Search Results (76)

The feasibility of utilizing biochar as a static floating material for agricultural applications was researched to prevent evaporation from open water static storage systems or as a floating barrier in slurry pits, for instance. Five types of biochar were created from chips, bark, and pellets of pine and residues from two acacia species using a pyrolysis time between 60 and 120 min and mean temperatures between 380 and 690 °C in a simple double-chamber reactor. Biomass and biochar were characterized for their main properties: bulk density, moisture content, volatile matter, ash content, fixed carbon, and pH. Biochar was also evaluated through a basic floatability test over 27 days (648 h) in distilled water. The highest fixed carbon content was observed in pine bark biochar (69.5%), followed by the pine pellets (67.4%) and pine chips (63.4%). Despite their high carbon content, the pellets exhibited a low floatability level, whereas pine bark biochar showed superior static floatage times, together with chip and ground chip biochar. These results suggest that biochar produced from bark and wood chips may be suitable for application as floatability material in water or slurry management systems. These results warrant further research into the static floating of biochar. Full article

Rapid economic growth has led to an increase in the use of multilayer plastic packaging, which involves complex polymer compositions and hinders recycling. This study investigated the catalytic pyrolysis of plastic packaging waste in a 3000 cm³ semibatch reactor, aiming to optimize kerosene-like hydrocarbon production. The temperature (420–500 °C), N₂ flow rate (25–125 mL/min), and catalyst loading (5–20 wt.%) were examined individually and in combination with activated carbon and an Fe-doped dolomite (Fe/DM) catalyst. Central composite design (CCD) and response surface methodology (RSM) were used to identify the optimal conditions and synergistic effects. Pyrolysis product analysis involved simulation distillation gas chromatography (Sim-DGC), gas chromatography/mass spectrometry (GC/MS), and Fourier transform infrared (FT-IR) spectroscopy. The optimal conditions (440 °C, 50 mL/min N₂ flow, catalyst loading of 10 wt.% using a 5 wt.% Fe-doped dolomite-activated carbon 0.6:0.4 mass/molar ratio) yielded the highest pyrolysis oil (79.6 ± 0.35 wt.%) and kerosene-like fraction (22.3 ± 0.22 wt.%). The positive synergistic effect of Fe/DM and activated carbon (0.6:0.4) enhanced the catalytic activity, promoting long-chain polymer degradation into mid-range hydrocarbons, with secondary cracking yielding smaller hydrocarbons. The pore structure and acid sites of the catalyst improved the conversion of intermediate hydrocarbons into aliphatic compounds (C₅–C₁₅), increasing kerosene-like hydrocarbon production. Full article

The production of food with a naturally enriched protein content is a strategic response to the growing global demand for sustainable protein sources. Wood distillate (WD), a by-product of the pyrolysis of woody biomass, has previously been shown to increase the protein concentration and bioavailability in chickpea seeds. Here, we evaluated the effect of 0.5% (v/v) WD soil drenching on chickpea productivity, nutritional profile, and proteomic pattern. WD treatment significantly improved the yield by increasing plant biomass (+144%), number of pods and seeds (+148% and +147%), and seed size (diameter: +6%; weight: +25%). Nutritional analyses revealed elevated levels of soluble proteins (+15%), starch (+11%), fructose (+135%), and polyphenols (+14%) and a greater antioxidant capacity (25%), alongside a reduction in glucose content, albeit not statistically significant, suggesting an unchanged or even lowered glycemic index. Although their concentration decreased, Ca (−31%), K (−12%), P (−5%), and Zn (−14%) in WD-treated plants remained within normal ranges. To preliminary assess the quality and safety of the protein enrichment, a differential proteomic analysis was performed on coarse flours from individual seeds. Despite the higher protein content, the overall protein profiles of the WD-treated seeds showed limited variation, with only a few storage proteins, identified as legumin and vicilin-like isoforms, being differentially abundant. These findings indicate a general protein concentration increase without a major alteration in the proteoform composition or differential protein synthesis. Overall, WD emerged as a promising and sustainable biostimulant for chickpea cultivation, capable of enhancing both yield and nutritional value, while maintaining the proteomic integrity and, bona fide, food safety. Full article

