Search Results (24)

The application of an ultrafiltration (UF) process with periodic membrane cleaning with the use of alkaline detergent solutions was proposed for the recovery of wash water from car wash effluent. In order to test the resistance of the membranes to the degradation caused by the cleaning solutions, a pilot plant study was carried out for almost two years. The installation included an industrial module with FP100 tubular membranes made of polyvinylidene fluoride (PVDF). The module was fed with synthetic effluent obtained by mixing foaming agents and hydrowax. To limit the fouling phenomenon, the membranes were cleaned cyclically with P3 Ultrasil 11 solution (pH = 11.7) or Insect solution (pH = 11.5). During plant shutdowns, the membrane module was maintained with a sodium metabisulphite solution. Changes in the permeate flux, turbidity, COD, and surfactant rejection were analysed during the study. Scanning electron microscopy (SEM), atomic force microscopy (AFM), differential scanning calorimetry (DSC), and Fourier-transform infrared spectroscopy (FTIR) analysis were used to determine the changes in the membrane structure. As a result of the repeated chemical cleaning, the pore size increased, resulting in a more than 50% increase in permeate flux. However, the quality of the recovered wash water did not deteriorate, as an additional separation layer was formed on the membrane surface due to the fouling phenomenon. Full article

Saponaria officinalis L., a plant rich in saponins, has long been used as a natural surfactant. It has traditionally been used for its cleansing and anti-inflammatory properties in the treatment of various skin conditions, including eczema, psoriasis, and acne. In this study, we investigated the potential of S. officinalis callus (SC), mass-produced via plant tissue culture, as a novel exfoliating cosmetic ingredient. The callus was induced using Murashige and Skoog (MS) medium supplemented with 1 mg/L 2,4-D, and the resulting extract (SCE) was analyzed via high-performance liquid chromatography (HPLC), confirming the presence of saponarin—a bioactive compound with known anti-inflammatory properties. In vitro assays demonstrated that SCE significantly suppressed nitric oxide production and reduced the expression of pro-inflammatory mediators, including iNOS, COX-2, TNF-α, IL-1β, and IL-6, in LPS-stimulated RAW264.7 macrophages. The foaming ability and stability of SC and SCE were also comparable to commercial surfactants. Clinical studies further supported the material’s cosmetic potential: a skin patch test in 30 volunteers revealed no signs of irritation (mean score: 0.28), while a desquamation index assessment in 21 participants showed a significant reduction of 44.07%, confirming its exfoliating efficacy. Taken together, these results suggest that the SC scrub is a safe, eco-friendly, and sustainable alternative to synthetic exfoliating agents, offering functional and industrial advantages for cosmetic applications. Full article

According to EU directives, it is necessary to improve the energy consumption of buildings. Therefore, the aim of this study was to improve the physical properties of foamed concrete produced using plaster mortar. For this purpose, polystyrene granulate with a bulk density of 13 kg/m³ in amounts of 4, 7, and 10 g per 1 kg of plaster mortar and a foaming agent in amounts of 2, 4, and 6% of the cement mass were used. The density, thermal conductivity coefficient, compressive and flexural strengths, and water absorption coefficient due to capillary action were determined. Based on the obtained results, it can be concluded that the density, thermal conductivity coefficient, and water absorption coefficient due to capillary action decreased with an increase in the content of polystyrene granulate addition, which is a beneficial outcome. However, at the same time, a reduction in mechanical properties was demonstrated. With an increase in the content of the foaming agent, the density and thermal and mechanical properties decreased. The water absorption coefficient due to capillary action increased with the foaming agent content for samples with the addition of polystyrene granulate. However, the coefficient for all the tested samples was lower than that for the base sample. Full article

Membrane technology is widely used in various aspects of wastewater treatment; however, single membrane technology has a series of disadvantages, such as high selectivity, poor recycling performance, and susceptibility to contamination. In this study, a treatment method combining an advanced oxidation process and membrane separation technology was proposed, and a geopolymer-based Fenton-like catalytic tubular membrane (GFM) was prepared by using H₂O₂ as a blowing agent by the direct foaming method. It was shown that the optimum conditions for the preparation of the membrane were a water glass modulus of 1.8 M, the addition of foaming agent of 1 mL, and a thickness of the membrane of 6.5 mm, with a flux of 6942 L·m⁻²·h⁻¹. Due to the characteristics of the tubular membrane, the possibility of adding hydrogen peroxide directly inside the membrane allows an optimal Fenton-like removal, which is better than outside the membrane, thus reducing the consumption of hydrogen peroxide. The tubular membrane has a multi-stage porous structure, high flux, and a high specific surface area (68.74 m²/g). The GFM/H₂O₂ Fenton-like system formed is capable of almost completely degrading all kinds of synthetic dyes under various stringent conditions, and the XRD, FTIR, and TG analyses and cycling tests showed that the GFM has excellent stability and a significant advantage in terms of reusability. Full article

