Search Results (1,385)

This study proposes an innovative Thermodynamic Activity Controlled Homogeneous Charge Compression Ignition (TAC-HCCI) strategy for diesel–natural gas dual-fuel engines, aiming to achieve high thermal efficiency while maintaining low emissions. By employing numerical simulation methods, the effects of the intake pressure, intake temperature, EGR rate, intake valve closing timing, diesel injection timing, diesel injection pressure, and diesel injection quantity on engine combustion, energy distribution, and emission characteristics were systematically investigated. Through a comprehensive analysis of optimized operating conditions, a high-efficiency and low-emission TAC-HCCI combustion technology for dual-fuel engines was developed. The core mechanism of TAC-HCCI combustion control was elucidated through an analysis of the equivalence ratio and temperature distribution of the in-cylinder mixture. The results indicate that under the constraints of PCP ≤ 30 ± 1 MPa and RI ≤ 5 ± 0.5 MW/m², the TAC-HCCI technology achieves a gross indicated mean effective pressure (IMEPg) of 24.0 bar, a gross indicated thermal efficiency (ITEg) of up to 52.0%, and indicated specific NOx emissions (ISNOx) as low as 1.0 g/kW∙h. To achieve low combustion loss, reduced heat transfer loss, and high thermal efficiency, it is essential to ensure the complete combustion of the mixture while maintaining low combustion temperatures. Moreover, a reduced diesel injection quantity combined with a high injection pressure can effectively suppress NOx emissions. Full article

Participation in organized sport is widely encouraged for youth development, yet positive outcomes are not guaranteed. Parents play a pivotal role in shaping young athletes’ experiences, requiring emotional support, interpersonal skills, and self-regulation. This study examines the meanings parents attribute to their children’s sports participation and how young athletes construct their experiences under parental and coaching influences. An interpretive phenomenological methodology involved semi-structured interviews with coaches, focus groups with parents, and open-ended questionnaires to young athletes. Seventeen players (M = 11.2 years, SD = 0.59), nineteen parents (M = 47.6 years, SD = 3.61), and two coaches from the same football club volunteered to participate in the study. Participants were selected through purposive sampling to ensure a homogeneous experience. The findings reveal that parental involvement balances support and pressure, while trust-building between parents and coaches significantly impacts the athletes’ experiences. The evolving role of technology and the importance of social dynamics within teams also emerged as critical factors. Intrinsic motivation, fostering emotional bonding through the sport, and adopting a developmental rather than purely competitive framework were emphasized factors identified as supporting positive youth sport experiences. These findings offer insights into how interconnected relationships among parents, coaches, and athletes influence children’s sports engagement and development. Full article

While personal thermal comfort is critical for well-being and productivity, it is often overlooked by traditional building management systems that rely on uniform settings. Modern data-driven approaches often fail to capture the complex interactions between various data streams. This pilot study introduces a high-accuracy, interpretable framework for thermal comfort classification, designed to identify the most significant predictors from a comprehensive suite of environmental, physiological, and anthropometric data in a controlled group of young adults. Initially, an XGBoost model using the full 24-feature dataset achieved the best performance at 91% accuracy. However, after using SHAP analysis to identify and select the most influential features, the performance of our ensemble models improved significantly; notably, a Random Forest model’s accuracy rose from 90% to 94%. Our analysis confirmed that for this homogeneous cohort, environmental parameters—specifically temperature, humidity, and CO₂—were the dominant predictors of thermal comfort. The primary strength of this methodology lies in its ability to create a transparent pipeline that objectively identifies the most critical comfort drivers for a given population, forming a crucial evidence base for model design. The analysis also revealed that the predictive value of heart rate variability (HRV) diminished when richer physiological data, such as diastolic blood pressure, were included. For final validation, the optimized Random Forest model, using only the top 10 features, was tested on a hold-out set of 100 samples, achieving a final accuracy of 95% and an F1-score of 0.939, with all misclassifications occurring only between adjacent comfort levels. These findings establish a validated methodology for creating effective, context-aware comfort models that can be embedded into intelligent building management systems. Such adaptive systems enable a shift from static climate control to dynamic, user-centric environments, laying the critical groundwork for future personalized systems while enhancing occupant well-being and offering significant energy savings. Full article

