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33 pages, 44898 KiB  
Article
The Supra-Salt Sedimentary Sequence of the North Caspian Depression: Stratigraphy and Sedimentary History
by Aitbek Akhmetzhanov, Saule Uvakova, Kenzhebek Ibrashev, Gauhar Akhmetzhanova and Vyacheslav Zhemchuzhnikov
Geosciences 2025, 15(4), 143; https://doi.org/10.3390/geosciences15040143 - 9 Apr 2025
Viewed by 611
Abstract
The North Caspian Basin, known for its oil and gas potential, was formed because of the evolution of the ancient Tethys Ocean and is also a result of the collision of the East European, Kazakhstania, and Siberian paleocontinents. At the beginning of the [...] Read more.
The North Caspian Basin, known for its oil and gas potential, was formed because of the evolution of the ancient Tethys Ocean and is also a result of the collision of the East European, Kazakhstania, and Siberian paleocontinents. At the beginning of the Mesozoic Era, it was a part of the northern continental margin of the Neo-Tethys, which formed Eurasia. In the Late Triassic and Early Jurassic, a major restructuring of the North Caspian sedimentary basin occurred, characterized by angular unconformity and the erosion of underlying sediments in the coastal zones of the basin. The sedimentary succession of the depression accumulating in the Mesozoic Era consisted of alternating siliciclastic and carbonate rocks. It began to form due to the destruction of the uplifts formed north and west of the East European craton and Urals, which resulted in coastal clastic material in the Triassic and Jurassic, but by the end of the Jurassic and Cretaceous, when all uplifts existing in the north of Tethys were leveled, it was mostly marine environments that contributed to the accumulation of siliciclastic and carbonate strata. The appearance of a large amount of sedimentary material towards the center of the depression, causing stress, as well as the deflection of the basement, contributed to fault tectonics and the resumption and manifestation of salt tectonics. As a result of the continuous diapirism of salt bodies during the Late Mesozoic, mini basins were formed, in which different sedimentogenesis was manifested. These processes contributed to the redistribution of hydrocarbons from the underlying pre-salt formations to the intermediate depth interval post-salt succession with Permian–Triassic and also near-surface Jurassic–Cretaceous formations. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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26 pages, 8635 KiB  
Review
The Mundeck Salt Unit: A Review of Aptian Depositional Context and Hydrocarbon Potential in the Kribi-Campo Sub-Basin (South Cameroon Atlantic Basin)
by Mike-Franck Mienlam Essi, Eun Young Lee, Mbida Yem, Jean Marcel Abate Essi and Joseph Quentin Yene Atangana
Geosciences 2024, 14(10), 267; https://doi.org/10.3390/geosciences14100267 - 11 Oct 2024
Viewed by 1325
Abstract
The Kribi-Campo sub-basin, located in the Gulf of Guinea, constitutes the southeastern segment of the Cameroon Atlantic Margin. Drilling in the Aptian salt unit revealed a sparse hydrocarbon presence, contrasting with modest finds in its counterparts like the Ezanga Salt in Gabon and [...] Read more.
The Kribi-Campo sub-basin, located in the Gulf of Guinea, constitutes the southeastern segment of the Cameroon Atlantic Margin. Drilling in the Aptian salt unit revealed a sparse hydrocarbon presence, contrasting with modest finds in its counterparts like the Ezanga Salt in Gabon and the Rio Muni Salt in Equatorial Guinea. This discrepancy prompted a reassessment of the depositional context and hydrocarbon potential of the Mundeck salt unit. By integrating 2D seismic reflection and borehole data analysis, this study established the structural and stratigraphic framework of the area, emphasizing the salt unit’s significance. Borehole data indicate a localized salt unit offshore Kribi, with seismic reflection data revealing distinct forms of diapir and pillow. This salt unit displays a substantial lateral extent with thicknesses ranging from 4000 m to 6000 m. The depositional context is linked to the following two major geological events: a significant sea-level drop due to margin uplift during the Aptian and thermodynamic processes driven by transfer faults related to mid-oceanic ridge formation. These events were crucial in forming and evolving the Mundeck Salt. Regarding hydrocarbon prospects, this study identifies the unit as being associated with potential petroleum plays, supported by direct hydrocarbon indicators and fault-related structures. The findings suggest that untapped hydrocarbon resources may still exist, underscoring the need for further exploration and analysis. Full article
(This article belongs to the Section Sedimentology, Stratigraphy and Palaeontology)
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29 pages, 19368 KiB  
Article
Mechanical Properties of Rock Salt from the Kłodawa Salt Dome—A Statistical Analysis of Geomechanical Data
by Malwina Kolano, Marek Cała and Agnieszka Stopkowicz
Materials 2024, 17(14), 3564; https://doi.org/10.3390/ma17143564 - 18 Jul 2024
Cited by 2 | Viewed by 1866
Abstract
Rock salt is a potential medium for underground storage of energy resources and radioactive substances due to its physical and mechanical properties, distinguishing it from other rock media. Designing storage facilities that ensure stability, tightness, and safety requires understanding the geomechanical properties of [...] Read more.
