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Keywords = the pressure of arc gas

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23 pages, 6098 KiB  
Article
Performance Optimization of Stacked Weld in Hydrogen Production Reactor Based on Response Surface Methodology–Genetic Algorithm
by Yu Liu, Hongtao Gu, Jincheng Zhang, Zhiyi Leng, Ziguang Wang and Shengfang Zhang
Coatings 2025, 15(8), 889; https://doi.org/10.3390/coatings15080889 (registering DOI) - 31 Jul 2025
Viewed by 286
Abstract
To address the issues of hydrogen embrittlement, creep, and fatigue that commonly occur in the welds of hydrogen production reactor operating under hydrogen exposure, high temperature and high pressure, this study proposes adding Si and Mo as reinforcing elements to the welding materials [...] Read more.
To address the issues of hydrogen embrittlement, creep, and fatigue that commonly occur in the welds of hydrogen production reactor operating under hydrogen exposure, high temperature and high pressure, this study proposes adding Si and Mo as reinforcing elements to the welding materials to enhance weld performance. Given the varying performance requirements of different weld layers in the stacked weld, a gradient performance optimization method for the stacked weld of hydrogen production reactors based on the response surface methodology (RSM)–genetic algorithm (GA) is proposed. Using tensile strength, the hydrogen embrittlement sensitivity index, fatigue strain strength, creep rate and weld performance evaluation indices, a high-precision regression model for Si and Mo contents and weld performance indices was established through RSM and analysis of variance (ANOVA). A multi-objective optimization mathematical model for gradient improvement of the stacked weld was also established. This model was solved using a GA to obtain the optimal element content combination added to the welding wire and the optimal weld thickness for each weld layer. Finally, submerged arc welding experiments of the stacked weld were conducted according to the optimization results. The results show that the tensile strength of the base layer, filling layer and cover layer of the stacked weld increased by 5.60%, 6.16% and 4.53%, respectively. Hydrogen embrittlement resistance increased by 70.56%, 52.40% and 45.16%, respectively. The fatigue and creep resistance were also improved. The experimental results validate the feasibility and accuracy of the proposed optimization method. Full article
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29 pages, 8216 KiB  
Article
Research on the Diaphragm Movement Characteristics and Cavity Profile Optimization of a Dual-Stage Diaphragm Compressor for Hydrogen Refueling Applications
by Chongzhou Sun, Zhilong He, Dantong Li, Xiaoqian Chen, Jie Tang, Manguo Yan and Xiangjie Kang
Appl. Sci. 2025, 15(15), 8353; https://doi.org/10.3390/app15158353 - 27 Jul 2025
Viewed by 305
Abstract
The large-scale utilization of hydrogen energy is currently hindered by challenges in low-cost production, storage, and transportation. This study focused on investigating the impact of the diaphragm cavity profile on the movement behavior and stress distribution of a dual-stage diaphragm compressor. Firstly, an [...] Read more.
The large-scale utilization of hydrogen energy is currently hindered by challenges in low-cost production, storage, and transportation. This study focused on investigating the impact of the diaphragm cavity profile on the movement behavior and stress distribution of a dual-stage diaphragm compressor. Firstly, an experimental platform was established to test the gas mass flowrate and fluid pressures under various preset conditions. Secondly, a simulation path integrating the finite element method simulation, theoretical stress model, and movement model was developed and experimentally validated to analyze the diaphragm stress distribution and deformation characteristics. Finally, comparative optimization analyses were conducted on different types of diaphragm cavity profiles. The results indicated that the driving pressure differences at the top dead center position reached 85.58 kPa for the first-stage diaphragm and 75.49 kPa for the second-stage diaphragm. Under experimental conditions of 1.6 MPa suction pressure, 8 MPa second-stage discharge pressure, and 200 rpm rotational speed, the first-stage and second-stage diaphragms reached the maximum center deflections of 4.14 mm and 2.53 mm, respectively, at the bottom dead center position. Moreover, the cavity profile optimization analysis indicated that the double-arc profile (DAP) achieved better cavity volume and diaphragm stress characteristics. The first-stage diaphragm within the optimized DAP-type cavity exhibited 173.95 MPa maximum principal stress with a swept volume of 0.001129 m3, whereas the second-stage optimized configuration reached 172.57 MPa stress with a swept volume of 0.0003835 m3. This research offers valuable insights for enhancing the reliability and performance of diaphragm compressors. Full article
(This article belongs to the Section Mechanical Engineering)
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21 pages, 3490 KiB  
Article
Energy-Efficient CO2 Conversion for Carbon Utilization Using a Gliding Arc/Glow Discharge with Magnetic Field Acceleration—Optimization and Characterization
by Svetlana Lazarova, Snejana Iordanova, Stanimir Kolev, Veselin Vasilev and Tsvetelina Paunska
Energies 2025, 18(14), 3816; https://doi.org/10.3390/en18143816 - 17 Jul 2025
Viewed by 310
Abstract
The dry conversion of CO2 into CO and O2 provides an attractive path for CO2 utilization which allows for the use of the CO produced for the synthesis of valuable hydrocarbons. In the following work, the CO2 conversion is [...] Read more.
