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23 pages, 14673 KB  
Article
Sequence Stratigraphy, Sedimentary Evolution, and Coal-Accumulation Model of the Lower Xishanyao Formation in the Nileke Sag, Yili Basin
by XinFei Wang, Xin Li, RenDong Peng, ShuGuang Yang and Bin Zhang
Geosciences 2026, 16(1), 31; https://doi.org/10.3390/geosciences16010031 - 6 Jan 2026
Viewed by 37
Abstract
The Lower-Middle Jurassic Xishanyao Formation in the Nileke Sag of the Yili Basin contains substantial reserves of coal and coalbed methane (CBM). Elucidating its depositional evolution and the controlling factors of coal accumulation within a sequence-stratigraphic framework is crucial for guiding future exploration. [...] Read more.
The Lower-Middle Jurassic Xishanyao Formation in the Nileke Sag of the Yili Basin contains substantial reserves of coal and coalbed methane (CBM). Elucidating its depositional evolution and the controlling factors of coal accumulation within a sequence-stratigraphic framework is crucial for guiding future exploration. This study integrates regional geological surveys, core observations, well-log analysis, and quantitative lithofacies statistics of the lower member to establish a sequence-stratigraphic framework and reconstruct the sedimentary paleogeography. Eleven minable coal seams are identified, exhibiting a depositionally controlled spatial thickness distribution. The coal is classified as low-rank bituminous (Rank I–II), characterized by high inertinite, low ash, medium-high volatile matter, and ultra-low sulfur content, indicating formation in a freshwater swamp influenced by seasonal droughts and floods. Three third-order sequences (SQ1–SQ3) are recognized. SQ2, deposited during peak transgression as a braided-river delta plain, provided the optimal environment for peat accumulation. In contrast, SQ3 is dominated by progradational deltas with coarser sediments, where coal accumulation weakened. The results demonstrate that coal accumulation was jointly controlled by tectonic subsidence (providing accommodation space), climate (causing peat oxidation and fine-clastic input), and sedimentation (with interdistributary bays on the delta plain being the most favorable sites). Coal accumulation in the Lower Xishanyao Member resulted from the coupling of tectonic, climatic, and sedimentary processes. This genetic model provides a theoretical basis for regional coal and CBM exploration. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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32 pages, 2805 KB  
Article
Geologically Constrained Multi-Scale Transformer for Lithology Identification Under Extreme Class Imbalance
by Xiao Li, Puhong Feng, Baohua Yu, Chun-Ping Li, Junbo Liu and Jie Zhao
Eng 2026, 7(1), 8; https://doi.org/10.3390/eng7010008 - 25 Dec 2025
Viewed by 174
Abstract
Accurate identification of lithology is considered very important in oil and gas exploration because it has a direct impact on the evaluation and development planning of any reservoir. In complex reservoirs where extreme class imbalance occurs, as critical minority lithologies cover less than [...] Read more.
Accurate identification of lithology is considered very important in oil and gas exploration because it has a direct impact on the evaluation and development planning of any reservoir. In complex reservoirs where extreme class imbalance occurs, as critical minority lithologies cover less than 5%, the identification accuracy is severely constrained. Recent deep learning methods include convolutional neural networks, recurrent architectures, and transformer-based models that have achieved substantial improvements over traditional machine learning approaches in identifying lithology. These methods demonstrate great performance in catching spatial patterns and sequential dependencies from well log data, and they show great recognition accuracy, up to 85–88%, in the case of a moderate imbalance scenario. However, when these methods are extended to complex reservoirs under extreme class imbalance, the following three major limitations have been identified: (1) single-scale architectures, such as CNNs or standard Transformers, cannot capture thin-layer details less than 0.5 m and regional geological trends larger than 2 m simultaneously; (2) generic imbalance handling techniques, including focal loss alone or basic SMOTE, prove to be insufficient for extreme ratios larger than 50:1; and (3) conventional Transformers lack depth-dependent attention mechanisms incorporating stratigraphic continuity principles. This paper is dedicated to proposing a geological-constrained multi-scale Transformer framework tailored for 1D well-log sequences under extreme imbalance larger than 50:1. The systematic approach addresses the extreme imbalance by deep-feature fusion and advanced class-rebalancing strategies. Accordingly, this framework integrates multi-scale convolutional feature extraction using 1 × 3, 1 × 5, 1 × 7 kernels, hierarchical attention mechanisms with depth-aware position encoding based on Walther’s Law to model long-range dependencies, and adaptive three-stage class-rebalancing through SMOTE–Tomek hybrid resampling, focal loss, and CReST self-training. The experimental validation based on 32,847 logging samples demonstrates significant improvements: overall accuracy reaches 90.3% with minority class F1 scores improving by 20–25% percentage points (argillaceous siltstone 73.5%, calcareous sandstone 68.2%, coal seams 65.8%), and G-mean of 0.804 confirming the balanced recognition. Of note, the framework maintains stable performance even when there is extreme class imbalance at a ratio of up to 100:1 with minority class F1 scores above 64%, representing a two-fold improvement over the state-of-the-art methods, where former Transformer-based approaches degrade below. This paper provides the fundamental technical development for the intelligent transformation of oil and gas exploration, with extensive application prospects. Full article
(This article belongs to the Section Chemical, Civil and Environmental Engineering)
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26 pages, 5845 KB  
Article
Automated 3D Multivariate Domaining of a Mine Tailings Deposit Using a Continuity-Aware Geostatistical–AI Workflow
by Keyumars Anvari and Jörg Benndorf
Minerals 2025, 15(12), 1249; https://doi.org/10.3390/min15121249 - 26 Nov 2025
Viewed by 560
Abstract
Geochemical data from mine tailings are layered, compositional, and noisy, complicating automated domaining. This study introduces a continuity-aware workflow the Geostatistical k-means Recurrent Neural Network (GkRNN) that links compositional preprocessing and geostatistical continuity to sequence learning, allowing depth order and lateral context to [...] Read more.
