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Search Results (895)

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Keywords = process related phenomena

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17 pages, 12279 KB  
Article
Spatiotemporal Assessment of Urban Heat Vulnerability and Linkage Between Pollution and Heat Islands: A Case Study of Toulouse, France
by Aiman Mazhar Qureshi, Khairi Sioud, Anass Zaaoumi, Olivier Debono, Harshit Bhatia and Mohamed Amine Ben Taher
Urban Sci. 2025, 9(12), 541; https://doi.org/10.3390/urbansci9120541 - 16 Dec 2025
Viewed by 108
Abstract
Urban heat vulnerability is an increasing public health concern, particularly in rapidly urbanizing regions of southern France. This study aims to quantify and map the Heat Vulnerability Index (HVI) for Toulouse and to analyze its temporal trends to identify high-risk zones and influencing [...] Read more.
Urban heat vulnerability is an increasing public health concern, particularly in rapidly urbanizing regions of southern France. This study aims to quantify and map the Heat Vulnerability Index (HVI) for Toulouse and to analyze its temporal trends to identify high-risk zones and influencing factors. The assessment integrates recent years’ remote sensing data of pollutant emissions, land use/land cover and land surface temperature, statistical data of climate-related mortalities, and socioeconomic and demographic factors. Following a detailed analysis of recent real-time air quality and weather data from multiple monitoring stations across the city of Toulouse, it was observed that Urban Pollution Island (UPI) and Urban Heat Island (UHI) are closely interlinked phenomena. Their combined effects can significantly elevate the annual mortality risk rate by an average of 2%, as calculated using AirQ+ particularly, in densely populated urban areas. Remote sensing data was processed using Google Earth Engine and all factors were grouped into three key categories: heat exposure, heat sensitivity, and adaptive capacity to derive HVI. Temporal HVI maps were generated and analyzed to identify recent trends, revealing a persistent increase in vulnerability across the city. Comparative results show that 2022 was the most critical summer period, especially evident in areas with limited vegetation and extensive use of heat-absorptive materials in buildings and pavements. The year 2024 indicates resiliency and adaptation although some areas remain highly vulnerable. These findings highlight the urgent need for targeted mitigation strategies to improve public health, enhance urban resilience, and promote overall human well-being. This research provides valuable insights for urban planners and municipal authorities in designing greener, more heat-resilient environments. Full article
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24 pages, 2569 KB  
Article
Symmetry Breaking Mechanisms and Pressure Pulsation Characteristics in a Large-Scale Francis Turbine Under Variable Head Operation
by Hong Hua, Zhizhong Zhang, Xiaobing Liu and Haiku Zhang
Symmetry 2025, 17(12), 2151; https://doi.org/10.3390/sym17122151 - 14 Dec 2025
Viewed by 146
Abstract
Flexible grid regulation necessitates Francis turbines to operate at heads of 120–180 m (compared to the rated head of 154.6 m), breaking the designed rotational symmetry and inducing hydraulic instabilities that threaten structural integrity and operational reliability. This study presents extensive field measurements [...] Read more.
