Search Results (31)

Enhancing the thermal resistance of carbon fiber-reinforced polymers (CFRPs) with flame retardants or coatings often leads to increased weight and reduced mechanical integrity. To address these challenges, this study introduces an innovative approach for developing nanocomposites using carbon-based nanoparticles, while preserving the structural lightweight properties. For this, carbon black particles (CBPs) up to 10% and carbon nanotubes (CNTs) up to 1.5% were incorporated into the RTM6/G939 composite material. The obtained samples were then analyzed for their properties and heat resistance under one-sided thermal loading at a heat flux of 50 kW/m². Results demonstrate that integrating these particles improves heat conduction without compromising the material’s inherent advantages. As a result, thermo-induced damage and the resulting loss of mechanical strength are delayed by 17% with CBPs and 7% with CNTs compared to the unmodified material. Thereby, the thermal behavior can be accurately modeled by a straightforward approach, using calibrated, effective measurements of the nanoparticles in the polymer matrix rather than relying on theoretical assumptions. This approach thus provides a promising methode to characterize and improve thermal resistance without significant trade-offs. Full article

To solve the problems of channel crosstalk and edge jitter caused by the Fourier transform demodulation of polarimetric-spectral intensity modulation in polarization spectral data, this paper proposes a Four-Channel Polarimetric Spectrometer (FCPS) with two groups of polarimetric-spectral intensity modulation (PSIM). FCPS can demodulate the full Stokes spectra information by system matrix calibration in the spatial domain. The traditional channel filtering method and the FCPS data demodulation method are simulated, and their results are compared. The simulated results show that the FCPS does not have the problem of the edge jitter, and the demodulation accuracy is higher. It is confirmed that the angle error of phase retarders has little influence on the data reconstruction, and the maximum allowable angle error of the calibration light linear polarizer cannot exceed 0.4°. Full article

A snapshot multi-wavelength birefringence imaging measurement method was proposed in this study. The RGB-LEDs at wavelengths 463 nm, 533 nm, and 629 nm were illuminated with circularly polarized light after passing through a circular polarizer. The transmitted light through the birefringent sample was captured by a color polarization camera. A single imaging process captured light intensity in four polarization directions (0°, 45°, 90°, and 135°) for each of the three RGB spectral wavelength channels, and subsequently measured the first three elements of Stokes vectors (S₀, S₁, and S₂) after the sample. The birefringence retardance and fast-axis azimuthal angle were determined simultaneously. An experimental setup was constructed, and polarization response matrices were calibrated for each spectral wavelength channel to ensure the accurate detection of Stokes vectors. A polymer true zero-order quarter-wave plate was employed to validate measurement accuracy and repeatability. Additionally, stress-induced birefringence in a PMMA arch-shaped workpiece was measured both before and after the application of force. Experimental results revealed that the repeatability of birefringence retardance and fast-axis azimuthal angle was better than 0.67 nm and 0.08°, respectively. This approach enables multispectral wavelength, high-speed, high-precision, and high-repeatability birefringence imaging measurements through a single imaging session. Full article

Harmful substances in consumer goods pose serious hazards to human health and the environment. However, due to the vast variety of consumer goods and the complexity of their substrates, it is difficult to simultaneously detect multiple harmful substances in different materials. This paper presents a method for the simultaneous determination of 41 harmful substances comprising 17 phthalates (PAEs), 8 organophosphate flame retardants (OPFRs), and 16 polycyclic aromatic hydrocarbons (PAHs) in five types of products using the matrix-matching calibration strategy. The method employs an efficient ultrasonic extraction procedure using a mixture of dichloromethane and methylbenzene, followed by dissolution–precipitation and analysis through gas chromatography–mass spectrometry. Compared with previous experiments, we established a universal pretreatment method suitable for multi-matrix materials to simultaneously determine multiple harmful substances. To evaluate the effects of the matrix on the experimental results, we compared neat standard solutions and matrix-matching standard solutions. The results demonstrated that all compounds were successfully separated within 30 min with excellent separation efficiency. Additionally, the linear relationships of all analytes showed strong correlation coefficients (R²) of at least 0.995, ranging from 0.02 mg/L to 20 mg/L. The average recoveries of the target compounds (spiked at three concentration levels) were between 73.6 and 124.1%, with a relative standard deviation (n = 6) varying from 1.2% to 9.9%. Finally, we tested 40 different materials from consumer products and detected 16 harmful substances in 31 samples. Overall, this method is simple and accurate, and it can be used to simultaneously determine multiple types of hazardous substances in multi-matrix materials by minimizing matrix effects, making it an invaluable tool for ensuring product safety and protecting public health. Full article