Geochemical data from mine tailings are layered, compositional, and noisy, complicating automated domaining. This study introduces a continuity-aware workflow the Geostatistical k-means Recurrent Neural Network (GkRNN) that links compositional preprocessing and geostatistical continuity to sequence learning, allowing depth order and lateral context to influence final domain labels. The workflow begins with a centered log-ratio (CLR) transform, followed by construction of a spectral embedding derived from kernelized direct and cross variograms. Clustering is carried out in this embedded space, and depth sequences are regularized with a hidden Markov model (HMM) model and a long short-term memory (LSTM) network. When applied to a multivariate set of tailing drillholes, stratigraphically coherent zones were obtained, depthwise proportions were stabilized, and vertical as well as lateral semivariograms remained consistent with laminated material. Compared with k-means and Gaussian Mixture baselines, over-segmentation was reduced and the intended layered architecture was recovered in most drillholes. The result is a reproducible domaining workflow that enables clearer grade estimation and more transparent risk evaluation. Full article
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19 pages, 172530 KB  
Article
Cenozoic Stratigraphic Architecture of the Beikang Basin (South China Sea): Insights into Tectonic Evolution and Sedimentary Response
by Shuaibing Luo, Xiaoxue Wang, Lifu Zhang, Li Zhang, Kangshou Zhang, Guanghui He and Qiuhua Yu
J. Mar. Sci. Eng. 2025, 13(12), 2216; https://doi.org/10.3390/jmse13122216 - 21 Nov 2025
Viewed by 446
Abstract
Since the onset of the Cenozoic, the South China Sea has experienced complex plate interactions including peripheral plate collisions, the demise of the Paleo-South China Sea, and the subsequent opening of the modern basin. These processes produced three major types of sedimentary basins: [...] Read more.
Since the onset of the Cenozoic, the South China Sea has experienced complex plate interactions including peripheral plate collisions, the demise of the Paleo-South China Sea, and the subsequent opening of the modern basin. These processes produced three major types of sedimentary basins: extensional, strike-slip, and compressional. The Beikang Basin represents a typical extensional continental-margin rift basin that preserves the stratigraphic and sedimentary record of the transition from syn-rift to post-rift stages. Subsidence happened mainly during the post-rift stage. Five structural styles exist: extensional, compressional-inversion, strike-slip–extensional, magmatic, and diapiric. While the first three are fault-related, the last two are mainly controlled by the volcanic phases. Using a seismic-facies-to-sedimentary-system workflow, we delineate a tectono-stratigraphic framework, comprising five seismic facies, seven lithofacies, and eight depositional facies. This framework indicates that the Beikang Basin evolved through four major tectonic stages including initial rifting, inherited rifting, climax rifting, and post-rift thermal subsidence. Each stage has primary control on sediment supply and accommodation development. Our findings refine the basin’s tectono-sedimentary evolution and improve predictions for sediment distribution and hydrocarbon exploration in the underexplored Beikang Basin. Full article
(This article belongs to the Special Issue Advances in Sedimentology and Coastal and Marine Geology, 3rd Edition)
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19 pages, 10082 KB  
Article
Enhanced Resolution of Martian Polar Stratigraphy via Structure Enhancement Denoising and Sparse Deterministic Deconvolution of SHARAD Data
by Peng Fang and Jinhai Zhang
Remote Sens. 2025, 17(23), 3783; https://doi.org/10.3390/rs17233783 - 21 Nov 2025
Viewed by 462
Abstract
The Martian North Polar Layered Deposits (NPLD) are a thick sequence of ice and dust layers that serve as a primary archive of the planet’s recent climate history. The Shallow radar (SHARAD) sounder provides critical data for probing this stratigraphy, but its resolution [...] Read more.
