Search Results (716)

Partial substitution of ordinary Portland cement (OPC) with supplementary cementitious materials is a key strategy for reducing the clinker factor and associated CO₂ emissions from cement production. This study investigates the feasibility of incorporating untreated electric arc furnace steel slag (EAF-SS), collected from a steel plant in Kenitra, Morocco, as a partial replacement of OPC in Portland cement. The material was characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), and particle size distribution (PSD) analysis. Cement blends containing 2–15 wt.% EAF-SS as a replacement of OPC were prepared and tested in accordance with EN standards to evaluate consistency, setting time, density, porosity, and compressive and flexural strengths at 2, 7, and 28 days. Increasing EAF-SS content from 2% to 15% slightly delayed the initial setting time by 3–17 min and reduced early-age compressive strength from 36 MPa for OPC to 26 MPa for the 15% blend at 2 days. At 28 days, mixtures containing 2–5% EAF-SS achieved compressive strengths of 42–52 MPa, satisfying class 42.5R requirements, whereas higher replacement levels (10–15%) reduced strength to 36–39 MPa. Flexural strength decreased from 7.5 MPa for OPC to 5.7 MPa for the 15% blend at 2 days and to 7.3 MPa at 28 days, while density decreased by 2–4% and total porosity increased from 12% to 18% with increasing slag content. Drying shrinkage decreased slightly with increasing EAF-SS content, from 630 µm/m for OPC to 560 µm/m for BC15 at 28 days, suggesting a modest beneficial effect on dimensional stability. The investigated slag exhibited an Fe₂O₃ content of ~57 wt.%, substantially higher than values commonly reported for many European and Chinese EAF slags. Accordingly, the novelty of the present work lies not simply in the geographical origin of the material, but in the standardized experimental assessment of a compositionally atypical, untreated, Fe-rich EAF steel slag used directly as a partial replacement of OPC in Portland cement. The study is intended as a first performance-oriented evaluation of this Moroccan by-product under EN-based testing conditions, rather than as a complete mechanistic or environmental assessment. These findings support the feasibility of low-level EAF-SS incorporation in blended cement and indicate a potential contribution to clinker factor reduction and associated CO₂ savings under the assumptions adopted in this study. However, the environmental benefit assessment remains preliminary and should be confirmed by full life-cycle and leaching analyses. Full article

The growing demand for sustainable construction materials has stimulated interest in alternative binders derived from waste resources. This study investigates the use of calcined crab shell (CCS), a calcium-rich marine biowaste, as a partial replacement for Portland limestone cement. Cement pastes containing 0%, 5%, 10%, and 15% CCS were prepared and evaluated through compressive strength, water absorption, open porosity, bulk density, SEM, XRD, FTIR, and TGA analyses. The results showed that incorporating 10% CCS produced the most favorable performance, increasing compressive strength from 17.6 MPa to 33.6 MPa after 28 days of curing. This improvement was accompanied by reduced porosity, increased bulk density, and the development of a denser and more homogeneous microstructure. Physicochemical analyses suggest that CCS acts both as a filler and as a source of reactive calcium species. The CaO generated during calcination may participate in hydration processes and influence the formation of hydration products, contributing to matrix densification. In contrast, the incorporation of 15% CCS resulted in increased porosity, a less homogeneous microstructure, and lower mechanical performance. These findings indicate that replacing Portland limestone cement with up to 10% CCS can improve the properties of cement pastes while promoting the valorization of marine shell waste and reducing cement consumption, thereby supporting the development of more sustainable construction materials. Full article