The dry conversion of CO2 into CO and O2 provides an attractive path for CO2 utilization which allows for the use of the CO produced for the synthesis of valuable hydrocarbons. In the following work, the CO2 conversion is driven by an arc discharge at atmospheric pressure, producing hot plasma. This study presents a series of experiments aiming to optimize the process. The results obtained include the energy efficiency and the conversion rate of the process, as well as the electrical parameters of the discharge (current and voltage signals). In addition, optical emission spectroscopy diagnostics based on an analysis of C2’s Swan bands are used to determine the gas temperature in the discharge. The data is analyzed according to several aspects—an analysis of the arc’s motion based on the electrical signals; an analysis of the effect of the gas flow and the discharge current on the discharge performance for CO2 conversion; and an analysis of the vibrational and rotational temperatures of the arc channel. The results show significant improvements over previous studies. Relatively high gas conversion and energy efficiency are achieved due to the arc acceleration caused by the Lorentz force. The rotational (gas) temperatures are in the order of 5500–6000 K. Full article
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18 pages, 1801 KiB  
Article
MaxEnt Modeling of the Impacts of Human Activities and Climate Change on the Potential Distribution of Plantago in China
by Da Liao, Bing Zhou, Haiyan Xiao, Yuxin Zhang, Shujian Zhang, Qitao Su and Xiaohong Yan
Biology 2025, 14(5), 564; https://doi.org/10.3390/biology14050564 - 17 May 2025
Viewed by 642
Abstract
Human activities exert both beneficial and detrimental impacts on the ecosystem. In recent years, greenhouse gas emissions have significantly increased due to global climate change, causing profound alterations in ecosystem distribution and productivity. The synergistic interplay between climatic shifts and anthropogenic activities is [...] Read more.
Human activities exert both beneficial and detrimental impacts on the ecosystem. In recent years, greenhouse gas emissions have significantly increased due to global climate change, causing profound alterations in ecosystem distribution and productivity. The synergistic interplay between climatic shifts and anthropogenic activities is intensifying ecological transformations and disturbances, and accelerating biodiversity depletion. The Plantago genus (Plantaginaceae family) includes 14 herbaceous species among China’s flora. This study was conducted to elucidate the spatial distribution of Plantago species patterns across China and evaluate their differential responses to impending climate change and human interventions. In this study, we projected the potential distributions of Plantago species under three climate scenarios (SSP126, SSP245, and SSP585) across current and future temporal intervals (2021–2040, 2041–2060, 2061–2080, and 2081–2100) using the MaxEnt model integrated with ArcGIS V10.8 spatial analysis. A spatial trend analyses was also conducted to assess habitat suitability dynamics by incorporating anthropogenic influence parameters. The model validation yielded AUC values exceeding 0.9, demonstrating excellent model performance and predictive reliability. Precipitation variability and anthropogenic pressure emerged as the most predominant determinants shaping Plantago distributions. Centroid migration analyses further indicated the progressive northward displacement of optimal habitats under the projected climate scenarios. These findings significantly advance our understanding of Plantago species’ adaptive responses to environmental changes. This study also offers an invaluable scientific foundation for sustainable resource management and ecological conservation strategies. Full article
(This article belongs to the Section Ecology)
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20 pages, 7306 KiB  
Article
Shape Optimization of the Triangular Vortex Flowmeter Based on the LBM Method
by Qiji Sun, Chenxi Xu, Xuan Zou, Wei Guan, Xiao Liu, Xu Yang and Ao Ren
Symmetry 2025, 17(4), 534; https://doi.org/10.3390/sym17040534 - 31 Mar 2025
Viewed by 266
Abstract
In this paper, the D3Q19 multiple-relaxation-time (MRT) lattice Boltzmann method (LBM) for large eddy simulation (LES) was employed to optimize the shape of the vortex generator in a triangular vortex flowmeter. The optimization process focused on the vortex shedding frequency, lift force per [...] Read more.