Rock salt is a potential medium for underground storage of energy resources and radioactive substances due to its physical and mechanical properties, distinguishing it from other rock media. Designing storage facilities that ensure stability, tightness, and safety requires understanding the geomechanical properties of rock salt. Despite numerous research efforts on the behaviour of rock salt mass, many cases still show unfavourable phenomena occurring within it. Therefore, the formulation of strength criteria in a three-dimensional stress state and the prediction of deformation processes significantly impact the functionality of storage in salt caverns. This article presents rock salt’s mechanical properties from the Kłodawa salt dome and a statistical analysis of the determined geomechanical data. The analysis is divided into individual mining fields (Fields 1–6). The analysis of numerical parameter values obtained in uniaxial compression tests for rock salt from mining Fields 1–6 indicates an average variation in their strength and deformation properties. Upon comparing the results of Young’s modulus (E) with uniaxial compressive strength (UCS), its value was observed with a decrease in uniaxial compressive strength (E = 4.19968·UCS2, R-square = −0.61). The tensile strength of rock salt from mining Fields 1–6 also exhibits moderate variability. An increasing trend in tensile strength was observed with increased bulk density (σt = 0.0027697·ρ − 4.5892, r = 0.60). However, the results of triaxial tests indicated that within the entire range of normal stresses, the process of increasing maximum shear stresses occurs linearly ((σ1 − σ3)/2 = ((σ1 + σ3)/2)·0.610676 + 2.28335, r = 0.92). A linear relationship was also obtained for failure stresses as a function of radial stresses (σ1 = σ3·2.51861 + 32.9488, r = 0.73). Based on the results, the most homogeneous rock salt was from Field 2 and Field 6, while the most variable rock salt was from Field 3. Full article
(This article belongs to the Section Mechanics of Materials)
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24 pages, 5195 KiB  
Review
A Challenged Evaporite Paradigm?
by Hans Konrad Johnsen, Martin Torvald Hovland and Hakon Rueslatten
Minerals 2024, 14(5), 527; https://doi.org/10.3390/min14050527 - 20 May 2024
Viewed by 1689
Abstract
The general subject of this article deals with the term salt. Salt deposits usually contain chlorides, sulphates/gypsum, borates, carbonates, etc., that are seemingly part of the same system. Even though this article mainly presents data and observations on chlorides, which are not easily [...] Read more.
