Search Results (29)

For the large-scale fusion magnets of the International Thermonuclear Experimental Reactor (ITER) tokamak, wound with cable-in-conduit conductors, the application of sophisticated numerical models able to analyse the thermal–hydraulic behaviour during plasma scenarios is of paramount importance to guarantee an adequate stability margin during operating conditions. The SuperMagnet code has been developed by CryoSoft with the intent to simultaneously simulate the electrical, thermal and hydraulic phenomena occurring during the operation of superconducting coils. In this work, the SuperMagnet code is applied to analyse the thermal–hydraulic behaviour of the central solenoid of the ITER tokamak under the plasma scenario. The central solenoid (CS) is composed of six modules for a total amount of 240 pancakes. The software is able to tackle the complex structure of the CS and its cryogenic closed loop. In the present work, the circulation pump operation and the heat transfer to the helium bath are investigated. The results presented here show the temperature evolution of the magnet and of the supercritical helium during the plasma scenario, which allows the determination of the operation margin of the CS. Full article

This paper presents a decoupled bearingless cross-flow fan (CFF) that operates at a supercritical speed, thereby increasing the maximum achievable rotational speed and fluid dynamic power. In magnetically levitated CFF rotors, the rotational speed and fan performance are limited by the bending resonance frequency. This is primarily defined by the low mechanical bending stiffness of the CFF blades, which are optimised for fluid dynamic performance, and the heavy rotor magnets on both rotor sides, which add significant mass but a minimal contribution to the overall rotor stiffness. This results in detrimental deformations of the CFF blades in the vicinity of the rotor bending resonance frequency; hence, the CFF is speed-limited to subcritical rotational speeds. The novel CFF rotor presented in this study features additional mechanical decoupling elements with low bending stiffness between the fan blades and the rotor magnets. Thus, the unbalance forces primarily deform the soft decoupling elements, which enables them to pass resonances without CFF blade damage and allows rotor operation in the supercritical speed region due to the self-centring effect of the rotor. The effects of the novel rotor design on the rotor dynamic behaviour are investigated by means of a mass-spring-damper model. The influence of different decoupling elements on the magnetic bearing is experimentally tested and evaluated, from which an optimised decoupled CFF rotor is derived. The final prototype enables a stable operation at 7000 rpm in the supercritical speed region. This corresponds to a rotational speed increase of 40%, resulting in a $28\%$ higher, validated fluid flow and a $100\%$ higher static pressure compared to the previously presented bearingless CFF without decoupling elements. Full article

This work investigates the suitability of supercritical fluid technology for designing a safe, efficient and sustainable consolidation treatment for a pair of heavily degraded goalkeeper gloves. Traditional methods have revealed themselves as unsafe and inefficient, leading to material loss and a minimal enhancement of surface cohesion. To overcome these limitations, the use of supercritical carbon dioxide (scCO₂) was explored in a treatment, where scCO₂ behaves as a green solvent and consolidant carrier. In-depth and homogeneous application of the consolidant, without the need for direct contact with the foam material, was sought. As a proof of concept, the procedure was tested on samples that mimic the synthetic latex-based foam composition and condition of the object. Poly(vinyl acetate) was selected as a consolidant because its behaviour and solubility in scCO₂ are known. Several experimental conditions were explored to assess the impact and feasibility of the scCO₂-assisted consolidation procedure. Empirical observations, optical microscopy, scanning electron microscopy and infrared spectroscopy were used to monitor potential modifications in the samples and assess the treatment efficacy. The results highlighted the advantages and pitfalls of scCO₂-assisted consolidation, paving the way for fine-tuning the process. It neither damaged the fragile surfaces of the foam samples nor increased material loss, which is an advantage compared to traditional treatments. The performed analysis suggested that homogeneous impregnation of the foams was achieved. This study might be a turning point in the conservation of foam-based museum objects, as the results indicate the suitability of the scCO₂-assisted consolidation process as a non-toxic and more efficient alternative, being safer for the object. Full article