In this paper, the D3Q19 multiple-relaxation-time (MRT) lattice Boltzmann method (LBM) for large eddy simulation (LES) was employed to optimize the shape of the vortex generator in a triangular vortex flowmeter. The optimization process focused on the vortex shedding frequency, lift force per unit area, and symmetry of the vortex street. The optimal shape of the vortex generator was determined to feature a 180° incoming flow surface, a concave arc side with a curvature radius of 25 mm, and a fillet radius of 4 mm at the end. Numerical simulations revealed that the optimized vortex generator achieves a 2.72~13.8% increase in vortex shedding frequency and a 17.2~53.9% reduction in pressure drop and can adapt to the flow conditions of productivity fluctuations (6.498 × 105 ≤ Re ≤ 22.597 × 105) in the gas well production. The results demonstrated significant advantages, including low pressure loss, minimal secondary vortex generation, high vortex shedding frequency, and substantial lift force. These findings underscore the robustness and efficiency of the LBM-LES method in simulating complex flow dynamics and optimizing vortex generator designs. Full article
(This article belongs to the Section Engineering and Materials)
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19 pages, 10969 KiB  
Article
Heat Shield Properties of Lightweight Ablator Series for Transfer Vehicle Systems with Different Laminated Structures Under High Enthalpy Flow Environments
by Masayuki Ohkage, Kei-ichi Okuyama, Soichiro Hori and Tsumugi Ishida
Aerospace 2025, 12(4), 281; https://doi.org/10.3390/aerospace12040281 - 27 Mar 2025
Viewed by 743
Abstract
The thermal protection system of a re-entry vehicle requires a high-heat-resistant heat shield to protect the spacecraft. Most of the ablative materials developed so far have high heat resistance but have technical issues such as long production times. In this study, we propose [...] Read more.
The thermal protection system of a re-entry vehicle requires a high-heat-resistant heat shield to protect the spacecraft. Most of the ablative materials developed so far have high heat resistance but have technical issues such as long production times. In this study, we propose a new ablative material (LATS/PEEK) consisting of PEEK and carbon felt as a material that can solve these problems. PEEK has excellent properties such as a short production time and its ability to be produced using 3D printer technology. In addition, PEEK can be molded with a variety of fusion bonding methods, so it is possible to mold the heat shield and structural components as a single structure. However, heating tests conducted in previous research have confirmed the expansion phenomenon of CF/PEEK produced by 3D printers. The expansion of the ablative material is undesirable because it changes the aerodynamic characteristics during re-entry flight. Therefore, the purpose of this research is to clarify the mechanism of the expansion phenomenon of the ablative material based on PEEK resin. Therefore, we conducted thermal gravimetric analysis (TGA) and thermomechanical analysis (TMA) and concluded that the expansion phenomenon during the heating test was caused by the pressure increase inside the ablative material due to pyrolysis gas. Based on this mechanism, we developed a new 3D LATS/PEEK with a structure that can actively release pyrolysis gas, and we conducted a heating test using an arc-heating wind tunnel. As a result, it was found that 3D LATS/PEEK had less expansion and deformation during the heating test than CF/PEEK manufactured using a 3D printer. Full article
(This article belongs to the Section Astronautics & Space Science)
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14 pages, 2198 KiB  
Article
Online Calibration Strategy for SF6 Gas Density Relay Based on Weighing Pressure Measurement
by Wenjuan Dong, Xingang Wang, Yuwei Wang, Changao Ji and Chunwei Song
Electronics 2025, 14(6), 1216; https://doi.org/10.3390/electronics14061216 - 20 Mar 2025
Cited by 1 | Viewed by 391
Abstract
SF6 gas has high electrical insulation strength and excellent arc-extinguishing properties, making it widely used in high-voltage equipment. However, gas leakage or liquefaction can reduce its performance, necessitating density monitoring. This paper presents an online calibration device based on balance pressure measurement [...] Read more.
