Search Results (827)

Although non-structural walls do not determine the structural safety of a building, they are responsible for its functionality by serving as acoustic, thermal, and fire-resistant partitions. They may be freely located and relocated and are typically constructed during the finishing stage of building works. Reliable performance of non-structural walls depends on appropriate connections to floors and adjacent walls. Connections to walls are most commonly achieved using traditional masonry bonding or sufficiently durable wall connectors, usually made of steel. An alternative to steel connectors may be connectors made of polymer-based materials or meshes. This paper proposes an innovative method for connecting non-structural masonry walls using a spatially arranged mesh, which serves not only as reinforcement of the wall connection but also as reinforcement of the bed joints. The aim of the study was to evaluate the effectiveness of this method in comparison with other connection techniques, including traditional solutions. Experimental investigations were carried out using an original test setup on 12 specimens made of AAC masonry units, divided into three series: series P—traditional connection (reference series), series H—connection with mesh placed in bed joints, and series SHP—connection with spatially arranged mesh. Silica Glass Mesh (SGM), intended for reinforcement of bed joints in AAC masonry, was used in the study. The experiments focused on the analysis of connection behavior and load-bearing capacity, with particular emphasis on maximum load values and failure mechanisms. Individual stages of the behavior of mesh-reinforced connections were identified, and empirical relationships enabling estimation of maximum loads were developed. The results confirmed that the traditional connection achieved the highest load-bearing capacity. However, as expected, the mesh-reinforced connections—particularly those with the spatial mesh arrangement—exhibited a more stable response and a greater ability for progressive load transfer. The SHP series connections with spatially arranged meshes exhibited significantly lower load-bearing capacity compared to the reference unreinforced connections, while at the same time demonstrating substantially greater deformability. The stiffness degradation in the mesh-reinforced connections did not occur abruptly, as observed in the reference models, which makes them an effective alternative for practical applications. Technical models for predicting forces and displacements of connections reinforced with spatially arranged meshes and meshes placed in bed joints were also developed. Full article

Polymer/Silica aerogel (SA) composites improve mechanical properties strategically, but the mixing process disrupts the aerogel’s structure, reducing its efficiency due to polymer chains filling the pores. Pre-vulcanized natural rubber latex (PVNRL) with a higher crosslink density can strain the moving chains, thereby preserving the SA-porous structure in the bulk composite for thermal insulation materials. This study aimed to investigate the effects of PVNRL pre-vulcanization time and SA-immersion time in PVNRL. For PVNRL/SA composite preparation, various PVNRL, from 0 days to 8 days of pre-vulcanization time, were mixed with a fixed SA content of 20 parts per hundred of rubber (phr) using a latex compounding method. Subsequently, the PVNRL/SA slurries were cast on glass plates with 0, 3, and 6 days to obtain the PVNRL/SA composite. Considering the effect of pre-vulcanization time, the crosslink density of the composite increased and revealed a peak at PVNRL/SA with 8-day PVNRL by 7.277 ± 0.881 μmol , corresponding to the closest percentage of pore area in the SA’s structure to the pristine SA, and eventually a 42.41% lower thermal conductivity than the PVNRL/SA with 0-day PVNRL exhibited. In addition, the thermal conductivity increased more slowly over immersion time with the presence of 8-day PVNRL. The proposed correlation states that increasing the pre-vulcanization improves the thermal insulation performance of PVNRL/SA composites, emphasizing the reduction of filled SA’s pore with unvulcanized NR chains. Furthermore, the PVNRL/SA composite with 8-day PVNRL maintains thermal stability at 387.3 °C, and can be flexed at room temperature. These fascinating discoveries may be advantageous for further applications related to thin-film and flexible thermal insulation materials. Full article