The Martian North Polar Layered Deposits (NPLD) are a thick sequence of ice and dust layers that serve as a primary archive of the planet’s recent climate history. The Shallow radar (SHARAD) sounder provides critical data for probing this stratigraphy, but its resolution is limited by the radar wavelet and the signal-to-noise ratio (SNR). Deconvolution aims to overcome the resolution limitation, with recent techniques like sparse deterministic deconvolution (SDD) showing promise. However, the performance of these methods is fundamentally constrained by noise, which can obscure weak reflectors from deep or subtle layers and introduce artifacts into the results. This study proposes a two-stage workflow that directly addresses the noise problem by applying structure enhancement denoising (SED) to improve the SNR and reflector echo power of SHARAD radargrams prior to deconvolution, thereby enhancing the overall fidelity of the results. The efficacy of this integrated SED-SDD workflow is validated first on synthetic radargrams, demonstrating a marked reduction in reflectivity error and superior preservation of structural detail compared to the baseline SDD method, especially under low-SNR conditions. Subsequently, the workflow is applied to a real SHARAD observation of the NPLD, revealing enhanced lateral continuity of subtle reflectors and a significant reduction in noise-induced artifacts. The results demonstrate that this synergistic approach provides a powerful tool for extracting higher-resolution stratigraphic information from noisy planetary orbital radar data, thereby advancing our ability to interpret the sedimentary history of Mars. Full article
(This article belongs to the Section Remote Sensing in Geology, Geomorphology and Hydrology)
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30 pages, 20231 KB  
Article
Effect of Sedimentary Environment on Mudrock Lithofacies and Organic Matter Enrichment in a Freshwater Lacustrine Basin: Insight from the Triassic Chang 7 Member in the Ordos Basin, China
by Meizhou Zhang, Xiaomin Zhu, Wenming Ji, Xingyue Lin and Lei Ye
Sustainability 2025, 17(22), 10248; https://doi.org/10.3390/su172210248 - 16 Nov 2025
Cited by 1 | Viewed by 448
Abstract
Gradually replacing fossil fuels with renewable energy constitutes a long-term strategy for achieving sustainable development. In the short term, it is necessary to explore unconventional oil and gas resources to support current economic sustainability and to secure essential time for the energy transition. [...] Read more.
Gradually replacing fossil fuels with renewable energy constitutes a long-term strategy for achieving sustainable development. In the short term, it is necessary to explore unconventional oil and gas resources to support current economic sustainability and to secure essential time for the energy transition. With the continuous growth in global energy demand, unconventional resources such as shale oil and shale gas have become important alternative energy sources. Lacustrine mudrock successions demonstrate significant potential for unconventional oil and gas resources. However, the unclear understanding of how paleoenvironmental evolution influences lithofacies and organic matter enrichment restricts the optimization of shale oil reservoirs and evaluation of shale oil resources, thereby hindering the progress of lacustrine shale oil exploration and development. The mudrocks in the Chang 7 Member of the Triassic Yanchang Formation, Ordos Basin, were deposited in a pro-delta to a deep lacustrine environment and are rich in shale oil resources. Through petrographic, sedimentological, sequence stratigraphic, and geochemical analyses, this study reveals how the evolution of the paleoenvironment controlled the development of mudrocks and the enrichment of organic matter, and establishes a sedimentary model for freshwater lacustrine systems. Six lithofacies have been identified within the mudrock interval of the Chang 7 Member. According to the T-R (transgressive–regressive) sequence model, the Chang 7 Member can be subdivided into three fourth-order sequences, termed Parasequence Set 1–3 (PPS1–3). Mudrock is predominantly developed in the fourth-order sequences PSS1 and PSS2. The PSS1 and the lower part of PSS2 consist of lithofacies 1–4, representing semi-deep to deep lacustrine deposits. The upper part of PSS2 develops lithofacies 5, representing shallow lacustrine to pro-delta deposits. Fluctuations of the lake level controlled the vertical stacking of lithofacies and the transition in depositional mechanisms. During lake-level rise, bottom currents shifted to suspension settling, whereas the opposite occurred during lake-level fall. The organic matter is derived from algae, and its enrichment is jointly controlled by productivity and the redox conditions. Volcanic–hydrothermal activity and a humid climate promoted high productivity in the water body. This high productivity promotes dyoxic conditions in the bottom water. Fourth-order relative lake-level fluctuations also influence organic matter enrichment. During lake-level rise, increased productivity coupled with reduced consumption and dilution favors organic matter enrichment. Conversely, organic matter accumulation is inhibited during lake-level fall. Ultimately, a depositional model for a freshwater lacustrine basin under a humid to semi-humid climatic background was established. This paper elucidates the influence of sedimentary environment on mudrock lithofacies and organic matter enrichment, providing a theoretical basis for optimizing shale oil reservoir selection and resource assessment, thereby promoting efficient exploration and low-carbon development of shale oil in lacustrine basins. Full article
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20 pages, 4783 KB  
Article
Provenance and Tectonic Setting of the Mesoproterozoic Pudeng Formation in the Western Yangtze Block
by Jian Yao, Youliang Chen, Luyu Huang, Jing Zhao, Mengjuan Gu and Baoling Zhang
Minerals 2025, 15(11), 1195; https://doi.org/10.3390/min15111195 - 13 Nov 2025
Viewed by 488
Abstract
The Yangtze Block provides a natural window into the tectonic evolution of Precambrian continental crusts. The Julin Group is a dominant Precambrian stratigraphic unit in the southwestern block, the depositional age of which is still poorly constrained. The lowest sequence of this group, [...] Read more.
