Search Results (420)

The Wadi Al-Ahsaba watershed is an arid to semi-arid catchment situated in southwestern Saudi Arabia, characterized by intermittent surface flow, high evaporation and low rainfall, and a dam reservoir built for flood control. The work aims to assess hydrological and anthropogenic controls on surface and groundwater quality, pollution status, and human health risks using an integrated approach of hydrogeochemical analysis, multivariable statistics, and water quality and contamination indices. A total of 21 water samples (15 surface water, 6 groundwater) were analyzed for general chemistry, major ions, and trace elements. Hydrogeochemical analysis and principal component analysis (PCA) were implemented to differentiate the geogenic from anthropogenic control on water quality. The pollution status and associated risk were evaluated using water quality index (WQI), contamination degree (Cd), Hazard Quotient (HQ), and Hazard Index (HI). Results suggest limited surface–groundwater interaction, with surface water dominated by Ca–Mg–HCO₃ facies, indicating recent recharge and limited water–rock interaction, whereas groundwater exhibits mixed Ca–Mg–Cl and Ca–Na–Cl–SO₄ types, revealing longer residence time and water–rock interaction. Nitrate (9.5–109 mg/L) and TDS (522–1003 mg/L) exceeded drinking water standards in 90% and 95% of tested samples, respectively, and WQI ranged from 43 to 134, reflecting excellent to poor water. High non-carcinogenic risk from nitrate was observed, especially for infants. The study concluded that the geogenic processes (water–rock interaction, evaporation, and mineral dissolution) control the general chemistry of tested water, while anthropogenic input from wastewater and agriculture input are likely contributors to nitrate contamination. The study contributes to the understanding of arid wadi-dam systems by revealing how limited recharge, hydrological connectivity, and episodic flow control contaminant transport and persistence, underscoring the critical role of integrated hydrological analysis and land use management in safeguarding freshwater resources in arid environments. Full article

Surface water-groundwater interaction zones are critical ecohydrological interfaces in arid regions, yet quantitative spatiotemporal patterns and soil-vegetation responses under coupled water-salt-heat gradients remain poorly documented. Based on a one-year monitoring period (August 2024–August 2025) at four sites along a river-to-desert transect (LW3: 25 m, LW2: 200 m, LW1: 300 m, LW4: 400 m from the Niya River) in the hyper-arid Tarim Basin, this study reveals the following quantitative patterns. Groundwater depth increased with distance from the river and followed an annual decrease-increase trend, with an anomalous shallow peak in March 2025 (−20 cm) linked to precipitation recharge. Soil temperature stability increased with depth: the 20 cm layer recorded the widest annual fluctuation (e.g., −1.5 °C to 24 °C at LW1), whereas the 80 cm layer varied only between approximately −0.2 °C and 28 °C. Proximity to the river dampened thermal extremes. Shallow soil moisture was highly dynamic (with a coefficient of variation [CV] reaching 40–50% at LW1 and LW4), while deeper layers remained stable; LW3 near the river stayed saturated year-round (CV = 0). Soil electrical conductivity (EC) decreased with distance from the river: LW3 exhibited the highest surface values (5000–16,000 μS cm⁻¹), whereas LW1 recorded the lowest (1000–2700 μS cm⁻¹). Vegetation performance was governed by coupled water-salt conditions rather than moisture alone: P. australis at LW1 achieved the tallest growth (>200 cm) and highest photosynthetic rates (20.25–37.38 μmol m⁻² s⁻¹), outperforming LW3 (104 cm, winter photosynthesis dropping to 2.01) and LW4 (~100 cm). Correlation analysis further showed strong vertical temperature coupling (r > 0.96 across all depths) and depth-stratified water-salt relationships (e.g., EC-volumetric water content r = 0.95 at 20 cm in LW4), reflecting spatial differentiation driven by freeze-thaw cycles, evaporative enrichment, and homogeneous silt-textured soils (54–96% fine fraction). These quantitative findings provide a detailed observational baseline for riparian ecohydrology in hyper-arid inland rivers and underscore that sustainable vegetation management requires balancing water availability against salinity stress. Full article