The general subject of this article deals with the term salt. Salt deposits usually contain chlorides, sulphates/gypsum, borates, carbonates, etc., that are seemingly part of the same system. Even though this article mainly presents data and observations on chlorides, which are not easily explained by the present paradigm, it should also prove relevant for the formation of sulphates and other types of salts observed in major salt deposits. The paradigm explaining large salt deposits rests on two pillars governing salt formation and salt deformation. Salt formation is thought to occur vis solar evaporation of seawater in restricted basins. Salt deformation and forming of salt diapirs is thought to occur due to gravity-induced movements. Our review presents peer-reviewed and published data and observations from different authors within different disciplines that challenge the present evaporite paradigm. The current theory/paradigm rests on numerous observations and interpretations in support of it. Adding more observational interpretations in support of the paradigm will not nullify even one observation that contradicts or remains unexplained by the theory. The contradicting evidence must be explained within the present paradigm for it to survive. Significant observations of and within salt deposits are presented, as well as visual and geophysical observations of salinity in crusts and mantles in relevant tectonic settings. In our view, the omnipresent salinity observed in the subsurface needs to be understood and included in the description of a new salt formation mechanism in order to fully explain all features presented herein. Full article
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15 pages, 48647 KiB  
Article
Three-Dimensional Amplitude versus Offset Analysis for Gas Hydrate Identification at Woolsey Mound: Gulf of Mexico
by Saiful Alam, Camelia Knapp and James Knapp
GeoHazards 2024, 5(1), 271-285; https://doi.org/10.3390/geohazards5010014 - 8 Mar 2024
Cited by 4 | Viewed by 2156
Abstract
The Gulf of Mexico Hydrates Research Consortium selected the Mississippi Canyon Lease Block 118 (MC118) as a multi-sensor, multi-discipline seafloor observatory for gas hydrate research with geochemical, geophysical, and biological methods. Woolsey Mound is a one-kilometer diameter hydrate complex where gas hydrates outcrop [...] Read more.
The Gulf of Mexico Hydrates Research Consortium selected the Mississippi Canyon Lease Block 118 (MC118) as a multi-sensor, multi-discipline seafloor observatory for gas hydrate research with geochemical, geophysical, and biological methods. Woolsey Mound is a one-kilometer diameter hydrate complex where gas hydrates outcrop at the sea floor. The hydrate mound is connected to an underlying salt diapir through a network of shallow crestal faults. This research aims to identify the base of the hydrate stability zone without regionally extensive bottom simulating reflectors (BSRs). This study analyzes two collocated 3D seismic datasets collected four years apart. To identify the base of the hydrate stability zone in the absence of BSRs, shallow discontinuous bright spots were targeted. These bright spots may mark the base of the hydrate stability field in the study area. These bright spots are hypothesized to produce an amplitude versus offset (AVO) response due to the trapping of free gas beneath the gas hydrate. AVO analyses were conducted on pre-stacked 3D volume and decreasing amplitude values with an increasing offset, i.e., Class 4 AVO anomalies were observed. A comparison of a time-lapse analysis and the AVO analysis was conducted to investigate the changes in the strength of the AVO curve over time. The changes in the strength are correlated with the decrease in hydrate concentrations over time. Full article
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25 pages, 33945 KiB  
Article
A Multidisciplinary Investigation of an Abandoned Old Mining Area Which Has Been Affected by the Combined Influences of Salt Karst and Human Exploration Activity
by Zbigniew Szczerbowski and Rafał Gawałkiewicz
Appl. Sci. 2023, 13(22), 12196; https://doi.org/10.3390/app132212196 - 10 Nov 2023
Viewed by 1140
Abstract
The authors discuss a case that is full of examples of the problems faced by civil engineers whose task is to develop areas in the face of natural, technological, or post-mining hazards. The study area is in the central part of Inowrocław, a [...] Read more.
The authors discuss a case that is full of examples of the problems faced by civil engineers whose task is to develop areas in the face of natural, technological, or post-mining hazards. The study area is in the central part of Inowrocław, a town located on a massive salt dome of Zechstein salts. A strong deformation zone expanded in its upper part; this was caused by a natural process (related to so-called salt karst) and by mining activities that occurred in the past, creating a problem with regard to any potential spatial development in the town. The authors show a combination of data obtained using gravimetric and geodetic methods, which helps us to assess the geohazard risk. These include remote sensing data, which can be used to evaluate displacements of the ground surface. The authors used an approach that they term the Elevation Difference Method. This consists of determining displacements between ground surfaces: estimated on the basis of remote sensing data and on the basis of the historical data, when mounted measurement points (and remote sensing data) did not exist. The authors discuss the results in the light of the geological background. Within the area of the study, the displacements of the positive values dominate. The displacement occurs at 6 mm/yr on average and indicates diapiric uplift movement. The results are important for the town authorities for planning and development and for infrastructure management. Full article
(This article belongs to the Special Issue Recent Advances in Exploration Geophysics)
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23 pages, 11610 KiB  
Article
Static Reservoir Simulations and Seismic Attributes Application to Image the Miocene Deep-Water Reservoirs in Southeast Asia
by Muhammad Tayyab Naseer, Raja Hammad Khalid, Shazia Naseem, Wei Li, George Kontakiotis, Ahmed E. Radwan, Hammad Tariq Janjuhah and Assimina Antonarakou
Water 2023, 15(14), 2543; https://doi.org/10.3390/w15142543 - 11 Jul 2023
Cited by 6 | Viewed by 2288
Abstract
Globally, deep-water reservoir systems are comprised of a variety of traps. Lateral and downdip trapping features include sand pinch-outs, truncation against salt or shale diapirs, and monoclinal dip or faulting with any combination of trapping designs; the potential for massive hydrocarbon accumulations exists, [...] Read more.