The Yangtze Block provides a natural window into the tectonic evolution of Precambrian continental crusts. The Julin Group is a dominant Precambrian stratigraphic unit in the southwestern block, the depositional age of which is still poorly constrained. The lowest sequence of this group, the Pudeng Formation, is primarily composed of mica-quartz schists and quartzites intruded by a biotite monzogranite. LA–ICP–MS zircon U-Pb ages of biotite monzogranite and detrital zircons constrain the deposition of the Julin Group to between 1099 and 1052 Ma. Geochemical compositions of the mica-quartz schists and quartzites display high δCe, ΣREE, Th/Sc, and Th/U, along with low δEu, La/Sc, Ce/Th, and Al2O3/(Al2O3 + Fe2O3) ratios, indicating their derivation from felsic volcanic protoliths in a passive continental margin setting. The detrital zircons show distinct age peaks at 2.5, 1.85, and 1.6 Ga, with their source regions primarily located along the western and northern Yangtze Block. Integrating the magmatic records within the Yangtze Block with the ages and εHf(t) values of detrital zircons indicates that the tectonic setting of the western Yangtze Block evolved from a subduction-related arc at ~2.5 Ga to an orogenic belt at ~1.86 Ga and subsequently to intracontinental extensional (rift) environments at ~1.6 Ga and ~1.2 Ga. This evolution reflects the geodynamic transition from the Arrowsmith orogeny to the assembly and development of the Columbia and Rodinia supercontinents. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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27 pages, 31928 KB  
Article
Migration Patterns and Sedimentary Evolution of Deepwater Channels in the Niger Delta Basin
by Fei Liu, Xiaoming Zhao, Jiawang Ge, Kun Qi, Massine Bouchakour and Shuchun Cao
J. Mar. Sci. Eng. 2025, 13(11), 2135; https://doi.org/10.3390/jmse13112135 - 12 Nov 2025
Viewed by 565
Abstract
The internal architecture of deep-water channels is highly complex. Previous research has primarily emphasized the sedimentary processes governing channel migration, yet the linkage between sediment-source mechanisms and migration patterns—particularly their vertical evolution—remains insufficiently understood. Drawing on 3D seismic data, well logs, and core [...] Read more.
The internal architecture of deep-water channels is highly complex. Previous research has primarily emphasized the sedimentary processes governing channel migration, yet the linkage between sediment-source mechanisms and migration patterns—particularly their vertical evolution—remains insufficiently understood. Drawing on 3D seismic data, well logs, and core analyses, this study delineates the channel architecture within the deep-water succession of the Niger Delta Basin. Furthermore, by correlating high-frequency sea-level fluctuations with the formation timing of structural units, we explore how sea-level changes influence the spatial distribution and evolutionary dynamics of submarine fan systems. This study investigated the bottom-up evolution of two channel-lobe systems—the East Channel System (ECS) and West Channel System (WCS) within the stratigraphic succession, identifying two principal channel migration styles: expansive migration and downstream migration. In the ECS, migration was primarily characterized by a combination of downstream and expansive patterns. In contrast, the WCS displayed intermittent downstream migration, accompanied by some irregular migration. Correlation of sea-level variation curves with corresponding core photographs indicates that the ECS developed during a fourth-order sea-level. Its lower lobe and upper channel intervals each correspond to two complete five-stage sea-level cycles. In this system, debris flows and high-density turbidity currents produced stronger lateral erosion and channel migration, giving rise to the expansive migration style. Conversely, the WCS formed during a four-stage sea-level rise, with its lobe and channel sections likewise corresponding to two complete five-stage sea-level cycles. Here, sedimentation dominated by high- and low-density turbidity currents promoted enhanced erosion and migration along the flow direction, resulting in the predominance of downstream migration patterns. The ECS and WCS together constitute a complete three-tiered stratigraphic sequence representing two lobe–channel systems. This configuration deviates to some extent from the conventional understanding of the spatial distribution of debris flows, lobate channels, main channels, and deep-sea mud deposits. Consequently, during intervals of frequent sea-level fluctuation, deep-water sedimentary components within the continental slope region can partially record the signals of fourth- and even fifth-order sea-level variations, facilitated by a stable tectonic framework and favorable sediment preservation conditions. These findings offer valuable insights for reconstructing regional sedimentary processes and interpreting sea-level evolution. Full article
(This article belongs to the Special Issue Advances in Sedimentology and Coastal and Marine Geology, 3rd Edition)
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24 pages, 7830 KB  
Article
Research on the Metallogenic Enrichment Model of Poly-Metallic Black Shales and Their Geological Significance: A Case Study of the Cambrian Niutitang Formation
by Kai Shi, Zhiyong Ni, Ganggang Shao, Wen Zhang and Nuo Cheng
Processes 2025, 13(11), 3537; https://doi.org/10.3390/pr13113537 - 4 Nov 2025
Viewed by 529
Abstract
The Lower Cambrian Niutitang Formation was deposited precisely during the Cambrian Explosion period, a short-lived interval marked by drastic shifts in oceanic chemistry and climate. This stratigraphic sequence preserves a comprehensive record of early-ocean evolution and constitutes a world-class reservoir for rare and [...] Read more.