Research on the river-groundwater cross-contamination of per- and polyfluoroalkyl substances (PFAS) in karst regions is limited. We therefore investigated the PFAS occurrence, spatial distribution, sources and ecological risks in the Lijiang River basin, a typical karst area. PFAS concentrations were relatively low (0.08–74.0 ng/L, mean 4.13 ng/L). PFBA, PFHxA, PFNA and 6:2 FTS were widely detected. Short-chain PFAS concentrations (0.08–74.0, mean 4.75 ng/L) were higher than long-chain ones (0.02–3.31, mean 0.72 ng/L). Unusually, groundwater PFAS concentrations (0.08–74.0, mean 7.97 ng/L) exceeded those in rivers (0.08–11.7, mean 2.31 ng/L). Positive matrix factorization (PMF) combined with spatial distribution identified five main sources: sewage treatment plants (24.0%), gas station leaks/wastewater discharges (21.3%), untreated domestic sewage (18.1%), small-scale industrial wastewater (16.7%), and agricultural/aquaculture wastewater (20.2%). The ecological risk assessment showed that, except for PFUnDA posing a low risk to algae, the other PFASs presented no significant risk to algae, daphnia or fish. The human health risk assessment indicated minimal direct health risks. Our findings indicate that some PFASs in groundwater and river water may share common sources, highlighting the complex PFAS migration between rivers and groundwater in karst regions. Full article

Per- and polyfluoroalkyl substances (PFASs) are persistent environmental contaminants whose mobility in soil and groundwater is strongly controlled by adsorption and desorption processes. In saturated clay-rich soils, these processes are complex because PFASs interact with hydrated mineral surfaces, organic matter, metal oxides, exchangeable cations, and pore-water constituents. This review synthesizes the current literature on PFAS adsorption and desorption in saturated soils, with an emphasis on clay mineralogy, mineral–water interfaces, pore-water chemistry, and electrochemical double layer (EDL) effects. PFAS retention is influenced by molecular properties such as chain length, functional head group, and charge state, as well as soil properties such as organic carbon content, clay mineral type, surface charge, cation exchange capacity, and Fe/Al oxide content. Longer-chain PFASs and sulfonate-based compounds generally show stronger retention, while shorter-chain PFASs tend to remain more mobile. This review focuses particularly on how an EDL affects PFAS behavior in saturated clay systems. Unlike dry clay surfaces, saturated clay surfaces are covered by structured water, exchangeable ions, and diffuse counterion layers. These hydrated interfacial conditions influence how closely anionic PFASs can approach negatively charged clay surfaces, how dissolved cations reduce electrostatic repulsion or promote cation-mediated binding, and how effectively short-range interactions such as hydrophobic association, van der Waals forces, hydrogen bonding, and surface association contribute to adsorption. Desorption is also emphasized because adsorption does not necessarily represent permanent immobilization. Changes in pH, ionic strength, cation composition, dissolved organic matter, or competing solutes can weaken retention and promote PFAS release. Overall, PFAS mobility in saturated clay-rich soils should be interpreted as a coupled interfacial process rather than simple partitioning to soil solids. Future work should better connect molecular-scale mechanisms, EDL behavior, adsorption–desorption experiments, and saturated transport studies to improve predictions of PFAS retention and long-term groundwater release. Full article

Coastal land reclamation is widely implemented to support coastal development, yet its effects on microbial indicators in coupled surface water–groundwater systems remain poorly understood. This study examined the spatiotemporal variability of four microbial indicators and their environmental associations using 46 months of monthly monitoring (April 2016–January 2020) in eastern Guanghai Bay, China. Total bacterial counts, fecal coliforms, Escherichia coli, and total coliforms were analyzed using multivariate statistical methods. Surface water exhibited elevated levels of fecal indicators, with consistently higher pollution levels in the Xiaoma River than in the Dama River and clear seasonal variation associated with climatic and hydrological conditions. Groundwater showed pronounced spatial heterogeneity: Wells 1 and 2 exhibited relatively elevated microbial contamination, whereas Well 3 maintained persistently low microbial levels under high-salinity and high-alkalinity conditions. These patterns suggest that reclamation may be associated with groundwater microbial distribution through changes in groundwater transport pathways and hydrochemical conditions, while anthropogenic pressures also played an important role in shaping contamination patterns. These findings offer practical insights for groundwater protection and sustainable management in reclaimed coastal environments. Full article