Poor solubility and bioavailability have limited the application of fucoxanthin in drug and functional food processing. In order to encapsulate fucoxanthin in delivery systems, in this study, cellulose was isolated from industrial brown algae residues and high-pressure homogenized into cellulose nanofibrils (CNFs). Then, fucoxanthin was encapsulated into the Pickering emulsion stabilized by the CNFs. The effect of high-pressure homogenization on the characteristics of cellulose and the stability of fucoxanthin emulsion was evaluated. The results indicated that CNFs prepared at 105 MPa had a diameter of 87 nm and exhibited high zeta potential and thermal stability. Encapsulation efficiency peaked at 70.8% with 1.0 mg/mL fucoxanthin, and after three freeze–thaw cycles the encapsulation efficiency was higher than 60%. The DPPH scavenging activity after 12 days’ storage at 4 °C was still 42%. Furthermore, the Pickering emulsion with 1.0 mg/mL fucoxanthin showed high stability and antioxidant activity under different pH values, salinity, temperature, and UV light exposure duration. The CNFs effectively protected fucoxanthin from degradation, offering a novel delivery system for marine bioactive compounds. To the best of our knowledge, this is the first study on the fucoxanthin delivery system of Pickering emulsion stabilized by the CNFs. Such emulsion might benefit the encapsulation and release of bioactive components in marine drugs. Full article

A model for the flow and thermal explosion of a micropolar gas is investigated, assuming the equation of state for a real gas. This model describes the dynamics of a gas mixture (fuel and oxidant) undergoing a one-step irreversible chemical reaction. The real gas model is particularly suitable in this context because it more accurately reflects reality under extreme conditions, such as high temperatures and high pressures. Micropolarity introduces local rotational dynamic effects of particles dispersed within the gas mixture. In this paper, we first derive the initial-boundary value system of partial differential equations (PDEs) under the assumption of spherical symmetry and homogeneous boundary conditions. We explain the underlying physical relationships and then construct a corresponding approximate system of ordinary differential equations (ODEs) using the Faedo–Galerkin projection. The existence of solutions for the full PDE model is established by analyzing the limit of the solutions of the ODE system using a priori estimates and compactness theory. Additionally, we propose a numerical scheme for the problem based on the same approximate system. Finally, numerical simulations are performed and discussed in both physical and mathematical contexts. Full article

Antimicrobial food packaging with natural antimicrobials and biodegradable polymers presents an innovative solution to mitigate microbial contamination, prolong freshness, reduce food waste, and alleviate environmental burden. This study developed antimicrobial hemicellulose-based films by incorporating carvacrol (1% and 2%) as a natural antimicrobial agent through micro-emulsification produced by high-pressure homogenization (M-films). For comparison, films with the same formula were constructed using coarse emulsions (C-films) without high-pressure homogenization. These films were investigated for their antimicrobial efficacy, mechanical and barrier properties, and physicochemical attributes to explore their potential as sustainable antimicrobial packaging solutions. The M-films demonstrated superior antimicrobial activity, achieving reductions exceeding 4 Log CFU/mL against Listeria monocytogenes, Escherichia coli, and Salmonella enterica, compared to the C-films. High-pressure homogenization significantly reduced the emulsion’s particle size, from 11.59 to 2.55 μm, and considerably enhanced the M-film’s uniformity, hydrophobicity, and structural quality. Most importantly, the M-films exhibited lower oxygen transmission (35.14 cc/m²/day) and water vapor transmission rates (52.12 g/m²/day) than the C-films at 45.1 and 65.5 cc/m²/day, respectively, indicating superior protection against gas and moisture diffusion. Markedly improved mechanical properties, including foldability, toughness, and bubble-free surfaces, were also observed, making the M-films suitable for practical applications. This study highlights the potential of high-pressure homogenization as a method for enhancing the functional properties of hemicellulose-based films (i.e., M-films). The fabricated films offer a viable alternative to conventional plastic packaging, paving the way for safer and greener solutions tailored to modern industry needs. Full article

The current study examines the influence of a varying gravity field and its interaction with density stratification. This represents a novel area in baroclinic flow analysis. The classical vortex and internal wave structures in stratified flows are shown to be significantly modified when gravity varies with height. Vortices may shift, stretch, or weaken depending on the direction and strength of gravity variation, and internal waves develop asymmetries or damping that are not present under constant gravity. We examine the influence of gravity variation on the flow of both homogeneous and density-stratified fluids in a channel with topography consisting of a Gaussian obstacle lying at the bottom of the channel. The flow is without inertia, induced by the translation of the top plate. Both the density and gravity are assumed to vary linearly with height, with the minimum density at the moving top plate. The narrow-gap approach is used to generate the flow field in terms of the pressure gradient along the top plate, which, in turn, is obtained in terms of the bottom topography and the three parameters of the problem, namely, the Froude number and the density and gravity gradients. The resulting stream function is a fifth-order polynomial in the vertical coordinate. In the absence of stratification, the flow is smooth, affected rather slightly by the variable topography, with an essentially linear drop in the pressure induced by the contraction. For a weak stratified fluid, the streamlines become distorted in the form of standing gravity waves. For a stronger stratification, separation occurs, and a pair of vortices generally appears on the two sides of the obstacle, the size of which depends strongly on the flow parameters. The influence of gravity stratification is closely coupled to that of density. We examine conditions where the coupling impacts the pressure and the velocity fields, particularly the onset of gravity waves and vortex flow. Only a mild density gradient is needed for flow separation to occur. The influence of the amplitude and width of the obstacle is also investigated. Full article

