Search Results (184)

Climate change resulting from human development necessitates increased land use, food, and energy consumption, underscoring the need for sustainable development. Incorporating various feedstocks into value-added liquid fuels and bioproducts is essential for achieving sustainability. Most biomass consists of cell walls, which serve as a primary carbon source for bioenergy and biorefinery processes. This structure contains a cellulose core, where lignin and hemicelluloses are crosslinked and embedded in a pectin matrix, forming diverse polysaccharide architectures across different species and tissues. Nineteen agro-industrial waste products were analyzed for their potential use in a circular economy. The analysis included cell wall composition, saccharification, and calorific potential. Thermal capacity and degradation were similar among the evaluated wastes. The feedstocks of corn cob, corn straw, soybean husk, and industry paper residue exhibited a higher saccharification capacity despite having lower lignin and uronic acid contents, with cell walls comprising 30% glucose and 60% xylose. Therefore, corn, soybeans, industrial paper residue, and sugarcane are more promising for bioethanol production. Additionally, duckweed, barley, sorghum, wheat, rice, bean, and coffee residues could serve as feedstocks for other by-products in green chemistry, generating valuable products. Our findings show that agro-industrial residues display a variety of polymers that are functional for various applications in different industry sectors. Full article

Oilseed cakes, by-products of oil extraction, represent an underutilized resource with significant potential for sustainable food and pharmaceutical applications. This comprehensive review examines the valorization strategies for oilseed cakes, focusing on their rich protein (up to 56%) and fiber (up to 66%) content. We analyze both conventional and innovative extraction methods, highlighting the advantages of ultrasound-assisted (96.64% phenolic compound yield), enzymatic (82–83% protein recovery), and subcritical water extraction techniques in improving efficiency while reducing environmental impact. This review demonstrates diverse applications of oilseed cake components from gluten-free bakery products and plant-based meat alternatives to advanced nanoencapsulation systems for bioactive compounds. Each major oilseed type (soybean, rapeseed, sunflower and flaxseed) exhibits unique nutritional and functional properties that can be optimized through appropriate processing. Despite technological advances, challenges remain in scaling extraction methods and balancing yield with functionality. This paper identifies key research directions, including the development of integrated biorefinery approaches and the further exploration of health-promoting peptides and fibers. By addressing these challenges, oilseed cakes can play a crucial role in sustainable food systems and the circular economy, transforming agricultural by-products into high-value ingredients while reducing waste. Full article

This study evaluates the effects of solid-state fermentation inoculated with Aspergillus spp. on the nutritional profile of selected agro-industrial by-products (AIBPs: cowpea shell, groundnut shell, soybean hull, and maize shaft). These AIBPs were assessed as potential feedstuffs in weaner rabbit diets, which often exhibit digestive disorders when introduced to highly lignified feed ingredients. The AIBPs were milled to a particle size of 2 mm, sterilized, and subjected to fermentation with Aspergillus spp. under microaerophilic conditions at 28 ± 2 °C for 10 days. Samples (four replicates per treatment) were analyzed for chemical constituents (mineral and proximate composition, anti-nutritional factors, and fibre fractions) before and after fermentation. Digestible energy and digestibility coefficient of gross energy were calculated. Data were subjected to two-way analysis of variance (ANOVA). There was an increase (p < 0.05) in mineral profile, proximate composition, digestible energy, digestibility coefficient of gross energy, and dry matter, with a reduction (p < 0.05) in crude fibre, fibre fractions, and anti-nutritional factors. It was concluded that fermentation with Aspergillus spp. improved the nutritional value of the selected agro-industrial by-products. Therefore, fermented materials possess a better nutritional profile to be used in feeding programs for weaner rabbits. This will ensure sustainable animal production and add value to agricultural waste, which would otherwise constitute an environmental nuisance. Full article