This study investigates the effects of waste glass (GL) and silica fume (SF) on the physical, mechanical, and microstructural properties of clay-based ceramic materials produced from low-grade calcite-rich clay loam. Waste glass and silica fume were incorporated at 10–20 wt.%, and the specimens were fired at temperatures ranging from 1050 to 1150 °C. The average density, water absorption, compressive strength, phase composition (XRD), and microstructure (SEM) were evaluated. The results showed that waste glass significantly enhanced the sintering behavior of the ceramic body through liquid-phase formation at elevated temperatures. The average density increased from approximately 1650 to 2200 kg/m³, while water absorption decreased from 6.5% to 3.2%. The optimum firing temperature was 1125 °C, at which the ceramic compositions containing 10 wt.% and 15 wt.% waste glass exhibited no visible deformation and achieved compressive strengths of 32–36 MPa. In contrast, silica fume was less effective as a fluxing additive, resulting in lower strength, increased deformation, and cracking at temperatures above 1100 °C. SEM observations confirmed the formation of a denser, more homogeneous microstructure in the waste glass-modified specimens, while XRD analysis revealed a reduction in quartz content, accompanied by enhanced formation of the diopside and anorthite phases. Among all investigated compositions, the ceramic material containing 10 wt.% waste glass and fired at 1125 °C exhibited the most balanced combination of density, water absorption, and compressive strength, demonstrating its potential for producing high-performance clay-based ceramic materials. Full article

Nanotechnology has emerged as a promising strategy in restorative dentistry and endodontics due to the physicochemical and biological properties of nanomaterials. This narrative review aimed to critically analyze the current applications of nanomaterials in restorative dentistry and endodontics, highlighting their mechanisms of action, biological properties, and translational potential. A literature search was performed in the PubMed/MEDLINE database using combinations of MeSH terms and free keywords related to nanomaterials and dental applications. Studies published in English within the last twenty years and addressing restorative or endodontic applications were considered. After screening and eligibility assessment, 69 studies were included in the descriptive analysis. The findings indicate that nanomaterials have been investigated in preventive strategies, adhesive systems, restorative materials, intracanal medicaments, endodontic sealers, vital pulp therapy, and regenerative formulations. In restorative dentistry, nanoparticles such as silver nanoparticles, nano-hydroxyapatite, amorphous calcium phosphate, bioactive glass nanoparticles, and chitosan-based systems showed favorable antimicrobial, remineralizing, and material-enhancing properties. In endodontics, silver and chitosan nanoparticles showed potential for intracanal disinfection and biofilm disruption, while chlorhexidine, zinc, and bioactive glass nanoparticles enhanced the antimicrobial activity and sealing ability of endodontic sealers. In addition, magnetic nanoparticles, mesoporous silica nanoparticles, and hydroxyapatite nanoparticles presented promising applications in regenerative endodontics and vital pulp therapy. However, most of the available evidence is still based on in vitro studies, with limited long-term clinical validation. Overall, nanotechnology offers potential experimental advantages for improving preventive, restorative, and endodontic therapies; however, its successful clinical translation remains strictly dependent on overcoming critical biosafety barriers and addressing long-term toxicity concerns. Full article

The growing global consumption of concrete is driving up the demand for cement, which has a negative environmental impact due to intensive CO₂ emissions. This impact can be reduced by replacing cement with reactive mineral industrial waste, simultaneously addressing the issue of waste accumulation in landfills. However, to ensure the effective use of such materials, it is essential to comprehensively investigate their influence on concrete durability. This study analyzes glass processing waste (GPW) generated during glass grinding. The waste is removed using water, resulting in the formation of glass processing waste. In the experiment, CEM I 42.5 R cement, GPW, sand, crushed dolomite stone, concrete sludge (CS), chemical admixtures, and water were used. In the tests, cement was replaced with glass processing waste in amounts ranging from 5% to 30%, analyzing a total of seven different compositions. The properties of the sustainable concrete mixture were evaluated, and the mechanical–physical properties of the hardened concrete were determined. Resistance to alkali–silica reaction was tested according to the RILEM AAR-4 methodology, while the environmental impact of glass processing waste was assessed using Life Cycle Assessment (LCA). The results showed that glass processing waste increases the concrete’s resistance to alkali corrosion: as the amount of waste increased, a smaller change in the linear dimensions of the specimens was recorded, and the lowest mass loss was found in the composition where 20% of the cement was replaced by glass processing waste. The environmental impact assessment confirmed a direct correlation—as the amount of glass waste increases, CO₂ emissions decrease proportionally. To produce sustainable concrete, it is recommended to use up to 20% glass processing waste: this allows for the maximum reduction in environmental impact while maintaining mechanical properties and high resistance to alkali–silica reaction. Full article