SF6 gas has high electrical insulation strength and excellent arc-extinguishing properties, making it widely used in high-voltage equipment. However, gas leakage or liquefaction can reduce its performance, necessitating density monitoring. This paper presents an online calibration device based on balance pressure measurement and outlines the calibration process. It also analyzes the impact of factors such as the measuring balance, gravitational acceleration, cylinder friction, and installation alignment on calibration accuracy. To address uncertainty in the stabilization time of the cylinder gas temperature, a simulation model was created to observe the temperature equilibrium. Furthermore, power consumption analysis of the test device was conducted under different calibration cycles. The experimental results confirm the effectiveness of this calibration strategy. Full article
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10 pages, 699 KiB  
Article
Method for Removing Impurities by Treating Silicon Tetrachloride with Hydrogen Plasma
by Roman Kornev, Georgy Mochalov, Nikita Maleev, Sergei Romanov, Konstantin Kornev and Alexandra Kalinina
Inorganics 2025, 13(3), 80; https://doi.org/10.3390/inorganics13030080 - 10 Mar 2025
Viewed by 942
Abstract
The transformation of organochlorine and organic impurities such as CCl4, C2H2Cl2, C2HCl3, C2Cl4, C2H2Cl4, CH4, C3H8 [...] Read more.
The transformation of organochlorine and organic impurities such as CCl4, C2H2Cl2, C2HCl3, C2Cl4, C2H2Cl4, CH4, C3H8, C4H10, and C6H6 in the content range of 10−2–10−6 wt.%, as well as BCl3 impurities at the level of 3 × 10−2 wt.%, was considered. A method has been developed for removing limiting impurities of carbon and boron during the process of the hydrogen reduction of silicon tetrachloride in a high-frequency arc gas discharge at atmospheric pressure. The thermodynamic and gas-dynamic analyses of the reduction process of silicon tetrachloride in hydrogen plasma, along with the behavior of organochlorine impurities, organic substances, and boron trichloride, was conducted. These analyses suggest that under equilibrium conditions, the conversion reactions of impurities result in the formation of silicon carbide and boron silicide. Potential chemical reactions for the conversion of the studied impurities into silicon carbide and boron silicide have been proposed. A new potential for plasma chemical processes has been identified, enabling the effective purification of chlorosilanes from both limiting and limited impurities. The results demonstrate the possibility of significantly reducing the concentrations of organochlorine and organic impurities, as well as boron trichloride, during the reduction of silicon tetrachloride in hydrogen plasma. The maximum conversion rates achieved included 99% for the organochlorine impurity CCl4 to silicon carbide, 91% for benzene impurity to silicon carbide, and 86% for boron trichloride to boron silicide. Full article
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23 pages, 11470 KiB  
Article
Working Characteristics of the Scroll Expander for Residual Pressure Recovery in Microscale Gas Pipeline Networks
by Yanqin Mao, Liang Cai, Roman Chertovskih, Jiahong Ji and Shen Su
Machines 2025, 13(3), 196; https://doi.org/10.3390/machines13030196 - 28 Feb 2025
Viewed by 528
Abstract
A widespread distribution of gas-regulating stations creates challenges in energy recovery during pressure reduction. This study employs a scroll expander as a central mechanism to enhance the efficiency of residual gas pressure recovery, demonstrating its adaptability. We conducted experimental tests on its power [...] Read more.
A widespread distribution of gas-regulating stations creates challenges in energy recovery during pressure reduction. This study employs a scroll expander as a central mechanism to enhance the efficiency of residual gas pressure recovery, demonstrating its adaptability. We conducted experimental tests on its power generation capabilities and numerically studied the expansion characteristics. Our results indicate significant improvements as the inlet pressure was increased from 85 kPa to 375 kPa: the generator speed increased from 1238 rpm to 4615 rpm, the power output increased from 9.64 W to 165.48 W, and the temperature difference between the inlet and outlet flows changed from 5.41 K to 27.3 K. Turbulent dissipative and wall friction were identified as primary contributors to the energy loss, overcoming the temperature and viscosity loss, and increasing together with the radial and axial clearances. A comparative analysis of scroll designs reveals that the scrolls modified with higher order and arc curves display a reduced torque compared with the traditional circular involutes, and more scrolls are beneficial for handling high-pressure gas. These findings offer insights into scroll expander design, enhancing the energy efficiency of microscale gas residual pressure recovery systems. Full article
(This article belongs to the Section Electromechanical Energy Conversion Systems)
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21 pages, 15002 KiB  
Article
Photographic Analysis of a Low-Current, Vacuum Electric Arc Using an Ultrafast Camera
by Michał Lech and Paweł Węgierek
Materials 2025, 18(3), 693; https://doi.org/10.3390/ma18030693 - 5 Feb 2025
Viewed by 736
Abstract
The main component of vacuum interrupters responsible for ensuring the correct flow of current is the contact system. In a vacuum environment, due to the higher values of the mean free path of electrons and particles in the contact gap, the material and [...] Read more.
