-oil yield with increasing temperature, with a drop of around 30% when comparing 500 °C to 400 °C. In contrast, co-pyrolysis with 50% of each material and 100% of the tire resulted in increases in bio-oil yield as the temperature rose. A Fourier Transform Infrared Spectroscopy (FTIR) analysis of the bio-oils showed the presence of relevant functional groups, while an elemental analysis and ANN provided accurate predictions of carbon, hydrogen, and nitrogen content. The results suggest that the co-pyrolysis of waste tires and banana peels is a viable alternative for the production of bio-oil. Full article

The continuous increase in solid waste materials, such as waste tires, underscores the critical importance of recycling them to mitigate environmental impact and promote sustainable resource management. This research study evaluated the effectiveness of utilizing waste tire pyrolysis oils (WTPOs) as recycling agents for asphalt materials. The chemical composition and thermal behavior of WTPO were analyzed using Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). Mechanically, the prepared WTPO binders were assessed by measuring dynamic viscosity and changes in high- and intermediate-temperature performance grades. Additionally, the cracking susceptibility of the binders was evaluated using the Glover-Rowe (G-R) parameter. The findings indicated that WTPOs might contain water and light aromatics in varying percentages, depending on the pyrolysis process. Incorporating WTPOs enhanced the workability of asphalt mixtures and ensured a high degree of blending between recycled/aged asphalt and raw binder. A 12% WTPO dosage was identified as the most effective for enhancing fatigue and low-temperature cracking resistance, facilitating improved interactions between the virgin binder and recycled asphalt materials. Finally, utilizing WTPOs as rejuvenating agents in pavement construction supports sustainable practices by recycling waste materials and significantly improving the performance and durability of asphalt mixtures. Full article

This research assesses the effect of carbonated pyrolysis oil (CPO) derived from scrap car tires on the metallurgical efficiency of coal flotation as a flotation additive. Using a statistical experimental design, the influence of various operational variables, including solid percent of feed pulp and dosages of reagents, i.e., CPO as an additive, diesel oil as a collector, and pine oil as a frother, on the ash content and yield of the final concentrate were investigated. Experimental data vary significantly based on operational conditions, ranging from 6.6% ash content with a 15% yield to 19.1% ash content with a 76.8% yield. The composition of the pyrolysis oil was identified by using Fourier transform infrared spectroscopy (FTIR). The analysis of variance (ANOVA) of experimental results demonstrated that almost all variables had a substantial effect on the flotation responses, positive or negative, depending on the variable or variable interaction. It was discovered that the usage of CPO intensified the total yield and ash content of concentrate in a nonlinear fashion in a range of 15% and 4%, respectively. The results revealed a non-selective interaction effect between CPO and pine oil, as well as competitive adsorption between diesel oil and CPO, which contributed to the curved behavior of flotation measurements. The detrimental effect of CPO on the flotation response of the studied coal sample was also related to the interaction of the hydrophilic groups in the CPO structure and the oxide groups of ash material in coal particles. This work shows the potential of carbonated pyrolysis oil to enhance coal flotation performance and sheds light on the underlying mechanisms. Full article

In this study, a flash pyrolysis process is developed using an entrained flow reactor for recycling of waste tires. The flash pyrolysis system is tested for process stability and reproducibility of the products under similar operating conditions when operated continuously. The study is performed with two different feedstock materials, i.e., passenger car (PCT) and truck tire (TT) granulates, to understand the influence of feedstock on the yield and properties of the pyrolysis products. The different pyrolytic products i.e., pyrolytic carbon black (pCB), oil, and pyro-gas, are analyzed, and their key properties are discussed. The potential applications for the obtained pyrolytic products are discussed. Finally, a mass and energy balance analysis has been performed for the developed pyrolysis process. The study provides insight into the governing mechanisms of the flash pyrolysis process for waste tires, which is useful to optimize the process depending on the desired applications for the pyrolysis products, and also to scale up the pyrolysis process. Full article

