Search Results (1,457)

Ultrahigh-temperature ceramic composites based on hafnium diboride have a wide range of applications, including as components for high-speed aircraft and energy generation and storage devices. Consequently, developing methodologies for their fabrication and studying their properties are of paramount importance, in particular in using them as an electrode material for energy storage devices with increased oxidation resistance. This study investigates the behavior of ceramic composites based on the HfB₂-HfO₂-SiC system, obtained using 15 vol% Ti₂AlC MAX-phase as a sintering component, under the influence of subsonic flow of dissociated air. It was determined that incorporating the modifying component (Ti₂AlC) altered the composition of the silicate melt formed on the surface during ceramic oxidation. This modification led to the observation of a protective antioxidant function. Consequently, liquation was observed in the silicate melt layer, resulting in the formation of spherical phase inhomogeneities in its volume with increased content of titanium, aluminum, and hafnium. It is hypothesized that the increase in the high-temperature viscosity of this melt prevents it from being carried away in the form of drops, even at a surface temperature of ~1900–2000 °C. Despite the established temperature, there is no sharp increase in its values above 2400–2500 °C. This is due to the evaporation of silicate melt from the surface. In addition, the electrochemical behavior of the obtained material in a liquid electrolyte medium (KOH, 3 mol/L) was examined, and it was shown that according to the value of electrical conductivity and specific capacitance, it is a promising electrode material for supercapacitors. Full article

Using solid particulates as a heat transfer medium for concentrated solar power (CSP) systems has many advantages, positioning them as a superior option compared with conventional heat transfer media such as steam, oil, air, and molten salt. However, a critical imperative lies in the comprehensive evaluation of the properties of potential solid particulates intended for utilization under such extreme thermal conditions. This paper undertakes an exhaustive examination of both ambient and high-temperature thermophysical properties of four naturally occurring particulate materials, Riyadh white sand, Riyadh red sand, Saudi olivine sand, and US olivine sand, and one well-known engineered particulate material. The parameters under scrutiny encompass loose bulk density, tapped bulk density, real density, sintering temperature, and thermal conductivity. The results reveal that the theoretical density decreases with the increase in temperature. The bulk density of solid particulates depends strongly on the particulate size distribution, as well as on the compaction. The tapped bulk density was found to be larger than the loose density for all particulates, as expected. The sintering test proved that Riyadh white sand is sintered at the highest temperature and pressure, 1300 °C and 50 MPa, respectively. US olivine sand was solidified at 800 °C and melted at higher temperatures. This proves that US olivine sand is not suitable to be used as a thermal energy storage and heat transfer medium in high-temperature particle-based CSP systems. The experimental results of thermal diffusivity/conductivity reveal that, for all particulates, both properties decrease with the increase in temperature, and results up to 475.5 °C are reported. Full article

With the rise of carbon capture and storage, liquefied carbon dioxide (LCO₂) has emerged as a promising medium for large-scale marine transport. This study evaluates the structural integrity of an IMO Type C cargo tank for a medium-range LCO₂ carrier under four conditions: ultimate limit state, accidental limit state, hydrostatic pressure test, and fatigue limit state, based on IGC Code and classification rules. Seventeen load cases were analyzed using finite element methods with multi-step loading to ensure stability. The highest stress occurred at the pump dome–shell junction due to geometric discontinuities, but all stress and buckling criteria were satisfied. The fatigue damage from wave-induced loads was negligible, with low-cycle fatigue from loading/unloading operations governing the fatigue life, which exceeded 31,000 years. The findings confirm the tank’s structural robustness and its suitability for safe, efficient medium-pressure LCO₂ transport. Full article