Flexible grid regulation necessitates Francis turbines to operate at heads of 120–180 m (compared to the rated head of 154.6 m), breaking the designed rotational symmetry and inducing hydraulic instabilities that threaten structural integrity and operational reliability. This study presents extensive field measurements of pressure pulsations in a 600 MW prototype Francis turbine operating at heads of 120–180 m and loads of 20–600 MW across 77 operating conditions (7 head levels × 11 load points). We strategically positioned high-precision piezoelectric pressure sensors at three critical locations—volute inlet, vaneless space, and draft tube cone—to capture the amplitude and frequency characteristics of symmetry-breaking phenomena. Advanced signal processing revealed three distinct mechanisms with characteristic pressure pulsation signatures: (1) Draft tube rotating vortex rope (RVR) represents spontaneous breaking of axial symmetry, exhibiting helical precession at 0.38 Hz (approximately 0.18 fn, where fn = 2.08 Hz) with maximum peak-to-peak amplitudes of 108 kPa (87% of the rated pressure prated = 124 kPa) at H = 180 m and P = 300 MW, demonstrating approximately 70% amplitude reduction potential through load-based operational strategies. (2) Vaneless space rotor-stator interaction (RSI) reflects periodic disruption of the combined C24 × C13 symmetry at the blade-passing frequency of 27.1 Hz (Nr × fn = 13 × 2.08 Hz), reaching peak amplitudes of 164 kPa (132% prated) at H = 180 m and P = 150 MW, representing the most severe symmetry-breaking phenomenon. (3) Volute multi-point excitation exhibits broadband spectral characteristics (4–10 Hz) with peak amplitudes of 146 kPa (118% prated) under small guide vane openings. The spatial amplitude hierarchy—vaneless space (164 kPa) > volute (146 kPa) > draft tube (108 kPa)—directly correlates with the local symmetry-breaking intensity, providing quantitative evidence for the relationship between geometric symmetry disruption and hydraulic excitation magnitude. Systematic head-dependent amplitude increases of 22–43% across all monitoring locations are attributed to effects related to Euler head scaling and Reynolds number variation, with the vaneless space demonstrating the highest sensitivity (0.83 kPa/m, equivalent to 0.67% prated/m). The study establishes data-driven operational guidelines identifying forbidden operating regions (H = 160–180 m, P = 20–150 MW for vaneless space; H = 160–180 m, P = 250–350 MW for draft tube) and critical monitoring frequencies (0.38 Hz for RVR, 27.1 Hz for RSI), providing essential reference data for condition monitoring systems and operational optimization of large Francis turbines functioning as flexible grid-regulating units in renewable energy integration scenarios. Full article
(This article belongs to the Section Engineering and Materials)
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28 pages, 6534 KB  
Article
Multi-Parameter and Multi-Layer Observations of Electromagnetic Precursors to a Huge Hokkaido Earthquake (M = 6.7) on 5 September, 2018, and Lithosphere–Atmosphere–Ionosphere Coupling Channel
by Masashi Hayakawa, Maria Solovieva, Galina Kopylova, Shinji Hirooka, Sudipta Sasmal, Kousik Nanda, Shih-Sian Yang, Koichiro Michimoto and Hide’aki Hinata
Atmosphere 2025, 16(12), 1372; https://doi.org/10.3390/atmos16121372 - 3 Dec 2025
Viewed by 289
Abstract
A series of multi-parameter, multi-layer observations was conducted to study possible electromagnetic precursors associated with the M 6.7 earthquake that struck Iburi, Hokkaido, Japan, at 18:07:59 UT on 5 September 2018. The most significant observation is seismogenic lower-ionospheric perturbations in the propagation anomalies [...] Read more.
A series of multi-parameter, multi-layer observations was conducted to study possible electromagnetic precursors associated with the M 6.7 earthquake that struck Iburi, Hokkaido, Japan, at 18:07:59 UT on 5 September 2018. The most significant observation is seismogenic lower-ionospheric perturbations in the propagation anomalies of sub-ionospheric VLF/LF signals recorded in Japan and Russia. Other substantial observations include the GIM-TEC irregularities, the intensification of stratospheric atmospheric gravity waves (AGWs), and the satellite and ground monitoring of air temperature (T), relative humidity (RH), atmospheric chemical potential (ACP), and surface latent heat flux (SLHF). We have found that there were very remarkable VLF/LF anomalies indicative of lower-ionospheric perturbations observed on 4 and 5 September just before the EQ date and even after it