Search Results (57)

This study presents the first comprehensive assessment of per- and polyfluoroalkyl substances (PFAS) in surface waters of northern Serbia (Middle Danube region), combining targeted analysis of 25 PFAS with high-resolution mass spectrometry suspect screening (SSA) at 12 settlement-adjacent sites on major rivers and part of the Danube–Tisa–Danube (DTD) canal network. The sum of 10 quantified PFAS showed pronounced spatial variability: the Great Bačka Canal (GBC) exhibited the highest mean and maximum values (18.4 ng/L and 52.6 ng/L, respectively); the Danube averaged 9.05 ng/L (2.92–22.2 ng/L); the Tisa averaged 10.5 ng/L (4.53–16.5 ng/L); and the Sava and Tamiš exhibited the lowest means (~5.4 ng/L each). In total, 19 of 24 sites exceeded the proposed EU group Environmental Quality Standard (EQS) of 4.4 ng/L, expressed as PFOA-equivalents, with exceedances of 5.4–20.2 ng/L; PFOS exceeded the 0.65 ng/L inland surface water annual average (AA) EQS in 17 samples. SSA expanded coverage beyond targets, revealing ultra-/short-chain PFAS and replacements, with TFA as the most abundant (337–1165 ng/L; mean 513 ng/L) and notable maxima for PFPrA (51.3 ng/L), ADONA (24.9 ng/L), and TFMS (11.2 ng/L). Compared with European freshwaters, the maximum obtained here lies in the lower-mid part of the reported range, consistent with short-chain perfluoroalkyl carboxylic acids (PFCA) dominance and diffuse-source influences. Full article

This study investigates groundwater levels (GWLs) in the alluvial aquifer of the Sava River valley, located in the north-western part of Croatia. It provides the first quantitative assessment of groundwater levels using machine learning in this part of Europe. Groundwater levels from 1998 to 2017 were predicted using support vector regression (SVR). The input variables were initially monthly data on two basic elements that influence groundwater dynamics (precipitation and the Sava River levels). Later, GWLs from the previous month (GWL-1) were added as an additional predictor. Results demonstrated that the SVR model effectively predicts groundwater levels. Introducing GWL-1 reduced RMSE and MAE values by more than 47% and 46%, respectively, while increasing the R² value by over 36%. The improvement was more pronounced farther from the Sava River, since GWLs near the river are more directly influenced by river stage fluctuations, diminishing the impact of GWL-1. Compared to the existing regional numerical model (NM), the SVR model outperformed the NM with improvements of approximately 12% to 76% across performance indicators. Our findings suggest that the SVR model provides a reliable method for predicting groundwater levels at specific observation wells, making it a valuable tool for applications such as forecasting groundwater availability for farmers during dry periods and flood risk assessment during periods of heavy rainfall. Full article

Intensifying urbanization in Central Europe is increasingly pushing flood retention areas onto private farmland, yet the agronomic and socio-economic trade-offs remain poorly quantified. We conducted a narrative review of published field data and post-event assessments from 2014–2023 along the transboundary Sava River. Information was collected from research articles, case studies, and environmental monitoring reports, and synthesized in relation to national and EU regulatory thresholds to evaluate how floods altered soil functions and agricultural viability. Water erosion during floods stripped up to 30 cm of topsoil in torrential reaches, while stagnant inundation deposited 5–50 cm of sediments enriched with potentially toxic elements, occasionally causing food crops to exceed EU contaminant limits due to uptake from the soil. Flood sediments also introduced persistent organic pollutants: 13 modern pesticides were detected post-flood in soils, with several exceeding sediment quality guidelines. Waterlogging reduced maize, pumpkin, and forage yields by half where soil remained submerged for more than three days, with farm income falling by approximately 50% in the most affected areas. These impacts contrast with limited public awareness of long-term soil degradation, raising questions about the appropriateness of placing additional dry retention reservoirs—an example of nature-based solutions—on agricultural land. We argue that equitable flood-risk governance in the Sava River Basin requires: (i) a trans-boundary soil quality monitoring network linking agronomic, hydrological, and contaminant datasets; (ii) compensation schemes for agricultural landowners that account for both immediate crop losses and delayed remediation costs; and (iii) integration of strict farmland protection clauses into spatial planning, favoring compact, greener cities over lateral river expansion. Such measures would balance societal flood-safety gains with the long-term productivity and food security functions of agricultural land. Full article