Tripropyl phosphate (TnPP) is a commonly used organic phosphate flame retardant in the textiles, plastics, and coating industries. Residues are commonly detected in samples from the environment and food. The availability of certified reference materials (CRMs) is essential to ensure the accuracy and traceability of detection results. In this study, a comprehensive characterization of a CRM for TnPP was carried out, and its purity was evaluated using two distinct methodologies: mass balance (MB) and quantitative nuclear magnetic resonance spectroscopy (qNMR). In the MB method, the levels of structurally related organic impurities are 1.37 mg/g. The water content was determined to be 3.16 mg/g, while inorganic impurities were found to be 0.87 mg/g, and no residual organic solvents were detected. Benzoic acid and monocrotophos were chosen as internal standards for ¹H-qNMR and ³¹P-qNMR, respectively. The purity of the TnPP CRM was assessed as 994.6 mg/g, 994.1 mg/g, and 993.5 mg/g using MB, ¹H-qNMR, and ³¹P-qNMR techniques, respectively. The verified purity of the TnPP CRM was ultimately determined to be 994.1 mg/g, with an expanded uncertainty of 3.4 mg/g (k = 2), ensuring traceability to the International System of Units (SI). This CRM can be effectively utilized for preparing calibration solutions suitable for the routine monitoring of TnPP residues in plastics and food samples. Full article

Leveraging their unique phase modulation characteristics, birefringent waveplates have been widely used in various optical systems. With the development of material science and manufacturing techniques, the polarization properties of waveplates have become increasingly complex and diverse. Among these properties, the field-of-view effect of the waveplate caused due to manufacturing defects or improper installation procedures is extremely difficult to calibrate and seriously affects the precision and accuracy of the relevant optical systems. In this paper, a calibration method that can compensate for the field-of-view effect of waveplates installed in the instrument is proposed. Moreover, to approve the fidelity of the proposed calibration method, a series of film thickness measurement experiments are carried out. The results show that under different installation conditions of the waveplates, the precision and accuracy of the film thickness measured with the proposed method significantly improved. This method can be expected to reduce the assembly difficulty of such optical systems, while also improving their accuracy and stability. Full article

The behaviour of polymeric pipes in transient flows has been proved to be viscoelastic. Generalized Kelvin–Voigt (GKV) models perform very well when simulating the experimental pressure. However, in the literature, no general indications on the evaluation of the model parameters are given. In the present study, the calibration of GKV model parameters is carried out using a micro-genetic algorithm for experimental tests of transient flows in polymeric pipes taken from the literature. The results confirm that the higher the number of Kelvin–Voigt elements, the better the reproduction of experimental tests, but it is difficult to search for general rules for parameter characterization. Assuming a Kelvin–Voigt (KV) model with a single element, it is shown that the retardation time is related to the oscillation period that can be obtained from the elastic modulus and from easily evaluable pipe characteristics. A simple procedure is then proposed for the characterization of the viscoelastic parameters that can be used by manufacturers and technicians. Considering the limits of such a model, the procedure has to be considered as a first step for the characterization of the viscoelastic parameters of more complex models. Full article

Dual-rotating retarder polarimeters constitute a family of well-known instruments that are used today in a great variety of scientific and industrial contexts. In this work, the periodic intensity signal containing the information of all sixteen Mueller elements of depolarizing or nondepolarizing samples is determined for different ratios of angular velocities and non-ideal retarders, which are mathematically modeled with arbitrary retardances and take into account the possible diattenuating effect exhibited by both retarders. The alternative choices for generating a sufficient number of Fourier harmonics as well as their discriminating power are discussed. A general self-calibration procedure, which provides the effective values of the retardances and diattenuations of the retarders, the relative angles of the retarders and the analyzer, and the overall scale coefficient introduced by the detection and processing device are also described, leading to the absolute measurement of the Mueller matrix of the sample. Full article

To obtain highly sensitive, accurate, fast, and repeatable measurements of waveplate parameters over an entire clear aperture, a novel measurement method using dual differential frequency photoelastic modulations is proposed. Simple polarimetry is conducted based on two photoelastic modulators, which operate at different frequencies. The fast-axis azimuth and retardance parameters of the waveplate are loaded into the modulation signals. Employing digital phase-locked technology, the fundamental and differential frequency harmonic terms are extracted, and then the two parameters of the waveplate are demodulated. The principle is analyzed, and the measurement system is built for verification experiments. The experimental results reveal that the two parameters of the waveplate are simultaneously measured over the entire clear aperture. The standard deviations of the fast-axis azimuth and retardance are 0.02° and 0.03 nm, respectively, and the maximum relative deviations of the fast-axis azimuth and retardance are 0.6% and 0.06%, respectively. The single-point data measurement time is only 200 ms. The proposed method exhibits high precision and speed, and provides an effective quality inspection and calibration method for waveplates. Full article

The phase retardance of the optical system (PROS) is a crucial factor limiting the accuracy of the Stokes vector reconstruction for the channeled spectropolarimeter. The dependence on reference light with a specific angle of polarization (AOP) and the sensitivity to environmental disturbance brings challenges to the in-orbit calibration of PROS. In this work, we propose an instant calibration scheme with a simple program. A function with a monitoring role is constructed to precisely acquire a reference beam with a specific AOP. Combined with numerical analysis, high-precision calibration without the onboard calibrator is realized. The simulation and experiments prove the effectiveness and anti-interference characteristics of the scheme. Our research under the framework of fieldable channeled spectropolarimeter shows that the reconstruction accuracy of $S_2$ and $S_3$ in the whole wavenumber domain are 7.2 × 10⁻³ and 3.3 × 10⁻³, respectively. The highlight of the scheme is to simplify the calibration program and ensure that the PROS high-precision calibration is not disturbed by the orbital environment. Full article

