Search Results (544)

Waste lubricating oils (WLOs) represent a major stream of hazardous petroleum-based residues, with global generation exceeding 24 million tons annually. Improper disposal of WLOs poses risks to soil, water, and air quality, while their chemical composition makes them a potential secondary resource within circular economy frameworks. This review summarizes conventional, advanced, and emerging technologies reported for the recycling and valorization of WLOs into high-value petrochemicals and carbon-based materials. Established processes such as acid–clay treatment, solvent extraction, and vacuum distillation are discussed together with more recent approaches, including catalytic upgrading, hydrotreatment, membrane separation, and thermochemical conversion methods such as pyrolysis and catalytic cracking. Reported data on process performance, environmental considerations, techno-economic indicators, and life cycle assessment outcomes are comparatively analyzed to outline current trends, technical challenges, and future development directions in WLO recycling. Particular attention is given to thermochemical pathways capable of generating carbonaceous materials, including carbon black, porous carbons, and functional carbon nanostructures with potential applications in adsorption, catalysis, electrochemical systems, and tribological formulations. Hybrid and integrated process configurations described in the literature are highlighted for their potential to improve recovery efficiency, enhance product quality, and reduce environmental burdens. In addition, recent life cycle assessment (LCA) and techno-economic analysis (TEA) studies are reviewed to provide insight into the environmental and economic implications of advanced re-refining systems. Overall, the reviewed literature indicates that WLO recycling represents not only an important element of sustainable lubricant management but also a promising waste-to-carbon strategy for the production of value-added carbon-based materials and petrochemical products. Full article

Although foamed lightweight soil is widely used for its light weight and high strength, its insufficient dynamic performance under cyclic loading and the poorly understood reinforcement mechanism have become key bottlenecks restricting its optimized application. To investigate the dynamic characteristics and influencing factors of geogrid-reinforced foamed lightweight soil (GRFLS), laboratory dynamic triaxial tests were conducted using a DJSZ-100D dynamic–static triaxial testing system. The effects of the number of geogrid layers and wet density on the dynamic mechanical properties were examined, with analysis focused on failure patterns, backbone curves, dynamic strength, dynamic shear modulus, and damping ratio. The results indicate that the inclusion of geogrids effectively restrained the propagation of longitudinal cracks in the foamed lightweight soil. The hyperbolic backbone curves were well characterized by the Hardin–Drnevich model. An increase in wet density significantly enhanced the dynamic strength, and an optimal number of two reinforcement layers was identified based on the reinforced strength–stress ratio. The dynamic elastic modulus and damping ratio of GRFLS increased with growing dynamic strain. Compared with the unreinforced condition, the initial dynamic elastic modulus of the specimens with two geogrid layers increased by an average of 15.6%, and the maximum damping ratio increased by an average of 12.9%. While both geogrid reinforcement and higher wet density effectively increased the dynamic elastic modulus, only an increase in wet density notably improved the damping ratio. Finally, predictive models for the enhanced dynamic elastic modulus and damping ratio, which incorporate wet density and the number of reinforcement layers, were established. These models indirectly reflect the dynamic deviator stress–strain relationship of GRFLS. This study provides a theoretical basis for engineering construction. Full article

Freeze–thaw cycles cause mechanical deterioration and instability of slope rock masses in open-pit coal mines located in the cold regions of Northwest China. In this study, the research object is fine-grained sandstone from the Yan’an Formation in the Tarangole mining area of the Ordos Basin. Here, indoor freeze–thaw cycling, uniaxial compression, and triaxial compression tests were conducted to systematically analyze the deformation behavior, strength evolution, and failure modes of the sandstone under varying numbers of freeze–thaw cycles, freezing temperatures, and confining pressures, thereby revealing its freeze–thaw damage mechanism. The results show that the number of freeze–thaw cycles is the dominant factor affecting the elastic modulus. Freezing temperatures (especially between −5 °C and −15 °C) and the number of freeze–thaw cycles (particularly the first 10 cycles) significantly reduce peak strength. In addition, confining pressure can significantly enhance the resistance to deformation (under 15 freeze–thaw cycles, the elastic modulus increases by 181.8% as confining pressure rises from 0 to 2 MPa). Within the low confining pressure range (0–1.5 MPa), peak strain decreases monotonically with increasing confining pressure and is independent of the number of freeze–thaw cycles. Finally, the increase in the number of freeze–thaw cycles and the decrease in temperature jointly promote crack development, and the failure mode shifts from pure shear to a shear-tension composite mode. The underlying cause lies in the evolution of interparticle cementation within the soil skeleton and in the associated pore–crack structure. In addition, based on fracture damage mechanics and the modified Weibull distribution, a damage evolution equation and a constitutive model for sandstone considering freeze–thaw cycles and temperature effects were established and validated. Therefore, the research findings can provide a theoretical basis for slope support, freeze–thaw disaster prevention and mitigation, and stability assessment in the Tarangole mining area and other cold regions. Full article