The aim was to develop a series of handwashing gels containing a standardised extract of the aerial part of Gypsophila trichotoma as well as an essential oil from Xanthium strumarium fruits. The saponins present in the extract are a suitable alternative to synthetic sulphate surfactants and have better skin tolerance, and with the addition of essential oil, a higher antibacterial activity of the gels thus developed is achieved. The elaborated gels were characterised by good spreadability and a pH close to the physiological for healthy skin (pH 5.5), which is a prerequisite for improved skin tolerability. The dynamic rheological studies showed that the extract fraction increase was not associated with gel viscosity change, and it was only a function of the gelling agent concentration. The gels’ foam-forming ability increased with the increasing extract concentrations. The comparative evaluation of the antibacterial activity of elaborated gels vs. plain gel based on coco glucoside against a panel of selected pathogens demonstrated that the newly developed formulations have superior antibacterial effects. Based on the good technological characteristics and the results of antimicrobial testing of the washing gels thus developed, it can be concluded that they are promising candidates as personal hygiene products. Full article

This study examines the pore structure and distribution in 3D printed and cast foamed concrete using protein-based and synthetic foaming agents alongside various stabilizing additives. In 3D printed samples, pores are irregular and flattened due to mechanical forces during printing, whereas cast samples display uniform, spherical pores from homogeneous foam distribution. Samples containing the CA stabilizer show higher apparent densities (up to 2.05 g/cm³ for printed samples), correlating with lower water absorption. Protein-based foaming agents (PS) produce smaller, more evenly distributed pores, while synthetic agents (AS) result in larger, less uniform pores. Stabilizers significantly influence pore characteristics: commercial stabilizers yield smaller, more uniform pores, while recycled industrial oil (UO) leads to larger, more variable pores. Protein-based agents improve structural stability and reduce water absorption through uniform pore distributions, while synthetic agents lower density and increase water absorption. The highest sorption values were observed in samples with AS without stabilizer (1.7 kg/m²h¹/²) and AS and UO (1.6 kg/m²h¹/²) in a vertical orientation, with the horizontal orientation of sample AS and UO achieving a peak value of 2.0 kg/m²h¹/². Moreover, stabilization using UO resulted in higher sorption coefficients than stabilization with CA. High porosity in M1 resulted in low strength (0.2 MPa bending, 0.1 MPa perpendicular compression), while M5 showed superior performance (11.5 MPa perpendicular compression). PS-foamed samples (M4, M6) with uniform pores had the highest strengths, with M6 achieving 3.8 MPa bending and 10.3 MPa perpendicular compression. Perpendicular compression (M5: 11.5 MPa) was up to three times stronger than parallel compression due to weak interlayer bonds in 3D printing. Full article

Currently, the world faces serious challenges in meeting the growing demand for clean water. The present paper demonstrates the possibility of using the ultrafiltration (UF) process to reuse water from wastewater generated in car washes. Car washes commonly use foaming agents with dyes, which, although they are not necessary for washing cars, may hinder water reuse. For this reason, the aim of this work was to investigate the effect of the dyes present in car wash wastewater on the membrane fouling intensity. For this purpose, experimental tests were conducted with the application of a pilot plant with an industrial PCI B1 membrane module. The module was equipped with tubular FP100 (100 kDa) polyvinylidene fluoride (PVDF) membranes. For the feed, two types of cleaning agents and synthetic wastewater were used. The results obtained in the current study demonstrated that the UF membranes allowed the obtainment of the permeate characterized by high quality. In addition, it has been shown that the presence of Indigo carmine dye in the wastewater led to an increase in the fouling intensity. To sum up, it should be pointed out that the findings presented in the current study may be of key importance in the design of pilot installations used for the treatment of car wash wastewater. Full article

