Search Results (54)

The article documents the cause of a sharp decrease in the fracture toughness of HR3C austenitic steel intended for heat exchange surfaces of supercritical energy blocks during its exposure to elevated temperature. The documentation of the cause of the decrease in fracture toughness is based on a combination of fractographic observation of the fracture surfaces of the tested samples, linked through ongoing precipitation changes in the steel to the fracture toughness of the steel. The result is a description of the decrease in fracture toughness in relation to the Larson–Miller parameter and subsequently the change in fracture toughness in relation to the precipitation changes in HR3C steel. This dependence provides a tool for numerical calculations and simulations of heat exchange surfaces of power plants made of HR3C steel and the simulation of their behavior when cracks are present. Full article

Super duplex stainless steels (SDSS) are materials known for their exceptional mechanical strength and high resistance to corrosion due to their dual- phase microstructure consisting of ferrite and austenite in roughly equal proportions. However, the Gas Tungsten Arc Welding (GTAW) process used to join SDSS often causes microstructural imbalances, mainly ferritic structures, or the formation of harmful intermetallic phases, which can weaken the material’ s desirable properties. This study examines the effect of substrate preheating on the microstructure, mechanical properties, and corrosion resistance of UNS S32750 SDSS welds produced by GTAW. Preheating the substrate was considered as a strategy to improve phase balance in the fusion zone by extending the time within the ferrite- to- austenite transformation temperature range, thus slowing the cooling rates. Four conditions were tested: welding at room temperature (RT) and preheating to 100 °C (T100), 200 °C (T200), and 300 °C (T300). Welding parameters remained constant. The fusion zone microstructure was analyzed using metallographic techniques, while mechanical properties were evaluated through microhardness tests. Corrosion resistance was assessed with potential dynamic polarization in a 3.5% NaCl solution. The results showed significant improvements in microstructural balance with higher preheating temperatures. The austenite volume fraction in the fusion zone increased from about 16% at RT to 42% at T 300. Mechanical testing indicated a decrease in microhardness from 341 HV at RT to 314 HV at T 300, reflecting the increased austenite content and its associated toughness. Corrosion tests demonstrated enhanced resistance under preheated conditions, with T 300 exhibiting the highest corrosion potential and the lowest corrosion current, nearing the performance of the base metal. These findings suggest that preheating is a practical, cost- effective method for optimizing the GTAW process for SDSS, eliminating the need for expensive filler materials and stabilizing the microstructure elements. Full article

To investigate the fracture behavior of super-absorbent polymer (SAP) internally cured polyvinyl alcohol (PVA) fiber-reinforced concrete (SAP-PVAC), three-point bending tests were carried out. This study systematically examined the effects of (1) PVA fiber content and (2) initial crack-depth-to-beam-height ratios (a₀/D) on the failure modes, fracture toughness (K_IC), and residual flexural tensile strength (f_R,1) of SAP-PVAC beams. The test results demonstrate that SAP particles have a weakening effect on concrete strength (reduce about 6%). Still, the addition of PVA fibers can effectively improve the crack-resistance performance of SAP-PVAC and significantly increase the residual flexural tensile strength by 4.5–42%. The softening performance of the concrete is affected by the initial crack-height ratio. An increase in a₀/D leads to an obvious increase in the crack opening displacement but has little impact on the fracture toughness, while the fracture energy shows a downward trend. SEM microscopic analysis reveals that the synergistic effect of SAP and PVA fibers exhibits a positive promoting effect on the toughening and crack resistance of SAP-PVAC specimens. These results establish a theoretical framework for SAP-PVAC fracture assessment and provide actionable guidelines for its shrinkage-crack mitigation structure engineering applications. Full article

