Search Results (673)

A facile and versatile strategy to obtain NPs@ZnAlO nanocomposite materials, comprising controlled-size nanoparticles (NPs) within a ZnAlO matrix is reported. The mono-(Au, Ni) and bimetallic (Ni-Au) NPs serving as an active phase were prepared by the polyol-alkaline method, while the ZnAlO support was obtained via the thermal decomposition of its corresponding layered double hydroxide (LDH) precursors. X-ray diffraction (XRD) patterns confirmed the successful fabrication of the nanocomposites, including the synthesis of the metallic NPs, the formation of LDH-like structure, and the subsequent transformation to ZnO phase upon LDH calcination. The obtained nanostructures confirmed the nanoplate-like morphology inherited from the original LDH precursors, which tended to aggregate after the addition of gold NPs. According to the UV-Vis spectroscopy, loading NPs onto the ZnAlO support enhanced the light absorption and reduced the band gap energy. ATR-DRIFT spectroscopy, H₂-TPR measurements, and XPS analysis provided information about the functional groups, surface composition, and reducibility of the materials. The catalytic performance of the developed nanostructures was evaluated by the photodegradation of bisphenol A (BPA), under simulated solar irradiation. The conversion of BPA over the bimetallic Ni-Au@ZnAlO reached up to 95% after 180 min of irradiation, exceeding the monometallic Ni@ZnAlO and Au@ZnAlO catalysts. Its enhanced activity was correlated with good dispersion of the bimetals, narrower band gap, and efficient charge carrier separation of the photo-induced e⁻/h⁺ pairs. Full article

Photocatalytic redox processes significantly contribute to shaping Earth’s surface environment. Semiconductor minerals exhibiting favorable photocatalytic properties are ubiquitous on rock and soil surfaces. However, the sunlight-responsive characteristics and functions of TiO₂, an excellent photocatalytic material, within natural systems remain incompletely understood, largely due to its wide bandgap limiting solar radiation absorption. This study analyzed surface coating samples, determining their elemental composition, distribution, and mineralogy. The analysis revealed enrichment of anatase TiO₂ and β-carotene. Informed by these observations, laboratory simulations were designed to investigate the synergistic effect of β-carotene on the sunlight-responsive behavior of anatase. Results demonstrate that β-carotene-sensitized anatase exhibited a 64.4% to 66.1% increase in photocurrent compared to pure anatase. β-carotene sensitization significantly enhanced anatase’s electrochemical activity, promoting rapid electron transfer. Furthermore, it improved interfacial properties and acted as a photosensitizer, boosting photo-response characteristics. The sensitized anatase displayed a distinct absorption peak within the 425–550 nm range, with visible light absorption increasing by approximately 17.75%. This study elucidates the synergistic mechanism enhancing the sunlight response between anatase and β-carotene in natural systems and its broader environmental implications, providing new insights for research on photocatalytic redox processes within Earth’s critical zone. Full article

This research proposes an integrated lighting and solar shading strategy to improve energy efficiency and user comfort in a retrofit project in a temperate-humid climate. The study examines a future library addition to an existing faculty building in Bursa, featuring highly glazed façades (77% southwest, 81% northeast window-to-wall ratio), an open-plan layout, and situated within an unobstructed low-rise campus environment. Trade-offs between daylight availability, heating, cooling, lighting energy use, and visual and thermal comfort are evaluated through integrated lighting (DIALux Evo), climate-based daylight (CBDM), and energy simulations (DesignBuilder, EnergyPlus, Radiance). Fifteen solar shading configurations—including brise soleil, overhangs, side fins, egg crates, and louvres—are evaluated alongside a daylight-responsive LED lighting system that meets BS EN 12464-1:2021. Compared to the reference case’s unshaded glazing, optimal design significantly improves building performance: a brise soleil with 0.4 m slats at 30° reduces annual primary energy use by 28.3% and operational carbon emissions by 29.1% and maintains thermal comfort per ASHRAE 55:2023 Category II (±0.7 PMV; PPD < 15%). Daylight performance achieves 91.5% UDI and 2.1% aSE, with integrated photovoltaics offsetting 129.7 kWh/m² of grid energy. This integrated strategy elevates the building’s energy class under national benchmarks while addressing glare and overheating in the original design. Full article