This paper presents a proof-of-concept investigation into a novel hermetically sealed tunable-medium Extrinsic Fabry–Pérot Interferometer (EFPI) temperature sensor architecture. A series of tuneable-sensitivity EFPI temperature sensors is demonstrated, comprising a large-diameter fused silica diaphragm with a 800 $\mathrm{m}$ diameter, significantly exceeding conventional designs (typically ∼125 $\mathrm{m}$), with polished diaphragm thicknesses ranging from 28 to 49 $\mathrm{m}$, housed in hermetically sealed rigid melting point capillaries with a 1.8 mm internal diameter. By exploiting thermally induced pressure differentials generated by a tunable Krytox GPL 105 oil/air fill fraction within the sealed rigid cavity, the sensors demonstrate a continuously tuneable sensitivity design space spanning 0.45 to 190 $\mathrm{n}\mathrm{m}/\mathrm{K}$. An exact nonlinear thermal pressure model is derived and validated, replacing the linearised approximation which is shown to be inapplicable at fill fractions approaching unity. The low-sensitivity configuration (0.45 $\mathrm{n}\mathrm{m}/\mathrm{K}$) was characterised at the National Standards Authority of Ireland (NSAI) National Metrology Laboratory against ITS-90 fixed points: the Triple Point of Water (273.16 K) and the Gallium Fixed Point (302.9146 K), with traceability to the International Temperature Scale of 1990 (ITS-90), yielding an instrument-limited resolution of $<1.1$ mK, consistent with the metrological validation environment. The high-sensitivity configurations (21 and 190 $\mathrm{n}\mathrm{m}/\mathrm{K}$) were characterised on a laboratory bench, achieving instrument-limited theoretical resolutions of <24 $\mathrm{K}$ and $<2.6$$\mathrm{K}$ respectively, pending future metrological validation. The 190 $\mathrm{n}\mathrm{m}/\mathrm{K}$ sensitivity represents an improvement of approximately 21.7× over the closest directly comparable prior Citationutilised fusion splicing and manual polishing. Future development priorities include metrological validation of the high-sensitivity configurations, long-term stability characterisation, thermal cycling, and progression towards an all-glass hermetically sealed construction. Full article

The growing demand for sustainable construction materials has led to significant advancements in ultra-high-performance concrete (UHPC), with a particular focus on geopolymer-based systems as an alternative to conventional cementitious binders. This review explores the latest developments in sustainable Ultra-High-Performance Geopolymer Concrete (UHPGPC) by analysing key material composition, mechanical, durability and microstructural properties. The incorporation of ground granulated blast furnace slag (GGBFS), silica fume (SF), and fly ash (FA) has demonstrated notable improvements in compressive strength, durability, and workability. Additionally, the use of activators such as sodium silicate and sodium hydroxide optimizes geopolymerization, resulting in a denser microstructure and enhanced mechanical performance. This review highlights the critical role of fibre reinforcement in UHPGPC, where steel fibres (SFs) and hybrid fibres significantly enhance compressive and tensile strength, as well as crack resistance. The inclusion of waste materials such as rice husk ash and recycled glass promotes sustainability by reducing CO₂ emissions while maintaining structural integrity. However, higher waste-glass content may adversely affect bonding due to its smooth surface texture. The findings highlight the potential of UHPGC as a high-performance, eco-friendly alternative to traditional cement-based UHPC. By integrating industrial by-products and alternative activation techniques, UHPGPC can contribute significantly to the global shift towards sustainable and low-carbon construction materials. Full article

The valorization of phosphogypsum (PG), a byproduct of phosphoric acid production, along with waste glass (WG) and silica fume (SF) into value-added materials has attracted growing attention in recent years. The present study aims to synthesize three types of porous geopolymers (GD, GDP, and GDG) using Tunisian clay and locally available mineral wastes, and to investigate their potential as low-cost adsorbents for the removal of methylene blue (MB) dye from aqueous solutions. The physicochemical characteristics of the raw precursors and the resulting porous geopolymers were analyzed using various techniques, including FTIR, XRD, BET, and SEM. Variations in Si/Al, Na/Al, and Ca/Al ratios play a critical role in the geopolymer structure. The high Ca/Al ratio in GDP (porous geopolymer from calcined clay and phosphogypsum) promotes the formation of C-A-S-H, leading to increased macroporosity, which favors adsorption capacity despite the presence of a more heterogeneous morphology. The results indicated that the maximum adsorption capacity (Qmax) for MB dye was obtained for the GDP sample, reaching 68 mg/g. Adsorption experiments revealed the successful removal of MB dye by geopolymers, with the Langmuir isotherm and pseudo-second-order kinetic models adequately describing the adsorption process. The MB uptake by geopolymers was facilitated by weak physicochemical interactions, including electrostatic attraction, hydrogen bonding, and π–π interactions. This study proposes a simple and effective alkali activation strategy that combines different industrial wastes within a single geopolymer system, resulting in improved porosity and adsorption efficiency. Overall, the findings highlight the potential of these waste-derived geopolymers as promising and sustainable adsorbents for wastewater treatment applications. Full article