Surface water–groundwater interactions play a critical role in regulating hydrological fluxes and sustaining water availability, yet they remain poorly understood in hydrogeologically complex terrains. This study employed an integrated modeling approach combining SWAT+ and MODFLOW to quantify water balance components, groundwater flow dynamics, and river–aquifer exchanges in the Chemoga watershed, a representative headwater system of the Upper Blue Nile Basin characterized by strong environmental and geological contrasts. Model results revealed substantial spatial heterogeneity in hydrological partitioning, with annual groundwater recharge ranging from 105 to 711 mm (mean = 296 mm; 24% of annual rainfall). Simulated groundwater flow exhibited a pronounced topographic control, with hydraulic heads declining from highland recharge zones toward deeply incised lowland gorges. River–aquifer interactions showed marked spatial variability, with the Chemoga river predominantly acting as a gaining stream in the highland and nick-point gorge sections (up to 2867 m³ d⁻¹), while transitioning to a losing stream in the midland floodplains and lowland gorge areas, with leakage reaching up to 75.0 m³ d⁻¹. These findings highlight the value of integrated, process-based modeling for resolving complex hydrological interactions, advancing understanding of groundwater flow regimes and supporting sustainable groundwater management in the Ethiopian highlands and other similar regions worldwide. Full article

Accurate estimation of actual evapotranspiration (ETa) is essential for understanding hydrological processes and managing water resources, especially in regions characterized by intensive agriculture and complex groundwater–surface interactions. This study intercompares three independent satellite-based ETa estimation approaches applied over Northeast Italy. The first two methods correspond to the classical MODIS algorithm (MOD16), which is based on a simplified Penman–Monteith approach, and to the more recent Sen-ET modelling framework, which relies on a surface energy balance principle. The outputs of these methods are compared to those produced by a water balance algorithm, NDVI-Cws, which predicts ETa through the combination of conventional ancillary data and MODIS NDVI imagery. The results obtained show that, while the MODIS algorithm yields ETa estimates which are generally lower than those of Sen-ET and NDVI-Cws, the latter methods produce similar predictions for most cover types examined. The same two methods are potentially capable of providing higher spatial resolution daily ETa estimates depending on the satellite inputs used; out of them, however, only NDVI-Cws can yield spatially complete and temporally continuous datasets. The analysis therefore provides insights into the reliability and usability of different remote sensing approaches for regional-scale water resource monitoring. Full article

Computational models have gained recognition as effective tools for estimation of urban water balance. Beyond personal skills, the selection of an appropriate model requires an understanding of the city’s water system, the capabilities of the model and data requirements. Kabul represents a rapidly urbanizing city with limited water and sanitation infrastructure. To analyze the urban water balance of Kabul, ten prominent open-source and commercial hydrological models were evaluated. The characteristics of the models along with their data requirements, calibration parameters, and applications are assessed through a review of previous studies and user manuals. The study demonstrates that assessing Kabul’s urban water balance requires explicit consideration of processes such as snowmelt, groundwater abstraction, surface water–groundwater interaction and irrigation. The urban water balance of Kabul and cities with similar conditions can be effectively modeled using tools such as MIKE SHE, SWAT, and WEAP. The flexibility of the MIKE SHE model and its ability to use time-varying raster data make it a viable option for analyzing water balance under changing land cover and climatic conditions. Lumped models account for limited spatial variability and rely on empirical fitting. In contrast, physically based models reduce reliance on empirical calibration. However, they are more data-intensive and complex than simpler conceptual models. Full article