The influence of solution treatment time on the microstructural and mechanical properties of a super duplex stainless steel was investigated. A solution annealing treatment at 1120 °C was applied to the hot-rolled alloy, with soaking times varying between 10 and 30 min. The microstructural characteristics before and after solution treatment were examined using XRD and EBSD techniques by measuring lattice parameters and micro-strains, weight fraction, average grain size, and maximum misorientation angle. The experimental results showed that the constituent phases are δ-Fe and γ-Fe, regardless of the alloy state. The mechanical properties of the solution-treated alloy were evaluated by tensile testing, measuring the ultimate tensile strength (σ_UTS), yield strength (σ_0.2), fracture strain (ε_f), and impact toughness (KCV). Increasing the solution treatment time from 10 min to 30 min leads to improved ductility and reduced mechanical strength, with the volume of the ferrite phase increasing, the average austenite grain size decreasing, and the maximum misorientation angle decreasing. This is due to the ability of ferrite to absorb stress and to the greater participation of grains in the deformation process. Important decreases in high elastic strains and residual stress fields after solution treatment were also noted. Full article

The production of polymer nanocomposites from supertough blends reinforced with carbon-based nanofillers has garnered attention in recent years due to improvements in their mechanical, thermal, and electrical properties. Currently, the main challenge is to develop materials with balanced performance for diverse industrial demands. In this context, this work aimed to produce nanocomposites of poly(butylene terephthalate) (PBT) and poly(ethylene-octene) grafted with glycidyl methacrylate (POE-g-GMA), reinforced with carbon nanotubes (MWCNTs). The PBT, the PBT/POE-g-GMA blend, and the respective MWCNT nanocomposites were initially premixed in an internal mixer and then processed in a co-rotational twin-screw extruder. After processing, they were injection-molded to obtain tensile, impact, and HDT test specimens. Mechanical (tensile, impact, and Shore D hardness), thermal (differential scanning calorimetry—DSC), thermomechanical (heat deflection temperature—HDT), electrical resistivity/conductivity, morphology, and Fourier transform infrared spectroscopy (FTIR) properties were evaluated. The results demonstrated a good balance among the investigated properties, with improvements in mechanical, thermal, and thermomechanical properties when compared to PBT. The impact strength of the nanocomposites reached 186 J/m, approximately 158% higher than that of neat PBT. The HDT reached approximately 55 °C in the PBT/POE-g-GMA/MWCNT5 nanocomposites, while the crystallization temperature increased by 11 °C, as evidenced by DSC, an aspect of great relevance for industrial applications. Furthermore, the PBT/POE-g-GMA/MWCNT5 nanocomposites exhibited an electrical conductivity of 1.06 × 10⁻⁷ S/cm, indicating potential for electrical applications. Full article

Laser cladding rapid solidification technique is an effective strategy for manufacturing ultra-high-strength martensitic stainless steels (UHS-MSS). Due to super-saturation solution strengthening of interstitial atoms (IAs), martensitic stainless steels containing IAs exhibit excellent ultra-high strength and toughness and have high tolerance for oxygen impurities. Hence, studying the specific speciation and structural characteristics of IAs is of great significance for guiding laser cladding of ultra-high-strength steels. Herein, we use density functional theory (DFT) computations to analyze the stable occupancies of IAs and their interactions in body-centered cubic iron (BCC Fe). The findings show that single IAs prefer to occupy octahedral sites over tetrahedral sites. Therefore, octahedral sites are selected as the optimal sites for the following double IAs study. For homo IAs, C-C and N-N configurations exhibit greater stability at long-range distances, whereas O-O demonstrate optimal stability at intermediate distances. Crucially, hetero IAs configurations are more stable compared to single IAs and homo IAs, exhibiting a synergistic effect. Especially, the C-O combination shows the highest stability and strongest bonding character. Meanwhile, the dissociation behavior of O indicates that C-O and N-O have higher dissociation temperatures than single O, further verifying the synergistic effect of hetero IAs. This provides a theoretical basis for understanding the interstitial solution strengthening of laser cladding UHS-MSS. Full article