This paper investigates the viability of utilizing Fused Deposition Modeling (FDM) for the fabrication and follow-up testing of a hemispherical resonator (HR). This form of resonator has several significant applications, including the design of vibratory gyroscopes. While traditional high-precision resonators for this application rely on expensive fused-silica fabrication, this study proposes a macro-scale approach using Polylactic Acid (PLA) to enable accessible lab-scale experimentation. The specimens, featuring a unique central-hole mounting configuration, were designed in SolidWorks and analyzed via finite element methods to establish the modal hierarchy. Experimental Modal Analysis (EMA) was conducted using a Laser Doppler Vibrometer (LDV) to acquire vibration signals, which were then analyzed in NVGate, MATLAB, and MEscope to extract natural frequencies and quality factor. Results for a lab-scale HR specimen identified the n = 2 wine-glass mode with a deviation from theoretical natural frequency predictions largely attributed to inherent defects in the fabrication process. Furthermore, a frequency split of 2.15 Hz was observed due to the inherent asymmetries and mass imbalances of the fabrication method. The quality factor was evaluated via the ring-down method and validated using the half-power bandwidth (HPBW) technique. This work demonstrates that 3D-printed resonators serve as an effective, low-cost platform for isolating modal behaviors and optimizing geometric parameters before advancing to micro-scale fabrication. Full article

Photovoltaic modules require efficient sunlight modulation, including enhanced visible transmittance and conversion of unused ultraviolet light. This study develops a synthetic optical coating that achieves both functions by integrating down-conversion BAM (BaMgAl₁₀O₁₇:Eu²⁺, Mn²⁺) nanophosphors into a silica anti-reflection sol. The key novelty lies in a synergistic surface engineering strategy that decouples dispersion stabilization from luminescence protection. Five dispersants are systematically compared under combined ball and sand milling. The polyester-modified acrylic long-chain dispersant (DK062) yields a stable nanodispersion with an average particle size of 228 nm and a Zeta potential of −7.61 mV, effectively suppressing re-agglomeration while retaining high photoluminescence. Subsequent surface modification with KH570 grafts a dense silane passivation layer via Si–O–M covalent bonds, further increasing the photoluminescence intensity by 1.39-fold. The optimized nanophosphors are incorporated into a commercial anti-reflection sol and dip-coated onto photovoltaic glass. At a doping concentration of 2‰ and a withdrawal speed of 8 mm/s, the resulting DCSAR coating exhibits an average transmittance of 91.16%—slightly higher than that of the pure anti-reflection coating (90.96%)—while showing strong green emission at 515 nm. Industrial on-site testing further demonstrates an average transmittance of 94.20%–94.31% with uniform green emission. This work provides a scalable route to fabricate highly transparent, light-converting anti-reflection coatings by combining dispersant-assisted milling and silane passivation. Full article

To meet the requirements of forest fire prevention, a water glass-based composite gel foam was developed by introducing hydroxypropyl methylcellulose (HPMC) and nanosilica sol into a sodium silicate/sodium bicarbonate matrix. The resulting water glass/HPMC/silica sol ternary system (SGF-HPMC-SOL) was designed to improve water retention, foam stability, substrate adhesion, and fire-barrier durability. The results indicate that HPMC and silica sol contributed to network reinforcement through hydrogen bonding, polymer-chain entanglement, nanoscale filling, and possible interfacial condensation. The optimized SGF-HPMC-SOL retained 20.4% of its initial mass after heating at 100 °C for 5 h, compared with 4.65% for SGF and 9.54% for SGF-HPMC; reached a carbonization time of 164 s under direct-flame exposure, versus 100 s for SGF and 137 s for SGF-HPMC; and maintained a residual mass of 76% at 800 °C in TGA, compared with 58.3% for SGF and 55.1% for SGF-HPMC. These improvements were associated with the formation of a denser silica-rich protective layer after combustion, which delayed heat transfer to the wood substrate. Under the adopted direct-flame screening conditions, SGF-HPMC-SOL exhibited enhanced flame-retardant performance compared with the reference gel foams, indicating its potential for enhanced flame-retardant performance under laboratory screening conditions for forest fire prevention. Full article