Globally, deep-water reservoir systems are comprised of a variety of traps. Lateral and downdip trapping features include sand pinch-outs, truncation against salt or shale diapirs, and monoclinal dip or faulting with any combination of trapping designs; the potential for massive hydrocarbon accumulations exists, representing significant exploration prospects across the planet. However, deep-water turbidites and submarine fans are two different types of traps, which are developed along the upslope and the basin floor fans. Among these two traps, the basin floor fans are the most prolific traps as they are not influenced by sea-level rise, which distorts the seismic signals, and hence provides ambiguous seismic signatures to predict them as hydrocarbon-bearing zones for future explorations. Therefore, the deep-water channel-levee sand systems and basin floor fans sandstone define economically viable stratigraphic plays. The subsurface variability is significant, and hence, characterizing the thick (porous) channelized-basin floor fans reservoir is a challenge for the exploitation of hydrocarbons. This study aims to develop seismic-based attributes and wedge modeling tools to accurately resolve and characterize the porous and gas-bearing reservoirs using high-resolution seismic-based profiles, in SW Pakistan. The reflection strength slices better delineate the geomorphology of sand-filled channelized-basin floor fans as compared to the instant frequency magnitudes. This stratigraphic prospect has an area of 1180 km2. The sweetness magnitudes predict the thickness of channelized-basin floor fans as 33 m, faults, and porous lithofacies that complete a vital petroleum system. The wedge modeling also acts as a direct hydrocarbon indicator (DHI) and, hence, should be incorporated into conventional stratigraphic exploration schemes for de-risking stratigraphic prospects. The wedge model resolves a 26-m thick hydrocarbon-bearing channelized-basin floor fans lens with a lateral distribution of ~64 km. Therefore, this wedge model provides ~75% correlation of the thickness of the LSL as measured by sweetness magnitudes. The thickness of shale that serves as the top seal is 930 m, the lateral mud-filled canyons are 1190 m, and the thick bottom seal is ~10 m, which provides evidence for the presence of a vibrant petroleum play. Hence, their reveals bright opportunities to exploit the economically vibrant stratigraphic scheme inside the OIB and other similar global depositional systems. Full article
(This article belongs to the Special Issue Coastal and Continental Shelf Dynamics in a Changing Climate II)
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26 pages, 26287 KiB  
Article
Implications of Salt Diapirism in Syn-Depositional Architecture of a Carbonate Margin-to-Edge Transition: An Example from Plataria Syncline, Ionian Zone, NW Greece
by Ioannis Vakalas, Sotirios Kokkalas, Panagiotis Konstantopoulos, Constantinos Tzimeas, Isidoros Kampolis, Helen Tsiglifi, Ruben Pérez-Martin, Pablo Hernandez-Jiménez and Juan Pablo Pita-Gutierrez
Appl. Sci. 2023, 13(12), 7043; https://doi.org/10.3390/app13127043 - 12 Jun 2023
Cited by 5 | Viewed by 2384
Abstract
The present study examines the imprint of salt tectonics on carbonate depositional patterns of the Ionian zone platform edge to slope transition. The study area is part of an overturned rim syncline adjacent to a salt diapir. The Ionian zone is made up [...] Read more.