China has an existing building area of 80 billion square meters, where reinforced concrete structures have a large quantity and a wide surface area. The risk of structures being subjected to blast loading is relatively high. Reactive powder concrete has the specialties of ultra-high toughness, super strength, and a high strength to ponderance ratio. Reinforced concrete (RC) structures strengthened by RPC are called RPC-RC structures, which can easily elevate the explosive load resistance of building structures while also strengthening the building. It is a significant method used in avoiding the collapse of structures under explosive loads. The dynamic reaction and damage evaluation approaches of RPC-RC columns under explosive load have not been deeply studied. For addressing this issue, numerical simulation of RPC strengthened RC columns under explosive load was carried out by LS-DYNA (R10), and the correctness of the numerical simulation was verified by comparing it with relevant experimental results. In this paper, a finite element model of an RPC-RC column was established, and the main factors affecting the anti-explosion performance of an RPC-RC column were studied. The influence of the RPC reinforcement layer parameters (RPC thickness, RPC strength, longitudinal reinforcement ratio, and stirrup ratio) on the dynamic reaction and damage degree of RPC-RC columns was examined. The consequences indicated that the failure mode of the columns after RPC reinforcement can alter from bending shear damage to bending damage. As the thickness and strength of the RPC increases, the longitudinal reinforcement ratio increases, the stirrup ratio increases, and the maximum horizontal deformation of the center point of the RPC reinforced RC columns decreases. For RPC-RC columns with a height of 3–4 m and a width of 300–400 mm under blast loading, columns with an axial compression ratio greater than 0.3 will collapse, while columns with an axial compression ratio less than 0.3 are less likely to collapse. In the light of the calculation outcomes, a formula for reckoning the damage index of RPC-RC columns was proposed, taking into account factors such as proportional distance, axial compression ratio, RPC thickness, longitudinal reinforcement ratio, and stirrup ratio. Full article

Development of multi-component blends to prepare high-performance polymer materials is still challenging, and is a key technology for mechanical recycling of waste plastics. However, a multi-phase compatibilizer is prerequisite to create high-performance multi-component blends. In this study, POE-g-(MAH-co-St) and SEBS-g-(MAH-co-St) compatibilizers are prepared via melt-grafting of maleic anhydride (MAH) and styrene (St) dual monomers to polyolefin elastomer (POE) and poly [styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS), respectively. Subsequently, these compatibilizers are utilized to compatibilize the PA6/PP/ABS/SEBS quaternary blends through melt-blending. When POE-g-(MAH-co-St) and SEBS-g-(MAH-co-St) are added, respectively, both can promote the distribution of the dispersed phases, significantly reducing the dispersed phase size. When adding 10 wt% POE-g-(MAH-co-St) and 10 wt% SEBS-g-(MAH-co-St) together, compared to the non-compatibilized blend, the fracture strength, fracture elongation, and impact strength surprisingly increased by 106%, 593%, and 823%, respectively. It can be attributed to the hierarchical interfacial interactions which facilitate gradual energy dissipation from weak to strong interfaces, resulting in the improvement of mechanical properties. The synergistic effect of the enhanced phase interfacial interactions and toughening effect of elastomer compatibilizer achieved simultaneous growth in strength and toughness. Full article

Hydrogels endure various dynamic stresses, demanding robust mechanical properties. Despite significant advancements, matching hydrogels’ strength to biological tissues and plastics is often challenging without applying potentially harmful crosslinkers. Using hydrogen bonds as sacrificial bonds offers a promising strategy to produce tough, versatile hydrogels for biomedical and industrial applications. Poly(methacrylic acid) (PMA)/gelatin hydrogels were synthesized by thermally induced free-radical polymerization and crosslinked only by physical bonds, without adding any chemical crosslinker. The addition of gelatin increased the formation of hydrophobic domains in the structure of the hydrogels, which acted as permanent crosslinking points. The increase in PMA and gelatin contents generally led to a lower equilibrium water content (WC), higher thermal stability and better mechanical properties. The values of tensile strength and toughness reached up to 1.44 ± 0.17 MPa and 4.91 ± 0.51 MJ m⁻³, respectively, while the compressive modulus and strength reached up to 0.75 ± 0.06 MPa and 24.81 ± 5.85 MPa, respectively, with the WC being higher than 50 wt.%. The obtained values for compressive mechanical properties are comparable with super-strong hydrogels reported in the literature. In addition, hydrogels exhibited excellent fatigue resistance and biocompatibility, as well as great shape memory properties, which make them prominent candidates for a wide range of biomedical applications. Full article