This study investigates the structure–performance relationship of Fe³⁺- and Zr⁴⁺-modified layered double hydroxides (LDHs) for fluoride removal from water. Mg–Al LDHs with different metal loadings (Zr0.05, Zr0.1, Fe0.8, and Fe1) were synthesized via ultrasound-assisted coprecipitation and characterized using XRD, SEM–EDS, FTIR, XPS, and N₂ physisorption. Among the synthesized materials, Zr0.05-LDH exhibited the highest adsorption performance. Response surface methodology identified adsorbent dosage as the most influential parameter, achieving a maximum fluoride removal efficiency of 98.17% under optimal conditions (pH ≈ 5, adsorbent dose of 0.88 g/L, and initial fluoride concentration of 12.6 mg/L). Zr0.05-LDH showed the largest specific surface area (261 m²/g) and a maximum adsorption capacity of 137 mg/g, as described by the Langmuir isotherm model. Kinetic studies indicated rapid adsorption, with equilibrium reached at approximately 180 min. Fluoride removal was governed primarily by inner-sphere complexation at Zr⁴⁺ and Fe³⁺ sites, accompanied by anion exchange and electrostatic interactions. The adsorbent retained 89% of its capacity after five regeneration cycles. Groundwater tests from Durango, Mexico, demonstrated effective fluoride reduction below Mexican and WHO guideline limits despite competing anions. These results demonstrate the potential of modified LDHs for fluoride-contaminated groundwater treatment. Full article

A one-pot strategy was developed for preparing a chitosan/Mg–Fe layered double hydroxide (LDH) composite by alkaline coprecipitation from an acidic chitosan solution containing Mg(II) and Fe(III) precursors, avoiding separate LDH synthesis and subsequent incorporation into chitosan. X-ray diffraction confirmed LDH formation within the chitosan matrix, and ICP analysis indicated an LDH-equivalent content of approximately 4.1 wt.% on an anhydrous basis. The composite exhibited enhanced chromate adsorption compared with both starting components. The experimental plateau adsorption capacity reached 137.4 mg/g, exceeding those of chitosan (92.2 mg/g) and Mg–Fe LDH (53.5 mg/g). Nonlinear isotherm fitting showed that Mg–Fe LDH was better described by the Freundlich model, whereas chitosan and the composite were better described by the Langmuir model. The kinetic behavior followed the pseudo-second-order equation, while Weber–Morris analysis indicated multistep uptake involving surface interaction and diffusion-related processes. In simulated groundwater containing chloride, bicarbonate, and sulfate, the composite removed 82% of Cr(VI) at 1.0 g/L. It also retained complete chromate uptake over five sorption/desorption cycles, although desorption efficiency decreased from 97.3% to 90.3%. A limitation of this study is that performance was evaluated mainly in batch systems and simplified simulated groundwater; validation with real contaminated waters and dynamic flow conditions is still required. Full article

Numerical simulations quantify the transient impacts of implementing green infrastructure (GI) grass swales on unconfined aquifer storage and groundwater-surface water interactions around the Red Butte Creek (RBC) of Utah, USA. The Red Butte Creek Watershed (RBCW) transitions from undeveloped mountainous National Forest land to downstream urbanized areas within Salt Lake Valley (SLV). This reconnaissance-level study demonstrates that increasing stormwater infiltration in urbanized areas during the rainy months (April-June) can, until at least the subsequent March, (a) enhance aquifer recharge and support sustainable groundwater yields; and (b) improve surface water availability. Simulations predict hydrologic impacts of aquifer recharge resulting from hypothetical grass-swale implementation within a 704-acre area located around RBC. The employed model, HyperRBC, is an adaptation of a United States Geological Survey (USGS) transient numerical flow, MODFLOW, model implementation for SLV. Adaptations involved (a) uniformly refined horizontal discretization of seven aquifer layers within a sub-area encompassing parts of RBCW and an adjacent watershed; (b) updated input data; and (c) MODFLOW’s Streamflow-Routing (SFR) package to simulate RBC flow and aquifer-stream seepage. Model predictions indicated that by the end of next March: (a) about 3% of the GI-induced recharge would remain within the unconfined aquifer in the HyperRBC area; (b) 66.6% of the recharge would flow northward into the downgradient continuation of the unconfined aquifer; and (c) 30.3% would discharge to nearby stream and river. In summary, predicted hydrologic changes due to the short-term GI-induced recharge highlight increased groundwater availability within and outside the study area for at least the subsequent 12 months, including high-water-demand summer. These findings show the importance of GI in interim environmental management and in enhancing the effective use of water resources. Full article