This study evaluates the feasibility of utilizing wood ash (WA), derived from grilled-fish barbecue waste, as a supplementary cementitious material, in combination with crushed clay blocks (CCB) as partial or full replacements for natural coarse aggregate, to improve the sustainability of concrete. A total of twelve concrete mixtures were produced using WA replacement levels of 0%, 10%, 20%, and 30% and CCB replacement levels of 0%, 50%, and 100%. The concrete specimens were evaluated in terms of workability, compressive strength, splitting tensile strength, flexural strength, density, water absorption, ultrasonic pulse velocity (UPV), thermal conductivity, and microstructural characteristics using scanning electron microscopy (SEM). The results show that replacing cement with 10% WA achieved the highest mechanical performance at 56 days, with compressive, splitting tensile, and flexural strengths of 50.58 MPa, 5.54 MPa, and 6.07 MPa, respectively. These results represent an improvement of 11% in concrete properties compared with the control mixture. However, the use of 20% of WA enhanced microstructural densification through pozzolanic reactions, whereas higher replacement levels resulted in increased porosity, the presence of unreacted particles, and reductions in strength and UPV values. In contrast, increasing the WA and CCB contents reduced density and workability while significantly increasing water absorption. Among the investigated mixtures, the combination of 10% WA and 50% CCB provided the most favorable balance between mechanical performance, thermal efficiency, and sustainability. Further studies are recommended to evaluate the long-term durability and economic feasibility of the proposed replacement levels for sustainable concrete production. Full article

The significant CO₂ emissions from cement manufacturing and overuse of natural aggregates, especially river sand mining, have been a global environmental concern for decades. This is a review study that aimed to evaluate the solution by reviewing past studies on the incorporation of supplementary cementitious materials (SCMs) and recycled aggregates (RAs) to produce sustainable concrete (SC). Regarding environmental consequences, the results highlighted that the cement industry accounts for a 5–8% carbon footprint. Concurrently, the demand for high-quality river sand has escalated, leading to widespread river degradation, altered channel morphology, and effects on river ecosystems. Past studies’ experimental results indicate that silica fume (SF), as an effective SCM, enhances the strength and durability of sustainable concrete to its optimal levels. However, the higher RA content resulted in reductions in engineering properties. The published studies also reported that lower percentages of SF combined with RAs had a positive effect on the strength and durability of design mix concrete, thereby further strengthening the findings of this review. This factor was found to be missing in most studies. A cost–benefit analysis for combined SCMs and RAs was introduced in this study. This review study evaluated the cost–benefit analysis of 1 m³ of sustainable concrete. The highest benefit was observed at 20.97% in a study when optimized 10%SF + 100 RAs were combined. It showed that the combined use of SCMs with RAs at optimal levels satisfied the strength and durability requirements. In addition, the benefits of sustainable concrete were achieved without any cost increase, a new outcome revealed by this review. Full article

Urbanisation-driven housing demand and the environmental burden of sewage sludge disposal highlight the need for low-carbon, circular construction materials. This study evaluates incinerated sanitary sludge ash (ISSA) as a supplementary cementitious material in stabilised earth blocks, aiming to reduce the use of cement and lime while valorising waste sludge. Lateritic soil blocks were produced with a binder-to-soil ratio of 1:7 by mass, in which ISSA partially replaced the primary stabilising binder (cement or lime) at a replacement level of 10–40% within the binder fraction. ISSA’s mineralogical characteristics were analysed using XRD and XRF. The compressive strength and density of earth blocks were measured at 7 and 28 days under curing conditions (29–36 °C; 60–75% humidity). Cement-stabilised blocks were water-cured to support cement hydration, whereas lime-stabilised blocks were air-cured to promote carbonation and pozzolanic reactions. The results, therefore, compared practical binder-specific curing regimes rather than strictly identical curing environments. ISSA exhibited moderate pozzolanic potential, and its incorporation enabled substantial partial replacement of both binders. Cement-stabilised blocks achieved higher strengths, up to 7.7 MPa, after 28 days of curing, whereas lime-stabilised blocks developed strength more gradually, reaching 4.8 MPa. Optimal mixtures were identified at 40% cement + 60% ISSA and 30% lime + 70% ISSA, balancing mechanical performance and binder reduction. A positive density–strength relationship was observed, but chemical bonding predominated over densification effects. ISSA-based stabilised earth blocks show promising structural performance and reduced binder use, but durability and life-cycle assessment need further evaluation before large-scale implementation. Full article