Mycotoxins are a large family of secondary metabolites produced by filamentous fungi species that may be present in food following fungal growth. Mycotoxins are found in a variety of crops, including wheat, millet, maize, sorghum, peanut, soybean, and their by-products. In recent years, the consumption of ready-to-eat food (RTE) has increased exponentially. An increasing number of consumers have elected to purchase and consume ready-made meals, a choice that allows for a more expedient and convenient dining experience. The aim of this review was to investigate recent literature to find a link between the consumption of mycotoxin-contaminated RTEs, modern detection methods (artificial intelligence), and potential health risks to consumers. The regular exchange of information between the Member States and the European Community (EU) concerning the monitoring of contaminants and undesirable chemical substances, and the subsequent communication of the findings to the EFSA, provides the foundation for the evolution of the legislative framework with the objective of enhancing food safety and reducing the risks associated with the consumption of food. It is imperative that governments, the food industry, and the scientific community collaborate to reduce this risk and ensure consumer safety. Full article

The management through co-hydrothermal carbonization (co-HTC) of swine manure (SM) and soybean hulls (SH), a by-product of animal feeding, is established as a strategy for their material and/or energy recovery. The effect of hydrothermal carbonization (HTC) temperature (210–240 °C) and mass ratio (1:0, 1:1, 1:3, 0:1) on hydrochar characteristics revealed that an improved hydrochar (C (51–59%), HHV (21–24 MJ/kg), N (~2%), S (~0.3%), and ash (<9%)) is produced with respect to hydrochar obtained from individually treated wastes. Regarding biofuel characteristics, hydrochar obtained from the SM/SH mass ratio (1:3) at 240 °C complied with the requirements of the ISO/TS 17225-8:2023 (N < 2.5%; S < 0.3%; HHV > 17 MJ/kg; ash < 12%) and showed high energy content (23.2 MJ/kg) and a greater thermal stability than the hydrochar obtained from individual wastes. Hydrochar retained relatively high amounts of nutrients such as phosphorus (6.5–9.7 g/kg), potassium (2.0–3.5 g/kg), and calcium (9–20 g/kg), which supports their use as soil improvers. Moreover, all hydrochar fulfill the standards (Spanish Royal Decrees 1051/2022, 824/2024 and EU Regulation 2019/1009) for sustainable nutrition in agriculture soils in terms of heavy metals concentration. The co-HTC of swine manure and soybean hulls demonstrated a promising transformation of waste materials into biofuel and/or soil improvers. Full article

Black soybean okara is a common food byproduct in Asia. This study conducted collaborative fermentation with Rhizopus oligosporus and Yarrowia lipolytica to produce a GABA-enriched okara product. Two black soybean varieties, TN3 and TN5, were used, and optimal fermentation conditions were predicted using response surface methodology (RSM). After 24 h of Rhizopus oligosporus incubation, Yarrowia lipolytica was inoculated under 20 trial conditions with variations in temperature, incubation time, and inoculation size. The model predicted that the highest GABA content would be achieved at 34–35 °C, 47–49 h incubation, and 3–4 log CFU/mL inoculation. Under these optimal conditions, the maximum GABA yields achieved were 868.3 µg/g for TN3 and 853.1 µg/g for TN5. Fermentation conditions had minimal influence on protease activity, which may be attributed to the distinct roles of Rhizopus oligosporus and Yarrowia lipolytica in the fermentation process. The solid-state collaborative fermentation technology supports food waste recycling and enhances product functionality, contributing to the circular economy. Full article