Biofouling is the major factor that limits long-term monitoring studies with automated optical instruments. Protection of the sensing areas, surfaces, and structural housing of the sensors must be considered to deliver reliable data without the need for cleaning or maintenance. In this work, we present the design and field validation of different techniques for biofouling protection based on different housing materials, biocides, and transparent coatings. Six optical turbidity probes were built using polylactic acid (PLA), acrylonitrile butadiene styrene (ABS), PLA with copper filament, ABS coated with PDMS, ABS coated with epoxy and ABS assembled with a system for in situ chlorine production. The probes were deployed in the sea for 48 days and their anti-biofouling efficiency was evaluated using the results of the field experiment, visual inspections, and calibration signal loss after the tests. The PLA and ABS were used as samplers without fouling protection. The probe with chlorine production outperformed the other techniques, providing reliable data during the in situ experiment. The copper probe had lower performance but still retarded the biological growth. The techniques based on transparent coatings, epoxy, and PDMS did not prevent biofilm formation and suffered mostly from micro-biofouling. Full article

We applied a polarization filter array and high-speed camera to the imaging of biological tissues during large, dynamic deformations at 7000 frames per second. The results are compared to previous measurements of similar specimens using a rotating polarizer imaging system. The polarization filter eliminates motion blur and temporal bias from the reconstructed collagen fiber alignment angle and retardation images. The polarization imaging configuration dose pose additional challenges due to the need for calibration of the polarization filter array for a given sample in the same lighting conditions as during the measurement. Full article

The safety of deep geological repositories is important in the disposal of high-level radioactive waste (HLW). In this study, advection–dispersion experiments were designed to build a transport model through a calibration/validation process, and the transport behavior of tritiated water (HTO) and various iodine species (iodide: I⁻ and iodate: IO₃⁻) was studied on a dynamic compacted granite column. Breakthrough curves (BTCs) were plotted under various flow rates (1–5 mL/min). BTCs showed that the non-sorption effect by anion exclusion was observed only in I⁻ transport because the retardation factor (R) of I⁻ was lower than that of HTO (R = 1). Moreover, equilibrium and nonequilibrium transport models were used and compared to identify the mobile/immobile zones in the compacted granite column. The anion exclusion effect was influenced by the immobile zones in the column. The non-sorption effect by anion exclusion (R < 1) was only observed for I⁻ at 5.0 ± 0.2 mL/min flow rate, and a relatively higher Coulomb’s repulsive force may be caused by the smaller hydration radius of I⁻(3.31 Å) than that of IO₃⁻(3.74 Å). Full article

Scattered light polarization serves as an indicator and a characteristic of various processes in the atmosphere. The polarization measurements of all scattering matrix elements provide an adequate description of the optical and morphological parameters and orientation of particles in clouds. In this article, we consider the problem of the calibration of matrix polarization lidar (MPL) parameters. Calibration by air is an effective alternative to the technique for correcting optical element parameters and among the calibration parameters of the MPL optical path are the relative transmission coefficient of a two-channel receiver, the angular positions of the transmission axes of the optical elements of the transmitter and receiver units, including the polarizers and wave plates, and the retardance of wave plates. For the first time, the method of calibration by air was partially implemented in the MPL to study Asian dust in the atmosphere. We considered the calibration problem more generally and this was due to the need to calibrate different MPL modifications from stationary to mobile ones. The calibration equations have been derived in terms of instrumental vectors, and the method of their solution by the generalized least squares method has been proposed. The method has been verified on a numerical MPL model and validated using MPL measurements in Daejeon, Republic of Korea. Full article

Ephemeral rivers commonly occur in regions with a shortage of water resources, and their channel configuration tends to change substantially owing to long drying times and artificial sand extraction. During short-term water conveyance, water storage in large potholes and leakage along the dry riverbed retards the flow, which is detrimental for the river landscape and ecological water demand. The objective of this study is to evaluate the flow process corresponding to a certain release scheme. A coupled dynamic leakage loss and flood routing model was established to predict the flood routing distance for dry rivers with potholes and strong leakage. The model mainly includes three sub-models of flow dynamics, dynamic leakage loss and water balance along multiple cross sections of the river channel. The water head was dominated by flow velocity and the overflow from potholes. The model was applied to Yongding River, a typical ephemeral river in northern China, and the model parameters were calibrated and verified using monitoring data from ecological water releases into the Yongding River in 2019 and 2020, thus, making the model more stable and reliable. Finally, the model was used to evaluate the impact of cross section optimization and pothole treatment on the flow process. This study can provide scientific guidance for ecological water conveyance and the ecological restoration of ephemeral rivers. Full article