To enable accurate evaluation of satellite laser communication terminals under solar outage interference, this paper presents the design and implementation of a solar radiation simulation system targeting the 1540–1560 nm communication band. The system reconstructs co-propagating interference conditions through standardized and continuously tunable output, based on high irradiance and spectral uniformity. A compound beam homogenization structure—combining a multimode fiber and an apodizator—achieves 85.8% far-field uniformity over a 200 mm aperture. A power–spectrum co-optimization strategy is introduced for filter design, achieving a spectral matching degree of 78%. The system supports a tunable output from 2.5 to 130 mW with a 50× dynamic range and maintains power control accuracy within ±0.9%. To suppress internal background interference, a BRDF-based optical scattering model is established to trace primary and secondary stray light paths. Simulation results show that by maintaining the surface roughness of key mirrors below 2 nm and incorporating a U-shaped reflective light trap, stray light levels can be reduced to 5.13 × 10⁻¹² W, ensuring stable detection of a 10⁻¹⁰ W signal at a 10:1 signal-to-background ratio. Experimental validation confirms that the system can faithfully reproduce solar outage conditions within a ±3° field of view, achieving consistent performance in spectrum shaping, irradiance uniformity, and background suppression. The proposed platform provides a standardized and practical testbed for ground-based anti-interference assessment of optical communication terminals. Full article

The growing number of daylighting metrics—often overlapping in scope or terminology—combined with the need for prior familiarization to interpret and apply them effectively, has created a barrier to their adoption beyond academic settings. Consequently, this study analyzes a representative set of established and emerging daylighting metrics to evaluate applicability, synergies, and limitations. Particular attention is given to their implications for occupant health, well-being, performance, and energy use, especially within the context of sensorless smart control systems. A virtual room model was simulated using DaySim 3.1 in two contrasting climates—Seville and London—with varying window-to-wall ratios, orientations, and occupancy schedules. The results show that no single metric provides a comprehensive daylighting assessment, highlighting the need for combined approaches. Daylighting Autonomy (DA) proved useful for task illumination, while Useful Daylight Illuminance (UDI) helped identify areas prone to excessive solar exposure. Spatial metrics such as Spatial Daylight Autonomy (sDA) and Annual Sunlight Exposure (ASE) offer an overview but lack necessary granularity. Circadian Stimulus Autonomy (CSA) appears promising for evaluating circadian entrainment, though its underlying models remain under refinement. Continuous Overcast Daylight Autonomy (DAo.con) shows the potential for sensorless lighting control when adjusted for orientation. A nuanced, multi-metric approach is therefore recommended. Full article

The rapid recombination of photoinduced charge carriers in semiconductors remains a significant challenge for their practical application in photocatalysis. This study presents the design of a step-scheme (S-scheme) heterojunction composed of carbon nitride (g-C₃N₄) and nickel-based metal–organic framework (Ni-MOF) to achieve enhanced charge separation. The establishment of an S-scheme charge transfer configuration at the interface of the Ni-MOF/g-C₃N₄ heterostructure plays a pivotal role in enabling efficient charge carrier separation, and hence, high CO₂ photoreduction efficiency with a CO evolution rate of 1014.6 µmol g⁻¹ h⁻¹ and selectivity of 95% under simulated solar illumination. CO evolution represents an approximately 3.7-fold enhancement compared to pristine Ni-MOF. Density functional theory (DFT) calculations, supported by in situ irradiated X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR) experimental results, confirmed the establishment of a well-defined and strongly bonded interface, which improves the charge transfer and separation following the S-scheme mechanism. This study sheds light on MOF-based S-scheme heterojunctions as fruitful and selective alternatives for practical CO₂ photoreduction. Full article