Traps are central to petroleum exploration, where hydrocarbons accumulate during migration. Reservoirs are likewise an essential petroleum system element and serve as the primary medium for hydrocarbon storage. The buried hill is a geological formation highly favorable for reservoir development. However, the factors influencing hydrocarbon accumulation in buried hill reservoirs are highly diverse, especially in areas with complex, active fault systems. Fault systems play a dual role, both in the formation of reservoirs and in the migration of hydrocarbons. Therefore, understanding the impact of complex fault systems helps enhance the exploration success rate of buried hill traps and guide drilling deployment. In the Beibuwan Basin in the South China Sea, buried hill traps are key targets for deep-buried hydrocarbon exploration in this faulted basin. The low level of exploration and research in buried hills globally limits the understanding of hydrocarbon accumulation conditions, thereby hindering large-scale hydrocarbon exploration. By using drilling data, logging data, and seismic data, stress fields and tectonic faults were restored. There are two types of buried hills developed in the Beibuwan Basin, which were formed during the Late Ordovician-Silurian period and Permian-Triassic period, respectively. The tectonic genesis of the Late Ordovician-Silurian period buried hills belongs to magma diapirism activity, while the tectonic genesis of the Permian-Triassic period buried hills belongs to reverse thrust activity. The fault systems formed by two periods of tectonic activity were respectively altered into basement buried hills and limestone buried hills. The negative structural inversion controls the distribution and interior stratigraphic framework of the deformed Carboniferous strata in the limestone buried hill. The faults and derived fractures of the Late Ordovician-Silurian period and Permian-Triassic period promoted the diagenesis and erosion of these buried hills. The faults formed after the Permian-Triassic period are not conducive to calcite cementation, thus facilitating the preservation of the reservoir space formed earlier. The control of hydrocarbon accumulation by the fault system is reflected in two aspects: on the one hand, the early to mid-Eocene extensional faulting activity directly controlled the depositional process of lacustrine source rocks; on the other hand, the Late Eocene-Oligocene, which is closest to the hydrocarbon expulsion period, is the most effective fault activity period for connecting Eocene source rocks and buried hill reservoirs. This study contributes to understanding of the role of complex fault activity in the formation of buried hill traps within hydrocarbon-bearing basins. Full article

Unspecific peroxygenases (UPOs) are promising biocatalysts for oxyfunctionalizations in future sustainable economies and can be efficiently immobilized on the cell surface of their heterologous production yeast. This immobilization has versatile uses, ranging from the mL to m³ scale; but the production of the yeast surface displayed UPOs, and their handling has yet to be optimized to advance sustainable industrial processes in light of the UN’s sustainable development goals. Here, we present optimized production protocols for surface-displayed UPOs for shaken and stirred systems in different scales and describe suitable storage conditions and a sterilization method. We utilized one-factor-at-a-time and design of experiments approaches. We were able to streamline published protocols for shaken flask cultivations to achieve a 60% increase in volumetric activity, using reduced amounts of media. We also show at least a doubling of final activity for bioreactor cultivations by utilizing a different medium than the industry standard. Finally, we present a novel, robust protocol for parallelized methanol-induced enzyme production in Komagataella phaffii in a BioLector XT^® reactor. Enzyme activity did not decrease and even increased by our recommended sterilization method and during storage over 87 days. This study aims to advance the yeast surface display immobilization method by providing methods for efficient production, storage and utilization of this promising biocatalyst. Full article

Dual-active bridge (DAB) converters have emerged as a preferred topology in electric vehicle charging and energy storage applications, owing to their structurally symmetric configuration and intrinsic galvanic isolation capabilities. However, conventional triple-phase shift (TPS) control strategies face significant challenges in maintaining high efficiency across ultra-wide output voltage and load ranges. To exploit the inherent structural symmetry of the DAB topology, a symmetric optimization strategy based on triple-phase shift (SOS-TPS) is proposed. The method specifically targets the forward buck operating mode, where an optimization framework is established to minimize the root mean square (RMS) current of the inductor, thereby addressing both switching and conduction losses. The formulation explicitly incorporates zero-voltage switching (ZVS) constraints and operating mode conditions. By employing the Karush–Kuhn–Tucker (KKT) conditions in conjunction with the Lagrange multiplier method (LMM), the refined control trajectories corresponding to various power levels are analytically derived, enabling efficient modulation across the entire operating range. In the medium-power region, full-switch ZVS is inherently satisfied. In the low-power operation, full-switch ZVS is achieved by introducing a modulation factor λ, and a selection principle for λ is established. For high-power operation, the strategy transitions to a conventional single-phase shift (SPS) modulation. Furthermore, by exploiting the inherent symmetry of the DAB topology, the proposed method reveals the symmetric property of modulation control. The modulation strategy for the forward boost mode can be efficiently derived through a duty cycle and voltage gain mapping, eliminating the need for re-derivation. To validate the effectiveness of the proposed SOS-TPS strategy, a 2.3 kW experimental prototype was developed. The measured results demonstrate that the method ensures ZVS for all switches under the full load range, supports ultra-wide voltage conversion capability, substantially suppresses RMS current, and achieves a maximum efficiency of 97.3%. Full article