The present study examines the imprint of salt tectonics on carbonate depositional patterns of the Ionian zone platform edge to slope transition. The study area is part of an overturned rim syncline adjacent to a salt diapir. The Ionian zone is made up of three distinct stratigraphic sequences (pre-, syn- and post-rift sequences) represented by evaporites and shallow water carbonates at the base that pass gradually to a sequence consisting of pelagic limestones with shale intervals. In the study area, six cross sections were constructed, mainly covering the edge-to-slope overturned succession of Early Cretaceous to Eocene carbonates (post-rift stage) in the northern limb of the syncline. In the measured sections, abrupt changes in sediment texture resulted in the formation of distinct, thick-bedded carbonate layers, identified as packstones to grainstones–floatstones, with abundant fossil fragments, indicating deposition by debrites in a platform slope or slope-toe environment. Planar and ripple cross-lamination also suggest the involvement of turbidity currents in the depositional process. In the upper levels of the Lower Cretaceous carbonates, chert bodies with irregular shapes indicate soft sediment deformation due to instability of the slope triggered by salt intrusion. Internal unconformities identified in the field and in the available seismic data combined with the vertical to overturned dipping of the strata correspond to a basal megaflap configuration. Syn-sedimentary deformation resulted in the accumulation of debritic and turbiditic layers, while the compressional regime established in the area from the Late Cretaceous to Early Eocene enhanced the fracture porosity of carbonates, which could eventually affect the reservoir properties. Full article
(This article belongs to the Special Issue Advances in Structural Geology)
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7 pages, 1813 KiB  
Proceeding Paper
Salt Units of the Kribi-Campo Sub-Basin Revisited, Using Offshore 2D Seismic and Boreholes Data: Depositional Context and Petroleum Implications
by Mike-Franck Mienlam Essi, Joseph Quentin Yene Atangana, Mbida Yem, Serge Edouard Angoua Biouele and Eun Young Lee
Proceedings 2023, 87(1), 2; https://doi.org/10.3390/IECG2022-14295 - 20 Mar 2023
Cited by 1 | Viewed by 1516
Abstract
This work re-examines the salt unit through the Kribi-Campo sub-basin on the southeast part of the Cameroon Atlantic Margin. The results obtained from borehole data analysis show the occurrence of an evaporitic unit, localized in the Kribi area. The well to seismic-tie analysis [...] Read more.
This work re-examines the salt unit through the Kribi-Campo sub-basin on the southeast part of the Cameroon Atlantic Margin. The results obtained from borehole data analysis show the occurrence of an evaporitic unit, localized in the Kribi area. The well to seismic-tie analysis reveals that this unit is observed beneath the Top Albian Unconformity and between the Flooding and Maximum Flooding Surfaces. Two characteristics of the salt dome and salt strips are described. Their depositional context seems to be related to a significant sea-level drop induced by a margin uplift during the Aptian. Concerning the petroleum implications, the target units constitute the good potential of stratigraphic traps in the study area, due to the observation of flatspot indicators. Full article
(This article belongs to the Proceedings of The 4th International Electronic Conference on Geosciences)
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28 pages, 3928 KiB  
Article
Petroleum Systems Analysis of Turbidite Reservoirs in Rift and Passive Margin Atlantic Basins (Brazil and Portugal)
by Gustavo Santana Barbosa, Rui Pena dos Reis, Antônio Jorge Vasconcellos Garcia, Gabriel de Alemar Barberes and Gustavo Gonçalves Garcia
Energies 2022, 15(21), 8224; https://doi.org/10.3390/en15218224 - 3 Nov 2022
Cited by 5 | Viewed by 3376
Abstract
Due to the success of oil and gas production, turbidites have become exploratory targets over the past 40 years in the rift and passive margin basins in the North and South Atlantic. The turbiditic reservoirs in rift and passive margin settings of Atlantic [...] Read more.