This study employs near-infrared spectroscopy (NIRS) combined with chemometrics to explore the feasibility and methodology for the rapid analysis of lignocellulosic content in straw. As the demand for biofuels and bioproducts increases, the efficient utilization of agricultural waste, such as straw, has become particularly important. Rapid analysis of lignocellulosic content helps improve the resource utilization efficiency of agricultural waste, providing significant support for biofuel production, agricultural waste valorization, and environmental protection. A total of 148 straw samples were used in this study, collected from Zhejiang, Jiangsu, and Heilongjiang provinces in China, covering rice straw (Oryza sativa L.), corn straw (Zea mays L.), wheat straw (Triticum aestivum L.), soybean straw (Glycine max L.), sorghum straw (Sorghum bicolor L.), rapeseed straw (Brassica napus L.), and peanut straw (Arachis hypogaea L.). After collection, the samples were first air-dried until surface moisture evaporated and then ground and sifted before being numbered and sealed for storage. To ensure the accuracy of the experimental results, all samples were subjected to a 6 h drying treatment at 60 °C before the experiment to ensure uniform moisture content. Partial least squares (PLS) and support vector machine (SVM) regression methods were employed for modeling analysis. The results showed that NIRS in combination with PLS modeling outperformed SVM in the calibration and prediction of lignocellulosic content. Specifically, the cellulose PLS model achieved a prediction set coefficient of determination (R²_P) of 0.8983, root mean square error of prediction (RMSEP) of 0.6299, and residual predictive deviation (RPD) of 3.49. The hemicellulose PLS model had an R²_P of 0.7639, RMSEP of 1.5800, and RPD of 2.11, while the lignin PLS model achieved an R²_P of 0.7635, RMSEP of 0.6193, and RPD of 2.17. The results suggest that NIRS methods have broad prospects in the analysis of agricultural waste, particularly in applications related to biofuel production and the valorization of agricultural by-products. Full article

The main objective of energy balance analysis is to guide farmers in making informed decisions that promote the efficient management of natural resources, optimise the use of agricultural inputs, and improve the overall economic performance of their farms. In addition, it supports the adoption of sustainable agricultural practices, such as crop diversification, the use of renewable energy sources, and the recycling of agricultural by-products and residues into natural energy sources or fertilisers. This paper analyses the variation in energy efficiency between 2019 and 2022 of the main crops in Angola: maize, soybean, and rice, and the forest production of eucalyptus biomass in agroforestry farms. The research was based on the responses to interviews conducted with the managers of the farms regarding the machinery used, fuels and lubricants, labour, seeds, phytopharmaceuticals, and fertilisers. The quantities are gathered by converting data into Megajoules (MJ). The results show variations in efficiency and energy balance. In corn, efficiency fluctuated between 1.32 MJ in 2019 and 1.41 MJ in 2020, falling to 0.94 MJ in 2021 due to the COVID-19 pandemic before rising to 1.31 MJ in 2022. For soybeans, the energy balance went from a deficit of −8223.48 MJ in 2019 to a positive 11,974.62 MJ in 2022, indicating better use of resources. Rice stood out for its high efficiency, reaching 81,541.33 MJ in 2021, while wood production showed negative balances, evidencing the need for more effective strategies. This research concludes that understanding the energy balance of agricultural operations in Angola is essential not only to achieve greater sustainability and profitability but also to strengthen the resilience of agricultural systems against external factors such as climate change, fluctuations in input prices, and economic crises. A comprehensive understanding of the energy balance allows farmers to assess the true cost-effectiveness of their operations, identify energy inefficiencies, and implement more effective strategies to maximise productivity while minimising environmental impacts. Full article

The agri-food supply chain and other industries that convert agricultural raw materials into various consumer goods generate large quantities of by-products, most of which end up in landfills. This waste, rich in cellulose, provides a significant opportunity for the conversion of agricultural residues into valuable products. In this paper, soybean hulls and hemp waste were subjected to chemical treatments with alkaline (NaOH 2% w/v) and acidic solutions (HCl 1 M) to remove non-cellulosic components and isolate cellulose. The biomass was characterized after each chemical process through FTIR, SEM, EDX, elemental analysis, TGA, and XRD. Lignin was determined following two different procedures, a conventional TAPPI protocol and a method recently proposed in the literature (CASA method). The results indicated that the chemical treatments favored the removal of organic compounds and minerals, increasing the cellulose content in biomass after each step. The purified product of soybean hulls consists of fibers 35–50 µm long and 5–11 µm thick, containing nearly pure cellulose arranged in crystalline domains. Fibers of variable sizes, rich in crystalline cellulose, were isolated from hemp waste. These fibers have diameters ranging between 2 and 60 µm and lengths from 40 to 800 µm and contain considerable amounts of lignin (~14%). Full article