Capturing and storing CO₂ (CCS) was once regarded as a significant, urgent, and necessary option for reducing the emissions of CO₂ from coal and oil and gas industries and mitigating the serious impacts of CO₂ on the atmosphere and the environment. This recognition came about as a result of extensive research conducted in the past. The CCS cycle comes to a close with the last phase of CO₂ storage, which is accomplished primarily by the adsorption of CO₂ in the ocean and injection of CO₂ subsurface reservoir formation, in addition to the formation of limestone via the process of CO₂ reactivity with reservoir formation minerals through injectivities. CCS is the last stage in the carbon capture and storage (CCS) cycle and is accomplished chiefly via oceanic and subterranean geological sequestration, as well as mineral carbonation. The injection of supercritical CO₂ into geological formations disrupts the sub-surface’s existing physical and chemical conditions; changes can occur in the pore fluid pressure, temperature state, chemical reactivity, and stress distribution of the reservoir rock. This paper aims at advancing our current knowledge in CO₂ injection and storage systems, particularly CO₂ storage methods and the challenges encountered during the implementation of each method and analyses on how key uncertainties in CCS can be reduced. CCS sites are essentially unified systems; yet, given the scientific context, these storage systems are typically split during scientific investigations based on the physics and spatial scales involved. Separating the physics by using the chosen system as a boundary condition is a strategy that works effectively for a wide variety of physical applications. Unfortunately, the separation technique does not accurately capture the behaviour of the larger important system in the case of water and gas flow in porous media. This is due to the complexity of geological subsurface systems, which prevents the approach from being able to effectively capture the behaviour of the larger relevant system. This consequently gives rise to different CCS technology with different applications, costs and social and environmental impacts. The findings of this study can help improve the ability to select a suitable CCS application method and can further improve the efficiency of greenhouse gas emissions and their environmental impact, promoting the process sustainability and helping to tackle some of the most important issues that human being is currently accounting global climate change. Though this technology has already had large-scale development for the last decade, some issues and uncertainties are identified. Special attention was focused on the basic findings achieved in CO₂ storage operational projects to date. The study has demonstrated that though a number of CCS technologies have been researched and implemented to date, choosing a suitable and acceptable CCS technology is still daunting in terms of its technological application, cost effectiveness and socio-environmental acceptance. Full article

Living organisms are active open systems far from thermodynamic equilibrium. The ability to behave actively corresponds to dynamical metastability: minor but supercritical internal or external effects may trigger major substantial actions such as gross mechanical motion, dissipating internally accumulated energy reserves. Gaining a selective advantage from the beneficial use of activity requires a consistent combination of sensual perception, memorised experience, statistical or causal prediction models, and the resulting favourable decisions on actions. This information processing chain originated from mere physical interaction processes prior to life, here denoted as structural information exchange. From there, the self-organised transition to symbolic information processing marks the beginning of life, evolving through the novel purposivity of trial-and-error feedback and the accumulation of symbolic information. The emergence of symbols and prediction models can be described as a ritualisation transition, a symmetry-breaking kinetic phase transition of the second kind previously known from behavioural biology. The related new symmetry is the neutrally stable arbitrariness, conventionality, or code invariance of symbols with respect to their meaning. The meaning of such symbols is given by the structural effect they ultimately unleash, directly or indirectly, by deciding on which actions to take. The early genetic code represents the first symbols. The genetically inherited symbolic information is the first prediction model for activities sufficient for survival under the condition of environmental continuity, sometimes understood as the “final causality” property of the model. Full article

This paper investigates the heat transfer properties of liquefied natural gas (LNG) in a corrugated plate heat exchanger and explores its application in cold energy recovery for enhanced energy efficiency. The study aims to integrate this technology into a 500 MW gas-fired power plant and a district cooling system to contribute to sustainable city development. Using computational fluid dynamics simulations and experimental validation, the heat transfer behaviour of LNG in the corrugated plate heat exchanger is examined, emphasising the significance of the gas film on the channel wall for efficient heat transfer between LNG and water/ethylene glycol. The study analyses heat exchange characteristics below and above the critical point of LNG. Below the critical point, the LNG behaves as an incompressible fluid, whereas above the critical point, the compressible supercritical state enables a substantial energy recovery and temperature rise at the outlet, highlighting the potential for cold energy recovery. The results demonstrate the effectiveness of cold energy recovery above the critical point, leading to significant energy savings and improved efficiency compared to conventional systems. Optimal operational parameters, such as the number of channels and flow rate ratios, are identified for successful cold energy recovery. This research provides valuable insights for sustainable city planning and the transition towards low-carbon energy systems, contributing to the overall goal of creating environmentally friendly and resilient urban environments. Full article

An innovative simultaneous process, using supercritical fluid (SCF) chemistry, was used to recycle uncured prepregs and to functionalize the recovered carbon fibres with Fe₃O₄ magnetic nanoparticles (MNPs), to produce a new type of secondary raw material suitable for composite applications. This specific functionalization allows the fibres to be heated by induction through a hysteresis loss mechanism characteristic for nanoparticle susceptor-embedded systems, for triggered healing properties and a potentially easy route for CF reclamation. Using SCF and hydrothermal conditions for recycling, functionalization of fibres can be performed in the same reactor, resulting in the creation of ready-to-use fibres and limiting the use organic solvent. After cutting the uncured prepreg to the desired length to fit in future applications, supercritical CO₂ extraction is performed to partially remove some components of the uncured prepreg matrix (step 1). Then, the recycled carbon fibres (rCFs), still embedded inside the remaining organic matrix, are brought into contact with reactants for the functionalization step (step 2). Two possibilities were studied: the direct synthesis of MNPs coated with PAA in hydrothermal conditions, and the deposition of already synthesized MNPs assisted by supercritical CO₂-acetone. No CF surface activation is needed thanks to the presence of functional groups due to the remaining matrix. After functionalization, ready-to-use material with homogeneous depositions of MNPs at the surface of rCF is produced, with a strong magnetic behaviour and without observed degradation of the fibres. Full article