This study evaluates the effect of decorative ceramic screen printing on the optical and photovoltaic performance of glass covers intended for building-integrated photovoltaics (BIPV). Nine ceramic-printed glass samples with different colors and optical densities were compared with a 4 mm Optiwhite reference glass and a bare silicon solar cell. The samples were characterized by UV-VIS-NIR spectrophotometry, energy-dispersive X-ray spectroscopy (EDS), and electrical measurements under simulated AM 1.5G irradiation at 1000 W/m². The optical results showed that the Optiwhite reference provided the highest transmittance, whereas the printed samples exhibited lower transmission, typically in the range of 60–80% in the visible region, depending on the coating type. Among the decorative variants, sample 1 showed the highest transparency, while sample 6 exhibited the lowest transmittance. The spectral behavior of the coated glasses indicates that the ceramic layers modify the photon flux reaching the solar cell through wavelength-dependent absorption and scattering effects. The photovoltaic measurements confirmed a clear relationship between decorative coating and electrical performance. Relative to the Optiwhite-covered reference cell, the printed samples showed power losses ranging from approximately 17% to 32%, with sample 1 achieving the highest maximum power among the decorative variants at 1.41 W, and sample 4 the lowest at 1.16 W. The main electrical effect of the ceramic coatings was a reduction in short-circuit current, whereas the open-circuit voltage remained nearly constant across the tested samples. EDS analysis identified the presence of ceramic-layer constituents associated with silica-, zinc-, titanium-, iron-, cobalt-, aluminum-, and fluorine-containing compounds, supporting the interpretation of vitrified decorative coatings formed during high-temperature processing. Overall, the results demonstrate that decorative ceramic printing can provide a practical compromise between architectural appearance and photovoltaic output when the optical density of the coating is appropriately controlled. Full article

To address wellbore instability and the technical challenges associated with high-density water-based drilling fluid loss control in deep shale gas formations of the Sichuan-Chongqing region in China, a novel nano-micro sealant designated CLG-Seal was synthesized via molecular structural optimization. The molecular structure of newly developed CLG-Seal exhibits distinct core–shell structural characteristics. The inorganic nano-silica constitutes the rigid core of CLG-Seal, which guarantees its plugging performance. The hydrophobically associating polymer which is coated on the surface of nano-silica constructs the flexible shell of CLG-Seal, endowing the CLG-Seal with excellent gel-forming capacity, adhesion film-forming capacity, deformability and perfect dispersibility. Transmission electron microscopy and scanning electron microscopy were employed to characterize the morphology of the CLG-Seal nanomicron-scale plugging agent. The sealing performance and underlying mechanisms of CLG-Seal were subsequently evaluated via particle plugging apparatus tests, displacement experiments, and etched glass micromodel simulations. Field trials conducted in the third section of Well WY3-2-3HF validated the application effectiveness of this agent in drilling fluid systems. The results indicate that the nano-micro sealant CLG-Seal exhibits a median particle size of D₅₀ is 146 nm, which can be modulated by adjusting the synthesis conditions. The nano-micro sealant CLG-Seal significantly mitigates fluid loss in low-permeability microfractures and fissures. Notably, a concentration of merely 3% is sufficient to achieve optimal nano-micro plugging performance. The results of the mechanism study indicate that while the CLG-Seal particles are close to each other, the polymer chains with flexible long chain structure which are coated on the surface of nano-silica constructs tend to be intertwined, forming a cross-linked network structure of gel film, thereby increasing the interaction between nano-micron particles and forming an impermeable plugging film. In addition, due to the nanoscale effect, the CLG-Seal has a strong tendency to adsorb onto the surface of shale rock through hydrogen bonding with the shale matrix. The hydrophobically associating polymer with high elastic modulus and excellent mechanical properties can enhance the pressure-bearing capacity of the filter cake through elastic deformation. Therefore, these nano-micron particles can form a strong sealing film on the filter cake and at the micropores of shale rock, thereby creating a dense mud cake on the outside of the shale formation. Field trial results demonstrate that the incorporation of the nano-micro sealant CLG-Seal into the drilling fluid for the third section of Well WY3-2-3HF reduced the PPA fluid loss to 4.6 mL. This value represents a substantial reduction compared to adjacent wells and signifies a remarkable improvement over the drilling fluids previously employed in the Longmaxi Formation of this block. Furthermore, the treated drilling fluid exhibited a superior filtration control pressure capacity of 10.5 MPa. The operation was completed successfully without any lost circulation or wellbore instability, and achieved a drilling footage of 42 h with an average penetration rate of 7.81 m/h. The mud weight was reduced by approximately 0.08–0.10 g/cm³ compared to offset wells. These results confirm the excellent application efficiency of the newly developed CLG-Seal in field operations. Full article