The main component of vacuum interrupters responsible for ensuring the correct flow of current is the contact system. In a vacuum environment, due to the higher values of the mean free path of electrons and particles in the contact gap, the material and condition of the contacts exert the greatest influence on the development of the arc discharge. To accurately analyze the phenomenon of discharge development in vacuum insulating systems, the authors conducted a time-lapse photographic analysis of a vacuum electric arc. For this purpose, they used a test setup comprising a discharge chamber, a vacuum pump set, a power and load assembly, an ultra-high-speed camera, and an oscilloscope with dedicated probes. The measurement process involved connecting the system, determining the power supply, load, and measurement parameters and subsequently performing contact opening operations while simultaneously recording the process using the oscilloscope and ultra-high-speed camera. An analysis of a low-current vacuum arc in a residual helium gas environment, with a pressure of p = 1.00 × 101 Pa was carried out. Different phases of vacuum arc burning between electrodes in the discharge chamber were identified. In the stable phase, the arc voltage remained constant, while in the unstable phase, the arc voltage increased. The results of the time-lapse analysis were compared with the characteristics recorded by the oscilloscope, revealing a correlation between the increase in vacuum arc voltage and the intensity of flashes in the interelectrode space. The movement of microparticles ejected from the surface of the contacts—either reflecting or adhering to one of the electrodes—was observed. This analysis provides a deeper understanding of the processes involved in discharge formation and development under reduced pressure conditions. Understanding these mechanisms can support the design of vacuum interrupters, particularly in the selection of suitable contact materials and shapes. Full article
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14 pages, 11889 KiB  
Article
Thermal Propagation Test Bench for the Study of the Paschen Curve and Lightning Arcs of Venting Gas
by Björn Mulder, Kai Peter Birke, Björn Obry, Stefan Wigger, Ruslan Kozakov, Pavel Smirnov and Jochen Schein
Batteries 2024, 10(11), 397; https://doi.org/10.3390/batteries10110397 - 8 Nov 2024
Viewed by 1998
Abstract
Thermal propagation events are characterized by fire and thick black smoke, leading to propagation methods with a focus on preventing heat transfer and optimizing gas flow. Yet little attention is being paid to the electric conductivity of the gas, leading to possibly unexpected [...] Read more.
Thermal propagation events are characterized by fire and thick black smoke, leading to propagation methods with a focus on preventing heat transfer and optimizing gas flow. Yet little attention is being paid to the electric conductivity of the gas, leading to possibly unexpected battery casing openings due to lightning arcs as well as potentially providing the minimum ignition energy. This gas composition (omitting particles) was used at different temperatures and pressures in a lightning arc test bench, leading to the Paschen curve. Using a mini-module cell setup, filtered venting gas was flowed through another lightning arc test bench, allowing for in situ measurements. Full article
(This article belongs to the Special Issue Advances in Lithium-Ion Battery Safety and Fire)
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12 pages, 3361 KiB  
Article
Investigation of the Effects Caused by Current Interruption Devices of Lithium Cells at High Overvoltages
by Jan Haß, Christina Schieber, Florian Meilinger, Yash Kotak, Serkan Sevinc, Philipp Lang and Hans-Georg Schweiger
Appl. Sci. 2024, 14(18), 8238; https://doi.org/10.3390/app14188238 - 12 Sep 2024
Viewed by 2300
Abstract
A faulty voltage measurement can lead to the overcharging of a Li-Ion cell, resulting in gas formation and heating inside the cell, which can trigger thermal runaway. To mitigate this risk, cylindrical cells are equipped with a Current Interrupt Device (CID), which functions [...] Read more.