The growing demand for low-carbon cementitious materials has increased interest in natural zeolite as a supplementary cementitious material capable of reducing clinker consumption while modifying cement system performance. This study presents an integrated experimental evaluation of natural zeolite-modified cementitious materials by combining rheological behavior, hydration, compressive strength, density, scanning electron microscopy (SEM), and X-ray diffraction (XRD) within a single experimental framework. Natural zeolite was used as a partial replacement for cement at dosages of 5–12.5 wt.%. The results showed that zeolite significantly affected both fresh-state and hardened-state properties. Zeolite increased the rheological resistance of fresh mixtures, shifted the exothermic hydration peak from 12 h to 8–10 h, and reduced the maximum hydration temperature by approximately 8–12%. Among the investigated compositions, the mixture containing 7.5% zeolite exhibited the highest compressive strength (44.9 MPa at 28 days) together with increased hardened density, suggesting more efficient particle packing and matrix development than the reference mixture. SEM observations indicated a more uniform distribution of hydration products in mixtures containing moderate zeolite dosages, while XRD analysis confirmed changes in the crystalline phase assemblage associated with zeolite incorporation. The results demonstrate that moderate natural zeolite replacement, particularly at 7.5%, provides an effective balance between rheological behavior, hydration characteristics, mechanical performance, and microstructural development, highlighting its potential as a sustainable supplementary cementitious material for low-carbon cement-based composites. Full article

This study (Part B) examines the potential utilization of municipal solid waste (MSW) ash, produced in a semi-industrial incinerator in Israel, as a partial substitute for cement and natural sand in industrial concrete mixtures. The ash was produced at the temperature range 600–850 °C, and the ash was characterized using XRD and SEM to determine its mineralogical composition and morphology. The results indicate that ash composition is dominated by calcium-rich phases, with hatrurite (Ca₃SiO₅) representing approximately 51–66 wt.% of the identified crystalline phases, along with calcite, MgO, and silica phases. The ash consists of irregular, porous particles with a broad distribution. Concrete performance was evaluated in both fresh and hardened states. In terms of fresh concrete properties, it is observed that concrete containing ash showed improved workability, better workability retention, and better concrete density compared to concrete without ash. In terms of hardened concrete properties, the use of MSW ash as a partial sand replacement preserved the mechanical performance of the concrete, with compressive strength remaining within approximately 2% of the reference mixture. These findings suggest that semi-industrially produced MSW ash is more suitable as a fine aggregate replacement than as a supplementary cementitious material and represents a promising route for reducing landfill disposal and promoting circular economy practices in the construction industry. Full article

The growing demand for sustainable construction materials has led to significant advancements in ultra-high-performance concrete (UHPC), with a particular focus on geopolymer-based systems as an alternative to conventional cementitious binders. This review explores the latest developments in sustainable Ultra-High-Performance Geopolymer Concrete (UHPGPC) by analysing key material composition, mechanical, durability and microstructural properties. The incorporation of ground granulated blast furnace slag (GGBFS), silica fume (SF), and fly ash (FA) has demonstrated notable improvements in compressive strength, durability, and workability. Additionally, the use of activators such as sodium silicate and sodium hydroxide optimizes geopolymerization, resulting in a denser microstructure and enhanced mechanical performance. This review highlights the critical role of fibre reinforcement in UHPGPC, where steel fibres (SFs) and hybrid fibres significantly enhance compressive and tensile strength, as well as crack resistance. The inclusion of waste materials such as rice husk ash and recycled glass promotes sustainability by reducing CO₂ emissions while maintaining structural integrity. However, higher waste-glass content may adversely affect bonding due to its smooth surface texture. The findings highlight the potential of UHPGC as a high-performance, eco-friendly alternative to traditional cement-based UHPC. By integrating industrial by-products and alternative activation techniques, UHPGPC can contribute significantly to the global shift towards sustainable and low-carbon construction materials. Full article

Supplementary cementitious materials and aeolian sand have been used to produce low-carbon ultra-high-performance concrete (UHPC) due to their beneficial effects on the reduction in production cost and carbon emissions. However, low-carbon UHPC still faces some drawbacks, such as lowered mechanical properties, large shrinkage, and a tendency for cracking. This study proposed an approach to improve the performance of low-carbon UHPC by incorporating recycled coarse aggregate. The effects of recycled coarse aggregate type, particle size, and content on the workability and mechanical properties of low-carbon UHPC were investigated. Moreover, the internal relative humidity and volume stability of UHPC containing recycled coarse aggregate was also explored. At last, the hydration products and microstructure of UHPC was analyzed to shed light on the underlying mechanisms for the improved performance. Full article