Flexible polyurethane foams are a diverse class of materials encompassing furniture, packaging, automotive, and many other industrial and domestic applications. Polyurethane foams are synthesized by the addition of polyols and isocyanates; however, the petroleum origin and toxic nature of isocyanates have driven many to look for more sustainable routes to production. Renewable fillers have emerged as a biobased resource to decrease the carbon footprint of this widely used polymeric material. In this study, soy hulls, as mass-produced, industrial by-products of soybean production, were used to create a biochar beneficial in the synthesis of flexible polyurethane foam composites. The addition of soy hull biochar was found to maintain the compression properties of foams at a decreasing isocyanate index, reducing the amount of isocyanates needed for production. In addition, the addition of biochar decreased the flammability of foams, important for many applications where consumer safety is important. The results point to the ability to create safer, more sustainable, and even more cost-effective polyurethane foams through the reduction in isocyanate use while maintaining the properties of this important class of polymers. Full article

Over the past few decades, awareness has risen substantially about the limitations of non-renewable resources and the environmental challenges facing the chemical industry. This has necessitated a transition toward renewable resources, such as lignocellulosic biomass, which is among the most abundant renewable carbon sources on the planet. Lignocellulosic biomass represents a significant yet often underutilized source of fermentable sugars and lignin, with potential applications across multiple sectors of the chemical industry. The formation of humins (polymeric byproducts with a complex conjugated network, comprising furanic rings and various functional groups, including ketones) occurs inevitably during the hydrothermal processing of lignocellulosic biomass. This study presents the use of humin byproducts derived from soybean peels for the production of fluorescent carbon dots (CDs). A comparison between sonochemical and thermochemical methods was conducted for the synthesis of this nanomaterial. The obtained nanoparticles were characterized in terms of size, morphology (TEM, DLS), and Z-potential. Subsequently, the spectroscopic properties of the prepared CDs were studied using absorption and emission spectroscopy. In particular, the CDs displayed a blue/cyan fluorescence under UV irradiation. The emission properties were found to be dependent on the excitation wavelength, shifting to longer wavelengths as the excitation wavelength increased. The carbon dots that exhibited the most favorable photochemical properties (QY = 2.5%) were those produced through a sonochemical method applied to humins obtained from the dehydration of soybean husks with phosphoric acid and prior treatment. Full article

Pharmaceuticals are a class of emerging contaminants that have been widely detected in wastewater treatment facilities’ influent and effluent. They threaten the environment and non-target life. Thus, a promising treatment method, soybean peroxidase (SBP; EC 1.11.1.7), which catalyzes the oxidation of phenolic and anilino donors in the presence of hydrogen peroxide, was investigated as a treatment method. The aim was to remove two non-steroidal anti-inflammatory drugs, diclofenac (DCF) and aceclofenac (ACF), from synthetic wastewater via enzymatic oxidation, oligomerization, and precipitation. SBP can be extracted from soybean hulls, a byproduct of the soybean industry. DCF (0.10 mM) and ACF (0.10 mM) were amenable to SBP-catalyzed removal under the optimal operational parameters of pH 5 and 4; hydrogen peroxide: 0.40 and 0.45 mM; and minimum effective enzyme concentration: 0.15 and 0.60 U/mL, respectively. The initial first-order rate constant and half-life of each substrate were also determined under the established optimum conditions. Under these optimum conditions, the half-lives for DCF and ACF were 1.43 ± 0.01 and 0.84 ± 0.05 min, respectively. The results demonstrated that SBP is a robust enzyme that can achieve more than 95% removal for both compounds. Mass spectrometric analysis of the enzymatic treatment products of DCF revealed the formation of an oxidative tetramer. The SBP-catalyzed reaction is a highly effective method for removing DCF and ACF from synthetic wastewater, highlighting its potential for environmental cleanup of pharmaceutical contaminants. Full article