A faulty voltage measurement can lead to the overcharging of a Li-Ion cell, resulting in gas formation and heating inside the cell, which can trigger thermal runaway. To mitigate this risk, cylindrical cells are equipped with a Current Interrupt Device (CID), which functions as a pressure relief valve, disconnecting the electrical circuit within the cell when internal pressure rises. However, this disconnection causes the cell to suddenly become highly resistant, posing a significant issue in series-connected cells. In such configurations, a portion or even the entire system voltage may drop across the disconnected cell, substantially increasing the likelihood of an electric arc. This arc could ignite any escaping flammable gases, leading to catastrophic failures. In a series of tests conducted on three different cell chemistries—NMC (Nickel Manganese Cobalt), NCA (Nickel Cobalt Aluminum), and LFP (Lithium Iron Phosphate)—it was found that the safe operation of the CID cannot be guaranteed for system voltages exceeding 120 V. Although comparative tests at double the nominal cell voltage did not exhibit the same behavior, these findings suggest that current safety standards, which recommend testing at double the nominal voltage, may not adequately address the risks involved. The tests further revealed that series connections of cells with CIDs are inherently dangerous, as, in the worst-case scenario, the entire system voltage can be concentrated across a single cell, leading to potential system failure. Full article
(This article belongs to the Section Energy Science and Technology)
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29 pages, 4359 KiB  
Article
FMEA-TSTM-NNGA: A Novel Optimization Framework Integrating Failure Mode and Effect Analysis, the Taguchi Method, a Neural Network, and a Genetic Algorithm for Improving the Resistance in Dynamic Random Access Memory Components
by Chia-Ming Lin and Shang-Liang Chen
Mathematics 2024, 12(17), 2773; https://doi.org/10.3390/math12172773 - 7 Sep 2024
Cited by 3 | Viewed by 1445
Abstract
Dynamic random access memory (DRAM) serves as a critical component in medical equipment. Given the exacting standards demanded by medical equipment products, manufacturers face pressure to improve their product quality. The electrical characteristics of these products are based on the resistance value of [...] Read more.
Dynamic random access memory (DRAM) serves as a critical component in medical equipment. Given the exacting standards demanded by medical equipment products, manufacturers face pressure to improve their product quality. The electrical characteristics of these products are based on the resistance value of the DRAM components. Hence, the purpose of this study is to optimize the resistance value of DRAM components in medical equipment. We proposed a novel FMEA-TSTM-NNGA framework that integrates failure mode and effect analysis (FMEA), the two-stage Taguchi method (TSTM), neural networks (NN), and genetic algorithms (GA) to optimize the manufacturing process. Moreover, the proposed FMEA-TSTM-NNGA framework achieved a substantial reduction in experimental trials, cutting the required number by a factor of 85.3 when compared to the grid search method. Our framework successfully identified optimal manufacturing condition settings for the resistance values of DRAM components: Depo time = 27 s, Depo O2 flow = 151 sccm, ARC-LTO etch time = 43 s, ARC-LTO etch pressure = 97 mTorr, Ox-SiCO etch time = 91 s, Ox-SiCO gas ratio = 22%, and Polish time = 84 s. The results helped the case company improve the resistance value of DRAM components from 191.1 × 10−3 Ohm to 176.84 × 10−3 Ohm, which is closer to the target value of 176.5 × 10−3 Ohm. The proposed FMEA-TSTM-NNGA framework is designed to operate efficiently on resource-constrained, facilitating real-time adjustments to production attributes. This capability enables DRAM manufacturers to swiftly optimize product quality. Full article
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13 pages, 6237 KiB  
Article
Influence of Spraying Process Parameters on the Characteristics of Steel Coatings Produced by Arc Spraying Method
by Bauyrzhan Rakhadilov, Nurtoleu Magazov, Dauir Kakimzhanov, Akbota Apsezhanova, Yermakhan Molbossynov and Aidar Kengesbekov
Coatings 2024, 14(9), 1145; https://doi.org/10.3390/coatings14091145 - 5 Sep 2024
Cited by 8 | Viewed by 2067
Abstract
Arc spraying is one of the most effective and cost-efficient thermal spraying technologies for creating high-quality protective coatings. This paper examines the influence of arc spraying process parameters on the properties of steel coatings. The parameters varied in this study included gas pressure, [...] Read more.