In order to reduce gas consumption and increase the renewable energy proportion, this paper proposes a poly-generation system that couples geothermal, solar, and liquid natural gas (LNG) cold energy to produce steam, gaseous natural gas, and low-temperature nitrogen. The high-temperature flue gas is used to heat LNG; low-temperature flue gas, mainly nitrogen, can be used for cold storage cooling, enabling the staged utilization of the energy. Solar shortwave is used for power generation, and longwave is used to heat the working medium, which realizes the full spectrum utilization of solar energy. The influence of different equipment and operating parameters on the performance of a steam generation system is studied, and the multi-objective model of the multi-generation system is established and optimized. The results show that for every 100 W/m² increase in solar radiation, the renewable energy ratio of the system increases by 1.5%. For every 10% increase in partial load rate of gas boiler, the proportion of renewable energy decreases by 1.27%. The system’s energy efficiency, cooling output, and the LNG vaporization flow rate are negatively correlated with the scale of solar energy utilization equipment. The decision variables determined by the TOPSIS (technique for order of preference by similarity to ideal solution) method have better economic performance. Its investment cost is 18.14 × 10 CNY, which is 7.83% lower than that of the LINMAP (linear programming technique for multidimensional analysis of preference). Meanwhile, the proportion of renewable energy is only 0.29% lower than that of LINMAP. Full article

This paper addresses the critical gap in the existing literature regarding the combined buoyancy–Marangoni convection of power-law fluids in three-dimensional porous media with complex evaporation surfaces. Previous studies have rarely investigated the convective heat transfer mechanisms in such systems, and there is a lack of effective methods to accurately track fractal evaporation surfaces, which are ubiquitous in natural and engineering porous media (e.g., geological formations, industrial heat exchangers). This research is significant because understanding heat transfer in these complex porous media is essential for optimizing energy systems, enhancing thermal management in industrial processes, and improving the efficiency of phase-change-based technologies. For this scientific issue, a general model is designed. There is a significant temperature difference on the left and right sides of the model, which drives the internal fluid movement through the temperature difference. The upper end of the model is designed as a complex evaporation surface, and there is flowing steam above it, thus forming a coupled flow field. The VOF fractal reconstruction method is adopted to approximate the shape of the complex evaporation surface, which is a major highlight of this study. Different from previous research, this method can more accurately reflect the flow and phase change on the upper surface of the porous medium. Through numerical simulation, the influence of the evaporation coefficient on the flow and heat transfer rate can be determined. Key findings from numerical simulations reveal the following: (1) Heat transfer rates decrease with increasing fractal dimension (surface complexity) and evaporation coefficient; (2) As the thermal Rayleigh number increases, the influence of the Marangoni number on heat transfer diminishes; (3) The coupling of buoyancy and Marangoni effects in porous media with complex evaporation surfaces significantly alters flow and heat transfer patterns compared to smooth-surfaced porous media. This study provides a robust numerical framework for analyzing non-Newtonian fluid convection in complex porous media, offering insights into optimizing thermal systems involving phase changes and irregular surfaces. The findings contribute to advancing heat transfer theory and have practical implications for industries such as energy storage, chemical engineering, and environmental remediation. Full article

The increase in power generation facilities from nonprogrammable renewable sources is posing several challenges for the management of electrical systems, due to phenomena such as congestion and reverse power flows. In mitigating these phenomena, Power-to-Gas plants can make an important contribution. In this paper, a linear optimisation study is presented for the sizing of a Power-to-Hydrogen plant consisting of a PEM electrolyser, a hydrogen storage system composed of multiple compressed hydrogen tanks, and a fuel cell for the eventual reconversion of hydrogen to electricity. The plant was sized with the objective of minimising reverse power flows in a medium-voltage distribution network characterised by a high presence of photovoltaic systems, considering economic aspects such as investment costs and the revenue obtainable from the sale of hydrogen and excess energy generated by the photovoltaic systems. The study also assessed the impact that the electrolysis plant has on the power grid in terms of power losses. The results obtained showed that by installing a 737 kW electrolyser, the annual reverse power flows are reduced by 81.61%, while also reducing losses in the transformer and feeders supplying the ring network in question by 17.32% and 29.25%, respectively, on the day with the highest reverse power flows. Full article