Windows are a major contributor to energy loss in buildings, particularly in hot climates where solar radiation heat gain significantly increases cooling demand. An ideal energy-efficient window must maintain high visible light transmittance while effectively blocking ultraviolet and near-infrared radiation, presenting a significant challenge for material design. We propose a plasma silica aerogel window utilizing the local surface plasmon resonance effect of plasmonic nanoparticles. This design incorporates indium tin oxide (ITO) nanospheres (for broad-band UV/NIR blocking) and silver (Ag) nanocylinders (targeted blocking of the 0.78–0.9 μm NIR band) co-doped into the silica aerogel. This design achieves a visible light transmittance of 0.8, a haze value below 0.12, and a photothermal ratio of 0.91. Building simulations indicate that compared to traditional glass, this window can achieve annual energy savings of 20–40% and significantly reduce the economic losses associated with traditional glass, providing a feasible solution for sustainable buildings. Full article

This paper presents the synthesis of La₂Ti₂O₇ nanoparticles by the sol–gel method starting from lanthanum nitrate and titanium alkoxide (noted as LTA). Subsequently, the lanthanum titanium oxide nanoparticles are modified with noble metals (platinum) using the chemical impregnation method, followed by a reduction process with NaBH₄. The comparative analysis of the structure and surface characteristics of the nanopowders subjected to thermal treatment at 900 °C is conducted using Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray fluorescence (XRF), ultraviolet-visible (UV–Vis) spectroscopy, as well as specific surface area and porosity measurements. The photocatalytic activity is evaluated in the oxidative photodegradation of ethanol (CH₃CH₂OH) under simulated solar irradiation. The modified sample shows higher specific surfaces areas and improved photocatalytic properties, proving the better conversion of CH₃CH₂OH than the pure sample. The highest conversion of ethanol (29.75%) is obtained in the case of LTA-Pt after 3 h of simulated solar light irradiation. Full article

Concentrating photovoltaic-thermal (CPVT) collectors use reflective surfaces to focus sunlight onto a smaller receiver area, increasing thermal energy output while maintaining annual energy efficiency. Ray-tracing simulations are employed in this study using Tonatiuh to optimise the characteristics of the Double MaReCo (DM) collector, which is an improved version of the commercially available Solarus Power Collector (PC). Focused on enhancing electrical performance, the photovoltaic (PV) cell configurations are varied on the bottom side of the receiver, while the top-side PV cells remain constant. The study also analyses the influence of diodes and transparent gables on the annual solar irradiance received by the PV cells. From the analysis, it is observed that the specific annual irradiance received by the PV cells in the DM collector with transparent gables is nearly 64% more compared to that of the PC counterpart. It is also observed that the transparency of gables becomes significant only when the whole area of the receiver is covered by PV cells. With the goal of improving performance while lowering the cost and complexity of the DM collector, the study investigates various collector design characteristics that may shed more light on optimising the current model. Full article

Urban thermal environments, characterized by the interplay between indoor and outdoor conditions, pose growing challenges in high-density coastal cities. This study proposes a multi-scale, integrative framework that couples a satellite-derived land surface temperature (LST) analysis with microscale building performance simulations to holistically evaluate the high-density urban thermal environment in subtropical climates. The results reveal that compact, high-density morphologies reduce outdoor heat stress (UTCI) through self-shading but lead to significantly higher cooling loads, energy use intensity (EUI), and poorer daylight autonomy (DA) due to restricted ventilation and limited sky exposure. In contrast, more open, vegetation-rich forms improve ventilation and reduce indoor energy demand, yet exhibit higher UTCI values in exposed areas and increased lighting energy use in poorly oriented spaces. This study also proposes actionable design strategies, including optimal building spacing (≥15 m), façade orientation (30–60° offset from west), SVF regulation (0.4–0.6), and the integration of vertical greenery to balance solar access, ventilation, and shading. These findings offer evidence-based guidance for embedding morphological performance metrics into planning policies and building design codes. This work advances the integration of outdoor and indoor performance evaluation and supports climate-adaptive urban form design through quantitative, policy-relevant insights. Full article