from the observations in Japan and Russia. In particular, the anomaly was detected for a particular propagation path from the JJY transmitter (Fukushima) to a VLF station at Wakkanai one day before the EQ, i.e., on 4 September, and is objectively confirmed by machine/deep learning analysis. An anomaly in TEC occurred only on 5 September, but it is unclear whether it is related to a pre-EQ effect or a minor geomagnetic storm. We attempted to determine whether any seismo-related atmospheric gravity wave (AGW) activity occurred in the stratosphere. Although numerous anomalies were detected, they are most likely associated with convective weather phenomena, including a typhoon. Finally, the Earth’s surface parameters based on satellite monitoring seem to indicate some anomalies from 29 August to 3, 4, and 5 September, a few days prior to EQ data, but the ground-based observation close to the EQ epicenter has indicated a clear T/RH and ACP on 2 September with fair weather, but no significant data on subsequent days because of severe meteorological activities. By integrating multi-layer observations, the LAIC (lithosphere–atmosphere–ionosphere coupling) process for the Hokkaido earthquake appears to follow a slow diffusion-type channel, where ionospheric perturbations arise a few days after ground thermal anomalies. This study also provides integrated evidence linking concurrent lower-ionospheric, atmospheric, and surface thermal anomalies, emphasizing the diagnostic value of such multi-parameter observations in understanding EQ-associated precursor signatures. Full article
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25 pages, 1083 KB  
Review
Carnot and Joule Cycles Implied in Generalized Entropy and Exergy Properties as Fundamentals of Extrema Principles
by Pierfrancesco Palazzo
Entropy 2025, 27(12), 1219; https://doi.org/10.3390/e27121219 - 29 Nov 2025
Viewed by 232
Abstract
Thermodynamic laws and principles overarch all domains of physics, chemistry and biology. In this broad perspective, further generalizations with respect to the “state-of-the-art” of current theories are still viable considering all aspects of systems’ states and phenomena. This research aims to discuss the [...] Read more.
Thermodynamic laws and principles overarch all domains of physics, chemistry and biology. In this broad perspective, further generalizations with respect to the “state-of-the-art” of current theories are still viable considering all aspects of systems’ states and phenomena. This research aims to discuss the physical and informational implications of Carnot and Joule cycles and the properties inferred from their definitions, as well as the extrema principles governing non-equilibrium phenomena in complex systems. The approach adopted can be viewed as an analytical variational method focusing cycles’ performances and maxima of properties and parameters along cyclic processes. The dualisms and symmetries characterizing Carnot and Joule cycles imply the inference of the necessity and sufficiency of the stable equilibrium for equality of thermodynamic potentials of any system in any state. The conclusions provide a perspective on complex systems and non-equilibrium processes governed by the extrema principles and the physical and informational properties relating to complexity and self-organization. This treatise also represents a basis and a proposal for further developments looking forward to unifying thermodynamic and informational aspects of extrema principles in the direction of complexity, self-organization, constructal emergence and autopoiesis of non-living and living systems in the frame of a general unifying paradigm. Implications and applications are envisaged in an extended perspective accounting for sustainability, circularity and biotechnologies representing future scenarios of industry and environmental protection. Full article
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22 pages, 4497 KB  
Article
Experimental and Analytical Framework for Predicting Nonlinear Viscoelastic–Viscoplastic Behavior of Polymers
by Alen Oseli, Matic Šobak and Lidija Slemenik Perše
Polymers 2025, 17(23), 3095; https://doi.org/10.3390/polym17233095 - 21 Nov 2025
Viewed by 528
Abstract
The present research addresses the modeling of viscoelastic–viscoplastic behavior of polymers with a theoretical expansion of Schapery’s nonlinear viscoelastic model by incorporating two components of irrecoverable processes, displaying material flow and viscoplastic behavior (structure- and load-related irrecoverable process). The theory is accompanied by [...] Read more.
