Search Results (14)

Diesel fuel is among the most persistent petroleum-derived pollutants in soils, posing long-term ecological and toxicological risks, especially in cold-climate regions where natural degradation is limited. Reliable assessment of diesel-contaminated soils remains difficult because conventional solvent-based analyses are incompatible with bioassays, while aqueous extracts underestimate hydrocarbon toxicity. This study evaluated dimethyl sulfoxide (DMSO) as a biocompatible extractant for enzymatic bioluminescent toxicity assays employing the coupled NAD(P)H:FMN-oxidoreductase and bacterial luciferase (BLuc–Red) system. Soil samples artificially contaminated with diesel fuel were analyzed using DMSO extracts in combination with molecular dynamics (MD) simulations to examine enzyme stability in solvent environments. Moderate DMSO concentrations (4–6% v/v) maintained enzymatic activity, whereas higher levels caused partial inhibition. Diesel hydrocarbons dissolved in DMSO strongly suppressed luminescence, and soil extracts exhibited a clear dose–response relationship between contamination level and enzymatic inhibition. MD simulations confirmed that neither DMSO nor diesel induced large-scale unfolding of luciferase or reductase, though localized flexibility changes and partial dehydration of active site residues was observed, which may account for the detected inhibition of luminescence at higher DMSO concentrations. These results demonstrate that DMSO provides an effective and biocompatible extraction medium for enzymatic bioluminescent assays, enabling accurate toxicity evaluation of petroleum-contaminated soils and offering a promising tool for ecotoxicological risk assessment in oil-impacted environments. Full article

In this research, a comprehensive series of Pr³⁺-doped lithium niobate and sodium niobate materials were obtained at different temperatures via solid-state sintering, and their structures and properties were compared. NaNbO₃: 0.75% Pr³⁺ phosphors were synthesized by sintering at 1150 °C for 2 h and emitted red persistent luminescence for more than 1200 s, peaking at 612 nm under UV excitation, which was a typical long persistent luminescence phenomenon. Furthermore, the sample glowed when pressurized, and a red bright luminescence which lasted for several seconds was visible to the naked eye. This was a typical mechanical luminescence phenomenon of samples under mechanical stress, directly converting mechanical energy into light energy. It was determined that NaNbO₃:Pr³⁺ and LiNbO₃:Pr³⁺ both possess multimode luminescence. Owing to their red long persistent luminescence (LPL) and mechano-luminescence (ML) properties, Pr³⁺ phosphors can be employed in fields, such as display technologies, stress sensing, structural damage detection, and other complex applications. Full article

In the domain of environmental science, pollutants of nanoscale plastic dimensions are acknowledged as subjects of intricate significance. Such entities, though minuscule, present formidable challenges to ecological systems and human health. The diminutive dimensions of these contaminants render their detection arduous, thus demanding the inception of avant-garde methodologies. The present manuscript postulates the employment of the tetraphenylethylene functional group with a fused xanthene (TPEF), a distinguished fluorophore, as an exemplary system for the discernment of nanoplastic particulates. The synthesis and characterization of TPEF have been exhaustively elucidated, revealing its paramount fluorescence attributes and inherent affinity for interaction with nanoplastics. When subjected to comparison with TPEF, nanoplastics are observed to manifest a more pronounced fluorescent luminescence than when associated with the conventional Nile Red (NR). Particularly, the TPEF has shown exceptional affinity for polystyrene (PS) nanoplastics. Further, the resilience of nanoplastics within the hypocotyl epidermis of soybeans, as well as their persistence in mung bean sprouts subsequent to rigorous rinsing protocols, has been meticulously examined. Additionally, this investigation furnishes empirical data signifying the existence of nano-dimensional plastic contaminants within HeLa cellular structures. The urgency of addressing the environmental ramifications engendered by these diminutive yet potent plastic constituents is emphatically highlighted in this manuscript. TPEF paves the way for prospective explorations, with the aspiration of devising efficacious mitigation strategies. Such strategies might encompass delineating the trajectories undertaken by nanoplastics within trophic networks or their ingress into human cellular architectures. Full article