Supercritical carbon dioxide (S-CO₂) has the advantages of amphoteric liquid and gas, which possesses many unique characteristics, such as good compressibility, high density, high solubility, good fluidity and low viscosity. The Brayton cycle with S-CO₂ is considered to have many promising applications, especially for power conversion industries. However, the corrosion and degradation of structural materials hinder the development and application of the Brayton cycle with S-CO₂. Nickel-based alloys have the best corrosion resistance in S-CO₂ environments compared to austenitic stainless steels and ferritic/martensitic steels. Thus, the present article mainly reviews the corrosion behaviour of nickel-based alloys in S-CO₂ under high temperature and pressure. The effect of alloying elements and environment parameters on the corrosion behaviour of different nickel-based alloys are systematically summarized. The conclusion and outlook are given at the end. Full article

We consider the thermodynamics of the Einstein-power-Yang–Mills AdS black holes in the context of the gauge-gravity duality. Under this framework, Newton’s gravitational constant and the cosmological constant are varied in the system. We rewrite the thermodynamic first law in a more extended form containing both the pressure and the central charge of the dual conformal field theory, i.e., the restricted phase transition formula. A novel phenomena arises: the dual quantity of pressure is the effective volume, not the geometric one. That leads to a new behavior of the Van de Waals-like phase transition for this system with the fixed central charge: the supercritical phase transition. From the Ehrenfest’s scheme perspective, we check out the second-order phase transition of the EPYM AdS black hole. Furthermore the effect of the non-linear Yang–Mills parameter on these thermodynamic properties is also investigated. Full article

Experimental studies were conducted to identify the physical and chemical features of gold’s behaviour in hydrothermal processes linked to ore formation and involving CO₂ in oxidized deposits. With the aid of the autoclave method, in a temperature range of between 200 and 400 °C, the isochoric dependences of the PVT parameters of concentrated sulphate chloride fluids were plotted, both in the presence and absence of CO₂. Our experiments established that concentrated sulphate–chloride fluids (22 wt % Na₂SO₄ + 2.2 wt % NaCl) that lack CO₂ are characterized by a wide supercritical temperature range, with homogenization temperatures of between 250 and 325 °C. In the presence of CO₂, the same type of fluids showed heterogenization at a molar fraction of X_CO2 = 0.18 (t = 192 °C, P = 176 bar). The process of homogenization for these low-density and high-salinity fluids was impossible at temperatures between 375 and 400 °C and at pressures between 600 and 700 bar. The behaviour of gold was studied during its interaction with a basic composition fluid of sulphate–chloride. We applied the autoclave method under the conditions of a simultaneous synthesis of pyrite and gold dissolution (metallic Au), at a temperature of 340 °C and at a pressure of 440 bar. High Au concentrations (up to 4410 ppm of Au in CO₂-bearing fluids) were attained at high gold solubilities (up to 13.5 ppm in the presence of CO₂), owing to the process of Au reprecipitation within the pyrite phase. We did not detect Au in the pyrite when we used the XRD or SEM methods, which suggested that it might be present as invisible gold. High values of the distribution coefficient (K_D = C_Au(solid)/C_Au(solution)) in the fluids lacking (K_D = 62) and bearing CO₂ (K_D = 327) empirically confirmed the possibility that gold concentrates in pyrite in structurally non-binding forms. Full article

Thermal energy storages represent important devices for the decarbonisation of heat; hence, enabling a circular economy. Hereby, important tasks are the optimisation of thermal losses and providing a tuneable storage capacity, as well as tuneable storage dynamics for thermal energy storage modules which are composed of either sensible or phase change-based heat storage materials. The thermal storage capacity and the storage dynamics behaviour are crucial for fulfilling certain application requirements. In this work, a novel macro-encapsulated and spherical heat storage core-shell structure is presented and embedded in a supercritical ammonia working fluid flow field. The core of the macro-capsule is built by an organic low molecular weight substance showing a solid–liquid phase transition in a respective temperature zone, where the shell structure is made of polyvinylidene fluoride. Due to the direct coupling of computational fluid dynamics and the simulation of the phase transition of the core material, the influence of the working fluid flow field and shell thickness on the time evolution of temperature, heat transfer coefficients, and accumulated heat storage is investigated for this newly designed material system. It is shown that due to the mixed sensible and phase change storage character, the shell architecture and the working fluid flow field, the heat storage capacity and the storage dynamics can be systematically tuned. Full article