The present research addresses the modeling of viscoelastic–viscoplastic behavior of polymers with a theoretical expansion of Schapery’s nonlinear viscoelastic model by incorporating two components of irrecoverable processes, displaying material flow and viscoplastic behavior (structure- and load-related irrecoverable process). The theory is accompanied by an experimental and analytical framework for identifying model parameters. Introduced multi-scale analysis allows evaluation of pure linear and nonlinear viscoelastic, as well as viscoplastic behavior, enabling the study of their contribution to overall material response. Model performance was examined with creep recovery tests on two versatile and well-established thermoplastic polymers with different morphological structures: amorphous ABS exhibiting notable flow and semi-crystalline POM, where flow may be neglected. Results show extremely accurate predictions and exceptional agreement with experimental data, as the error was found to be less than 5% ranging from infinitesimally small to relatively high loading magnitudes (from 0.1 to 15 MPa of shear stress) at 70 °C (maximum operating temperature). Notably, viscoplastic strains were detected even within linear viscoelastic domain, suggesting that these effects are not related to yield phenomena (associated with progressive/damaging mechanisms), but rather provide an explanation for the material’s inability to fully recover. With its predictive capability and adaptability, the model demonstrates to be a powerful tool for capturing realistic material responses not only for the considered but also applicable to other molecular systems. Full article
(This article belongs to the Section Polymer Physics and Theory)
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24 pages, 6444 KB  
Article
The Deformation Characteristics and Patterns of Adjacent Existing Metro Structures Caused by Foundation Pit Excavation Under Different Support Forms
by Zhitong Mao, Tian Ding, Fengchao Hu, Shuaihua Ye, Linzhao Ding, Rong Shu, Xiaoning Zhang and Minghua Song
Buildings 2025, 15(22), 4178; https://doi.org/10.3390/buildings15224178 - 19 Nov 2025
Viewed by 272
Abstract
With the continuous development of cities, underground space has become increasingly crowded, making the efficient and safe utilization of underground space an urgent issue to address. At present, research on foundation pit construction adjacent to existing subway structures mainly focuses on the impact [...] Read more.
With the continuous development of cities, underground space has become increasingly crowded, making the efficient and safe utilization of underground space an urgent issue to address. At present, research on foundation pit construction adjacent to existing subway structures mainly focuses on the impact of pit excavation on tunnels. While these studies have established a basic understanding of how pit excavation affects tunnels, research on adjacent subway stations and tunnels is nearly nonexistent—especially regarding the impact of the coupling effect between stations and tunnels during the excavation process. Additionally, most studies are conducted in soft soil areas, with no research yet on the impact in loess areas. To study the impact of foundation pit construction on subway tunnels and stations and reveal their coupling mechanism, model tests and numerical simulations were conducted based on actual engineering conditions. The model box had dimensions of 1.5 m in length, 1 m in width, and 1.2 m in height, while numerical simulations adopted the same dimensions as the actual project. Two different support structures—pile-anchor support and double-row pile support—were used for separate research and comparative analysis. The results show that with the increase in excavation depth, the foundation pit unloading effect becomes increasingly obvious. The pressure borne by both support structures increases, and the disturbance to the subway structure also becomes more significant. The maximum disturbance of tunnel earth pressure under the double-row pile support is 7.92 kPa, which is 224% higher than that under the pile-anchor support. The impacts on the subway tunnel and station under the double-row pile support are significantly greater than those under the pile-anchor support. Additionally, affected by the station, the locations of maximum tunnel deformation are not at the positions corresponding to the center of the foundation pit, but offset 10 m away from the station. Both the station and the tunnel exhibit a certain degree of uplift deformation, and the tunnel has significant convergence deformation in the horizontal direction. The maximum disturbance of the bending moment under the double-row pile support is 101.87 N·m, which is 19.8% higher than that under the pile-anchor support. This study reveals the coupling mechanism of the impact of adjacent foundation pit excavation on subway structures (including subway stations and tunnels) and presents the corresponding causes and phenomena, and it is of great significance for the development of related projects in loess areas and the protection of subway structures. Full article
(This article belongs to the Section Architectural Design, Urban Science, and Real Estate)
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24 pages, 4540 KB  
Review
From Field Effect Transistors to Spin Qubits: Focus on Group IV Materials, Architectures and Fabrications
by Nikolay Petkov and Giorgos Fagas
Nanomaterials 2025, 15(22), 1737; https://doi.org/10.3390/nano15221737 - 17 Nov 2025
Viewed by 836
Abstract
In this review, we focus on group IV one-dimensional devices for quantum technology. We outline the foundational principles of quantum computing before delving into materials, architectures and fabrication routes, separately, by comparing the bottom-up and top-down approaches. We demonstrate that due to easily [...] Read more.