The Lower Cambrian Niutitang Formation was deposited precisely during the Cambrian Explosion period, a short-lived interval marked by drastic shifts in oceanic chemistry and climate. This stratigraphic sequence preserves a comprehensive record of early-ocean evolution and constitutes a world-class reservoir for rare and precious metals, widely termed the “poly-metallic enrichment layer”. Despite its metallogenic prominence, the genetic model for metal enrichment in the Niutitang Formation remains contentious. In this study, we employed inductively coupled plasma mass spectrometry (ICP-MS), carbon and sulfur analyzer, and X-ray fluorescence spectrometry (XRF) to quantify trace-metal abundances, redox-sensitive element distribution patterns, rare-earth element signatures, and total organic carbon contents. Results reveal that metal enrichment in the Niutitang Formation was governed by temporally distinct mechanisms. Member I records extreme enrichment in As, Ag, V, Re, Ba, Cr, Cs, Ga, Ge, Se and In. This anomaly was driven by the Great Oxidation Event and intensified upwelling that oxidized surface waters, elevated primary productivity and delivered abundant organic matter. Subsequent microbial sulfate reduction generated high H2S concentrations, converting the water column to euxinic conditions. Basin restriction imposed persistent anoxia in bottom waters, establishing a pronounced redox stratification. Concurrent vigorous hydrothermal activity injected large metal fluxes, leading to efficient scavenging of the above metals at the sulfidic–anoxic interface. In Members II and III, basin restriction waned, permitting enhanced water-mass exchange and a concomitant shift from euxinic to anoxic–suboxic conditions. Hydrothermal metal fluxes declined, yet elevated organic-matter fluxes continued to sequester Ag, Mo, Ni, Sb, Re, Th, Ga, and Tl via carboxyl- and thiol-complexation. Thus, “organic ligand shuttling” superseded “sulfide precipitation” as the dominant enrichment mechanism. Collectively, the polymetallic enrichment in the Niutitang Formation reflects a hybrid model controlled by seawater redox gradients, episodic hydrothermal metal supply, and organic-complexation processes. Consequently, metal enrichment in Member I was primarily governed by the interplay between vigorous hydrothermal flux and a persistently sulfidic water column, whereas enrichment in Members II and III was dominated by organic-ligand complexation and fluctuations in the marine redox interface. This study clarifies the stage-dependent metal enrichment model of the Niutitang Formation and provides a theoretical basis for accurate prediction and efficient exploration of polymetallic resources in the region. Full article
(This article belongs to the Section Energy Systems)
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29 pages, 1325 KB  
Article
Digital Stratigraphy—A Pattern Analysis Framework Integrating Computer Forensics, Criminology, and Forensic Archaeology for Crime Scene Investigation
by Romil Rawat, Hitesh Rawat, Mandakini Ingle, Anjali Rawat, Anand Rajavat and Ashish Dibouliya
Forensic Sci. 2025, 5(4), 48; https://doi.org/10.3390/forensicsci5040048 - 17 Oct 2025
Viewed by 1192
Abstract
Background/Objectives—Traditional forensic investigations often analyze digital, physical, and criminological evidence separately, leading to fragmented timelines and reduced accuracy in reconstructing complex events. To address these gaps, this study proposes the Digital Stratigraphy Framework (DSF), inspired by archaeological stratigraphy, to integrate heterogeneous evidence [...] Read more.