The long-term exposure of rocks to supercritical carbon dioxide (scCO₂) during sequestration creates structural and chemical changes. In turn, these lead to changes in the permeability of inter-layers and caprocks that can alter plume migration behaviour and/or lead to the loss of the sealing efficiency of caprocks. This review first surveys experimental studies of changes to the pore structure and mass transport properties of caprocks and interlayers, including novel experimental protocols and data analysis methods. These methods provide more accurate measures of basic parameters, such as surface area, as well as new information on pore network features that are essential to properly understanding changes to mass transport properties. The subsequent evolution of rocks exposed to scCO₂ involves a complex coupling of geomechanics, geochemistry, and mass transport processes over different length and time scales. The simultaneous combination of all three factors together is rarely considered and this review also surveys such fully integrated work to understand the complex interplay and feedback arising between the different processes. We found that it was necessary to include all three coupled processes to obtain truly representative behaviour in reservoir simulations; otherwise, counter-intuitive effects are missed. These include the unexpected greater sealing efficiency of thin shale layers. Full article

The paper’s aim is the assessment of corrosion behaviour of a CrN_x-coated 310 H stainless steel under simulated supercritical water conditions (550 °C and 25 MPa) for up to 2160 h. The CrN_x coating was obtained by the thermionic vacuum arc (TVA) method. The oxides grown on this coating were characterized using metallographic and gravimetric analysis, SEM with EDS, and grazing incidence X-ray diffraction (GIXRD). A diffusion mechanism drives oxidation kinetics because it follows a parabolic law. By XRD analysis, the presence of Cr₂O₃ and Fe₃O₄ on the surface of the autoclaved CrN_x-coated 310 H samples were highlighted. Corrosion susceptibility assessment was performed by electrochemical impedance spectroscopy (EIS) and linear potentiodynamic polarization. EIS impedance spectra show the presence of two capacitive semicircles in the Nyquist diagram, highlighting both the presence of the CrN_x coating and the oxide film formed during autoclaving on the 310 H stainless steel. Very low corrosion rates, with values up to 11 nm × year⁻¹, obtained in the case of autoclaved for 2160 h, CrN_x-coated samples indicated that the oxides formed on these samples are protective and provide better corrosion resistance. The determination of micro hardness Vickers completed the above investigation. Full article

The melting behaviour of the triblock polymers, Pluronic F38, F68, F77, F108, and F127, was investigated in pressurised CO₂ and in the presence of menthol. The melting points of the polymers combined with 0, 10, 25, and 50 wt% of menthol were studied at atmospheric pressure and compared with those at 10 and 20 MPa in supercritical carbon dioxide (scCO₂). The highest melting point depressions of 16.8 ± 0.5 °C and 29.0 ± 0.3 °C were observed at 10 and 20 MPa, respectively. The melting point of triblock polymers in pressurised CO₂ was found to be dependent on molecular weight, poly(propylene oxide) (PPO) content, and menthol percentage. The melting point of most of the polymers studied in this work can be reduced to room temperature, which can be pivotal to the formulation development of thermolabile substances using these polymers. Full article

Self-organized criticality theory proved that information transmission and computational performances of neural networks are optimal in critical state. By using recordings of the spontaneous activity originated by dissociated neuronal assemblies coupled to Micro-Electrode Arrays (MEAs), we tested this hypothesis using Approximate Entropy (ApEn) as a measure of complexity and information transfer. We analysed 60 min of electrophysiological activity of three neuronal cultures exhibiting either sub-critical, critical or super-critical behaviour. The firing patterns on each electrode was studied in terms of the inter-spike interval (ISI), whose complexity was quantified using ApEn. We assessed that in critical state the local complexity (measured in terms of ApEn) is larger than in sub- and super-critical conditions (mean ± std, ApEn about 0.93 ± 0.09, 0.66 ± 0.18, 0.49 ± 0.27, for the cultures in critical, sub-critical and super-critical state, respectively—differences statistically significant). Our estimations were stable when considering epochs as short as 5 min (pairwise cross-correlation of spatial distribution of mean ApEn of 94 ± 5%). These preliminary results indicate that ApEn has the potential of being a reliable and stable index to monitor local information transmission in a neuronal network during maturation. Thus, ApEn applied on ISI time series appears to be potentially useful to reflect the overall complex behaviour of the neural network, even monitoring a single specific location. Full article