In this review, we focus on group IV one-dimensional devices for quantum technology. We outline the foundational principles of quantum computing before delving into materials, architectures and fabrication routes, separately, by comparing the bottom-up and top-down approaches. We demonstrate that due to easily tunable composition and crystal/interface quality and relatively less demanding fabrications, the study of grown nanowires such as core–shell Ge-Si and Ge hut wires has created a very fruitful field for studying unique and foundational quantum phenomena. We discuss in detail how these advancements have set the foundations and furthered realization of SETs and qubit devices with their specific operational characteristics. On the other hand, top-down processed devices, mainly as Si fin/nanowire field-effect transistor (FET) architectures, showed their potential for scaling up the number of qubits while providing ways for very large-scale integration (VLSI) and co-integration with conventional CMOS. In all cases we compare the fin/nanowire qubit architectures to other closely related approaches such as planar (2D) or III–V qubit platforms, aiming to highlight the cutting-edge benefits of using group IV one-dimensional morphologies for quantum computing. Another aim is to provide an informative pedagogical perspective on common fabrication challenges and links between common FET device processing and qubit device architectures. Full article
(This article belongs to the Special Issue Semiconductor Nanowires and Devices)
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30 pages, 8975 KB  
Article
Modelling of Exploitation Influence on Rock Mass Seismicity in Boundary Coal Pillar Areas—A Single-Longwall Option
by Dariusz Chlebowski and Grażyna Dzik
Appl. Sci. 2025, 15(22), 12126; https://doi.org/10.3390/app152212126 - 15 Nov 2025
Viewed by 345
Abstract
The article is devoted to the issues of designing the exploitation of a seam deposit in the boundary areas of underground mines in terms of minimizing the risk of dynamic phenomena. Its main goal was to attempt to demonstrate the relationship between the [...] Read more.
The article is devoted to the issues of designing the exploitation of a seam deposit in the boundary areas of underground mines in terms of minimizing the risk of dynamic phenomena. Its main goal was to attempt to demonstrate the relationship between the method of extracting resources trapped in the boundary pillar and the magnitude of the induced seismicity of the rock mass accompanying this process. The substantive considerations concerned the single-wall model and were divided into two main parts—theoretical and verification. As part of the theoretical piece, based on model studies, a geomechanical assessment of the impact of the working face advance on changes in the stress–strain behaviour occurring in the burst-prone layer in terms of the possible loss of continuity of its original structure was carried out. The starting point for the key analyses were the results of numerical simulations based on the algorithms of S. Knothe and W. Budryk’s theories in combination with classical solutions of the mechanics of deformable bodies. Two variants of mining operations in a two-sided environment of goaf were considered, differing in the direction of progress, the degree of constraint of the start and end of the face advance, and mining circumstances in the vicinity of both sides of the advancing face. As part of the verification piece, the results of model analyses were related to an example polygon of a crossing longwall in one of the functioning, rockburst USCB hard coal mines. The scope of the research included a comparison of the experimentally indicated zones of occurrence of tremor-favourable effort processes in the roof of the seam with the actual location of the seismic phenomena foci recorded during the ongoing exploitation. The considerations included in the work formed the basis for formulating conclusions of a cognitive and applicable nature. Full article
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15 pages, 5332 KB  
Article
Experimental Study and Numerical Simulation of Oscillation Phenomena in a Pressure Swirl Injector
by Juan Liu and Yifan Han
Aerospace 2025, 12(11), 1014; https://doi.org/10.3390/aerospace12111014 - 14 Nov 2025
Viewed by 351
Abstract
In this study, experiments and numerical simulations were conducted to investigate the oscillation phenomena in a pressure swirl injector. The flow field was captured using high-speed photography, and the gray values were analyzed using the Matlab image processing program. The oscillation frequency was [...] Read more.
