Search Results (379)

High electrostrain, excellent thermal stability, and low hysteresis are critical requirements for advanced high-precision actuators. However, simultaneously achieving these synergistic properties in lead-free ferroelectric ceramics remains a significant challenge. In this work, a targeted B-site doping strategy was employed to develop novel lead-free (0.99-x)BaTiO₃-xBaZrO₃-0.01Bi(Zn_2/3Nb_1/3)O₃ (BT-xBZ-BZN, x = 0–0.2) ceramics. Systematic investigation identified optimal Zr⁴⁺ substitution at x = 0.1, which yielded an outstanding combination of electromechanical properties. For this optimal composition, a high unipolar electrostrain (S_max = 0.11%) was achieved at 50 kV/cm, accompanied by an ultra-low hysteresis (H_S = 1.9%). Concurrently, a large electrostrictive coefficient (Q₃₃ = 0.0405 m⁴/C²) was determined, demonstrating excellent thermal robustness with less than 10% variation across a broad temperature range of 30–120 °C. This superior comprehensive performance is attributed to a composition-driven evolution from a long-range ferroelectric to a pseudocubic relaxor state. In this state, the dominant electrostrictive effect, propelled by reversible dynamics of polar nanoregions (PNRs), minimizes irreversible domain switching. These findings not only present BT-xBZ-BZN (x = 0.1) as a highly promising lead-free candidate for high-precision, low-loss actuator devices, but also provide a viable design strategy for developing high-performance electrostrictive materials with synergistic large strain and superior thermal stability. Full article

Adsorption chillers can produce chilled and desalinated water using low-grade heat, but their performance is limited by low coefficient of performance (COP) and large system mass. Enhancing heat and mass transfer in the sorbent bed is key to improving efficiency. This work introduces and systematically evaluates binder-stabilized silica gel composites as a structural and thermal enhancement strategy for adsorption chillers. Silica gel composites bonded with epoxy resin and polyvinyl alcohol (PVA) were evaluated for adsorption chiller applications. Thermal stability, conductivity, microstructure, equilibrium sorption, and sorption hysteresis were assessed. The results indicate that PVA-based composites were thermally unstable and discarded, whereas epoxy-bonded silica gel showed high thermal stability and mechanically robust granules with preserved pore connectivity. The epoxy composite exhibited 109% higher thermal conductivity than loose silica gel, improving internal heat transfer. This improvement is accompanied by a reduction in sorption capacity of approximately 58%, attributable to the inert resin fraction. Notably, the composite exhibits a reduced and locally negative sorption hysteresis, indicating facilitated desorption and lowered internal diffusion resistance. The epoxy-bonded silica gel therefore provides a promising combination of thermal stability, improved heat transfer, and enhanced sorption–desorption behaviour, supporting its potential to increase the efficiency of next-generation adsorption chillers. Full article

Viscoelastic polyurethane foams were prepared using four different bio-based polyols derived from coconut oil (CO), palm oil (PO), duck fat (DF), and pork fat (PF), employing up to 20 wt.% of the polyol component in a conventional formulation. The introduction of bio-polyols into the polyurethane formulation gave rise to an early minor decomposition of modified foams at low temperatures; however, the overall thermal stability improved slightly by the elimination of some intermediate decomposition stages. The glass transition temperature of foams was only moderately influenced and remained in the typical temperature range (around 10 °C). The effect of biopolyol type and content (5–20 wt.%) on the mechanical properties of the foams was investigated over the temperature range −20 to 40 °C. At 20 and 40 °C, all foams exhibited comfortable viscoelastic properties suitable for furniture applications. Hysteresis and the damping behavior of foams were also influenced by biopolyol type and concentration, with CO and DF providing enhanced energy absorption. Overall, these bio-based foams demonstrate potential for eco-friendly, high-performance applications, although their use at temperatures below 10 °C may be limited by increased stiffness. Full article