The main disadvantages of using soybean oil extraction waste as a raw feed material are its high contents of fiber, fat, and anti-nutritional factors. Therefore, several processing methods such as extrusion and hydrolysis are used to overcome these disadvantages and increase the availability of high-quality proteins to animals from this by-product. This study is concerned with the hydrolysis of extruded soybean meal in the presence of bacterial alkaline proteases. The effects of various process parameters were investigated to determine the optimal process parameters for hydrolysis in terms of the total free amino acid and amine nitrogen contents. The experiment included two sets of parameters that were selected for comparison: the temperature and pH in ranges of t 45–50 °C, pH 8–11, compared to the temperature and pH ranges of t = 40–45 °C and pH 7–9, using three enzyme/substrate ratios (1:10, 1:20, and 1:30). The protein hydrolysate was stored for three months after it was treated with two different preservatives (sorbic acid and thymol). Based on the results, it was found that the total free amino acid content was higher when the temperature range was 45–50 °C, the pH range was 8–11, and sorbic acid was used as a preservative. Full article

Fusarium oxysporum is a fungal plant pathogen for over 100 agricultural crop species. There are strategies for managing Fusarium wilt, including antagonistic bacteria that offer a promising and sustainable effect. In this work, among the various endophytic bacterial strains, Paenibacillus polymyxa EB.KN35 was selected as the best antifungal strain against F. oxysporum. For eco-friendly biomass production of this bacterium, some agricultural byproducts were tested for cultivation, and a soybean processing byproduct (SPBP) was found to be a suitable C/N source for P. polymyxa EB.KN35 fermentation. The utilization of a 14 L bioreactor system for P. polymyxa EB.KN35 fermentation achieved a high biomass productivity (3.46 × 10¹¹ CFU/mL) in a short time (8 h). In bioactive compound analysis, EB.KN35 was found to be secreting several plant growth-promoting compounds such as GA3, IAA, kinetin, and zeatin (via HPLC) and eleven volatile compounds (via GC–MS). The docking study indicated that some volatile compounds (1, 2, 4, and 9) may play a significant role in inhibiting F. oxysporum. The study results highlight the potential for reusing a soybean processing byproduct as a C/N source for the bioproduction of P. polymyxa EB.KN35 with potential use as a biocontrol agent and biofertilizer. Full article

Soybean expeller (SBE), a by-product of soybean oil extraction through the extruding-expelling process, is widely used as a protein source in animal feed and soy-based foods. This study evaluated fungal contamination and mycotoxin levels in SBE samples from 11 extruding-expelling facilities in Argentina, assessing fungal load, moisture content (MC), and mycotoxin profiles. Fungal biota was quantified through colony forming unit (CFU) counts and identified via morphological analysis, while mycotoxins were quantified using liquid chromatography and tandem mass spectrometry. CFU counts were low (0 to 4 CFU g⁻¹ DM), with Penicillium spp. (28.0%) and Mucoraceae (family) (25.6%) being the most frequently isolated genera. Deoxynivalenol (DON) and aflatoxins (AFB₁, AFB₂, AFG₁, and AFG₂) were detected in 20% to 40% of the samples. The average concentration was 215.19 µg kg⁻¹ for DON and 41.68, 0.39, and 0.34 µg kg⁻¹ for AFB₁, AFG₁, and AFG₂, respectively. Although most mycotoxin concentrations were below regulatory limits, a few samples exceeded the threshold for DON (8.6%) and AFB₁ (2.9%). Co-occurrence of two mycotoxins was observed in 60% of the samples. These results highlight the importance of monitoring fungal contamination and mycotoxin levels to ensure the safety and quality of SBE for feed and food applications. Full article