There is a need to investigate the flexural behavior and mechanical properties of super high-performance concrete (SHPC) for a better understanding of its response to compression, tension, and bending. Super-high-performance concrete (SHPC) lies between high-performance concrete (HPC) and ultra-high-performance concrete (UHPC) in strength, durability, and workability and is suitable for sustainable buildings. This paper presents an extensive experimental and analytical study to investigate the effect of the hybridization of micro-polypropylene and macro-steel fibers on the flexural behavior and mechanical properties of super-high-performance concrete (SHPC). The hybridization of both micro-PP fibers and macro-hooked-end ST fibers gathers the benefits of their advantages and offsets their disadvantages. Three types of fibers (micro polypropylene fibers (PP), macro hooked-end steel fiber (ST), and hybrid fiber (PP + ST)) with different fiber content up to 2% were tested to study their effect on the following: (a) the workability of fresh concrete, (b) concrete compressive strength, (c) splitting tensile strength, (d) flexural behavior, including flexural tensile strength and toughness, and (e) the optimum percentage of each of the two fibers, PP and ST, in the hybrid to get the maximum structural and economic benefits of hybridization. Based upon the experimental results and using a statistical program, formulae to calculate both the tensile splitting strength ($f_{sp}$) and the flexural tensile strength in the form of the modulus of rupture ($f_{ctr}$) were obtained. These formulae were able to predict accurately both the splitting tensile strength and modulus of rupture for SHPC with each of the three types of fibers used in this research. Also, they were in very good agreement with the values corresponding to different experimental results of other research, which means the ability to use these equations more generally. In addition, the prediction of the additional ultimate moment provided for all fibers was investigated. This research confirms the structural and the economical efficiency of hybridization in the behavior of SHPC. It was found that the optimum percentage of the fiber volume content for the hybrid of ST and PP is 1%; 0.5% for each of the two kinds. Full article

The development of a cost-effective and accurate model for predicting the fatigue life of materials is essential for designing thermal power plants and assessing their structural reliability under operational conditions. This paper reports a novel energy-based approach for developing unified models that predict the fatigue life of boiler tube materials in ultra-supercritical (USC) power plants. The proposed method combines the Masing behavior with a cyclic stress–strain relationship and existing stress-based or strain-based fatigue life prediction models. Notably, the developed models conform to the structure of the modified Morrow model, which incorporates material toughness (a temperature compensation parameter) into the Morrow model to account for the effects of temperature. A significant advantage of this approach is that it eliminates the need for tensile tests, which are otherwise essential for assessing material toughness in the modified Morrow model. Instead, all material constants in our models are derived solely from fatigue test results. We validate our models using fatigue data from three promising USC boiler tube materials—Super304H, TP310HCbN, and TP347H—and their welded joints at operating temperatures of 500, 600, and 700 °C. The results demonstrate that approximately 91% of the fatigue data for all six materials fall within a 2.5× scatter band of the model’s predictions, indicating a high level of accuracy and broad applicability across various USC boiler tube materials and their welded joints, which is equivalent to the performance of the modified Morrow model. Full article

Super 304H has been a crucial material for ultra-supercritical boilers. However, the relationship between microstructure evolution, strengthening mechanism, and embrittling behavior during long-term aging was lacking investigation. This investigation aimed to reveal the strengthening and embrittling mechanism from precipitates in Super 304H. The results showed that the hardness increment came from the grain boundary’s M₂₃C₆ (GB’s M₂₃C₆) and intragranular nano Cu-rich particles. After being aged for 5000 h, the GB’s M₂₃C₆ and nano Cu-rich particles provided a hardness increment of approximately 10 HV and 30 HV, respectively. The impact toughness gradually decreased from 213 J/cm² to 161 J/cm² with the extending aging time. For the aged Super 304H, the GB’s M₂₃C₆ provided a higher cracking source. In addition, the nano Cu-rich particle restricted the twin-induced plastic deformation of austenitic grain and depressed the absorbed energy from austenitic grain deformation. Full article