Underground hydrogen storage (UHS) in saline aquifers offers a viable alternative to surface-based storage systems, which are limited by capacity constraints, high operational pressures, complex thermal regulation, low energy densities, and potential safety hazards. This study uses a fully compositional reservoir simulation model to evaluate hydrogen behavior in the Mt. Simon Sandstone in the Illinois Basin. The analysis focuses on the effects of hysteresis, solubility, diffusivity, and production well perforation location on recovery efficiency. Cyclic injection and withdrawal scenarios were simulated to assess storage performance and operational strategies. The results show that accounting for hydrogen diffusivity shows essentially unchanged withdrawal efficiency at 79%, the same as the base case. Solubility causes a slight decrease to 78%, while hysteresis leads to a more significant reduction to 63%. The location of injection well perforations also influences recovery: top-perforated wells increase efficiency from 60% after the first cycle to 74% after six cycles, whereas bottom-perforated injection wells increase efficiency from 56% to 79% over the same period. These findings emphasize the importance of accounting for multiphase flow dynamics and strategic well placement in optimizing UHS system performance. The insights contribute to advancing reliable, large-scale hydrogen storage solutions essential for supporting renewable energy integration and long-term energy security. Full article

(1) Background: This study presents an adaptive, contactless, and privacy-preserving respiratory-rate monitoring system based on thermal imaging, designed for real-time operation on embedded edge hardware. The system continuously processes temperature data from a compact thermal camera without external computation, enabling practical deployment for home or clinical vital-sign monitoring. (2) Methods: Thermal frames are captured using a $256\times 192$ TOPDON TC001 camera and processed entirely on an NVIDIA Jetson Orin Nano. A YOLO-based detector localizes the nostril region in every even frame (stride = 2) to reduce the computation load, while a Kalman filter predicts the ROI position on skipped frames to maintain spatial continuity and suppress motion jitter. From the stabilized ROI, a temperature-based breathing signal is extracted and analyzed through an adaptive median–MAD hysteresis algorithm that dynamically adjusts to signal amplitude and noise variations for breathing phase detection. Respiratory rate ($RR$) is computed from inter-breath intervals (IBI) validated within physiological constraints. (3) Results: Ten healthy subjects participated in six experimental conditions including resting, paced breathing, speech, off-axis yaw, posture (supine), and distance variations up to 2.0 m. Across these conditions, the system attained a MAE of $0.57\pm 0.36$ BPM and an RMSE of $0.64\pm 0.42$ BPM, demonstrating stable accuracy under motion and thermal drift. Compared with peak-based and FFT spectral baselines, the proposed method reduced errors by a large margin across all conditions. (4) Conclusions: The findings confirm that accurate and robust respiratory-rate estimation can be achieved using a low-resolution thermal sensor running entirely on an embedded edge device. The combination of YOLO-based nostril detector, Kalman ROI prediction, and adaptive MAD–hysteresis phase that self-adjusts to signal variability provides a compact, efficient, and privacy-preserving solution for non-invasive vital-sign monitoring in real-world environments. Full article

Ultra-soft injectable hydrogels are paramount in biomedical applications such as tissue fillers, drug depots, and tissue regeneration scaffolds. Synthetic approaches relying on linear polymers are confronted by the necessity for significant dilution of polymer solutions to reduce chain entanglements. Bottlebrush polymers offer an alternative approach due to suppressed chain overlap and entanglements, which facilitates lower solution viscosities and increased gel softness. Leveraging the bottlebrush architecture in linear-bottlebrush-linear (LBL) block copolymer systems, where L is a thermosensitive linear poly(N-isopropylacrylamide) block, and B is a hydrophilic polyethylene glycol brush block, injectable hydrogels were designed to mimic tissues as soft as the extracellular matrix at high polymer concentrations. Compared to an analogous system with shorter brush side chains, increasing the side chain length enables a decrease in modulus by up to two orders of magnitude within 1–100 Pa at 20 wt% polymer concentrations, near to the physiological water content of ~70%. This system further exhibits thermal hysteresis, enabling stability with inherent body temperature fluctuations. The observed features are ascribed to kinetically hindered network formation by bulky macromolecules. Full article