In this study, experiments and numerical simulations were conducted to investigate the oscillation phenomena in a pressure swirl injector. The flow field was captured using high-speed photography, and the gray values were analyzed using the Matlab image processing program. The oscillation frequency was recorded using FFT transform. Additionally, the flow field of the pressure swirl injector was simulated based on the volume of fluid (VOF) interface-tracking method. Both the experimental and numerical results revealed periodic oscillations in the pressure swirl injector, with a corresponding frequency of several hundred Hertz. The oscillation frequency is closely related to the behavior of the central gas core, which has greater turbulent kinetic energy than the liquid phase. As the mass flow rate increases, the velocity of the gas core is increased. The turbulent kinetic energy of the central gas core increased, which led to an increase in the oscillation frequency. Finally, the relationship between Re and the oscillation frequency was obtained. Full article
(This article belongs to the Special Issue Fluid Flow Mechanics (4th Edition))
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35 pages, 558 KB  
Review
A Comparative Neurophenomenology of the Psychedelic State and Autism: Predictive Processing as a Unifying Lens
by William Roseby and Catriona Osborn Moar
Psychoactives 2025, 4(4), 41; https://doi.org/10.3390/psychoactives4040041 - 14 Nov 2025
Viewed by 2044
Abstract
Serotonergic psychedelics, particularly psilocybin, lysergic acid diethylamide (LSD), and dimethyltryptamine (DMT), are increasingly recognised as powerful tools to advance the understanding of consciousness and its relation to brain activity. Psychedelic research has informed neuroscientific theories that attempt to map neural observations of network [...] Read more.
Serotonergic psychedelics, particularly psilocybin, lysergic acid diethylamide (LSD), and dimethyltryptamine (DMT), are increasingly recognised as powerful tools to advance the understanding of consciousness and its relation to brain activity. Psychedelic research has informed neuroscientific theories that attempt to map neural observations of network connectivity and signal diversity to phenomenological qualities like psychological flexibility. Thus far, however, there have been relatively limited efforts to bridge the gap between psychedelic-informed theory and the experiential differences observed in neurodevelopmental conditions such as autism. In this narrative review and conceptual synthesis, we compare the psychedelic state and autism in adults from a neurophenomenological perspective. Predictive processing is invoked as a unifying framework. This procedure highlights both phenomena as involving a shift towards sensory information relative to prior knowledge, but potentially implicating alterations at opposite ends of the cortical hierarchy. This contrastive approach also reveals opportunities for refining concepts—including psychological flexibility—as well as interpretations of results across fields. However, neurobiological findings, especially in autism, are heterogeneous and there are inherent restrictions in comparing transient state and lifelong trait phenomena. Conclusions of this comparison are primarily conceptual and offer testable hypotheses for the neurophenomenology of the psychedelic state, autism, and their interaction. Full article
15 pages, 293 KB  
Article
Relaxed Boundary Conditions in Poisson–Nernst–Planck Models: Identifying Critical Potentials for Multiple Cations
by Xiangshuo Liu, Henri Ndaya, An Nguyen, Zhenshu Wen and Mingji Zhang
Membranes 2025, 15(11), 339; https://doi.org/10.3390/membranes15110339 - 13 Nov 2025
Viewed by 703
Abstract
Ion channels are protein pores that regulate ionic flow across cell membranes, enabling vital processes such as nerve signaling. They often conduct multiple ionic species simultaneously, leading to complex nonlinear transport phenomena. Because experimental techniques provide only indirect measurements of ion channel currents, [...] Read more.