The objective of this study was to investigate the chemical composition of the obtained products, as well as the antioxidant activity and bio-stimulant potential of the liquid fractions. The biomass was subjected to pyrolysis in a pilot-scale reactor, followed by distillation of the pyroligneous liquid to separate volatile compounds and enrich bioactive fractions. The samples were analysed by FTIR, TGA/DTG, and GC-MS. Antioxidant activities were assessed through DPPH, FRAP, and total phenolic content assays, while the bio-stimulant potential was evaluated through germination and growth tests of lettuce and arugula seeds. The results showed that the distilled fraction had lower acidity, greater chemical stability, and high antioxidant activity, with the presence of industrially valuable compounds such as methoxylated phenols and furfural. Furthermore, application of the distilled liquid at 0.1% concentration stimulated early seedling development—especially in arugula—while higher concentrations demonstrated inhibitory effects. These findings show that distillation of pyroligneous liquid is an effective strategy to enhance its bioactive properties, enabling its use as a natural antioxidant and plant bio-stimulant. Full article

The moth Helicoverpa armigera (Lepidoptera: Noctuidae), better known as the pod borer, poses significant threats to chickpea (Cicer arietinum L.) production. Therefore, effective and sustainable crop management strategies are required to mitigate the impact of this cosmopolitan pest. The present study aimed at investigating the potential of wood distillate (WD), a liquid byproduct of the pyrolysis of waste lignocellulosic biomass, to both reduce H. armigera pest incidence and to enhance crop yields in field-grown chickpea. The application of WD as a foliar spray effectively reduced the number of damaged pods by 35% during the plant´s reproductive stage compared with water-sprayed plants (~16 vs. 24 bored pods plant⁻¹, respectively) and increased the number of healthy pods (~16 vs. 10 pods plant⁻¹, respectively). Moreover, the lower pest incidence was accompanied by an improvement of both the seed yield and the quality at the plant´s full maturity stage. Specifically, WD-treated plants increased both the number and weight of seeds by ~80% compared to water-sprayed plants (~23 vs. 13 and 5.5 vs. 3 plant⁻¹, respectively) which further showed a remarkable improvement in their nutritional value, with the concentration of total polyphenols, flavonoids, starch, calcium, and magnesium increasing by 17%, 56%, 43%, 23%, and 15%, respectively. These results underscore the potential of WD to both improve chickpea performance and to reduce H. armigera damage to sustainably improve the productivity of this critical legume crop, aligning with the principles of the circular economy and offering an environmentally friendly alternative to synthetic pesticides and fertilizers in agriculture. Full article

The present study investigates the catalytic conversion of low-density polyethylene (LDPE) into high-grade fuel oil using a semi-batch reactor at 350 °C under ambient pressure, with a catalyst-to-LDPE ratio of 1:20. Zeolite-based catalysts were synthesized by impregnating different metals (Fe, Zn, Cr, Mn, and Ga) onto ZSM-5 with a silica-to-alumina ratio of 30 (Z30). These catalysts were characterized using BET, XRD, and NH3-TPD techniques to evaluate their physicochemical properties. The results showed that catalytic pyrolysis of LDPE yielded less pyrolytic oil compared to non-catalytic pyrolysis. The obtained pyrolytic oil was analysed through elemental composition, gross calorific value (GCV), Simulated Distillation, and GC-DHA. The elemental analysis revealed a high carbon (85–86%) and hydrogen (13–14%) content, resulting in a high GCV of approximately 42 MJ/kg. GC-DHA analysis indicated that the pyrolytic oil was rich in aromatic and olefinic compounds. Among the catalysts, 5Fe/Z30 exhibited the highest aromatic selectivity (35%), a research octane number of 91, and 100% LDPE conversion. These findings underscore the potential of low-cost iron-based catalysts for efficiently converting LDPE waste into valuable chemicals and fuels. Full article

The aim of the article is to present the impact of blending diesel fuel with tire pyrolysis (TPO) oil on the changes in the fuel’s rheological properties and to evaluate these changes in the context of meeting legal requirements for various types of fuels. This research presents the impact of normative D100 diesel oil with TPO as an admixture on the rheological properties of the blends. Measurements are made for the content of TPO in the blend equal to 5, 7, 10, 15, and 20% m/m. In addition, the reference measurements are made for pure diesel oil and pure pyrolytic oil. Kinematic viscosity density, dynamic viscosity, viscosity index, pour point, cloud point, and cold filter plugging point are determined. The density of each sample is found at 15, 20, 30, 40, 50, 60, 70, 80, 90, and 100 °C. Viscosity is determined at the reference temperatures of 20, 40, and 100 °C, which are typically used as reference temperatures for petroleum products. Approximating models are built for all the analyzed parameters, which can be used in future studies. The fit of each model to empirical data is evaluated using the coefficient of determination R². At the same time, the individual values of the analyzed indicators are compared to the limit values specified in selected standards and regulations, thus allowing us to assess the usefulness of individual fuels in terms of compliance with effective and reliable engine operation requirements. The fuels under study fulfill the normative requirements for the parameters for marine distillate fuels for blends with a pyrolysis oil content of 0–20% m/m and the requirements for standard-grade diesel oils indicated in the Regulation of the Minister of Economy of Poland for blends with a pyrolysis oil content of 0–7% m/m. Full article