This paper presents a proof-of-concept for a natural-language-based closed-loop controller that regulates the temperature of a simple single-input single-output (SISO) thermal process. The key idea is to express a relay-with-hysteresis policy in plain English and let a local large language model (LLM) interpret sensor readings and output a binary actuation command at each sampling step. Beyond interface convenience, we demonstrate that natural language can serve as a valid medium for modeling physical reality and executing deterministic reasoning in control loops. We implement a compact plant model and compare two controllers: a conventional coded relay and an LLM-driven controller prompted with the same logic and constrained to a single-token output. The workflow integrates schema validation, retries, and a safe fallback, while a stepwise evaluator checks agreement with the baseline. In a long-horizon (1000-step) simulation, the language controller reproduces the hysteresis behavior with matching switching patterns. Furthermore, sensitivity and ablation studies demonstrate the system’s robustness to measurement noise and the LLM’s ability to correctly execute the hysteresis policy, thereby preserving the theoretical robustness inherent to this control law. This work demonstrates that, for slow thermal dynamics, natural-language policies can achieve comparable performance to classical relay systems while providing a transparent, human-readable interface and facilitating rapid iteration. Full article

Accurate suction control underpins thermo-hydro-mechanical (THM) characterization of unsaturated soils, yet conventional polyethylene-glycol (PEG) osmotic methods suffer from membrane degradation, polymer intrusion, and marked temperature sensitivity. This study evaluates a potassium-neutralized poly (acrylamide-co-acrylic acid) hydrogel (PP) as a high-suction osmotic medium for water-retention testing of compacted kaolin using a sealed cell with a grade-42 filter paper separator (no semi-permeable membrane). The water-activity–suction relation of PP was calibrated with a chilled-mirror hygrometer (WP4C) over the high-suction domain, and temperature effects were assessed between 20–30 °C. The PP imposed stable target suctions across the practical engineering range, with cross-validation to WP4C of R² ≈ 0.985 and RMSE ≈ 0.09 MPa, and exhibited modest thermal sensitivity (~2–3% per 10 °C). Mass–time records showed a two-regime equilibration (rapid first-day moisture loss then slowing to asymptote), with time to 95% equilibrium t₉₅ ≈ 3–7 days depending on suction, and equilibrium within ~2 weeks under a normalized mass change, ${\displaystyle \frac{1}{m}}\left|{\displaystyle \frac{∆m}{∆t}}\right|<{\displaystyle \frac{0.1\%}{24h}}$ criterion. The resulting kaolin water-retention curves are smooth soil moisture factor (SMF) reproducible, and exhibited minor wetting–drying hysteresis (~20–25% gap at matched suctions). Collectively, the results indicate that PP provides a practical, membrane-free (in the semi-permeable sense) and accurate means to control high-range suction for unsaturated soil testing, showing only modest suction variations within the tested 20–30 °C range, while mitigating long-standing PEG limitations and simplifying laboratory workflows. Full article

Tailoring the spin crossover (SCO) effect in molecular materials remains a fundamental challenge, driven by the need to control critical parameters, such as the spin transition temperature (T₁/₂), hysteresis width, cooperativity, and switching kinetics for applications in sensing, memory, and actuation devices. SCO behavior is highly sensitive to small changes in the structure or crystal structure of the surrounding environment. In this context, achieving predictable and reproducible control remains elusive. Embedding SCO complexes into polymer matrices offers a more versatile and processable approach, but understanding how matrix–guest interactions affect spin-state behavior is still limited. In this study, we investigate a polymer-mediated strategy to tune SCO properties by incorporating the well-characterized Fe(II) complex [Fe(1,10-phenanthroline)₂(NCS)₂] into three polymers with distinct structural features: polylactic acid (PLA), polystyrene (PS), and polysulfone (PSF). In terms of potential electrostatic interaction between the complex and the polymeric matrixes, the polymers offer distinct features. Either there does not seem to be any specific interaction (PLA case) or, rather, there is π-π stacking between the aromatic rings of the SCO complex, and the corresponding ones present either in the backbone or in the side chain of the polymer (PSF and PS, respectively). The latter can potentially influence spin-state energetics and dynamics. Importantly, we also reveal and quantify the migration behavior of SCO particles within different polymer matrices, an aspect that has not been previously examined in SCO–polymer systems. Using magnetic susceptibility, spectroscopic, diffraction, and migration studies, we show that the polymer environment, PLA as well, actively modulates the SCO response. PSF yields lower T₁/₂, slower switching kinetics, and enhanced retention of the complex, indicative of strong matrix confinement and interaction. In contrast, PLA and PS composites exhibit sharper transitions and higher migration, suggesting weaker interactions and greater mobility. In addition, the semi-crystalline nature of PLA seems to induce the extension of the hysteresis width. These results highlight both the challenge and the opportunity in SCO polymer composites to tune SCO behavior, offering a scalable route toward functional hybrid materials for thermal sensing and responsive devices. Full article