Background/Objectives—Traditional forensic investigations often analyze digital, physical, and criminological evidence separately, leading to fragmented timelines and reduced accuracy in reconstructing complex events. To address these gaps, this study proposes the Digital Stratigraphy Framework (DSF), inspired by archaeological stratigraphy, to integrate heterogeneous evidence into structured, temporally ordered layers. DSF aims to reduce asynchronous inconsistencies, minimize false associations, and enhance interpretability across digital, behavioral, geospatial, and excavation evidence. Methods—DSF employs Hierarchical Pattern Mining (HPM) to detect recurring behavioral patterns and Forensic Sequence Alignment (FSA) to synchronize evidence layers temporally and contextually. The framework was tested on the CSI-DS2025 dataset containing 25,000 multimodal, stratified records, including digital logs, geospatial data, criminological reports, and excavation notes. Evaluation used 10-fold cross-validation, Bayesian hyperparameter tuning, and structured train-validation-test splits. Metrics included accuracy, precision, recall, F1-score, and Stratigraphic Reconstruction Consistency (SRC), alongside ablation and runtime assessments. Results—DSF achieved 92.6% accuracy, 93.1% precision, 90.5% recall, 91.3% F1-score, and an SRC of 0.89, outperforming baseline models. False associations were reduced by 18%, confirming effective cross-layer alignment and computational efficiency. Conclusions—By applying stratigraphic principles to forensic analytics, DSF enables accurate, interpretable, and legally robust evidence reconstruction. The framework establishes a scalable foundation for real-time investigative applications and multi-modal evidence integration, offering significant improvements over traditional fragmented approaches. Full article
(This article belongs to the Special Issue Feature Papers in Forensic Sciences)
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28 pages, 5715 KB  
Article
Paleobiodiversity and Paleoecology Insights from a New MIS 5e Highstand Deposit on Santa Maria Island (Azores Archipelago, Portugal)
by Sergio Moreno, Mohamed Amine Doukani, Ana Hipólito, Patrícia Madeira, Sergio Pérez Pérez, Laura S. Dalmau, Gonçalo Castela Ávila, Luís Silva, Gustavo M. Martins, Esther Martín-González, Markes E. Johnson and Sérgio P. Ávila
Quaternary 2025, 8(4), 53; https://doi.org/10.3390/quat8040053 - 30 Sep 2025
Viewed by 1359
Abstract
During the last two decades, the Macaronesian archipelagos have been the focus of multiple studies targeting the abundant and diversified fossil record from late Neogene and Quaternary deposits. This record of past biota, ecosystems and climates is crucial for understanding the impact of [...] Read more.
During the last two decades, the Macaronesian archipelagos have been the focus of multiple studies targeting the abundant and diversified fossil record from late Neogene and Quaternary deposits. This record of past biota, ecosystems and climates is crucial for understanding the impact of glacial–interglacial cycles on Atlantic littoral marine organisms. Coupled with ongoing studies on the factors responsible for global climate change and associated sea-level variations, they contributed decisively towards the development of the modern marine island biogeography theory. Our current knowledge of the evolutionary and biogeographic history of the past and extant, shallow-water marine organisms from the Macaronesian geographic region relies on detailed analysis of many individual fossiliferous outcrops by means of quantitative and qualitative methodologies. Here, we focus on the fossil record of a newly studied MIS 5e outcrop at Pedra-que-pica (PQP), on Santa Maria Island (Azores Archipelago, Portugal). This multidisciplinary work integrates geology, paleontology and biology, providing the first detailed description of the sedimentary facies and stratigraphic framework of the PQP MIS 5e sequence that, coupled with the documentation of the biodiversity and ecological composition of PQP molluscan assemblages, allows us to produce a paleoecological reconstruction and to compare PQP with other last interglacial outcrops from Santa Maria Island. Our results increase the number of the Azorean MIS 5e marine molluscs to 140 taxa (116 Gastropoda and 24 Bivalvia). Ervilia castanea (Montagu, 1803) is the most abundant bivalve, while Bittium nanum (Mayer, 1864) and Melarhaphe neritoides (Linnaeus, 1758) are the most abundant gastropod species. In addition, this work emphasizes the crucial importance of complementing quantitative collecting with qualitative surveys of the fossiliferous outcrops, because nearly 42% of the bivalve species and 28% of the gastropod taxa would be missed if only quantitative samples were used. Derivation of Hill numbers and rarefaction curves both indicate that the sampling effort should be increased at PQP. Thus, although Santa Maria Island is recognized by the scientific community as one of the best-studied islands regarding the last interglacial fossil record, this study emphasizes the need to continue with similar efforts in less known outcrops on the island. Full article
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23 pages, 13715 KB  
Article
Sedimentary Environment, Tectonic Setting, and Paleogeographic Reconstruction of the Late Jurassic Weimei Formation in Dingri, Southern Tibet
by Jie Wang, Songtao Yan, Hao Huang, Tao Liu, Chongyang Xin and Song Chen
Minerals 2025, 15(10), 1040; https://doi.org/10.3390/min15101040 - 30 Sep 2025
Viewed by 856
Abstract
The Weimei Formation, the most complete Upper Jurassic sedimentary sequence in the Tethyan Himalaya, is crucial for understanding the tectono-sedimentary evolution of the northern Indian margin. However, its depositional environment remains debated, with conflicting shallow- and deep-water interpretations. This study integrates sedimentary facies, [...] Read more.