With rapid global urbanization, glass curtain wall buildings have been widely adopted due to aesthetics and natural lighting. However, during summer time, intense solar radiation leads to significant indoor heat gain, which adversely affect thermal comfort and energy efficiency. The conventional air conditioning systems are typically equipped with a cooling capacity sufficient to maintain an indoor air temperature at the design values specified in the Design standard for energy efficiency of public buildings, which fails to account for the effects of radiation temperature, potentially resulting in reduced thermal comfort and energy inefficiency. By integrating the Thermal Comfort Tool to calculate the PMV index, this study evaluates the affection of solar heat gain on indoor occupants’ thermal comfort and proposes an optimized air temperature control strategy to realize thermal comfort. Based on the dynamic air temperature strategy, an energy consumption model is developed to evaluate the affection of solar radiation on energy consumption for glass curtain wall buildings based on the PMV index. The synergistic effects of shading measures are then evaluated. This study conducts simulation analysis using an office building with a glass curtain wall located in Beijing as a case study. When accounting for radiant heat gain, a significant portion of the time (53.89%) fall outside the thermal comfort range, even when the air conditioning is set to the designated temperature. To maintain thermal comfort, the air conditioning temperature must be lowered by 1.4–3.5 °C, resulting in a 28.08% increase in energy consumption. To address this issue, this study finds that installing interior shading can reduce radiant heat gain. Under the same thermal comfort conditions, the required air temperature reduction is only 0.8–2.1 °C, leading to a 24.26% reduction in energy consumption compared to the case without interior shading. Full article

This study presents the first comprehensive theoretical investigation utilizing SCAPS-1D simulation to systematically evaluate eight hole transport materials for CsPbI₂Br perovskite solar cells under authentic indoor LED conditions (560 lux, 5700 K color temperature). Unlike previous studies employing simplified illumination assumptions, our work establishes fundamental design principles for indoor photovoltaics through rigorous material property correlations. The investigation explores the influence of layer thickness and defect concentration on performance to identify optimal parameters. Through detailed energy band alignment analysis, we demonstrate that CuI achieves superior performance (PCE: 23.66%) over materials with significantly higher mobility, revealing that optimal band alignment supersedes carrier mobility under low-light conditions. Analysis of HTL and absorber layer thickness, bulk defect concentration, interface defect density, and an HTL-free scenario showed that interface defect concentration and absorber layer parameters have greater influence than HTL thickness. Remarkably, ultra-thin HTL layers (0.04 μm) maintain >99% efficiency, offering substantial cost reduction potential for large-scale manufacturing. Under optimized conditions of a 0.87 μm absorber layer thickness, defect concentration of 10¹⁵ cm⁻³, interface defect concentration of 10⁹ cm⁻³, and CuI doping concentration of 10¹⁷ cm⁻³, PCE reached 28.57%, while the HTL-free structure achieved 17.6%. This study establishes new theoretical foundations for indoor photovoltaics, demonstrating that material selection criteria differ fundamentally from outdoor applications. Full article