Land surface temperature (LST) is crucial for understanding winter landslide evolution. This study combines Unmanned Aerial Vehicle (UAV) photogrammetry and infrared thermography (IRT) to monitor winter landslides in China’s Wumeng Mountain region. Using the Yangjiazhai landslide—induced by underground coal mining—as a case study, we demonstrate significant correlations between IRT-detected LST anomalies and surface cracks: (1) cracks with elevated temperatures are likely connected to subsurface goaf zones; (2) excessively widened cracks show no thermal anomalies due to enhanced air convection. The research reveals that key landslide components have distinct LST signatures, governed by differential soil–rock moisture and crack networks. For accurate high-altitude winter LST acquisition, UAV thermal surveys should be conducted under overcast, fog-free conditions to reduce solar interference. This validates UAV visible–infrared fusion for extracting landslide boundaries, cracks, slumping zones, bedrock patterns, and moisture distribution. The methodology establishes a new pathway for investigating winter landslide deformation and instability, confirming IRT’s operational viability in high-altitude alpine regions. Full article

The sustainability, crop production, and food safety of agriculture are increasingly challenged by microplastic pollution, as agricultural soils are the largest reservoirs and may serve as points of contact for plastic particles in the food chain. This review provides a comprehensive overview of plant materials, fate and uptake pathways, detection techniques, and the possible risks of microplastics in agriculture. Agroecosystems are also a source of microplastics, such as plastic mulch films, sewage sludge, compost and manure additives, wastewater irrigation, polymer-coated fertilizers, greenhouse materials, atmospheric deposition, and decomposition of discarded agricultural plastics. Their distribution and mobility in soil are controlled by polymer composition, particle size, morphology, density, surface ageing, soil texture, organic matter content, tillage practices, runoff, leaching, and soil biota. Recent data show that microplastics, especially smaller microplastics and nanoplastics, can attach to root surfaces, penetrate plants via cracks in roots, areas of lateral root development, and apoplastic pathways, and eventually move to tissues aboveground. Plant tissue detection is often accomplished by digestion of the sample, density separation, visual and fluorescence microscopy, Fourier-transform infrared spectroscopy, Raman spectroscopy, pyrolysis–gas chromatography mass spectrometry, and electron microscopy, but standardization of these methods remains a significant challenge. Microplastics can disrupt seed germination, root structure, nutrient absorption, photosynthesis, oxidative homeostasis, biomass buildup, yield development, and quality. Further, their capacity to transport additives, plasticizers, heavy metals, and persistent organic pollutants raises concerns about the transfer of contaminants to edible plant parts and their potential transfer to human diets. Further studies are needed focusing on field-realistic exposure conditions, long-term crop–soil interactions, nanoplastics behaviour, standardised analysis procedures, uptake and translocation pathways, edible crop risk assessments, and sustainable mitigation approaches to reduce microplastics in agroecosystems. Full article

This paper develops foamed mixture lightweight soil (FMLS) using dredged soil for ecological floating landscapes applications, focusing on key performance indices including dry density, compressive strength, splitting tensile strength, water absorption, and fluidity. Orthogonal experiments determined the optimal mix ratio, while CaO expansion agent, MgO expansion agent, polypropylene fiber (PPF), and basalt fiber (BF) were employed to modify material properties. The microstructural mechanisms of FMLS before and after modification were characterized by scanning electron microscopy (SEM). The results show that FMLS achieves optimal comprehensive performance at a cement-to-sand ratio of 0.4, foam content of 10%, and water-to-sand ratio of 0.35, with all parameters conforming to technical specifications. The optimal dosage for both CaO and MgO expansion agents is 5%, PPF is 0.3% and BF is 0.5%, respectively. MgO expansion agent and PPF demonstrate superior suitability for floating landscapes due to enhanced pore-filling efficiency and crack-bridging effects by SEM. Finally, correlation analysis further indicates that the water–binder ratio critically governs the strength characteristics of FMLS. This paper not only provides a new direction to promote the effective use of dredged soil resources, but also provides new ideas for carrier materials for ecological floating landscapes. Full article