This study investigated if the foliar application of wood distillate (WD, a by-product of biomass pyrolysis, containing bioactive compounds, including organic acids and phenols) influences some key parameters (fresh weight, photosynthetic efficiency, antioxidant compounds, stress-related biochemical markers, and mineral content) of basil plants, used as a model crop, grown under water-limited conditions. The experimental setup included control and WD treatments (applied via foliar application at 0.2%) under three drought levels: no stress, moderate, and high stress. The results indicated that the application of WD contributed to improving the fresh weight, chlorophyll, reduced oxidative stress, and stable levels of essential nutrients across varying drought intensities. These outcomes highlight the potential of WD as an effective biostimulant for enhancing drought tolerance in basil plants under water deficiency. Full article

As a kind of high-oxygen organic liquid produced during biomass pyrolysis, wood vinegar possesses significant industrial value due to its rich composition of acetic acid, phenols, and other bioactive compounds. In this study, we explore the application of advanced machine learning models in optimizing the dual-column distillation process for wood vinegar production, such as Random Forest algorithms. Through the integration of Aspen Plus simulation and deep learning, an adaptive control strategy is proposed to enhance the separation efficiency of key components under varying feed conditions. The experimental results demonstrate that the Random Forest model exhibits superior predictive accuracy to traditional decision tree methods, and an R² of 0.9728 can be achieved for phenol concentration prediction. This AI-driven system can provide real-time process optimization, enhancing energy efficiency, stabilizing component yields, and contributing to the advancement of sustainable practices within the biomass chemical industry. These findings are anticipated to offer valuable insights into the integration of green chemistry principles with intelligent control systems to facilitate the achievement of Industry 4.0 objectives in bio-based production. Full article

This research presents the impact of diesel blends with tire pyrolysis oil (TPO) as an additive for minimizing the wear and tear of engine components. This study investigates the blends of normative diesel oil with TPO content ranging from 5% m/m to 20% m/m. Reference measurements are made for pure diesel oil (D100) and pure TPO. This investigation included an evaluation of the corrosion effect and the effect of the fuels tested on abrasive wear. For each fuel, the sulfur content, water content, lubricity (which is defined as the corrected average diameter of the wear trace during the high-frequency reciprocating rig (HFRR) test), and impurity content are determined. Impurities are assessed using indicators such as ash residue, coking residue from 10% distillation residue, determination of wear metals and contaminants, insoluble impurity content, and total sediment by hot filtration. All parameters are determined using recognized methods described in international standards. Approximation models are built for all the analyzed parameters, which can be used in future studies. At the same time, the individual values of the analyzed factors are compared with the threshold values specified in selected standards and regulations. Consequently, it is possible to assess the usefulness of individual fuels in terms of meeting the requirements for minimum wear of engine components. The results show the suitability of pyrolysis oil and the potential for its use as an additive to fossil fuels in terms of meeting most factors. Some of the fuels tested did not meet the standards for acceptable sulfur content. However, in terms of sulfur content, all of the analyzed fuels can be used to power watercraft and land-based power and thermal power plants equipped with flue gas desulphurization systems. A second indicator for not meeting the standards is the ash residue value, which indicates the high content of non-combustible, mainly metallic, substances in the pyrolysis oil used for the tests. Post-recycled oils must, therefore, undergo appropriate purification before being used as an additive to diesel fuels for internal combustion engines. Once the post-recycling oil has been subjected to desulfurization and advanced filtration, it can be used as a fuel additive for land vehicles, which fits in with closed-loop economies and sustainable development strategies. Full article

The results of testing the ignition properties of fuels in the form of blends of diesel oil with pyrolysis oil produced from tires, used as an additive at concentrations of 0, 5, 7, 10, 15, and 20% m/m, are presented in this paper. The experiment included the preparation of distillation curves and the determination of the flash points, derived cetane number, and calculated cetane ratios. The results are related to the limits indicated in selected standards and regulations on requirements for marine- and land-based compression ignition engine fuels. The obtained results show the suitability of pyrolysis oil and the possibility of its use as an additive to fossil fuels, which fits in with the requirements of the policies currently being developed for reducing the use of fossil fuels and building a circular economy. Full article