Persistent luminescence materials (PLMs) are widely used across a multitude of fields due to their distinct optical properties. However, like other micron-sized materials such as microplastics, the production and recycling processes of PLMs can lead to their accumulation in soil and water, potentially posing detrimental effects on plant growth and development. In this study, we investigated the impact of commercially available blue PLM (bPLM), green PLM (gPLM), and red PLM (rPLM) on germination, seedling growth, and oxidative stress responses in rice. Our findings demonstrate that the morphology and size of PLMs do not significantly differ in their effects on rice growth. All three types of PLMs significantly inhibited root length and stem length, disrupted root cell structures, and decreased seedling biomass. Interestingly, gPLM and bPLM were found to stimulate the synthesis of osmolytes and chlorophyll in rice, while rPLM had the opposite effect. Changes in the antioxidant enzyme system in rice clearly indicated that the three types of PLMs induced reactive oxygen species (ROS) damage in rice. This study enhances our understanding of the potential environmental impacts of PLMs, offering valuable insights for the safe and responsible use of these materials in various applications. Full article

Karst reservoirs have always been a key field of oil and gas exploration. However, quantifying the process of meteoric transformation remains a persistent challenge that limits the accuracy of reservoir quality prediction. To explore the controlling factors of meteoric cementation on karst reservoirs, the Majiagou Formation of the Ordos Basin in China was selected as an example. The petrology; carbon, oxygen, and strontium isotopes; and in situ major, trace, and rare earth elements were used, types and origins of calcite cements were analyzed in detail. The results revealed five types of calcite cements (Cal-1~Cal-5), four types of cathodoluminescence (CL) intensities (dull, dull red, deep red, and bright red luminescence), and six types of rare earth element patterns (Pattern-1~Pattern-6). These five types of calcite cements developed in three periods. Cal-1 (transition CL) and Cal-2 (dull CL) were precipitated during the Early Pennsylvanian period, the meteoric freshwater was clean; Cal-3 (transition CL) and Cal-4 (bright red CL) were precipitated at the end of the Late Carboniferous period, the fluids had strong dissolution ability and were polluted by terrigenous debris; Cal-5 (transition CL) was deposited during the burial period, the fluid was pure pore water or groundwater. The control of the cement on the reservoir during the burial period was much weaker than that of meteoric cements. Therefore, explorations of karst reservoirs should be focused on weak cementation during the epigenetic period. Full article

The property of persistent luminescence shows great potential for anti-counterfeiting technology and imaging by taking advantage of a background-free signal. Current anti-counterfeiting technologies face the challenge of low security and the inconvenience of being limited to visible light emission, as emitters in the NIR optical windows are required for such applications. Here, we report the preparation of a series of Zn_1+xGa_2−2xSn_xO₄ nanoparticles (ZGSO NPs) with persistent luminescence in the first and second near-infrared window to overcome these challenges. ZGSO NPs, doped with transition-metal (Cr³⁺ and/or Ni²⁺) and in some cases co-doped with rare-earth (Er³⁺) ions, were successfully prepared using an improved solid-state method with a subsequent milling process to reach sub-200 nm size particles. X-ray diffraction and absorption spectroscopy were used for the analysis of the structure and local crystal field around the dopant ions at different Sn⁴⁺/Ga³⁺ ratios. The size of the NPs was ~150 nm, measured by DLS. Doped ZGSO NPs exhibited intense photoluminescence in the range from red, NIR-I to NIR-II, and even NIR-III, under UV radiation, and showed persistent luminescence at 700 nm (NIR-I) and 1300 nm (NIR-II) after excitation removal. Hence, these NPs were evaluated for multi-level anti-counterfeiting technology. Full article

Deep-red persistent luminescence (PersL) materials have promising applications in fluorescence labeling and tracking. PersL spectral range and PersL duration are considered to be the key factors driving the development of high-performance deep-red PersL materials. To address these two key issues, the performance of PersL materials was continually optimized by doping with cations (Si⁴⁺ and Al³⁺ ions), relying on the material of Li₂ZnGe₃O₈:Cr³⁺ from the previous work of our group, and a 4.8-fold increase in PersL radiation spectrum intensity and more than twice the PersL duration was achieved (PersL duration up to 47 h). Ultimately, the obtained PersL materials are used to demonstrate their potential use in multi-level anti-counterfeiting, tracking and localization, respectively. This study provides a unique and novel entry point for achieving high-performance PersL materials by optimizing the PersL material host to modulate the electronic structure. Full article