With the rapid expansion of urban underground space in China, anti-floating has become a critical challenge, and uplift piles are a key solution. Previous studies on composite anchor-cable uplift piles have primarily focused on small-diameter single-pipe types (≤600 mm), often simplifying the pile as an integral component, leaving the multi-interface stress transfer mechanisms of large-diameter piles inadequately understood. This study proposes a back-analysis method based on orthogonal experiments, implemented using Abaqus 3D finite element software, to determine interfacial mechanical parameters for three critical contact pairs (strand-grout, grout-steel pipe, steel pipe-concrete) in large-diameter multi-pipe composite anchor-cable uplift piles. These parameters are then implemented in a refined 3D finite element model to simulate the load-deformation behavior of such piles. Quantitative results show that the back-calculated parameters are highly reliable, with maximum simulation errors for pile head displacement limited to 13.0% and 9.6% for fully bonded and semi-bonded piles, respectively. Unlike conventional piles, stress and strain in this new pile type transfer progressively from the inner steel strands outward and from the top downward, resulting in reduced pile-soil displacement mismatch, fuller mobilization of side interfacial strength, and effective mitigation of concrete cracking. This study provides a systematic parameter-calibration framework and numerical platform, offering theoretical and technical support for optimized design and engineering application of large-diameter composite uplift piles. Full article

Expansive soils undergo structural changes in response to moisture fluctuations, often governed by suction hysteresis. This study investigates the microstructural evolution of three expansive soils using Environmental Scanning Electron Microscopy (ESEM) under controlled drying and wetting cycles across a broad suction range. Soils were prepared with varying compaction states, equilibration times, and physicochemical properties—including specific surface area (SA) and cation exchange capacity (CEC). Images captured at multiple magnifications revealed key trends in water film behavior, cracking, and fabric rearrangement. Image-derived pore-area ratios were used as comparative indicators of microstructural deformation during drying and wetting. High-activity clays (as defined by SA and CEC) displayed pronounced hysteresis and cracking, while low-activity soils exhibited minimal structural change. These findings highlight the role of microscale behavior in expansive soil performance and provide a foundation for improved predictive modeling. In addition, the study provides a framework for future quantitative microstructural characterization using fractal descriptors, enabling future analyses to capture pore complexity and scale-dependent fabric evolution during suction hysteresis. Full article

Argillaceous siltstone is widely distributed along expressways in southern China; however, its strong water sensitivity and slaking properties severely restrict its utilization as subgrade fill, particularly under wet–dry cyclic conditions where bearing capacity deteriorates sharply. Existing studies have predominantly focused on mechanical performance evaluation of stabilizers, while systematic comparisons of lime and cement improvement effects and durability evolution under wet–dry cycles remain insufficiently understood. Drawing on the Yongjin Expressway reconstruction and expansion project, this study systematically investigates the durability of lime- and cement-improved argillaceous siltstone fill. Through unconfined compressive strength (UCS) tests, California bearing ratio (CBR) tests, and five wetting–drying cycles, the evolution differences in strength development, water stability, and durability between the two improvement schemes are revealed. Results indicate that, under identical stabilizer contents (3–7%) and curing conditions, the UCS and CBR of cement-improved soil are significantly higher than those of lime-improved soil. At the same dosage, the strength of cement-improved soil is approximately 1.5–1.7 times that of lime-improved soil, and the absolute strength gap further widens with increasing dosage. Both stabilizers effectively inhibit water immersion swelling, but the swelling rate of lime-improved soil is about 1.3–1.5 times that of cement-improved soil at the same dosage. At 7% dosage, the swelling rates of cement- and lime-improved soils decrease to 0.40% and 0.60%, respectively, both meeting subgrade fill swelling control requirements. After five wet–dry cycles, the UCS retention rate of 7% cement-improved soil is 78.3%, while that of lime-improved soil is 69.0%; the residual strengths are 507.0 kPa and 303.6 kPa, respectively, both satisfying general subgrade engineering strength requirements. However, the 3% lime-improved soil declines to 47.5 kPa after cycling, falling below the engineering threshold. Integrating strength, deformation, and durability indices, high-grade highway roadbeds and other high-load-bearing sections should prioritize 7% cement improvement, whereas general subgrade sections and locations emphasizing crack resistance may adopt 7% lime improvement as an alternative. Low-dosage (<5%) lime improvement is not recommended for argillaceous siltstone subgrade engineering. The findings provide a scientific basis for the engineering application of argillaceous siltstone as subgrade fill and for optimization of improvement schemes. Full article