The oil content of shale oil reservoirs is a key parameter for reserve evaluation and “sweet spot” selection. However, discrepancies in the oil contents obtained by different methods have led to considerable disparities in the selection of exploration well locations and development strategies for shale oil. This study focuses on low to moderately mature sealed coring samples from the Dongying Depression in the Bohai Bay Basin. Three methods—NMR, Dean–Stark, and Rock-Eval—were employed to measure the oil content of shale. The results indicate that the oil content obtained by NMR is the highest, followed by the Dean–Stark distillation extraction method, while the pyrolysis method yields the lowest value. The study found that (1) the efficiency of the solvent extraction effect on moderately to low-mature shale is low since the occurrence of numerous closed pores leads to a lower yield when using the Dean–Stark method. (2) The exposure of shale samples to the air, sample crushing, and lag time for temperature increase cause a significant loss of light hydrocarbon components, resulting in the lowest oil content when measured by the Rock-Eval method. The NMR method, with its advantages of a short analysis time and non-destructive nature, appears to be the most advantageous method for shale oil content evaluation. Full article

This research aimed to evaluate the use of edible coating from a combination of liquid smoke and turmeric extract as a preservative for mackerel at room temperature. Liquid smoke was obtained from the pyrolysis of oil palm empty fruit bunches (OPEFB) at a temperature of 380 °C and purified by distillation at 190 °C. Liquid smoke with a concentration of 3% was combined with turmeric extract at a ratio of 2, 4, 6, and 8 g/L (CLS 2:1, CLS 4:1, CLS 6:1 and CLS 8:1). TVB-N testing showed that the mixture of liquid smoke and turmeric at a ratio of CLS 6: 1 and CLS 8: 1 maintains the freshness of fish for 48 h. Meanwhile, organoleptic testing reports that the best mixture was CLS 8:1. The number of colonies in the CLS 2:1, CLS 4:1, CLS 6:1, and CLS 8:1 mixtures were 4.92, 4.92, 4.16, and 4 × 10⁵ colonies/g after 44 h of soaking. The MPN test result at 48 h of soaking is 1.1 × 10³ MPN/g. Generally, mackerel preserved with a mixture of turmeric extract and liquid smoke with a ratio of 8:1 can be consumed up to a shelf life of 48 h at room temperature storage. Full article

Nowadays, tomato, a commercially important crop, is increasingly cultivated in a soilless cultivation system to counteract climate change. Normally, this system uses cocopeat as a substrate, but its high cost and environmental impact have led to growing interest in alternatives like biochar (BC). In addition, biostimulants, such as wood distillate (WD), a pyrolysis by-product, are increasingly being used to improve fruit yield and quality. BC was used to partially replace (2% and 5%) cocopeat in growth bags for soilless tomato cultivation. Moreover, WD (3 mL/L) was distributed in the substrate every two weeks. The effect of BC and WD on tomato plant growth, fruit quality, and substrate microbial community was investigated. The integration of BC and WD into a soilless growing system for tomato cultivation can improve the fruit quality and influence the microbial activity of the substrate. Replacing part of the cocopeat in the substrate with BC and using an agri-waste-derived biostimulant represent a step forward in making agriculture more sustainable. Full article

Plastics, once regarded as a revolutionary material shaping modern society, now pose an unprecedented threat to our environment. Household solid waste sorting stations produce several fractions, one of which contains a high concentration of Low-Density Polyethylene (LDPE) film waste (packaging, sunscreen film, etc.). This fraction is difficult to recycle because it contains quite a lot of impurities. Usually, it is sent to cement factories that burn it together with other fuels. However, with some processing techniques such as catalytic pyrolysis, this fraction could be valorized. In this paper, experiments were carried out in batches at a laboratory-scale installation, with a processing capacity of 1–3 kg of waste. A pyrolysis reactor was connected to a distillation column, enabling separation of the fractions. The gaseous and liquid fractions were characterized by GC-FID-TCD (gases) and GC-MS (liquids) analysis. Natural catalysts such as bentonite or clinoptilolite were studied and used in the melting of plastic mass to simplify the process as much as possible. To test the activity of the catalysts, the pyrolysis of LDPE granules was initially studied. It was found that natural zeolites are much more active than bentonite and that a minimum concentration of 5–10% is needed to have a positive effect on the composition of the fractions (increasing the weight of the light fractions (C1–C6, C6–C10, and C11–C13) in relation to the heavy fractions (C13–C20 and C20+). Catalytic pyrolysis gives a completely different distribution of light hydrocarbons. The best catalyst selected from LDPE lab experiments was then tested upon the pyrolysis of plastic film waste obtained by a waste treatment plant. The research objective reported in this paper was to obtain a fraction of combustible gases in the largest possible proportion, which can be much more easily exploited by burning in an engine that drives an electric generator. Full article