Near-infrared emitting nano-sized particles of ZnGa_2−x(Mg/Si)_xO₄:Cr³⁺ (x = 0–0.15, termed as ZGMSO:Cr³⁺) with persistent luminescence were prepared by sol-gel processing followed by calcination. The samples were tested by XRD, TEM, STEM, SAED, Raman, XPS, UV-Vis-NIR, TL, PLE/PL spectroscopy, and persistent luminescence decay analysis. Equimolar incorporation of Mg²⁺ and Si⁴⁺ ions did not change the spindle structure of ZnGa₂O₄ seriously. Most Mg²⁺ ions are more likely to occupy the sites in octahedron, but Si⁴⁺ ions are more likely to occupy the sites in tetrahedron in priority. A broader bandgap, up shift of conduction band minimum, and more anti-defects were found at a higher Mg²⁺/Si⁴⁺ doping concentration. ZGMSO:Cr³⁺ outputs near-infrared emission with a dominated band at 694 nm (²E → ⁴A₂ transition of Cr³⁺), which can last longer than 48 h after the stoppage of UV irradiation. Mg²⁺/Si⁴⁺ doping contributes to a better near-infrared persistent luminescence, and the strongest and the longest NIR afterglow was observed at x = 0.05, owing to that the x = 0.05 sample has the deepest defects. The synthesized nanoparticles of ZGMSO:Cr³⁺ not only output intense NIR afterglow but also can be recharged by the red light of LED several times, indicating that they are the potential nano probes for bio imaging in living animals. Full article

The ability to manipulate the luminescent color, intensity and long lifetime of nanophosphors is important for anti-counterfeiting applications. Unfortunately, persistent luminescence materials with multimode luminescent features have rarely been reported, even though they are expected to be highly desirable in sophisticated anti-counterfeiting. Here, the luminescence properties of Zn₃Ga₂GeO₈:Mn phosphors were tuned by using different preparation approaches, including a hydrothermal method and solid-state reaction approach combining with non-equivalent ion doping strategy. As a result, Mn-activated Zn₃Ga₂GeO₈ phosphors synthesized by a hydrothermal method demonstrate an enhanced red photoluminescence at 701 nm and a strong green luminescence with persistent luminescence and photostimulated luminescence at 540 nm. While Mn-activated Zn₃Ga₂GeO₈ phosphors synthesized by solid-state reactions combined with a hetero-valent doping approach only exhibit an enhanced single-band red emission. Keeping the synthetic method unchanged, the substitution of hetero-valent dopant ion Li⁺ into different sites is valid for spectral fine-tuning. A spectral tuning mechanism is also proposed. Mn-activated Zn₃Ga₂GeO₈ phosphors synthesized by a hydrothermal approach with multimodal luminescence is especially suitable for multiple anti-counterfeiting, multicolor display and other potential applications. Full article

In this study, glass-ceramics based on Sr₂MgSi₂O₇ phosphor co-doped with Eu/Dy were obtained from the sintering and crystallisation of glass powders. The glasses were melted in a gas furnace to simulate an industrial process, and the dopant concentration was varied to optimise the luminescence persistence times. The doped parent glasses showed red emission under UV light excitation due to the doping of Eu³⁺ ions, while the corresponding glass-ceramics showed persistent blue emission corresponding to the presence of Eu²⁺ in the crystalline environment. The dopant concentration had a strong impact on the sintering/crystallisation kinetics affecting the final glass-ceramic microstructure. The microstructures and morphology of the crystals responsible for the blue emission were observed by scanning electron microscopy–cathodoluminescence. The composition of the crystallised phases and the distribution of rare-earth (RE) ions in the crystals and in the residual glassy phase were determined by X-ray diffraction and energy dispersive X-ray analysis. The emission and persistence of phosphorescence were studied by photoluminescence. Full article