The inherent brittleness of poly(lactic acid) (PLA) limits its use in a wider range of applications that require plastic deformation at higher stress levels. To overcome this, a series of poly(l-lactic acid) (PLLA)/biodegradable thermoplastic polyester elastomer (TPE) blends and their ternary blends with an ethylene-methyl acrylate-glycidyl methacrylate (EMA-GMA) copolymer as a compatibilizer were prepared via melt blending to improve the poor impact strength and low ductility of PLAs. The thermal behavior, crystallinity, and miscibility of the binary and ternary blends were analyzed by differential scanning calorimetry (DSC). Tensile tests revealed a brittle–ductile transition when the binary PLLA/20TPE blend was compatibilized by 8.6 wt. % EMA-GMA, and the elongation at break increased from 10.9% to 227%. The “super tough” behavior of the PLLA/30TPE/12.9EMA-GMA ternary blend with the incomplete break and notched impact strength of 89.2 kJ∙m⁻² was observed at an ambient temperature (23 °C). In addition, unnotched PLLA/40TPE samples showed a tremendous improvement in crack initiation resistance at sub-zero test conditions (−40 °C) with an impact strength of 178.1 kJ∙m⁻². Morphological observation by scanning electron microscopy (SEM) indicates that EMA-GMA is preferentially located at the PLLA/TPE interphase, where it is partially incorporated into the matrix and partially encapsulates the TPE. The excellent combination of good interfacial adhesion, debonding cavitation, and subsequent matrix shear yielding worked synergistically with the phase transition from sea–island to co-continuous morphology to form an interesting super-toughening mechanism. Full article

To overcome challenging service conditions, a groundbreaking thermoset, “Super-Tough Resin” (STR), has been specifically designed for steel bridge deck paving. Currently, investigations of paving thermosets mainly focus on cured materials. Detailed investigations of the curing process and its impact on the evolving properties of STR are lacking. Therefore, this study aims to explore the curing kinetics and the performance evolution of STR. Specifically, spectroscopy test, time sweep, linear viscoelastic region, and weight loss tests were conducted. Our results show that the curing degrees increase significantly with the curing durations and temperatures at the initial stage. When cured for 10 h, the curing degrees at four temperatures all exceed 80%. Then, a kinetic model with an nth-order of 1.551 was established. Upon increasing the temperature from 35 to 80 °C, the gel point time decreases from 480 to 189 min but the corresponding curing degree remains constant at 75.73%. When curing time is increased from 2.5 to 4 h, the linear viscoelastic regions decrease from 20% to 3%. Finally, after 400 h, the weight losses of STR at 35 and 80 °C are about 8% and 20%, respectively. These outcomes are beneficial to understanding the dynamic curing behaviors of STR and similar thermosets. Full article

Background: Shear damage of beams is typically brittle damage that is significantly more detrimental than flexural damage. Purpose: Based on the super-high toughness and good crack control ability of engineered cementitious composites (ECC), the shear performance of concrete–ECC beams was investigated by replacing a portion of the concrete in the tensile zone of reinforced concrete beams with ECC and employing high-strength reinforcing bars to design concrete–ECC beams. The purpose of this investigation is to elucidate and clarify the shear performance of concrete–ECC beams. Methodology/approach: Experimental and FE analyses were conducted on the shear performance of 36 webless reinforced concrete–ECC composite beams with varied concrete strengths, shear-to-span ratios, ECC thicknesses, and interfacial treatments between the layers. Results: The results indicate that the effect of the shear-to-span ratio is greater, the effect of the form of interface treatment is smaller, the effect is weakened after the ECC thickness is greater than 70 mm (i.e., the ratio of the replacement height to section height is approximately 0.35), the shear resistance is reduced when the hoop rate is greater, and the best shear resistance is obtained when the ECC 70 mm thickness and the hoop rate of 0.29% are used together. Conclusions: This study can serve as a technical reference for enhancing the problems of low durability and inadequate fracture control performance of RC beams in shear and as a guide for structural design research. Full article