Ion channels are protein pores that regulate ionic flow across cell membranes, enabling vital processes such as nerve signaling. They often conduct multiple ionic species simultaneously, leading to complex nonlinear transport phenomena. Because experimental techniques provide only indirect measurements of ion channel currents, mathematical models—particularly Poisson–Nernst–Planck (PNP) equations—are indispensable for analyzing the underlying transport mechanisms. In this work, we examine ionic transport through a one-dimensional steady-state PNP model of a narrow membrane channel containing multiple cation species of different valences. The model incorporates a small fixed charge distribution along the channel and imposes relaxed electroneutrality boundary conditions, allowing for a slight charge imbalance in the baths. Using singular perturbation analysis, we first derive approximate solutions that capture the boundary-layer structure at the channel—reservoir interfaces. We then perform a regular perturbation expansion around the neutral reference state (zero fixed charge with electroneutral boundary conditions) to obtain explicit formulas for the steady-state ion fluxes in terms of the system parameters. Through this analytical approach, we identify several critical applied potential values—denoted Vka (for each cation species k), Vb, and Vc—that delineate distinct transport regimes. These critical potentials govern the sign of the fixed charge’s influence on each ion’s flux: depending on whether the applied voltage lies below or above these thresholds, a small positive permanent charge will either enhance or reduce the flux of each ion species. Our findings thus characterize how a nominal fixed charge can nonlinearly modulate multi-ion currents. This insight deepens the theoretical understanding of nonlinear ion transport in channels and may inform the interpretation of current–voltage relations, rectification effects, and selective ionic conduction in multi-ion channel experiments. Full article
64 pages, 8275 KB  
Article
Atmospheric Processes over the Broader Mediterranean Region 1980–2024: Effect of Volcanoes, Solar Activity, NAO, and ENSO
by Harry D. Kambezidis
Earth 2025, 6(4), 138; https://doi.org/10.3390/earth6040138 - 1 Nov 2025
Viewed by 1161
Abstract
The Mediterranean region is regarded as a hot spot on Earth because of its placement at the junction of many aerosols. Numerous studies have demonstrated that the North Atlantic Oscillation (NAO), which is closely related to the El Niño–Southern Oscillation (ENSO) phenomenon, influences [...] Read more.
The Mediterranean region is regarded as a hot spot on Earth because of its placement at the junction of many aerosols. Numerous studies have demonstrated that the North Atlantic Oscillation (NAO), which is closely related to the El Niño–Southern Oscillation (ENSO) phenomenon, influences the weather in the area. However, a recent study by the same author examined the ENSO effect on atmospheric processes in this area and discovered a slight but notable influence. This study builds on that earlier work, but it divides the Mediterranean region into four smaller regions during the same time span as the previous study, which is extended by two years, from 1980 to 2024. The division is based on geographical, climatological, and atmospheric process features. The findings demonstrate that volcanic eruptions significantly affect the total amount of aerosols. Additionally, the current study reveals that the Granger-causality test of the physical phenomena of solar activity, ENSO, and NAO indicates that all have a significant impact, either separately or in combination, on the atmospheric process over the four Mediterranean regions, and this effect can last up to six months. Moreover, a taxonomy of the different forms of aerosols across the four subregions is given. Full article
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49 pages, 15439 KB  
Article
Geomechanical Integrity of Offshore Oil Reservoir During EOR-CO2 Process: A Case Study
by Piotr Ruciński
Energies 2025, 18(21), 5751; https://doi.org/10.3390/en18215751 - 31 Oct 2025
Viewed by 483
Abstract
The aim of this work was to investigate the evolution of the mechanical integrity of the selected offshore oil reservoir during its life cycle. The geomechanical stability of the reservoir formation, including the caprock and base rock, was investigated from the exploitation phase [...] Read more.
The aim of this work was to investigate the evolution of the mechanical integrity of the selected offshore oil reservoir during its life cycle. The geomechanical stability of the reservoir formation, including the caprock and base rock, was investigated from the exploitation phase through waterflooding production to the final phase of enhanced oil recovery (EOR) with CO2 injection. In this study, non-isothermal flow simulations were performed during the process of cold water and CO2 injection into the oil reservoir as part of the secondary EOR method. The analysis of in situ stress was performed to improve quality of the geomechanical model. The continuous changes in elastic and thermal properties were taken into account. The stress–strain tensor was calculated to efficiently describe and analyze the geomechanical phenomena occurring in the reservoir as well as in the caprock and base rock. The integrity of the reservoir formation was then analyzed in detail with regard to potential reactivation or failure associated with plastic deformation. The consideration