The sustainable management of water bodies with hydropower plants (HPPs) and protected rheophilic fish species is challenging. The key question is whether impounded rivers can still provide habitat for protected rheophilic fish species, including Natura 2000 species. We investigated hydro-morphological conditions and fish communities, focusing on the bottom-dwelling Danube longbarbel gudgeon (Romanogobio uranoscopus) and the medium-distance migrating cactus roach (Rutilus virgo) in the Brežice HPP system on the Sava River in Slovenia. Fish sampling using an electric bottom trawl in the HPP impoundment, electrofishing in the nearshore, and video surveillance in the fish pass revealed a diverse and distinctive fish community. This community reflected rheophilic conditions in the upper impoundment and fish pass, and lentic conditions in the lower impoundment. These findings provide evidence that impounded rivers, when complemented by well-designed mitigation measures, can sustain rheophilic fish species, including the Danube longbarbel gudgeon and cactus roach. Maintaining rheophilic habitat within the impoundment, combined with a functioning river-like side channel, is crucial. However, at Brežice HPP, changes in the management of the fish pass water inflow are necessary to ensure adequate and consistent hydraulic conditions and water temperatures. Applying a knowledge co-creation approach, which requires productive interaction among scientists, managers and policy makers, could help to find the best solutions for sustainable water ecosystem management. Full article

This study investigates cross-border cascading hazards and infrastructure vulnerabilities in the Sava River Basin, a seismically active and flood-prone region spanning the Slovenia–Croatia border. Conducted within the CROSScade project, the research focuses on assessing cross-border hazards and the vulnerabilities of levees and bridges. Key earthquake and flood scenarios were identified using advanced hydraulic and seismic modelling, forming the basis for evaluating the cascading effects of these events, including the potential failure of hydropower plants and associated flood protection systems. The analysis reveals that levees are particularly vulnerable to failure during the recession phase of flooding that follows an earthquake. At the same time, bridges are primarily affected by seismic loading, with minimal structural impact from flood forces. These findings underscore the pressing need for enhanced cross-border collaboration, updated design standards, and the reinforcement of critical infrastructure. The study provides essential insights for multi-hazard resilience planning and emphasises the importance of integrated risk assessments in managing cascading disaster impacts across national boundaries. Full article

Different communities of primary producers were surveyed in a series of five river reservoirs on the Sava River in southeast Slovenia. Seasonal differences of phytoplanktonic and phytobenthic communities were studied in the reservoirs of hydroelectric power plants. Macrophytes were surveyed in the summer, while phytoplankton and periphyton were sampled in the winter and summer of 2021. The taxonomic composition of diatoms was studied in greater detail and additionally analysed. The results showed that the species composition of phytoplankton and phytobenthos differed between seasons. The communities were also more similar between the seasons at the same sampling site than between the sampling sites. Temperature was the parameter that had the greatest impact on the taxonomic composition of phytoplanktonic and phytobenthic communities. In total, 51 algal taxa and 81 species of diatoms were recorded, respectively. Furthermore, 15 species of aquatic macrophytes were found. The abundance of phytoplankton was the highest in the lowest reservoir in the series, in Brežice, where the temperature was also the highest. The number of macrophytes also increased downstream, but their abundances were low, mainly due to coarse substrate on the banks consisting of rocks and boulders. Constructing additional reservoirs on this section of the Sava River could increase the probability of the substantial growth of phytoplankton and cyanobacteria within it. On the other hand, providing patches of finer substrates (gravel, pebbles) would support the abundance of macrophyte species, which could control the concentrations of nutrients in the summer and prevent the blooms more efficiently. Full article

This paper examines two large urban projects within a defined theoretical and methodological framework. Firstly, we analyse how the city administration in Belgrade, in post-socialist Serbia, managed the initial steps of the transformation of a part of the old town into the new large-scale development, the Belgrade Waterfront (BW), on the right bank of the Sava River. The contested outcome of the land transformation process contributes to a recognition of the unethical decision-making and performance of the responsible city authorities. Secondly, the postwar planning and construction of New Belgrade, in particular its Central Zone, is critically examined from the aspect of radical urban landscape transformation and its impact on society. Through a critical examination of the spatial development of the socialist period, we aim to identify emancipatory architectural and urban practises that could be an alternative to contemporary spatial production and that might provide a notion of key strategies for (re)establishing corresponding forms of socio-spatial justice. The two aforementioned research subjects are examined using different research questions, methodological tools, and different theoretical frameworks, which overlap, merge, and combine in the part of the study where the obtained results are discussed. Full article