The widespread presence of pesticides—especially malathion—in aquatic environments presents a major obstacle to conventional remediation strategies, while the ongoing global energy crisis underscores the urgency of developing renewable energy sources such as hydrogen. In this context, photocatalytic water splitting emerges as a promising approach, though its practical application remains limited by poor charge carrier dynamics and insufficient visible-light utilization. Herein, we report the design and evaluation of a series of TiO₂-based ternary nanocomposites comprising commercial P25 TiO₂, reduced graphene oxide (rGO), and molybdenum disulfide (MoS₂), with MoS₂ loadings ranging from 1% to 10% by weight. The photocatalysts were fabricated via a two-step method: hydrothermal integration of rGO into P25 followed by solution-phase self-assembly of exfoliated MoS₂ nanosheets. The composites were systematically characterized using X-ray diffraction (XRD), Raman spectroscopy, transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (DRS), and photoluminescence (PL) spectroscopy. Photocatalytic activity was assessed through two key applications: the degradation of malathion (20 mg/L) under simulated solar irradiation and hydrogen evolution from water in the presence of sacrificial agents. Quantification was performed using UV-Vis spectroscopy, gas chromatography–mass spectrometry (GC-MS), and thermal conductivity detection (GC-TCD). Results showed that the integration of rGO significantly enhanced surface area and charge mobility, while MoS₂ served as an effective co-catalyst, promoting interfacial charge separation and acting as an active site for hydrogen evolution. Nearly complete malathion degradation (~100%) was achieved within two hours, and hydrogen production reached up to 6000 µmol g⁻¹ h⁻¹ under optimal MoS₂ loading. Notably, photocatalytic performance declined with higher MoS₂ content due to recombination effects. Overall, this work demonstrates the synergistic enhancement provided by rGO and MoS₂ in a stable P25-based system and underscores the viability of such ternary nanocomposites for addressing both environmental remediation and sustainable energy conversion challenges. Full article

In this research, an emerging, non-metallic photocatalyst was prepared by the thermal polymerization method from three different precursors: urea, melamine, and three mixtures of melamine and cyanuric acid. Graphitic carbon nitride (g-C₃N₄) samples from urea and melamine were synthesized in a muffle furnace at three different temperatures: 450°, 500°, and 550 °C for 2 h, while the samples made of a mixture of melamine and cyanuric acid (with mass ratios of 1:1, 1:2, and 2:1) were synthesized at 550 °C for 2 h. All the samples were characterized in order to determine their chemical and physical properties, such as crystallite size and structure, and phase composition by the following techniques: Fourier transform infrared spectroscopy (FTIR), X-ray diffraction analysis (XRD), and scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS). Nitrogen adsorption/desorption isotherms were used to investigate the Brunauer, Emmett, and Teller (BET) specific surface area and Barrett–Joyner–Halenda (BJH) pore size distribution. Band gap values were determined by diffuse reflectance spectroscopy (DRS). Furthermore, adsorption and photocatalytic degradation of the local anesthetic drug procaine were monitored under UV-A, visible, and simulated solar irradiation in a batch reactor. Kinetic parameters, as well as photocatalytic mechanisms using scavengers, were determined and analyzed. The results of the photocatalysis experiments were compared to the benchmark TiO₂ Evonik Aeroxide P25. The results indicated that the g-C₃N₄ sample synthesized from urea at 500 °C for 2 h exhibited the highest degradation rate of procaine under visible light. Full article

In this study, TiO₂-Fe₂O₃/polyvinylpyrrolidone (PVP) hybrids were prepared using the sol–gel method. The iron content in the synthesized samples was 10 and 20 wt%. The influence of PVP on the phase transformation, morphology and optical properties of the as-prepared hybrids was characterized by various physicochemical methods—XRD analysis, UV–Vis spectroscopy, IR spectroscopy and SEM. The obtained sol–gel powders were tested for photocatalytic activity against tetracycline hydrochloride in distilled water under ultraviolet and simulated solar light illumination. The obtained results were compared to commercial TiO₂ P25 (Evonik). The investigated samples exhibited good photocatalytic efficiency for the degradation of tetracycline hydrochloride; however, better activity was demonstrated by the 90TiO₂-10Fe₂O₃/PVP sample. The latter one displayed weak antibacterial action against E. coli ATCC 25922 in the presence of UVA light. Full article