The Xianglaqu River Basin, a major recharge area of the Xiagacuo endorheic lake basin on the Tibetan Plateau, provides an ideal setting for investigating hydrochemical evolution in alpine arid closed basins. In this study, 27 groundwater, spring-water, and surface-water samples collected from June to August 2023 were analyzed using correlation analysis, Piper diagrams, Gibbs diagrams, and ion-ratio methods. The results show that groundwater, spring water, and most surface water are predominantly of the HCO₃⁻–Ca·Mg type, indicating overall hydrochemical consistency across the basin. However, marked spatial differentiation occurs along the flow system: upstream waters are relatively simple and stable, whereas downstream and terminal surface waters show pronounced increases in Na⁺, Cl⁻, SO₄²⁻, and TDS, and some samples exhibit a tendency toward HCO₃⁻–Na facies. These patterns reflect progressive solute accumulation and terminal enrichment in the closed basin. Hydrochemical evolution is controlled mainly by water–rock interaction, with carbonate weathering as the dominant source of major ions, while silicate weathering, minor local saline-mineral dissolution, cation exchange, and evaporation concentration further influence water chemistry. Overall, the basin is characterized by local weathering release, along-path solute accumulation, and terminal evaporative enrichment. Full article

Transboundary basins in arid and semi-arid regions are increasingly stressed by groundwater depletion, drought, and competing upstream water-management policies. Quantifying surface–groundwater interactions in such systems remains challenging due to sparse hydroclimatic observations. This study develops and applies a fully coupled SWAT–MODFLOW model to the Tigris–Euphrates River Basin (TERB; ~900,000 km²), the largest transboundary basin in the Middle East, to evaluate spatiotemporal stream–aquifer interactions and basin-scale water balance. The model integrates SWAT 2012 with MODFLOW-NWT at daily and monthly time steps and was calibrated and validated against monthly streamflow records from 23 gauges and groundwater levels from four wells over 1981–2002, with a 1976–1980 warm-up period. A multi-stage calibration strategy was adopted, including standalone SWAT calibration using SUFI-2, standalone MODFLOW calibration using PEST, and subsequent coupled refinement. Model performance was satisfactory, with Nash–Sutcliffe efficiencies exceeding 0.5 for streamflow and strong agreement between simulated and observed groundwater levels (R² = 0.92). Basin-integrated total water storage anomalies showed reasonable agreement with GRACE-derived estimates for 2002–2013 (R² ≈ 0.72). The basin-averaged net stream–aquifer exchange was estimated at −7.08 × 10⁶ m³ yr⁻¹, indicating net river leakage to aquifers, with a marked intensification after 1987 consistent with major upstream reservoir developments. Recharge patterns were highest over permeable foothill formations and lowest over consolidated northern highlands. The integrated use of streamflow, groundwater, and GRACE observations within a fully coupled framework provides a transferable approach for water-resources assessment in data-scarce transboundary basins. Full article

Groundwater–surface water interactions in volcanic hydrogeological systems represent a key process in river dynamics and were preliminarily investigated along a river draining the southern sector of the Sabatini Mountains (central Italy) using an integrated hydrogeological and geochemical approach. Serial discharge measurements, combined with physico-chemical parameters, major ions, stable oxygen isotopes, and radon analyses, reveal marked spatial variability in river–aquifer exchanges along distinct river reaches. The Arrone River exhibits clear differences between upstream, intermediate, and downstream sections, reflecting the relative influence of localized anthropogenic inputs, diffuse groundwater discharge from the volcanic aquifer, and subsurface flow contributions. Upstream reaches are characterized by pronounced modifications in discharge and chemistry, whereas intermediate and downstream reaches show progressive groundwater influence, resulting in distinct geochemical signatures and changes in water quality. Correlation and cluster analyses identify reach-specific processes controlling water composition and support the recognition of gaining and mixed river conditions under varying hydrological regimes. These results constrain a conceptual model in which river behavior is governed by spatially heterogeneous groundwater inflows, modulated by seasonal discharge dynamics and local human pressures. This study highlights the importance of reach-scale investigations for understanding SW–GW interactions in volcanic settings and provides transferable insights relevant to groundwater-dependent river systems. Full article