Due to the success of oil and gas production, turbidites have become exploratory targets over the past 40 years in the rift and passive margin basins in the North and South Atlantic. The turbiditic reservoirs in rift and passive margin settings of Atlantic sedimentary basins located in Brazil (Campos Basin) and Portugal (Lusitanian Basin) represent potential economic units for the hydrocarbon exploration. However, despite being considered analogous reservoirs, these units present distinct potentials for the accumulation of hydrocarbons. In this context, the work presented discusses the results obtained from the analysis of static (source rock, reservoir rock, seal and trap) and dynamic elements (migration, tectonic, diagenetic and thermal processes) of both studied petroleum systems, using geological, seismic, well, geochemical and petrographic data. The developed methodology of multiscalar characterization of the two petroleum systems was successful, leading to a specific classification of the efficiency of the static and dynamic elements. These served as the basis for a petroleum systems analysis of the potential of turbiditic reservoirs in both analyzed basins. In the Campos Basin, the salt diapirs and the associated faults provided the origin of excellent migration routes for the hydrocarbons generated in lower intervals, allowing them to reach Cretaceous turbidite reservoirs. At Lusitanian Basin, the diagenetic processes reduced significantly the porosities of the potential turbiditic reservoirs, besides the intense influence of the salt tectonics that may have been responsible for the migration of hydrocarbons along faults or by their walls, towards upper formations and to the surface. Full article
(This article belongs to the Special Issue Advances in Petroleum Geology and Unconventional Oil and Gas)
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42 pages, 15010 KiB  
Review
Gas Sources, Migration, and Accumulation Systems: The Shallow Subsurface and Near-Seafloor Gas Hydrate Deposits
by Liping Liu, Fengyou Chu, Nengyou Wu, Lei Zhang, Xiaohu Li, Huaiming Li, Zhenggang Li, Weiyan Zhang and Xiao Wang
Energies 2022, 15(19), 6921; https://doi.org/10.3390/en15196921 - 21 Sep 2022
Cited by 7 | Viewed by 4317
Abstract
Compared with the deeply buried marine gas hydrate deposits, gas hydrates in the shallow subsurface, close to and at the seafloor, have attracted more attention owing to their concentrated distribution, high saturation, and easy access. They accumulate at relatively shallow depths <100–120 m [...] Read more.
Compared with the deeply buried marine gas hydrate deposits, gas hydrates in the shallow subsurface, close to and at the seafloor, have attracted more attention owing to their concentrated distribution, high saturation, and easy access. They accumulate at relatively shallow depths <100–120 m and occur as gas hydrate-bearing mounds (also known as hydrate outcrops, pingoes) at the seafloor derived from the growth of hydrates in the shallow subsurface or as pure hydrate chunks formed by gas leakage. This paper reviews and summarizes such gas hydrate systems globally from the perspective of gas sources, migration pathways, and accumulation processes. Here, we divided them into four categories: fault-chimney-controlled, diapir-fault-controlled, fault-controlled, and submarine mud volcano-controlled deposits. Gas chimneys originate immediately above the restricted regions, mostly affected by faults where high gas concentrations trigger elevated pore fluid pressures. Diapirism derives a dendritic network of growth faults facilitating focused gas discharge and hydrate formation near the seafloor. Furthermore, pre-existing faults or fractures created by overpressured gas from greater depths in accretionary tectonics at convergent margins act as preferential pathways channeling free gas upwards to the seafloor. Gas flux rates decrease from the submarine mud volcano center to its margins, creating a concentric pattern of distributing temperature, gas concentrations, and hydrate contents in shallow sediments around the mud volcano. Hydrate-bound hydrocarbons are commonly of thermogenic origin and correspond to high-background geothermal conditions, whereas microbial gas is dominant in a few cases. The presence of heavier hydrocarbons mitigates the inhibition of hydrate formation by salt or heat. Fluid migration and pathways could be compared to the “blood” and “bones” in an organic system, respectively. The root of a pathway serves as the “heart” that gathers and provides considerable free gas concentrations in a restricted area, thereby triggering pore fluid pressures as one important drive force for focused fluid flow in impermeable sediments (the organic system). Besides the suitable temperature and pressure conditions, a prerequisite for the formation and stability of hydrate deposits in the shallow subsurface and at the seafloor is the sufficient supply of gas-rich fluids through the hydrate stability zone. Thus, the proportion of gas migrating from deep sources is significantly larger than that trapped in hydrates. As such, such marine hydrate deposits seem more like temporary carbon storage rather than the main culprit for climate warming at least in a short period. Full article
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15 pages, 2601 KiB  
Article
Green Hydrogen Storage in an Underground Cavern: A Case Study in Salt Diapir of Spain
by Laura M. Valle-Falcones, Carlos Grima-Olmedo, Luis F. Mazadiego-Martínez, Antonio Hurtado-Bezos, Sonsoles Eguilior-Díaz and Ramón Rodríguez-Pons
Appl. Sci. 2022, 12(12), 6081; https://doi.org/10.3390/app12126081 - 15 Jun 2022
Cited by 38 | Viewed by 5372
Abstract
The Poza de la Sal diapir is a closed circular depression with Cretaceous Mesozoic materials, formed by gypsum, Keuper clays, and a large extension of salt in the center with intercalations of ophite. The low seismic activity of the area, the reduced permeability [...] Read more.