The temperature–frequency dependence of dielectric permittivity in Na_0.5Bi_0.5TiO₃ (NBT) -based compositions displays a diffused, frequency-independent maximum along with a frequency-dependent shoulder below this maximum. This behavior deviates from that of both classical ferroelectrics and conventional relaxor ferroelectrics, and its interpretation is further complicated by challenges in linking it to known structural phase transitions. This study proposes a new interpretation of the dielectric behavior of NBT-based materials through a comparative analysis of temperature–frequency permittivity data in both unpoled and poled NBT samples and 0.95Na_0.5Bi_0.5TiO₃–0.05CaTiO₃ solid solution over a broad frequency range (10 Hz–100 MHz). Results reveal that the steep permittivity change between the maximum and shoulder—accompanied by pronounced thermal hysteresis—can be attributed to a phase transition between two non-ferroelectric phases. When this contribution is excluded, the dielectric response aligns with classical relaxor ferroelectric behavior. To reconcile this with other known properties of NBT, the “breathing” model is employed, offering a unified framework for understanding its relaxor-like characteristics. Full article

An increase in the temperature of the magnetic core causes narrowing of its hysteresis loop and reduction in the saturation magnetic flux density. Therefore, at the same operating point on the magnetization characteristic, the nonlinear effect may become stronger. In the case of the inductive current transformers, this may result in change in their transformation accuracy and increased self-generation of the low-order higher harmonics to the secondary current. Consequently, the equivalent methods used to determine their values of current error and phase displacement without operating conditions resulting from the presence of the secondary current provide less reliable results, which is particularly important for inductive current transformers with high transformation accuracy requirements and may also be significant in certain borderline cases when determining its accuracy class and the value of error is close to the limit. However, ambient temperature does not affect the transformation accuracy of conventional inductive current transformers, as their internal operating temperature is solely driven by the relatively high RMS values of the rated secondary current (1 A or 5 A) and the large number of secondary winding turns evenly distributed over the magnetic core. During thermal testing of a current transducer operating in a closed-loop feedback configuration with a Hall sensor, a deterioration of its conversion accuracy was observed at high ambient temperatures. This was caused primarily by the thermal expansion of the magnetic core, which leads to a change in the dimensions of the air gap where the Hall sensor is placed, and thus also to a change in the electrical parameters of the feedback loop circuit. Full article

Hydroxy-functional poly(propenyl ether)s are promising thermoresponsive materials; here we establish a controlled synthesis via living cationic polymerization of silyl-protected monomers. Among the silyl protecting groups examined, only tert-butyldiphenylsilyl (TBDPS) enabled living cationic polymerization. The living cationic polymerization of tert-butyldiphenylsiloxybutyl propenyl ether (TBDPSBPE) afforded a high-molecular-weight polymer (poly(TBDPSBPE)) with a narrow molecular weight distribution (M_n = 12,900; M_w/M_n = 1.22). Additionally, chain propagation continued in monomer addition experiments, and the molecular weight increased further with a narrow molecular weight distribution, confirming the success of living cationic polymerization. Poly(TBDPSBPE) was successfully desilylated to afford poly(HBPE) with a narrow molecular weight distribution. Poly(HBPE) exhibited a glass transition temperature (T_g) of 44 °C, 82 °C higher than that of the corresponding polymer without β-methyl groups, poly(HBVE). The enhanced thermal properties of poly(HBPE) were attributed to the steric hindrance of the β-methyl group, which fixes the position of the hydroxy group and allows stronger hydrogen bonding. To investigate the aqueous thermoresponse, a hydroxylated analog with a shorter side-chain spacer (poly(HPPE)) was synthesized, and poly(HPPE) exhibited lower critical solution temperature (LCST)-type phase separation in water with a cloud-point temperature (T_cp) of 6 °C, showing reversible transitions with thermal hysteresis. Full article