The growing need for developing safer and more effective methods for obtaining enantiomers of chiral compounds, particularly those with pharmacological activity, highlights the potential of biocatalysis as an appropriate pharmaceutical research direction. However, low catalytic activity and stability of free enzymes are often among the substantial limitations to the wide application of biocatalysis. Therefore, to overcome these obstacles, new technological procedures are being designed. In this study, we present optimized protocols for the immobilization of Candida antarctica lipase B (CALB) on an octyl- agarose support, ensuring high enantioselectivity in an organic reaction medium. The immobilization procedures (with drying step), including buffers with different pH values and concentrations, as well as the study of the influence of temperature and immobilization time, were presented. It was found that the optimal conditions were provided by citrate buffer with a pH of 4 and a concentration of 300 mM. The immobilized CALB on the octyl-agarose support exhibited high catalytic activity in the kinetic resolution of (R,S)-1-phenylethanol via enantioselective transesterification with isopropenyl acetate in 1,2-dichloropropane (DCP), as a model reaction for lipase activity monitoring on an analytical scale. HPLC analysis demonstrated that the (R)-1-phenylethyl acetate was obtained in an enantiomeric excess of ee_p > 99% at a conversion of approximately 40%, and the enantiomeric ratio was E > 200. Thermal and storage stability studies performed on the immobilized CALB octyl-agarose support confirmed its excellent stability. After 7 days of thermal stability testing at 65 °C in a climatic chamber, the (R)-1-phenylethyl acetate was characterized by enantiomeric excess of ee_p > 99% at a conversion of around 40% (similar values of catalytic parameters to those achieved using a non-stored lipase). The documented high catalytic activity and stability of the developed CALB-octyl-agarose support allow us to consider it as a useful tool for enantioselective transesterification in organic medium. Full article

A fungal strain with comparably high chitosan yield was isolated from the Shivaganga hills and identified as Aspergillus versicolor AD07 through molecular characterization. Later, the strain was cultivated on Sabouraud Dextrose Broth (SDB) and wild jackfruit-based media to evaluate its potential for chitosan production. Among the various media formulations, the highest chitosan yield (178.40 ± 1.76 mg/L) was obtained from the jackfruit extract medium with added peptone and dextrose. The extracted chitosan was characterized through FTIR, XRD (reported a crystallinity index of 55%), TGA/DTG, and DSC analysis, confirming the presence of key functional groups and high thermal resistance. The extracted chitosan was fabricated into a sheet incorporated with 1% lemongrass oil; the sheet exhibited strong antibacterial activity against Escherichia coli (30 mm) and Bacillus megaterium (48 mm). The biodegradation studies reported a weight loss of 38.93 ± 0.51% after 50 days of soil burial. Further, the chitosan film was tested as a packaging material for paneer, demonstrating better preservation by maintaining nutritional quality and reducing microbial load over a 14-day storage period. These findings highlight the potential of A. versicolor AD07-derived chitosan, cultivated on a waste substrate medium, as a sustainable biopolymer for food packaging applications. Full article

The development of alternative energy is crucial to realizing the goals of the Paris Agreement. Hydrogen is a key energy carrier, and ammonia is considered its practical storage medium due to its high H₂ content and efficient storage and transportation. However, efficient NH₃ decomposition methods are needed to recover stored hydrogen. Plasma-assisted decomposition offers a potential solution, but high energy consumption, mainly due to inefficient power supply systems, remains a challenge. This study examines the impact of varying the driving frequency of a gliding discharge plasma system on ammonia decomposition, comparing low-frequency 50 Hz and high-frequency 20 kHz power supplies. Results show that high-frequency plasma enhances electron density and energy distribution, increasing the amount of vibrationally excited nitrogen molecules. This improves catalyst activation, leading to higher ammonia conversion and hydrogen production. Compared to the thyristor-powered system, the high-frequency system increased ammonia decomposition productivity by 30% and reduced energy consumption by 36% using a coprecipitated catalyst. These findings emphasize the importance of a plasma generator optimizing plasma-assisted ammonia decomposition and improving efficiency in hydrogen production. Full article