The utilization of construction and demolition waste (CDW) as a supplementary cementitious material (SCM) represents a promising strategy for reducing cement consumption, minimizing environmental impacts, and promoting sustainable waste valorization. In this study, hybrid recycled powder was produced from mixed CDW obtained from a Portuguese recycling facility and processed through mechanical grinding to achieve particle size characteristics comparable to Portland cement. The ground powder was subsequently thermally activated at 600 °C and evaluated as a partial replacement for Portland cement in concrete. Concrete mixtures were prepared with recycled powder replacement contents of 5%, 15%, 25%, and 35%. The physical, mechanical, and durability properties of the concrete were investigated, including density, water absorption, compressive strength, carbonation and chloride penetration resistance. The results indicate that thermally activated recycled powder can be successfully incorporated as a partial cement replacement while maintaining satisfactory mechanical and durability performance. These findings demonstrate that thermally activated hybrid recycled powder derived from mixed CDW has significant potential as a sustainable SCM, contributing to reduced cement consumption and supporting the development of low-carbon concrete. Full article

Concrete contributes significantly to global CO₂ emissions due to high energy demand for cement production. This research integrates multiple advanced ensemble ML-based prediction models by combining experimental evaluation, explainable framework, and life cycle sustainability analysis for SCM (supplementary cementitious materials)-incorporated concrete mixtures. A comprehensive experimental program was conducted to evaluate the compressive and tensile strength of concrete revealing that the hybrid mix of GF4 with a 40% replacement level of cement with fly ash (FA) and ground granulated blast furnace slag (GGBFS) exhibited optimum synergistic performance due to balanced hydration kinetics and improved microstructure characteristics. For computational model development, a k-fold cross validation technique was deployed to evaluate robustness across multiple data partitions and to control overfitting in models. Model performance was assessed through multiple metrics including R², RMSE, and MAE with particular emphasis on the gap between training and testing performance. The best performing model was optimized using Particle Swarm Optimization (PSO) and Bayesian Optimization (BO) techniques providing an additional safeguard against overfitting. Shapley Additive Explanation (SHAP) interpretation revealed w/b ratio and curing age as key parameters for compressive strength, while fine aggregate content and curing age influenced tensile strength. For compressive strength, XGBoost model performed well with an R² value of 0.879 which was increased to 0.918 with the PSO optimization technique. For tensile strength, the Gradient Boosting model was selected with an R² value of 0.840 which was optimized to 0.879 after the PSO optimization technique. Moreover, life cycle assessment was performed to evaluate the environmental impacts in terms of embodied carbon and energy associated with concrete mixes. The hybrid GF4 mix demonstrated a 36% reduction in embodied carbon compared to the control mix, indicating strong potential for low carbon concrete applications. This integrated research contributes to the advancement of green construction practices and supports global efforts to reduce atmospheric impacts through the circular use of industrial byproducts. Full article

This study systematically investigated the durability of low-carbon concrete under severe service conditions using industrial solid wastes. The mechanical properties and carbonation resistance (including carbonation depth, compressive strength after carbonation, and splitting tensile strength after carbonation) were tested. Multi-scale characterization techniques, including XRD, SEM-EDS, and nanoindentation, were employed to investigate the microstructure. This approach revealed a synergistic mechanism linking microstructural evolution to the concrete’s macroscopic mechanical and durability performance. Results showed that incorporating 25% fly ash (FA) reduced compressive strength by 11.30% and 11.39% in CF-25 and BF-25 mixes, respectively, and increased carbonation depth by 58.46% in CF-25. In contrast, the addition of 5% silica fume (SF) produced different effects. It significantly enhanced the compressive strength of the CS-5 and BS-5 mixes by 18.92% and 9.94%, respectively. Furthermore, it improved the micromechanical properties of the interfacial transition zone (ITZ) and reduced its thickness. Micro-mechanistic analysis revealed that the low pozzolanic activity of FA at early ages led to insufficient hydration products, higher porosity, and a weaker ITZ. Conversely, SF, through its high pozzolanic reactivity and nano-filling effect, promoted a dense, highly polymerized gel structure and optimized pore size distribution. The distinct chemical characteristics of high-calcium and low-calcium cementitious systems further amplified the differential effects of these supplementary materials. Full article