of poroelastic and thermoelastic effects made it possible to verify the development method of the selected oil reservoir with regard to water and CO2 injection. The numerical method that was applied to describe the evolution of an offshore oil reservoir in the context of evaluating the geomechanical state has demonstrated its usefulness and effectiveness. Thermally induced stresses have been found to play a dominant role over poroelastic stresses in securing the geomechanical stability of the reservoir and the caprock during oil recovery enhanced by water and CO2 injection. It was found that the injection of cold water or CO2 in a supercritical state mostly affected horizontal stress components, and the change in vertical stress was negligible. The transition from the initial strike-slip regime to the normal faulting due to formation cooling was closely related to the observed failure zones in hybrid and tensile modes. It has been estimated that changes in the geomechanical state of the oil reservoir can increase the formation permeability by sixteen times (fracture reactivation) to as much as thirty-five times (tensile failure). Despite these events, the integrity of the overburden was maintained in the simulations, demonstrating the safety of enhanced oil recovery with CO2 injection (EOR-CO2) in the selected offshore oil reservoir. Full article
(This article belongs to the Special Issue Advanced Solutions for Carbon Capture, Storage, and Utilization)
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24 pages, 4920 KB  
Article
Modeling of Singlet Oxygen Generation and Thermal Effects During Laser–Tissue Interaction
by Marek Jasiński and Maria Zadoń
Materials 2025, 18(21), 4908; https://doi.org/10.3390/ma18214908 - 27 Oct 2025
Viewed by 462
Abstract
This paper presents an analysis of the phenomena that occur during photodynamic therapy (PDT). For this purpose, models of laser energy deposition, bioheat transfer, and reactions occurring during the PDT process were used. Light distribution was estimated on the base of optical diffusion [...] Read more.
This paper presents an analysis of the phenomena that occur during photodynamic therapy (PDT). For this purpose, models of laser energy deposition, bioheat transfer, and reactions occurring during the PDT process were used. Light distribution was estimated on the base of optical diffusion equation, while for the bioheat analysis the Pennes formula has been used. The PDT reaction model includes equations related to the concentration of triplet oxygen, photosensitizer, and singlet oxygen. The tissue perfusion coefficient and the effective scattering coefficient have been assumed to be thermally damage dependent. Changes in blood velocity in capillary, which affects maximum oxygen supply in PDT model, were also considered. A way of modeling the abnormal vascular pattern in the tumor area was also proposed, and the initial distribution of triplet oxygen in the tumor region was determined on the Krogh cylinder model. At the stage of numerical calculation, the boundary element method, the finite difference method, and the shooting method were used. Full article
(This article belongs to the Section Materials Simulation and Design)
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17 pages, 491 KB  
Article
Psychological Experiences of Ocular Trauma and Traumatic Dental Injury Victims of Police Violence
by Gonzalo Rojas-Alcayaga, Andrea Herrera, Camila Corral Nuñez, Joaquín Varas, Sebastián Córdova, Carolina Lineros and Matías Ríos-Erazo
Dent. J. 2025, 13(10), 481; https://doi.org/10.3390/dj13100481 - 20 Oct 2025
Viewed by 532
Abstract
Background/Objectives: Ocular trauma (OT) and traumatic dental injuries (TDI) inflicted by police officers not only cause significant physical harm, but also psychological trauma. The clinical attention given by health care teams may induce revictimization or retraumatization phenomena, which affect the psychological status [...] Read more.
Background/Objectives: Ocular trauma (OT) and traumatic dental injuries (TDI) inflicted by police officers not only cause significant physical harm, but also psychological trauma. The clinical attention given by health care teams may induce revictimization or retraumatization phenomena, which affect the psychological status of the victim. The objective of this research is to bring to light the psychological experiences related to emergency care processes and rehabilitation of people affected by OT and TDI caused by police violence. Methods: Qualitative research was conducted based on in-depth interviews with eighteen people affected by OT or TDI during the social outbreak in Chile in 2019–2020. Data analysis was based on the principles of grounded theory. Results: Three main categories emerged: quality of interpersonal relationships with health care providers, expectations of care and treatment and psychological consequences. The findings show that retraumatization and revictimization arise from clinical care in the context of state violence. Conclusions: Revictimization and retraumatization are the most characteristic phenomena occurring in the health care of people affected by OT and TDI caused by police violence. The probability of their occurrence depends mainly on the interpersonal relationships established with the health care team and the management of patient expectations regarding health care. Full article
(This article belongs to the Section Restorative Dentistry and Traumatology)
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