Plastic pollution has become a major environmental problem, while the products of its degradation, microplastics (MPs), appear everywhere on Earth. Data on MPs in agricultural soils have appeared lately, but a significant knowledge gap exists regarding forest soils. In Serbia, municipal waste is often dumped in forests, creating environmental problems that have not been documented. To explore the impact of waste dumping and MPs on forest fluvisols, we evaluated MPs from topsoils of three waste dumps and adequate visibly plastic non-contaminated forest sites located in alluviums of the largest rivers in Serbia. For assessing the influence of environmental factors on soil MPs, samples were taken in three forest vegetational seasons, in two years. The impact of MPs on soil structure, chemistry, and microbial respiration (MR) was examined. Undisturbed soil columns from uncontaminated sites with added known MP particles were used to estimate the dynamic of MP transfer through the topsoil. Large aggregate formation, soil coarse sand content, specific mass, porosity, and available P, but not MR were affected by contamination. Seasonal and annual environmental changes significantly influenced the behavior of MPs in forest luvisols. MPs effectively penetrated the deeper layers of soil columns within 3 months, with strong accumulation in the 0–10 cm layer. Full article

This study reconstructs historical streamflow in the Sava River Basin (SRB), focusing on hydrological variability over extended timescales. Using a combination of Machine Learning (ML) and Deep Learning (DL) models, streamflow patterns were reconstructed from self-calibrated Palmer Drought Severity Index (scPDSI) proxies. The analysis included nine ML models and two DL architectures, with a post-prediction bias correction applied uniformly using the RQUANT method. Results indicate that ensemble methods, such as Random Forest and Gradient Boosted Tree, along with a six-layer DL model, effectively captured streamflow dynamics. Bias correction improved predictive consistency, particularly for models exhibiting greater initial variability, aligning predictions more closely with observed data. The findings reveal that the 2000–2022 period ranks as the lowest 23-year flow interval in the observed record and one of the driest over the past ~500 years, offering historical context for prolonged low-flow events in the region. This study demonstrates the value of integrating advanced computational methods with bias correction techniques to extend hydrological records and enhance the reliability of reconstructions. By addressing data limitations, this approach provides a foundation for supporting evidence-based water resource management in Southeastern Europe under changing climatic conditions. Full article

This study focused on the investigation of soil samples from the alluvial zone of the Sava River, located near the heating plant in New Belgrade, Serbia. Using gas chromatography with flame ionization detection (GC-FID), a broad range of alkanes, including linear n-alkanes (C₁₀ to C₃₃) and isoprenoids, was analyzed in all samples. The obtained datasets were effectively made simpler by applying multivariate statistical analysis. Various geochemical indices (CPI, ACL, AI, TAR, etc.) and ratios (S/L, Paq, Pwax, etc.) were calculated and used to distinguish between biogenic and anthropogenic contributions. This approach added a higher level of precision to the source identification of hydrocarbons and provided a detailed geochemical characterization of the investigated soil. The results showed that the topsoil had a high content of TPH (average value, 90.65 mg kg⁻¹), potentially related to an accidental oil spill that occurred repeatedly over extended periods. The uncommon n-alkane profiles reported for the investigated soil samples are probably the result of inputs related to anthropogenic sources, emphasizing that petroleum was the main source of the short-chain n-alkanes. The methodology developed in this study was proven to be efficient for the assessment of the environmental quality of the soil in an urban part of New Belgrade, but it can also be a useful tool for soil monitoring and for a pollution assessment in other (sub)urban areas. Full article

In this study, the activity of oxidative stress parameters superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GSH-Px), glutathione reductase (GR), and glutathione S-transferase (GST), as well as the concentrations of vitamin E (Vit E) and SH groups in the digestive glands and gills of freshwater mussels Unio pictorum and Sinanodonta woodiana from the Sava River in Serbia were investigated. These parameters were determined in native and invasive mussels under the same environmental conditions. The activities of GSH-Px and GR and the concentration of Vit E were significantly higher in the digestive glands of the autochthonous species U. pictorum than in the invasive species S. woodiana, while the CAT activity and the concentration of SH groups were lower. In the gills of U. pictorum, GSH-Px activity and Vit E concentration were significantly higher, while CAT, GST, and SH groups were lower. Principal component analysis (PCA) showed that oxidative stress parameters were strictly tissue- and species-specific. In addition, integrated biomarker response (IBR) showed a combined response of enzymatic and non-enzymatic oxidative stress parameters depending on the tissue or species studied, indicating different metabolic activities and behaviors of an autochthonous versus an introduced bivalve species. Full article