Population growth and the need for increased agricultural productivity pose a global problem. Therefore, the development of green compounds to ensure agricultural sustainability is an urgent necessity. Surfactant compounds hold significant commercial importance due to their diverse industrial uses. However, the synthetic origin of these agents limits their commercial application due to their toxicity. As a result, extensive research has focused on the production of microbial-originated green surfactants, known as biosurfactants, over the past fifteen years. These biomolecules not only offer a green alternative for agriculture but also exhibit reduced toxicity and excellent stability under specific environmental conditions. Biosurfactants can lower surface tension more effectively than synthetic surfactants. With properties such as detergency and foam formation, biosurfactants are suitable for various agricultural applications, particularly in pesticide and agrochemical formulations. They can function as biopesticides to manage pests, pathogens, phytopathogenic fungi, and weeds due to their antimicrobial activity. Moreover, plants can benefit from biosurfactant molecules and microorganisms as nutrients. They can also aid efficiently in the distribution of micronutrients and metals in the soil. They also stimulate plant immunity and are utilized for soil hydrophilization to ensure proper moisture levels and uniform fertilizer distribution. This review aims to provide valuable insights into the role and properties of biosurfactants as agricultural adjuvants, fostering the development of sustainable formulations to replace the chemical surfactants used in pesticides. For this purpose, the general aspects of global agricultural activity are initially described, followed by a discussion of pesticides, including herbicides, fungicides, and insecticide products. Next, the properties of chemical surfactants are discussed and the use of green surfactants, with emphasis on microbial biosurfactants, is demonstrated. The application of biosurfactants in the agricultural industry and trends are addressed and prospects for the application of these agents are discussed. Full article

Numerous innovative advancements in dressing technology for wound healing have emerged. Among the various types of wound dressings available, hydrogel dressings, structured with a three-dimensional network and composed of predominantly hydrophilic components, are widely used for wound care due to their remarkable capacity to absorb abundant wound exudate, maintain a moisture environment, provide soothing and cooling effects, and mimic the extracellular matrix. Composite hydrogel dressings, one of the evolved dressings, address the limitations of traditional hydrogel dressings by incorporating additional components, including particles, fibers, fabrics, or foams, within the hydrogels, effectively promoting wound treatment and healing. The added elements enhance the features or add specific functionalities of the dressings, such as sensitivity to external factors, adhesiveness, mechanical strength, control over the release of therapeutic agents, antioxidant and antimicrobial properties, and tissue regeneration behavior. They can be categorized as natural or synthetic based on the origin of the main components of the hydrogel network. This review focuses on recent research on developing natural polysaccharide-based composite hydrogel wound dressings. It explores their preparation and composition, the reinforcement materials integrated into hydrogels, and therapeutic agents. Furthermore, it discusses their features and the specific types of wounds where applied. Full article

The demand for sustainable and functional plant-based products is on the rise. Plant proteins and polysaccharides often provide emulsification and stabilization properties to food and food ingredients. Recently, chickpea cooking water, also known as aquafaba, has gained popularity as a substitute for egg whites in sauces, food foams, and baked goods due to its foaming and emulsifying capacities. This study presents a modified eco-friendly process to obtain process water from faba beans and isolate and characterize the foam-inducing components. The isolated material exhibits similar functional properties, such as foaming capacity, to aquafaba obtained by cooking pulses. To isolate the foam-inducing component, the faba bean process water was mixed with anhydrous ethanol, and a precipitated fraction was obtained. The precipitate was easily dissolved, and solutions prepared with the alcohol precipitate retained the foaming capacity of the original extract. Enzymatic treatment with α-amylase or protease resulted in reduced foaming capacity, indicating that both protein and carbohydrates contribute to the foaming capacity. The dried precipitate was found to be 23% protein (consisting of vicilin, α-legumin, and β-legumin) and 77% carbohydrate (amylose). Future investigations into the chemical structure of this foam-inducing agent can inform the development of foaming agents through synthetic or enzymatic routes. Overall, this study provides a potential alternative to aquafaba and highlights the importance of exploring plant-based sources for functional ingredients in the food industry. Full article

In recent years, numerous reports have described bioactive peptides (biopeptides)/hydrolysates produced from various food sources. Biopeptides are considered interesting for industrial application since they show numerous functional properties (e.g., anti-aging, antioxidant, anti-inflammatory, and antimicrobial properties) and technological properties (e.g., solubility, emulsifying, and foaming). Moreover, they have fewer side effects than synthetic drugs. Nevertheless, some challenges must be overcome before their administration via the oral route. The gastric, pancreatic, and small intestinal enzymes and acidic stomach conditions can affect their bioavailability and the levels that can reach the site of action. Some delivery systems have been studied to avoid these problems (e.g., microemulsions, liposomes, solid lipid particles). This paper summarizes the results of studies conducted on biopeptides isolated from plants, marine organisms, animals, and biowaste by-products, discusses their potential application in the nutricosmetic industry, and considers potential delivery systems that could maintain their bioactivity. Our results show that food peptides are environmentally sustainable products that can be used as antioxidant, antimicrobial, anti-aging, and anti-inflammatory agents in nutricosmetic formulations. Biopeptide production from biowaste requires expertise in analytical procedures and good manufacturing practice. It is hoped that new analytical procedures can be developed to simplify large-scale production and that the authorities adopt and regulate use of appropriate testing standards to guarantee the population’s safety. Full article