In recent years, packed-bed systems have emerged as an attractive design for thermal energy storage systems due to their high thermal efficiency and economic feasibility. As integral components of numerous large-scale applications systems, packed-bed thermal energy stores can be successfully paired with renewable energy and waste heat to improve energy efficiency. An analysis of the thermal performances of two packed beds (hot and cold) during six-hour charging and discharging cycles has been conducted in this paper using COMSOL Multiphysics software, utilizing the optimal design parameters that have been determined in previous studies, including porosity (0.2), particle diameters (4 mm) for porous media, air as a heat transfer fluid, magnesia as a storage medium, mass flow rate (13.7 kg/s), and aspect ratio (1). The performance has been evaluated during both the charging and discharging cycles, in terms of the system’s capacity factor, the energy stored, and the thermal power, in order to understand the system’s performance and draw operational recommendations. Based on the results, operating the hot/cold storage in the range of 20–80% of the full charge was found to be a suitable range for the packed-bed system, ensuring that the charging/discharging power remains within 80% of the maximum. Full article

This paper presents the results of laboratory tests on the intensity of mass and heat exchange in a polytunnel, with a focus on the synergy between the polytunnel and a stone accumulator. The subject of study was a standard polytunnel made of double polythene sheathing. In the process of selecting the appropriate working conditions for such a polytunnel, the characteristic operating parameters were modeled and verified. They were related to the process of mass and energy exchange, which takes place in regular controlled-environment agriculture (CEA). Then, experimental tests of a heat accumulator on a fixed stone bed were carried out. The experiments were carried out for various accumulator surfaces ranging from 18.7 m² to 74.8 m², which was measured perpendicularly to the heat medium. To standardize the results obtained, the analysis included the unit area of the accumulator and the unit time of the experiment. In this way, 835 heat and mass exchange events were analyzed, including 437 accumulator charging processes and 398 discharging processes from April to October, which is a standard period of polytunnel use in the Polish climate. During the tests, internal and external parameters of the process were recorded, such as temperature, relative humidity, solar radiation, wind speed and air flow speed in the accumulator system. Based on the parameters, a set of empirical relationships was developed using mathematical modeling. This provided the foundation for calculating heat gains as a result of its storage in a stone accumulator and its discharging process. The research results, including the developed dependencies, not only fill the scientific gap in the field of heat storage, but can also be used in engineering design of polytunnels supported by a heat storage system on a stone bed. In addition, the proposed methodology can be used in the study of other heat accumulators, not only in plant production facilities. Full article

The deep carbonate reservoirs in the Tarim Basin, Xinjiang, China, are widely developed with multi-scale complex reservoir spaces such as fractures, pores, and karst caves under the coupling of abnormal high pressure, diagenesis, karst, and tectonics and have strong heterogeneity. Among them, fracture–cavity carbonate reservoirs are one of the main reservoir types. Revealing the petrophysical characteristics of fracture–cavity carbonate reservoirs can provide a theoretical basis for the log interpretation and geophysical prediction of deep reservoirs, which holds significant implications for deep hydrocarbon exploration and production. In this study, based on the mineral composition and complex pore structure of carbonate rocks in the Tarim Basin, we comprehensively applied classical petrophysical models, including Voigt–Reuss–Hill, DEM (Differential Effective Medium), Hudson, Wood, and Gassmann, to establish a fracture–cavity petrophysical model tailored to the target block. This model effectively characterizes the complex pore structure of deep carbonate rocks and addresses the applicability limitations of conventional models in heterogeneous reservoirs. The discrepancies between the model-predicted elastic moduli, longitudinal and shear wave velocities (Vp and Vs), and laboratory measurements are within 4%, validating the model’s reliability. Petrophysical template analysis demonstrates that P-wave impedance (Ip) and the Vp/Vs ratio increase with water saturation but decrease with fracture density. A higher fracture density amplifies the fluid effect on the elastic properties of reservoir samples. The Vp/Vs ratio is more sensitive to pore fluids than to fractures, whereas Ip is more sensitive to fracture density. Regions with higher fracture and pore development exhibit greater hydrocarbon storage potential. Therefore, this petrophysical model and its quantitative templates can provide theoretical and technical support for predicting geological sweet spots in deep carbonate reservoirs. Full article