The study analyzed available data series of the Sava River’s water temperature measured at the Zagreb gauging station. Official data from the Croatian Meteorological and Hydrological Service (DHMZ) in Zagreb were utilized. Over the 73 years from 1948 to 2020, there are only 53 years with complete measurement records. Despite this limiting fact, it was considered important to analyze the behavior of the Sava River’s water temperatures in Zagreb over the past 70 years, during which a significant increase in air temperatures has been observed in the region, particularly in the city of Zagreb. Analyses were conducted on the characteristic (minimum, mean, and maximum) water temperatures over timescales of years, months, and days. The relationship between water temperatures (TW) and air temperatures (TA) measured at the Grič Observatory and the flows (Q) of the Sava River in Zagreb were investigated. A trend of rising water temperatures was observed throughout the entire period from 1948 to 2020, with the intensity significantly increasing in the recent period starting from 1988. The trend of rising air temperatures is the primary driver of the increase in the water temperatures of the Sava River in Zagreb. However, the impact of reduced water flow, especially during the warm season, should not be overlooked. This effect is amplified by the observed trend of decreasing minimum flows of the Sava during the warm season, from June to September. As a result, the most significant rise in water temperatures of the Sava River in Zagreb occurs during prolonged low-water summer periods, particularly in July. A strong trend has been observed in the increasing number of days per year with mean daily water temperatures of the Sava River exceeding 20 °C. This higher water temperature occurs increasingly earlier in the year, lasts longer, and ends later, often extending into September. Full article

Global warming and climate change cause large temperature oscillations and uneven annual rainfall patterns. The rainy cycles characterized by frequent high-intensity rainfall in the area of the Stubo–Rovni water reservoir, which in 2014 peaked at 129 mm of water in 24 h (the City of Valjevo, the Republic of Serbia), caused major floods in the wider area. Such extremes negatively affect erosion processes, sediment production, and the occurrence of flash floods. The erosion coefficient before the construction of the water reservoir was Z_m = 0.40, while the specific sediment production was about 916.49 m³∙km⁻²∙year⁻¹. A hydrological study at the profile near the confluence of the Jadar and Obnica rivers, i.e., the beginning of the Kolubara river, the right tributary of the Sava (in the Danube river basin), indicates that the natural riverbed can accommodate flows with a 20% to 50% probability of occurrence (about 94 m³/s), while centennial flows of about 218 m³/s exceed the capacities of the natural riverbed of the Jadar river, causing flooding of the terrain and increasing risks to the safety of the population and property. The paper presents the impacts of the man-made Stubo–Rovni water reservoir on the catchment area and land use as the primary condition for preventing erosion processes (specific sediment production has decreased by about 20%, the forest cover increased by about 25%, and barren land decreased by 90%). Moreover, planned and controlled management of the Stubo–Rovni reservoir has significantly influenced the downstream flow, reducing the risks of flash floods. Full article

The paper analyzes the concept of resilience in the context of the Cvjetno housing estate in Zagreb, Croatia, a recognized cultural and historical complex. While extensive literature exists on the estate’s architectural and historical significance, limited research explores its resilience. This study aims to fill this gap by examining the Cvjetno estate’s planned resilience to natural hazards and socioeconomic challenges. It investigates the estate’s design, historical context, and physical characteristics through archival documents, historical records, and field research. The analysis focuses on the estate’s planned resilience to natural disasters, particularly flooding from the nearby river Sava and seismic risks due to its location in a seismically active area. Based on the literature on resilient communities, the study draws on dimensions, characteristics, and qualities of resilience, and explores how the Cvjetno estate exemplifies these traits. Future research could explore and compare similar mid-20th century European settlements to enhance the understanding of urban resilience during the modern era. Full article

This study involves an investigation into the grain size distribution and provenance of the sand deposited near Zagreb (Croatia) in the riverbed of the regionally important, almost 1000 km long Sava River, which connects several SE European countries. Recent research in the study area has mainly focused on the deposits forming the Zagreb alluvial aquifer system, rather on the Sava River sediment deposited in its riverbed, which is the focus of this study. The grain size distribution results obtained by dry sieving and laser granulometry showed a predominately fine and medium sand deposition at riverbanks and sand point bars. Medium sand increased downstream towards the east, within the artificially more channelized riverbed in the urban area. Fine sand prevailed 50 km further downstream in a more meandering low-relief area, near the city of Sisak and Lonjsko Polje Nature Park. Provenance analysis showed predominately carbonate sand in the western part of the city of Zagreb, originating from distant (Alpine) and local (Medvednica Mt. and Samobor Hills) sources. More siliciclastic sand was deposited in the Sava riverbed in the middle and eastern parts of Zagreb, originating mainly from the Medvednica Mt. The prevailing siliciclastic sand further downstream of the Sava River is probably sourced from the Kupa River tributary. Although various studies of the Zagreb alluvial aquifer system have been conducted so far, this study represents a novelty in its investigation into the grain size distribution of the Sava riverbed sand itself, setting the foundations for investigations in the future. Full article