Temperature excursions during refrigerated transport strongly affect the quality and shelf life of perishable food, yet reproducing realistic, time-varying cold-chain temperature histories in the laboratory remains challenging. In this study, we present a compact, portable climate chamber driven by Peltier modules and an identification-guided control architecture designed to reproduce real refrigerated-truck temperature histories with high fidelity. Control is implemented as a cascaded regulator: an outer two-degree-of-freedom PID for air-temperature tracking and faster inner PID loops for module-face regulation, enhanced with derivative filtering, anti-windup back-calculation, a Smith predictor, and hysteresis-based bumpless switching to manage dead time and polarity reversals. The system integrates distributed temperature and humidity sensors to provide real-time feedback for precise thermal control, enabling accurate reproduction of cold-chain conditions. Validation comprised two independent 36-day reproductions of field traces and a focused 24-h comparison against traditional control baselines. Over the long trials, the chamber achieved very low long-run errors ($\mathrm{MAE}\cong 0.19 °\mathrm{C}$, $\mathrm{MedAE}\cong 0.10 °\mathrm{C}$, $\mathrm{RMSE}\cong 0.33 °\mathrm{C}$, $R^2=0.9985$). The 24-h test demonstrated that our optimized controller tracked the reference, improving both transient and steady-state behaviour. The system tolerated realistic humidity transients without loss of closed-loop performance. This portable platform functions as a reproducible physical twin for cold-chain experiments and a reliable data source for training predictive shelf-life and digital-twin models to reduce food waste. Full article

This study investigates the control of the phase-structural state in Ni–45Ti–xCu (x = 5, 7 at.%) shape memory alloys fabricated via a shortened powder metallurgy route: mechanical activation → spark plasma sintering (SPS) → heat treatment. Compact samples were produced from mechanically alloyed powders (650–750 rpm, up to 5 h) and sintered at 900 °C. The structure and microstructure were characterized using X-ray diffraction (to identify B2/B19′/Ni₄Ti₃ phases and assess ordering) and SEM–BSE/EDS (to analyze morphology, porosity, and Ni-rich precipitates). Two post-processing treatments were applied: single-stage annealing (500 °C, 2 h) and a three-stage treatment (900 °C/30 min → water quenching → 300 °C/20 min). Mechanical alloying transformed the initial elemental powder mixture (fcc-Ni, hcp-Ti, fcc-Cu) into a supersaturated fcc-(Ni, Cu, Ti) solid solution with emerging NiTi phases, with a minimum particle size achieved after ~300 min at 750 rpm. SPS compaction yielded a high-density matrix consisting predominantly of the B2 phase. Single-stage annealing preserved B19′ martensite and Ni₄Ti₃ precipitates, particularly in the 5 at.% Cu alloy. In contrast, the three-stage treatment dissolved the Ni₄Ti₃ precipitates, suppressed the formation of B19′ and R phases, and stabilized a highly ordered B2 matrix. Increasing the Cu content from 5 to 7 at.% significantly enhanced the B2 phase fraction, reduced secondary nickel-rich phases, and improved structural homogeneity, evidenced by a continuous neck network and closed porosity. The optimized condition—7 at.% Cu combined with the three-stage annealing—produced a microstructure with >95% B2 phase, <1% Ni₄Ti₃, and ~98% relative density. This forms the prerequisite microstructural state for a narrow transformation hysteresis and high functional cyclic stability. Full article

This paper discusses the magnetic properties of Fe-Nb-B-RE (RE = Tb, Tb/Y, Tb/Nd) melt-spun ribbons. Samples were obtained using a typical melt-spinning technique. The dominant amorphous state was confirmed by XRD and thermomagnetic measurements. It was shown that the alloying additions of the RE elements used introduce magnetic anisotropy into amorphous Fe-based structures. This fact was confirmed by magnetic hysteresis loops as well as Kerr microscopy observations. Moreover, increasing Tb content leads to the appearance of a “two-step” reverse magnetization curve. The mean field theory analysis revealed that Tb addition reduces the exchange interaction between the Fe-Fe magnetic moments. The applied thermal treatment caused partial crystallization and the formation of hard magnetic phases with ultra-high coercivity. Full article