Facing the increasingly severe energy challenges and environmental problems, the development of thermally stable, lightweight, and thermal insulating materials is critical. Herein, we report an organic-inorganic composite strategy combined with a high-temperature carbonization step to fabricate aerogel-containing composites synergistically reinforced with chopped glass fibers and hollow glass microspheres. By systematically varying the ratio of acrylic emulsion to potassium silicate solution, we investigated the effects on the forming behavior, microstructure, hydrophobicity, thermal stability, and thermal insulation performance. Increasing the acrylic emulsion fraction substantially enhanced hydrophobicity, yielding a maximum water contact angle of 129.3°. Concurrently, the apparent density decreased from 0.18 g/cm³ to 0.09 g/cm³ and the thermal conductivity dropped from 57.9 mW/(m·K) to 29.0 mW/(m·K). Mechanical testing revealed that the compressive Young’s modulus decreased with increasing acrylic content, from 3.6 MPa for the purely inorganic sample to 0.55 MPa at 70% acrylic content, reflecting a trade-off between stiffness and organic-derived porosity. Microstructural characterization revealed a hierarchical porous network in which uniformly dispersed hollow glass microspheres and the aerogel-derived silica network form an efficient thermal barrier system. Thermogravimetric analysis demonstrated excellent thermal stability, with total weight loss below 5% up to 800 °C. Infrared thermography analysis showed that, after unilateral heating at 300 °C and 400 °C for 10 min, the backside surface temperature of the composites decreased as the acrylic emulsion content increased. At 300 °C, the temperature decreased from 176.1 °C for AP-1 to 151.0 °C for AP-4, while at 400 °C, it decreased from 228.5 °C to 199.3 °C. These results indicate that the composites exhibit effective thermal insulation and maintain structural stability under high-temperature exposure. Taken together, this facile and scalable approach yields these aerogel-containing composites that combine low density, low thermal conductivity, robust structural integrity, and good environmental resistance, as evidenced by a water contact angle of 129.3°, making them promising candidates for aerospace, building, and industrial high-temperature insulation applications. Full article

With the rapid expansion of wind energy infrastructure, there is an increasing accumulation of wind turbine blade waste (WTBW), which is mainly composed of glass fiber-reinforced thermosetting composites. Due to the irreversible nature of polymer crosslinking, conventional recycling methods remain limited. In this study, plasma vitrification was employed to convert WTBW into a reactive calcium-aluminum-silicate slag suitable for use in geopolymer materials. Plasma treatment at a temperature of approximately 2750 K resulted in the formation of predominantly amorphous vitrified slag (VS). Structural characterization using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy with energy-dispersive X-ray spectroscopy (SEM-EDS) revealed the spatial heterogeneity of the VS. This heterogeneity was influenced by thermal gradients and varied between samples collected from different slag discharge zones, both vertically and horizontally from the reactor. All VS samples contained between 30 and 89% amorphous phase and 10–55% anorthite, with the proportions varying by sampling location. Chemical stability tests showed the dissolution of calcium and aluminum in acidic media, resulting in a silica-enriched residual structure in which the Ca and Al content decreased to less than 0.5 at.% after 100 days. In contrast, exposure to alkaline media caused only minimal surface reorganization—the addition of 5 wt.% VS to acid-based geopolymers made with two metakaolin precursors resulted in a 35% decrease in the mechanical strength of pure metakaolin-based systems. In contrast, when metakaolin containing illite impurities was used, strength values were similar to those of the reference geopolymer. The results quantitatively demonstrate that plasma-derived slag exhibits composition-dependent reactivity, directly linked to its amorphous content and dissolution behavior. Full article