The Weimei Formation, the most complete Upper Jurassic sedimentary sequence in the Tethyan Himalaya, is crucial for understanding the tectono-sedimentary evolution of the northern Indian margin. However, its depositional environment remains debated, with conflicting shallow- and deep-water interpretations. This study integrates sedimentary facies, petrography, zircon geochronology, and geochemical analyses to constrain the provenance, depositional environment, and tectonic setting of the Weimei Formation. The results reveal that the sedimentary system primarily consists of shoreface, delta, and shelf facies, with locally developed slope-incised valleys. Detrital zircon ages are concentrated at ~468 Ma and ~964 Ma, indicating a provenance mainly derived from the Indian continent. Geochemical characteristics, such as high SiO2, low Na2O–CaO–TiO2 contents, right-leaning REE patterns, and significant negative Eu anomalies, suggest the derivation of sediments from felsic upper crustal recycling within a passive continental margin. Stratigraphic comparison between southern and northern Tethyan Himalayan sub-zones reveals a paleogeographic “uplift–depression” pattern, characterized by the coexistence of shoreface–shelf deposits and slope-incised valleys. This study provides key evidence for reconstructing the Late Jurassic paleogeography of the northern Indian margin and the tectonic evolution of the Neo-Tethys Ocean. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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33 pages, 5470 KB  
Article
Geochemical Characterization of Kupferschiefer in Terms of Hydrocarbon Generation Potential and Hydrogen Content
by Irena Matyasik, Małgorzata Kania, Małgorzata Labus and Agnieszka Wciślak-Oleszycka
Molecules 2025, 30(19), 3886; https://doi.org/10.3390/molecules30193886 - 25 Sep 2025
Viewed by 606
Abstract
The Permian Kupferschiefer shale, a key stratigraphic unit within the Zechstein sequence of the Fore-Sudetic Monocline, represents both a metal-rich lithofacies and a potential source rock for hydrocarbon generation. This study presents a comprehensive geochemical characterization of selected Kupferschiefer samples obtained from the [...] Read more.
The Permian Kupferschiefer shale, a key stratigraphic unit within the Zechstein sequence of the Fore-Sudetic Monocline, represents both a metal-rich lithofacies and a potential source rock for hydrocarbon generation. This study presents a comprehensive geochemical characterization of selected Kupferschiefer samples obtained from the Legnica–Głogów Copper District (LGOM) and exploratory boreholes. Analytical methods included Rock-Eval pyrolysis, Py-GC/FID, elemental analysis, TG-FTIR, biomarker profiling, and stable carbon isotope measurements. Results indicate that the shales contain significant amounts of Type II and mixed Type II/III kerogen, derived primarily from marine organic matter with minor terrestrial input. The organic matter maturity, expressed by Tmax, places most samples within the oil window. Rock-Eval S2 values exceed 60 mg HC/g rock in some samples, confirming excellent generative potential. Py-GC/FID data further support high hydrocarbon yields, particularly in samples from the CG-4 borehole and LGOM mines. The thermal decomposition of kerogen reveals multiple degradation phases, with evolved gas analysis identifying sulfur-containing compounds and hydrocarbons indicative of sapropelic origin. Isotopic compositions of bitumen and kerogen suggest syngenetic relationships and marine depositional settings, with samples from a North Poland borehole showing isotopic enrichment consistent with post-depositional oxidation. Kinetic parameters calculated using the Kissinger–Akahira–Sunose method demonstrate variable activation energies (107–341 kJ/mol), correlating with differences in organic matter composition and mineral matrix. The observed variability in geochemical properties highlights both regional and facies-dependent influences on the shale’s generative capacity. The study concludes that the Kupferschiefer in southwestern and northern Poland exhibits substantial hydrocarbon generation potential. This potential has been previously underestimated due to the unit’s thinness, but localized zones with high TOC, favorable kerogen type, and low activation energy could be viable exploration targets for natural gas. Full article
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30 pages, 16948 KB  
Article
Dolomitization and Silicification in Syn-Rift Lacustrine Carbonates: Evidence from the Late Oligocene–Early Miocene Duwi Basin, Red Sea, Egypt
by Tawfiq Mahran, Reham Y. Abu Elwafa, Alaa Ahmed, Osman Abdelghany and Khaled M. Abdelfadil
Geosciences 2025, 15(9), 356; https://doi.org/10.3390/geosciences15090356 - 11 Sep 2025
Viewed by 1186
Abstract
Studies of early syn-rift successions in the Duwi Basin have revealed repetitive lacustrine carbonate deposits exhibiting regressive sequences and early diagenetic processes. Two main informal stratigraphic units (Units 1 and 2), spanning the Late Oligocene to Early Miocene, have been identified in the [...] Read more.