In order to explore the effect of the foaming agent type on the properties of foamed mixture lightweight soil mixed with bauxite tailings (FMLSB), low-density (437.5 kg/m³ and 670 kg/m³) and high-density (902.5 kg/m³ and 1170 kg/m³) FMLSB were prepared using protein-based and synthetic-based foaming agents (AF and SF, respectively). The foam stability, micro characteristics, compressive strength, fluidity, and volume of water absorption of the FMLSB were investigated. The results showed that the foam made from AF had better strength and stability compared to SF. The internal pore sizes of both AF- and SF-FMLSB at low density were large, but at high density the internal pore sizes and area porosity of AF-FMLSB were smaller than those of SF-FMLSB. In terms of compressive strength, the compressive strength of AF-FMLSB was improved by 17.5% to 43.2% compared to SF-FMLSB. At low density, the fluidity of AF- and SF-FMLSB is similar, while at high density the fluidity of AF-FMLSB is much higher than that of SF-FMLSB. In addition, the stable volume of water absorption of SF-FMLSB is smaller than that of AF-FMLSB at low density, and the corresponding water resistance is better, but the situation is reversed at high density. Full article

The study is focused on ultra-light foam concrete (FC) aimed as a thermal insulation material. Two important properties of such material were investigated: compressive strength and thermal conductivity. In the conducted tests, the influence of the air-dry density (200–500 kg/m³), type of foaming agent (synthetic and protein) and binder type (ordinary Portland cement—OPC; calcium sulphoaluminate cement—CSA; metakaolin; siliceous fly ash—SFA; calcareous fly ash—CFA) on the mentioned properties were examined. The results confirmed the dependence of compressive strength and thermal conductivity on the FC density but also indicated the important effect of the nature of the foaming agent and the binder type. The best thermo-mechanical properties were obtained for the foam concrete made of protein-based foaming agent, OPC and metakaolin. Simultaneously, the use of CSA mixed with metakaolin and foam based on the synthetic foaming agent also shows satisfactory properties. Full article

Minimally invasive endovascular embolization is a widely used clinical technique used for the occlusion of blood vessels to treat various diseases. Different occlusive agents ranging from gelatin foam to synthetic polymers such as poly(vinyl alcohol) (PVA) have been commercially used for embolization. However, these agents have some drawbacks, such as undesired toxicity and unintended and uncontrolled occlusion. To overcome these issues, several polymer-based embolic systems are under investigation including biocompatible and biodegradable microspheres, gelling liquid embolic with controlled occlusive features, and trackable microspheres with enhanced safety profiles. This review aims to summarize recent advances in current and emerging polymeric materials as embolization agents with varying material architectures. Furthermore, this review also explores the potential of combining injectable embolic agents and cell therapy to achieve more effective embolization with the promise of outstanding results in treating various devastating diseases. Finally, limitations and challenges in developing next-generation multifunctional embolic agents are discussed to promote advancement in this emerging field. Full article

Phenolic acids (PAs) are natural antioxidant agents in the plant kingdom that are part of the human diet. The introduction of naturally occurring PAs into the network of synthetic shape memory polymer (SMP) polyurethane (PU) foams during foam fabrication can impart antioxidant properties to the resulting scaffolds. In previous work, PA-containing SMP foams were synthesized to provide materials that retained the desirable shape memory properties of SMP PU foams with additional antimicrobial properties that were derived from PAs. Here, we explore the impact of PA incorporation on SMP foam antioxidant properties. We investigated the antioxidant effects of PA-containing SMP foams in terms of in vitro oxidative degradation resistance and cellular antioxidant activity. The PA foams showed surprising variability; p-coumaric acid (PCA)-based SMP foams exhibited the most potent antioxidant properties in terms of slowing oxidative degradation in H₂O₂. However, PCA foams did not effectively reduce reactive oxygen species (ROS) in short-term cellular assays. Vanillic acid (VA)- and ferulic acid (FA)-based SMP foams slowed oxidative degradation in H₂O₂ to lesser extents than the PCA foams, but they demonstrated higher capabilities for scavenging ROS to alter cellular activity. All PA foams exhibited a continuous release of PAs over two weeks. Based on these results, we hypothesize that PAs must be released from SMP foams to provide adequate antioxidant properties; slower release may enable higher resistance to long-term oxidative degradation, and faster release may result in higher cellular antioxidant effects. Overall, PCA, VA, and FA foams provide a new tool for tuning oxidative degradation rates and extending potential foam lifetime in the wound. VA and FA foams induced cellular antioxidant activity that could help promote wound healing by scavenging ROS and protecting cells. This work could contribute a wound dressing material that safely releases antimicrobial and antioxidant PAs into the wound at a continuous rate to ideally improve healing outcomes. Furthermore, this methodology could be applied to other oxidatively degradable biomaterial systems to enhance control over degradation rates and to provide multifunctional scaffolds for healing. Full article