This research aims to delve into the intricacies of combustion processes, specifically focusing on heating oil and a blend of heating oil with Tire Pyrolysis Oil (TPO) in a self-developed evaporative combustion chamber featuring steam injection. The primary objective is to scrutinize the impact of steam injection on the combustion dynamics. Conducting a series of tests, the investigation involved the meticulous manipulation of stoichiometric ratios while introducing ambient air through gravity fuel flow. Subsequent iterations of these tests incorporated the introduction of steam into the ambient air stream. The examination encompassed the combustion of both heating oil and the TPO blend within the combustion chamber. The evaluation criteria comprised an in-depth analysis of flame characteristics, temperature distribution within the combustion chamber, and the quantification of emissions such as particulate matter (PM), nitrogen oxides (NO_x), carbon dioxide (CO₂), carbon monoxide (CO), and water vapor (H₂O). Throughout the experimentation phase, commercially available diesel fuel served as the primary fuel source. To facilitate the tests, the combustion chamber under scrutiny was seamlessly integrated into an AVL engine test bench system. Essential parameters, including fuel consumption, were meticulously gauged using an AVL 735 fuel flow meter, while fuel temperature was monitored using the AVL 745 fuel temperature conditioning system. The intake air, a crucial element in the combustion process, was quantified with precision using an AVL Flowsonix sensor. Emission measurements were conducted meticulously using state-of-the-art equipment, with gaseous emissions analyzed using an AVL FTIR AMA i60 exhaust gas analyzer. Simultaneously, soot emissions were quantified through employment of an AVL Micro Soot sensor. This comprehensive approach not only delves into the fundamental aspects of combustion but also extends its reach to the exploration of innovative techniques, such as steam injection, to enhance combustion efficiency and reduce emissions. The integration of advanced measurement tools ensures a robust and thorough analysis of the combustion process and its environmental implications. Full article

Over one billion rubber tires are disposed of worldwide annually as a major component of the solid waste stream, posing a significant environmental risk. Therefore, recycling and taking advantage of the rubber component in End-of-Life Tires (ELTs) presents an advantageous opportunity to produce environmentally friendly and cost-effective products. This work studied multiple properties of oil extracted from ELTs using thermal pyrolysis (i.e., pyro-oil) as a potential candidate for industrial lubrication applications. First, pyro-oil was characterized by studying its morphological and chemical properties. Then, rheological studies were conducted to explore the oil properties at different temperatures and shear rates. A tribometer was also used to assess pyro-oil’s tribological performance at different temperatures and speeds. Finally, wettability and thermal analyses were performed to understand the wetting and thermal stability properties. The results revealed that pyro-oil has chemical properties similar to conventional engine oil with slightly higher sulfur content. Furthermore, the pyro-oil exhibited lower viscosity and lubrication performance than conventional engine oil, but this difference was smaller at higher temperatures. Thermal stability and wetting properties of pyro-oil were found to be significantly lower than those of conventional engine oil. Based on the properties found and compared with engine oil, pyro-oil presents itself as a suitable liquid lubricant for low-speed, low-load applications operating in temperatures below 61 °C. This work presents a comprehensive study of pyro-oil properties extracted from end-of-life waste tires, offering a feasible route to obtain sustainable and low-cost products. Full article

The demand for effective asphalt additives is growing as road infrastructure ages and more sustainable pavement solutions are needed. Tire pyrolysis oil (TPO) is an example material that has been gaining attention as a potential asphalt additive. While physical performance grade (PG) temperatures are the predominant performance requirements for asphalt binders, chemical properties are also significant in the evaluation of asphalt performance. There is a need to chemically characterize the aging of asphalt binders modified with TPO and link chemical changes in binder components to binder performance. This study compares 2%, 4%, and 8% TPO and asphalt binder blends via dynamic shear rheometry (DSR), Fourier-transform infrared (FTIR) spectroscopy, and nuclear magnetic resonance (NMR) relaxometry. The variability in the modified blends was seen by both physical and chemical testing during four different blending times (1, 60, 120, and 240 min). After blending, high and intermediate PGs were determined by physical testing. The 8% TPO blend reduced the high PG of the binder from 64 °C to 58 °C. This effect was confirmed by chemical testing through changes in carbonyl indices and NMR relaxation times. With more oil present in the binder matrix, the binder’s resistance to rutting was reduced. While the high PG was hindered, the intermediate PG remained unchanged for all TPO blends. This physical similarity was mirrored in chemical testing. The chemical and physical variability along with the hindrance of the high PG temperature indicate that more treatment may be needed before TPO can be effectively applied to asphalt binders. This study suggests a correlation between physical performance and key chemical indicators. Full article