The Poza de la Sal diapir is a closed circular depression with Cretaceous Mesozoic materials, formed by gypsum, Keuper clays, and a large extension of salt in the center with intercalations of ophite. The low seismic activity of the area, the reduced permeability and porosity of the salt caverns, and the proximity to the Páramo de Poza wind park, make it a suitable place for the construction of a facility for underground storage of green hydrogen obtained from surplus wind power. The design of a cavern for hydrogen storage at a depth of 1000 m takes into account the differences in stresses, temperatures, and confining pressures involved in the salt deformation process. During the 8 months of the injection phase, 23.0 GWh can be stored in the form of hydrogen obtained from the wind energy surplus, to be used later in the extraction phase. The injection and extraction ratio must be developed under the conditions of geomechanical safety of the cavity, so as to minimize the risks to the environment and people, by conditioning the gas pressure inside the cavity to remain within a given range. Full article
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30 pages, 10711 KiB  
Article
Stratigraphy, Paleogeography and Depositional Setting of the K–Mg Salts in the Zechstein Group of Netherlands—Implications for the Development of Salt Caverns
by Alexandre Pichat
Minerals 2022, 12(4), 486; https://doi.org/10.3390/min12040486 - 16 Apr 2022
Cited by 17 | Viewed by 6464
Abstract
The 1 km thick evaporitic Permian Zechstein group in the Netherlands is subdivided into 5 halite rich evaporitic sequences including K–Mg salts (polyhalite, kieserite, sylvite, carnallite and bischofite) for which the position in the Zechstein stratigraphy is still poorly constrained. Understanding the repartition [...] Read more.
The 1 km thick evaporitic Permian Zechstein group in the Netherlands is subdivided into 5 halite rich evaporitic sequences including K–Mg salts (polyhalite, kieserite, sylvite, carnallite and bischofite) for which the position in the Zechstein stratigraphy is still poorly constrained. Understanding the repartition of K–Mg salts is especially important for the development of salt caverns which require a salt as pure as possible in halite. By compiling well log and seismic data in the offshore and onshore domains of the Netherlands, regional cross-sections and isopach maps were performed in order to update the lithostratigraphy of the Zechstein group by including the K–Mg salts. Results enable (i) to propose paleogeographic maps representing the spatial repartition and the thickness variations of one to two K–Mg rich intervals in each evaporite cycle, (ii) to constrain the depositional setting of the different type of salts and the hydrological conditions which influenced the Zechstein stratigraphic architecture and (iii) to develop over the Netherlands risking maps assessing the risk of encountering K–Mg salts in salt pillows or salt diapirs eligible in term of depth and thickness for the development of salt caverns. Full article
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17 pages, 21672 KiB  
Article
Magnetic Fabrics and Petrography of Rocksalts Reveal Preferred Orientation of Anhydrites within a Halite Matrix
by Ran Issachar, Ram Weinberger, Tsafrir Levi, Jessica Barabasch and Janos L. Urai
Minerals 2022, 12(2), 192; https://doi.org/10.3390/min12020192 - 31 Jan 2022
Cited by 1 | Viewed by 2828
Abstract
We investigate the magnetic fabrics and microstructures of diamagnetic rocksalt samples from the Sedom salt wall (diapir), Dead Sea Basin, as possible strain markers. A comprehensive study of anisotropy of magnetic susceptibility (AMS), combined with magnetic, microtextural, geochemical and mineralogical analyses allows us [...] Read more.