Arc spraying is one of the most effective and cost-efficient thermal spraying technologies for creating high-quality protective coatings. This paper examines the influence of arc spraying process parameters on the properties of steel coatings. The parameters varied in this study included gas pressure, wire feed rate, and the distance from the spray gun to the substrate (standoff distance). Experimental evaluations focused on surface roughness, thickness, porosity, structure, and hardness of the coatings. The techniques used for these evaluations included profilometry for roughness measurement, scanning electron microscopy (SEM) for structural analysis, Vickers hardness testing, and optical microscopy. The results demonstrate a significant influence of arc spraying parameters on the characteristics of the resulting coatings. The analysis revealed that the coatings produced under different modes exhibit a layered structure and vary in thickness. A detailed examination of the coating structure identified defects such as unmelted particles, voids, and delamination in the interface zone. The study of coating thickness and porosity showed that increasing the wire feed rate and decreasing the standoff distance leads to the formation of thicker and denser coatings. Specifically, increasing the wire feed rate from 2 to 12 cm/s resulted in a decrease in porosity from 12.59% to 4.33% and an increase in coating thickness to 699 μm. The surface analysis highlighted the importance of a comprehensive approach to selecting the optimal roughness. While increasing the wire feed rate up to 12 cm/s can increase the Ra roughness parameter, gas pressure also significantly influences this parameter, reducing roughness from Ra = 18.63 μm at 6 MPa to Ra = 15.95 μm at 8 MPa. Additionally, it was found that varying the arc spraying parameters affects the hardness of the coatings, with all modes resulting in hardness values higher than that of the substrate. Therefore, optimizing these parameters enables the achievement of the best combination of mechanical and structural properties in the coatings. These findings can be valuable for further improvement of arc spraying technologies and the expansion of their application across various industries. Full article
(This article belongs to the Special Issue Additive Manufacturing of Metallic Components for Hard Coatings)
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19 pages, 6396 KiB  
Article
Enrichment Characteristics and Mechanisms of Lithium, Gallium, and Rare Earth Elements (REY) within Late Permian Coal-Bearing Strata in Wanfu Mine, Xian’an Coalfield, Guangxi Province, Southwest China
by Degao Zhang, Xiaoyun Yan, Baoqing Li, Jie Sun, Li Zhang, Xiangcheng Jin, Xiaotao Xu, Shaobo Di and Shaoqing Huang
Minerals 2024, 14(9), 853; https://doi.org/10.3390/min14090853 - 23 Aug 2024
Cited by 2 | Viewed by 1059
Abstract
The study of lithium (Li), gallium (Ga), and rare earth elements (REY) within coal-bearing strata represents a cutting-edge concern in coal geology, ore deposit studies, and metallurgy research. With the rapid advancement of technology and emerging industries, the global demand for Li-Ga-REY has [...] Read more.
The study of lithium (Li), gallium (Ga), and rare earth elements (REY) within coal-bearing strata represents a cutting-edge concern in coal geology, ore deposit studies, and metallurgy research. With the rapid advancement of technology and emerging industries, the global demand for Li-Ga-REY has significantly escalated. Several countries worldwide are facing immense pressure due to shortages in Li-Ga-REY resources. Coal-associated Li-Ga-REY depositions have emerged as a pivotal direction for augmenting Li-Ga-REY reserves. To ascertain the enrichment distribution patterns and genetic mechanisms of Li-Ga-REY within the coal-bearing strata of the late Permian Heshan Formation in Wanfu mine, Xian’an Coalfield, Guangxi Province, this study carried out comprehensive testing and analysis on Li-Ga-REY enriched in the mineralized layers within the strata. The Heshan Formation in Wanfu mine presents four layers of Li-Ga-REY-enriched mineralization, labeled from bottom to top as mineralized layers I, II, III, and IV, corresponding to coal seams K5, K4, K3, and K2. These critical metals are predominantly hosted within clay minerals (kaolinite, illite/smectite, and chlorite). The enrichment of critical metals within the Heshan Formation is closely related to terrigenous detrital materials from the Daxin paleocontinent, volcanic detrital materials induced by the Emeishan mantle plume and the Yuenan magmatic arc. The accumulation of Li-Ga-REY and other critical elements within the mineralized layers is the result of inputs from terrestrial and volcanic detrital sources, interactions between peatification and diagenesis stages, and occasionally the input of metal-enriched fluids. In the mineralized layers I, II, and III, the content of lithium oxide (Li2O) surpasses the boundary grade, and the levels of REY, Ga, and (Nb,Ta)2O5 are close to boundary grades, indicating promising exploration prospects. The Wanfu mine in the Xian’an Coalfield can be considered a primary target zone for the exploration and development of coal-associated critical metal resources in Guangxi. Full article
(This article belongs to the Special Issue Critical Metal Minerals in Coal)
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