Soil degradation is caused by frequent extreme weather events. The acceleration of soil degradation is due to the development of soil fissures, which form additional channels for water evaporation. This article investigates the effects of different concentrations of xanthan gum on soil water retention and crack resistance. The results indicate that xanthan gum slows down soil cracking and effectively enhances soil crack resistance. This article defines the first batch of cracks that appear at the beginning of crack formation as “trunks”, cracks branching from the trunks as “branches”, and cracks splitting from the branches as “twigs”. As the content of xanthan gum increases, the trunks decrease and gradually turn into branches and twigs. Compared with soil with a xanthan gum content of 0.2%, the fractal dimension and fracture rate of soil samples decreased by 8.62%, 26.83%, and 35.45% and 2.75%, 13.74%, and 20.88%, respectively, when the xanthan content was 0.4%, 0.6%, and 0.8%. The final residual water content of the soil increased by 30%, 142%, and 192.5%, respectively. Compared with soil with a xanthan gum content of 0.8%, soil with a xanthan gum concentration of 0.2% showed a 150% increase in deceleration phase time. Xanthan gum affects the evaporation process and fracture behavior by altering the pore volume of the soil and generating biological aggregates. This study provides new ideas for the use of xanthan gum in solving soil cracking caused by dryness and water-retention problems. Full article

Microbial-induced calcite precipitation (MICP) and enzyme-induced calcite precipitation (EICP) have emerged as research hotspots in recent years at the intersection of geotechnical engineering, environmental engineering, and materials engineering. Compared with traditional grouting reinforcement and repair methods, these methods exhibit greater environmental benignity, higher calcium carbonate precipitation yield, and more significant improvement in mechanical properties of repaired materials. The urease activity in the urease-based MICP and EICP techniques lies at the core of rock fracture repair, soil reinforcement, and concrete crack remediation. This paper presents a systematic review of urease-based MICP and EICP repair technologies, focusing on repair principles, environmental influencing factors, research methods, and application approaches, including microbial cultivation, enzyme activity determination, preparation of cementing solutions, selection of carriers, injection methods, and repair cycles. It also compares the advantages and disadvantages of MICP and EICP. This review clarifies the intrinsic similarities and differences between the two technologies in mineralization mechanism, crystal characteristics and engineering applicability, and constructs a complete technical system of urease-based biomineralization. Additionally, this paper discusses current macroscopic and microscopic evaluation methods for biomineralization repair effects, synthesizes existing mineralization repair systems, and assesses the challenges of self-healing biomaterials, including long-term microbial durability, repair strength stability, and the overall cost of widespread application. It includes long-term microbial durability, repair strength stability, enzyme activity retention, and the overall cost of widespread application, which are key issues to be solved for engineering implementation. The aim of this study is to provide a theoretical and practical reference for the theoretical improvement and engineering application of EICP and MICP technologies. Full article

Additive manufacturing with soil–cement mixtures is emerging as a disruptive approach to advancing sustainable manufacturing processes. However, its industrial scalability remains limited by material brittleness and a lack of process standardization. This study presents an integrative literature review that critically evaluates the influence of fiber reinforcement on the 3D printing process and the mechanical performance of soil–cement mixtures within the context of sustainable construction and circular economy principles. The analysis integrates fresh-state rheological behavior with hardened-state performance, showing that an optimized fiber dosage (0.3–0.5% by volume) shifts the failure mode from brittle to quasi-ductile while reducing crack propagation by approximately 60%. Additionally, the study compares various fiber types, including synthetic and natural alternatives. The results show that synthetic fibers used at low dosages (0.5–1.0% by volume) provide the greatest improvements in tensile strength and post-cracking ductility. In contrast, natural fibers, typically used at higher dosages (8.0–13.0% by volume), mainly improve toughness and thermal performance, with more limited gains in strength. The review also identifies key gaps in the existing literature, such as a lack of standardized protocols for measuring process parameters and the need for studies that address long-term durability and comprehensive lifecycle assessments. These findings outline a clear research roadmap to support the consolidation of reinforced soil–cement as a resilient and sustainable material for next-generation additive manufacturing. Full article