We investigate the magnetic fabrics and microstructures of diamagnetic rocksalt samples from the Sedom salt wall (diapir), Dead Sea Basin, as possible strain markers. A comprehensive study of anisotropy of magnetic susceptibility (AMS), combined with magnetic, microtextural, geochemical and mineralogical analyses allows us to depict the deformation mechanisms and to reveal the mineral sources of the AMS. The rocksalts are composed of halite as the major mineral phase (>80%) and anhydrite as a minor phase (5–20%), and have an average magnetic susceptibility value of −13.4 ± 0.7 × 10−6 SI. Ferromagnetic and paramagnetic minerals make a negligible contribution to the bulk magnetic properties of the samples. The AMS indicates and reveals significant anisotropy with the maximum susceptibility axis (K1) subparallel to the bedding strike, although the cubic halite crystals are isotropic. Polarizing microscope and SEM images show preferred alignment of needle-like anhydrite crystals parallel to the direction of the K1 axis. Petrographic investigation of gamma irradiated thin sections reveals the deformation recorded in the microstructures of the rocksalts and points to a dominant contribution by dislocation creep, although both dislocation creep and pressure solution were active deformation mechanisms. We infer that during dislocation creep, the thin bands of anhydrite crystals deform along with the surrounding halite grains. We suggest that although the shape preferred orientation of halite grains is not indicative of finite strain because of resetting by grain boundary migration, the preferred orientation of the anhydrite crystals may be. These results suggest that the AMS of the rocksalts provides a textural proxy that reflects deformation processes of the rocksalts, despite their very low magnetic susceptibility. Full article
(This article belongs to the Special Issue Petrophysical Characteristics of Naturally Deformed Rocks)
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16 pages, 123105 KiB  
Article
Tectonic Influence on Speleogenesis of Sea Caves on Biševo Island (UNESCO Global Geopark Vis Archipelago, Adriatic Sea, Croatia)
by Ivan Mišur, Marko Budić, Tomislav Kurečić and Tvrtko Korbar
Geosciences 2021, 11(8), 341; https://doi.org/10.3390/geosciences11080341 - 13 Aug 2021
Viewed by 3902
Abstract
A geological and speleological investigation was conducted in the famous Blue Cave (Modra špilja) and the Monk Seal Cave (Medvidina špilja) on Biševo Island (Croatia) to promote the island’s geoheritage through the new Visitor Centre. The island is mainly composed of Cretaceous to [...] Read more.
A geological and speleological investigation was conducted in the famous Blue Cave (Modra špilja) and the Monk Seal Cave (Medvidina špilja) on Biševo Island (Croatia) to promote the island’s geoheritage through the new Visitor Centre. The island is mainly composed of Cretaceous to Paleogene neritic carbonates, which form the bedrock, whereas parts of the island are covered with thin Quaternary sediments. The caves are of small dimensions and a simple layout, composed of the main channel and few shorter side channels, all positioned in the tidal zone. Thus, the caves are semi-submerged sea caves located along the coastline. The Blue Cave and the Monk Seal Cave developed within the bedrock limestones and dolostones, respectively, within a zone of left-lateral NNE–SSW striking strike-slip faults that belong to the Biševo fault system. Conjugated discontinuities within the carbonate bedrock indicate a specific strike-slip tectonic regime. Additionally, the host rocks were probably also deformed and fractured during the rise of salt diapirs that characterise this part of the Adriatic foreland. Tectonic and bedding discontinuities form the fragments of the host rock, that combined with the impacts of the strong southern waves, significantly influenced the genesis of the caves. Full article
(This article belongs to the Special Issue From Geoheritage to Geotourism—New Advances and Emerging Challenges)
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