High-performance and ultra-high-performance fiber-reinforced concretes (HPFRC/UHPFRC) have emerged as advanced cementitious composites capable of achieving superior mechanical performance, durability, and structural efficiency compared with conventional concrete. However, their widespread adoption remains challenged by relatively high material costs and significant embodied environmental impacts associated with elevated binder and fiber contents. This study presents a comprehensive life-cycle review of advanced high-performance cementitious composites, evaluating their sustainability from raw material extraction and mix design to structural application, service life, and end-of-life considerations. The review synthesizes current knowledge on material composition, production processes, structural performance, durability characteristics, and environmental impacts through the framework of life-cycle assessment (LCA). Particular attention is given to the influence of mix-design parameters, including binder composition, supplementary cementitious materials (SCMs), aggregate systems, and fiber type, on embodied carbon, energy demand, and mechanical performance. A dataset compiled from published experimental studies covering high-performance and ultra-high-performance concrete mixtures is analyzed to examine relationships between compressive strength, embodied energy, and carbon footprint, highlighting the dominant role of cementitious binders and fiber production in environmental impacts. Although advanced fiber-reinforced concretes generally exhibit higher cradle-to-gate emissions than conventional concrete, their superior mechanical properties, improved durability, reduced material demand, and extended service life can substantially reduce life-cycle environmental impacts at the structural level. The review further discusses emerging strategies for developing low-carbon high-performance cementitious composites, including clinker reduction, recycled and alternative fibers, optimized particle packing, and AI-assisted mix design. Finally, key research gaps are identified, particularly regarding standardized LCA methodologies, long-term durability data, harmonized performance-based functional units, and circular-economy strategies for material recycling and reuse. The findings highlight that performance-based life-cycle evaluation is essential for accurately assessing the sustainability potential of advanced high-performance cementitious composites in resilient and low-carbon infrastructure systems. Full article

Agricultural biomass ashes are increasingly used as sustainable supplementary cementitious materials (SCMs) to reduce cement-related carbon emissions and improve concrete performance. However, their effects on compressive strength depend on the SCM type, replacement level, and physical and chemical properties. These variables are often overlooked in machine learning studies focused on single SCM types and absolute strength prediction, limiting transferability across heterogeneous SCM datasets. This study develops an interpretable machine learning framework using a compiled dataset covering 18 agricultural biomass ash SCMs (bio-SCMs) used in concrete. Input features include concrete mixture proportions, the SCM replacement level, chemical composition, and specific surface area (SSA), while the target variable is the 28-day compressive-strength ratio relative to the companion control mixture. Among the five evaluated models, XGBoost achieved the best performance, with weighted 10-fold cross-validation R² values around 0.80. SHapley Additive exPlanations (SHAP) results were interpreted as model associations rather than causal mechanisms. Higher SCM SiO₂ content, pozzolanic oxide content, superplasticizer dosage, and baseline control mixture strength were associated with more favorable strength ratios; SCM SSA showed a mild positive tendency, whereas a higher SCM replacement level, water-to-binder ratio, and loss on ignition were associated with less favorable strength ratios. SCM-specific response analysis further identified literature-derived screening ranges based on observed and interpolated replacement levels rather than machine learning extrapolation. Full article

This study investigates the use of Alkali Bypass Dust (ABD), a cement kiln waste, as a supplementary cementitious material in mortar. Direct ABD incorporation reduced workability and strength. A dual-modification strategy employing a water reducer (WR) and silica fume (SF) was implemented. Mortars with 0–50% cement replaced by ABD were tested, with and without modifiers. Results showed that WR effectively restored workability and improved early strength, while SF enhanced long-term performance through pozzolanic reactions. A synergistic effect in ternary blends (ABD + WR + SF) yielded 28-day compressive strength at 50% ABD replacement comparable to the control (49.9 MPa). Statistical analysis via Response Surface Methodology confirmed that material interactions, not individual amounts, primarily govern strength development. All models are significant where R² value is higher than 0.80. The statistically validated models can be used to optimize the mix proportions for desired compressive and flexural performance. The study concludes that optimized blends with 30–50% ABD are viable for non-structural applications, offering a sustainable pathway for waste valorization and reduced cement consumption. Full article