Studies of early syn-rift successions in the Duwi Basin have revealed repetitive lacustrine carbonate deposits exhibiting regressive sequences and early diagenetic processes. Two main informal stratigraphic units (Units 1 and 2), spanning the Late Oligocene to Early Miocene, have been identified in the area. Unit 1 primarily consists of lacustrine limestone and calcrete deposits that formed in a palustrine environment, whereas Unit 2 is composed of dolomites and cherts, which developed during times of lake evaporation and desiccation under arid climatic conditions. A wide variety of pedogenic features, including brecciation, nodulization, rhizocretions, fissuring, microkarsts, and circumgranular cracks, dominate the carbonate sequence, indicating deposition in a marginal lacustrine setting. Integrated petrographic, mineralogical, geochemical, and isotopic studies of carbonate facies reveal two distinct evolutionary stages in the Duwi Basin, with dolomitization and silicification characterizing the late stage. Their isotopic compositions show a wide range of δ13C and δ18O values, ranging from −9.00‰ to −7.98‰ and from −10.03‰ to −0.68‰, respectively. Dolomite beds exhibit more negative δ13C and δ18O values, whereas palustrine limestones display higher (less negative) values. The upward trend of δ18O enrichment in carbonates suggests that the lake became hydrologically closed. Trace element concentrations serve as potential markers for distinguishing carbonate facies, aiding with paleoenvironmental and diagenetic interpretations. Our findings indicate that the studied dolomites and cherts formed under both biogenic and abiogenic conditions in an evaporative, alkaline-saline lake system. Biogenic dolomite and silica likely resulted from microbial activity, whereas abiogenic formation was driven by physicochemical conditions, including decreasing pH values and the presence of smectite clays. Tectonics, local climate, and provenance played crucial roles in controlling the overall diagenetic patterns and evolutionary history of the lake basin system during the Late Oligocene to Early Miocene. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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46 pages, 9391 KB  
Article
Multifactorial Controls on Carbonate–Clastic Sedimentation in Rift Basins: Integrated Foraminiferal, Sequence Stratigraphic, and Petrophysical Analysis, Gulf of Suez, Egypt
by Haitham M. Ayyad, Hatem E. Semary, Mohamed Fathy, Ahmed Hassan Ismail Hassan, Anis Ben Ghorbal and Mohamed Reda
Minerals 2025, 15(8), 864; https://doi.org/10.3390/min15080864 - 15 Aug 2025
Cited by 1 | Viewed by 1140
Abstract
The lithological dichotomy in the Hammam Faraun Member (Gulf of Suez, Egypt) reveals a stable western flank with Nullipore carbonate deposits, contrasting with the clastic-prone eastern margin influenced by tectonic activity. This study aims to decipher multifactorial controls on spatial lithological variability and [...] Read more.
The lithological dichotomy in the Hammam Faraun Member (Gulf of Suez, Egypt) reveals a stable western flank with Nullipore carbonate deposits, contrasting with the clastic-prone eastern margin influenced by tectonic activity. This study aims to decipher multifactorial controls on spatial lithological variability and reservoir implications through (1) foraminiferal-based paleoenvironmental reconstruction; (2) integrated sequence stratigraphic–petrophysical analysis for sweet spot identification; and (3) synthesis of lateral facies controls. This study uniquely integrates foraminiferal paleoenvironmental proxies, sequence stratigraphy, and petrophysical analyses to understand the multifactorial controls on spatial variability and its implications for reservoir characterization. Middle Miocene sea surface temperatures, reconstructed between 19.2 and 21.2 °C, align with warm conditions favorable for carbonate production across the basin. Foraminiferal data indicate consistent bathyal depths (611–1238 m) in the eastern region, further inhibited in photic depths by clastic influx from the nearby Nubian Shield, increasing turbidity and limiting carbonate factory growth. Conversely, the western shelf, at depths of less than 100 m, supports thriving carbonate platforms. In the sequence stratigraphy analysis, we identify two primary sequences: LA.SQ1 (15.12–14.99 Ma), characterized by evaporitic Feiran Member deposits, and LA.SQ2 (14.99–14.78 Ma), dominated by clastic deposits. The primary reservoir comprises highstand systems tract (HST) sandstones with effective porosity ranging from 17% to 22% (calculated via shale-corrected neutron density cross-plots) and hydrocarbon saturation of 33%–55% (computed using Archie’s equation). These values, validated in Wells 112-58 (ϕe = 19%, Shc = 55%) and 113M-81 (ϕe = 17%, Shc = 33%), demonstrate the primary reservoir potential. Authigenic dolomite cement and clay content reduce permeability in argillaceous intervals, while quartz dissolution in clean sands enhances porosity. This research emphasizes that bathymetry, sediment availability, and syn-sedimentary tectonics, rather than climate, govern carbonate depletion in the eastern region, providing predictive parameters for identifying reservoir sweet spots in clastic-dominated rift basins. Full article
(This article belongs to the Section Mineral Geochemistry and Geochronology)
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