The Vertical Shaft Machine (VSM) method is increasingly used in ultra-deep prefabricated shafts. However, as its application extends into hard ground, existing segment designs still largely follow soft soil experiences, resulting in insufficient material utilization and poor economic efficiency. Based on the first VSM shaft in South China, this study establishes a refined finite element model validated by field monitoring and subsequently constructs a structural response database. A GA-XGBoost surrogate model combined with the SHAP method quantifies the contributions of key parameters—concrete strength, rebar diameter, and steel plate thickness—to shaft structural stress. Following the optimization objective of reducing material consumption while maintaining the overall structural performance of the original design, an optimization scheme for Ring 0 reinforcement is proposed. Results show that SHAP analysis effectively identifies the contribution ranking of each parameter to the structural response: for Ring 0, concrete strength contributes the most while rebar diameter shows low sensitivity; for the cutting edge ring, steel plate thickness and concrete strength contribute significantly, whereas tie bars show the lowest sensitivity. After optimization of Ring 0, reinforcement consumption per linear meter of segment is reduced by 43.43 kg, and steel content decreases by 57.91 kg/m³. Verification confirms that the stress distribution remains largely unchanged and crack width meets specification limits. Tie bars in the cutting edge ring play an irreplaceable structural role during concrete pouring and should not be directly optimized. The proposed scheme reduces material consumption while ensuring structural safety, offering a reference for optimizing VSM shaft segment structures in hard ground conditions. Full article

To investigate the failure characteristics of 3D-printed concrete utility tunnels under loading, a 1:25 scaled model was designed using similarity theory. Vertical loading tests were conducted under soil lateral confinement, and the load–displacement curves, discrete-point strain responses, and crack evolution process were obtained. The test results show that the structure successfully undergoes an elastic stage, a crack development stage, and a plastic failure stage. The incorporated polypropylene fibers exert a bridging effect, enabling the component to retain a certain load-bearing capacity after cracking. Crack distribution was highly heterogeneous: cracks were densest on the top slab, widest on the side walls, and multi-directional on the inner wall. A clear correspondence exists between strain response and crack distribution, with tensile strain zones highly coinciding with crack opening zones. The failure mode generally agrees with the “top slab compression–side wall tensile cracking” characteristic of traditional closed-frame structures. However, the wall thickness deviations induced by the 3D printing process are amplified during internal force redistribution in the statically indeterminate structure, resulting in markedly asymmetric failure of the left and right side walls. Full article

Dredging projects associated with China’s expanding maritime transportation and waterway regulation produce substantial volumes of dredged soil each year. This dredged soil, characterized by poor engineering properties, cannot be directly used for filling projects and requires improvement. On the other hand, the use of solid waste curing agents to replace traditional curing agents for semi-curing improved dredged soil can achieve the goal of treating waste with waste. This study employs a CGF curing agent composed of calcium carbide slag, blast furnace slag, and fly ash for the semi-curing improvement of dredged soil. The impact of the curing agent content on the compaction properties of semi-cured improved dredged soil is investigated. Additionally, through freeze–thaw cycle tests and microscopic experiments, the influence of the number of freeze–thaw cycles on the strength of semi-cured improved dredged soil and its microscopic mechanism are examined. The results indicate that as the curing agent content increases, the maximum dry density of the CGF semi-cured improved dredged soil decreases, while the optimal moisture content increases. Under freeze–thaw cycles, both the mass and unconfined compressive strength of the CGF semi-cured improved dredged soil decrease with an increasing number of cycles. Microscopic test results show that alkali-activated products (C-S-H, C-A-S-H, C-A-H) cement soil particles, fill soil pores, and enhance the internal stability of the soil. However, as freeze–thaw cycles progress, the structure of the CGF semi-cured improved dredged soil is gradually damaged. The enlargement of pores and the formation of penetrating cracks and voids lead to a reduction in strength. Increasing the curing agent content can effectively improve the frost resistance of the CGF semi-cured improved dredged soil. Full article