Zn_1+xGa_2−2xGe_xO₄ (ZGGO:Cr)-persistent phosphor, with a molar fraction, x, of x = 0.1, doped with a 0.5% molar of chromium, was synthesised via solid-state reaction at 1350 °C for 36 h. X-ray diffraction measurements and Raman spectroscopy evidence a single crystalline phase corresponding to the cubic spinel structure. Room temperature (RT) photoluminescence (PL) and afterglow decay profiles were investigated using above and below bandgap excitation. In both cases, persistent PL was observed for almost 8 h, mainly originating from a Cr³⁺ defect, the so-called N2 optical centre. RT PL excitation and diffuse reflectance allow identification of the best pathways of Cr³⁺ red/NIR emission, as well as estimation of the ZGGO bandgap energy at 4.82 eV. An in-depth investigation of the observed luminescence at 15 K and temperature-dependent PL under site-selective excitation reveals the spectral complexity of the presence of several optically active Cr³⁺ centres in the ZGGO host that emit in almost the same spectral region. Furthermore, the temperature dependence of the R-lines’ intensity indicates the existence of thermal populating processes between the different optical centres. Such observations well account for a wide distribution of defect trap levels available for carrier capture/release, as measured by the persistent luminescence decay, from which the carriers are released preferentially to the N2 Cr³⁺-related optical centre. Full article

Colorful spectra are important for the diverse applications of persistent phosphors. A color conversion concept is developed to obtain abundant persistent luminescence color by mining capacities of known persistent phosphors with the most efficient persistent properties. Here, SiO₂/Sr₂MgSi₂O₇:Eu,Dy nanoparticles are chosen as a blue persistent luminescence donor nanophosphor, while ultrafine CaAlSiN₃:Eu is utilized as a red conversion phosphor to tune the persistent luminescence spectra from blue to red. The red afterglow emission can persist for more than 5 h. The decay of the red afterglow follows nearly the same kinetics as that of the blue one. Continuous color tuning can be successfully obtained by simply changing the mass ratio of the donor/conversion phosphor pair. This color conversion strategy may be significant in indicating numerous persistent/conversion nanocomposites or nanostructures and advance the development of persistent phosphors in diverse fields which need colorful spectral properties. Full article

Mn⁴⁺-activated phosphors are emerging as a novel class of deep red/near-infrared emitting persistent luminescence materials for medical imaging as a promising alternative to Cr³⁺-doped nanomaterials. Currently, it remains a challenge to improve the afterglow and photoluminescence properties of these phosphors through a traditional high-temperature solid-state reaction method in air. Herein we propose a charge compensation strategy for enhancing the photoluminescence and afterglow performance of Mn⁴⁺-activated LaAlO₃ phosphors. LaAlO₃:Mn⁴⁺ (LAO:Mn⁴⁺) was synthesized by high-temperature solid-state reaction in air. The charge compensation strategies for LaAlO₃:Mn⁴⁺ phosphors were systematically discussed. Interestingly, Cl⁻/Na⁺/Ca²⁺/Sr²⁺/Ba²⁺/Ge⁴⁺ co-dopants were all found to be beneficial for enhancing LaAlO₃:Mn⁴⁺ luminescence and afterglow intensity. This strategy shows great promise and opens up new avenues for the exploration of more promising near-infrared emitting long persistent phosphors for medical imaging. Full article

Persistent luminescent materials are able to emit light for hours after being excited. The majority of persistent phosphors emit in the blue or green region of the visible spectrum. Orange- or red-emitting phosphors, strongly desired for emergency signage and medical imaging, are scarce. We prepared the nitrido-silicates Ca₂Si₅N₈:Eu (orange), Sr₂Si₅N₈:Eu (reddish), Ba₂Si₅N₈:Eu (yellowish orange), and their rare-earth codoped variants (R = Nd, Dy, Sm, Tm) through a solid state reaction, and investigated their luminescence and afterglow properties. In this paper, we describe how the persistent luminescence is affected by the type of codopant and the choice and ratio of the starting products. All the materials exhibit some form of persistent luminescence, but for Sr₂Si₅N₈:Eu,R this is very weak. In Ba₂Si₅N₈:Eu the afterglow remains visible for about 400 s, and Ca₂Si₅N₈:Eu,Tm shows the brightest and longest afterglow, lasting about 2,500 s. For optimal persistent luminescence, the dopant and codopant should be added in their fluoride form, in concentrations below 1 mol%. A Ca₃N₂ deficiency of about 5% triples the afterglow intensity. Our results show that Ba₂Si₅N₈:Eu(,R) and Ca₂Si₅N₈:Eu(,R) are promising persistent phosphors for applications requiring orange or red light. Full article