In the search for alternative protein sources, single cell proteins have gained increasing attention in recent years. Among them, proteins derived from yeast represent a promising but still underexplored option. To enable their application in food product design, their techno-functional properties must be understood. In order to investigate the impact of precipitation pH on their emulsion-stabilizing properties, yeast proteins from Saccharomyces cerevisiae were isolated via precipitation at different pH (pH 3.5 to 5) after cell disruption in the high-pressure homogenizer. Emulsions containing 5 wt% oil and ~1 wt% protein were analyzed for stability based on their droplet size distribution. Proteins precipitated at pH 3.5 stabilized the smallest oil droplets and prevented partitioning of the emulsion, outperforming proteins precipitated at higher pH values. It is hypothesized that precipitation under acidic conditions induces protein denaturation and thereby exposes hydrophobic regions that enhance adsorption at the oil–water interface and the stabilization of the dispersed oil phase. To investigate the stabilization mechanism, the molecular weight of the proteins was determined using SDS-PAGE, their solubility using Bradford assay, and their aggregation behavior using static laser scattering. Proteins precipitated at pH 3.5 possessed larger molecular weights, lower solubility, and a strong tendency to aggregate. Overall, the findings highlight the potential of yeast-derived proteins as bio-surfactants and suggest that pH-controlled precipitation can tailor their functionality in food formulations. Full article

The pull-back method for determining dynamic tensile strength assumes one-dimensional stress wave propagation and material homogeneity. This study validates these assumptions for unidirectional reinforced concrete (UDRC) through experiments and numerical simulations. Split Hopkinson pressure bar tests were conducted on plain concrete, plain UDRC, and deformed UDRC specimens containing a central 6 mm steel bar. Ultra-high-speed digital image correlation at 500,000 fps enabled precise local strain rate measurements (3 s⁻¹ to 55 s⁻¹) at fracture locations. Finite element simulations revealed that while reinforcement induces localized multi-axial stresses near the steel–concrete interface, the bulk concrete maintains predominantly uniaxial stress conditions. Experimental results showed less than 1% variation in pull-back velocity between specimen types. Statistical analysis confirmed a unified strain rate-strength relationship: ${\sigma }_{\mathrm{spall}}=4.1+4.7{log}_{10}\left(\dot{\epsilon }\right)$$\mathrm{M}\mathrm{Pa}$, independent of reinforcement configuration (ANCOVA: $p=0.2182$ for interaction term). The dynamic tensile strength is governed by concrete matrix properties rather than reinforcement type. These findings are the first to experimentally and numerically validate the pull-back method’s applicability to UDRC systems, establishing that dynamic tensile failure is matrix-dominated and enabling simplified one-dimensional analysis for reinforced concrete under impact. Full article

The development of deep coalbed methane (buried depth > 2000 m) in the Yan’an block of Ordos Basin is limited by low permeability, the pore structure of the coal reservoir, and the gas–water occurrence relationship. It is urgent to clarify the key control mechanism of pore structure on gas migration. In this study, based on high-pressure mercury intrusion (pore size > 50 nm), low-temperature N₂/CO₂ adsorption (0.38–50 nm), low-field nuclear magnetic resonance technology, fractal theory and Pearson correlation coefficient analysis, quantitative characterization of multi-scale pore–fluid system was carried out. The results show that the multi-scale pore network in the study area jointly regulates the occurrence and migration process of deep coalbed methane in Yan’an through the ternary hierarchical gas control mechanism of ‘micropore adsorption dominant, mesopore diffusion connection and macroporous seepage bottleneck’. The fractal dimensions of micropores and seepage are between 2.17–2.29 and 2.46–2.58, respectively. The shape of micropores is relatively regular, the complexity of micropore structure is low, and the confined space is mainly slit-like or ink bottle-like. The pore-throat network structure is relatively homogeneous, the difference in pore throat size is reduced, and the seepage pore shape is simple. The bimodal structure of low-field nuclear magnetic resonance shows that the bound fluid is related to the development of micropores, and the fluid mobility mainly depends on the seepage pores. Pearson’s correlation coefficient showed that the specific surface area of micropores was strongly positively correlated with methane adsorption capacity, and the nanoscale pore-size dominated gas occurrence through van der Waals force physical adsorption. The specific surface area of mesopores is significantly positively correlated with the tortuosity. The roughness and branch structure of the inner surface of the channel lead to the extension of the migration path and the inhibition of methane diffusion efficiency. Seepage porosity is linearly correlated with gas permeability, and the scale of connected seepage pores dominates the seepage capacity of reservoirs. This study reveals the pore structure and ternary grading synergistic gas control mechanism of deep coal reservoirs in the Yan’an Block, which provides a theoretical basis for the development of deep coalbed methane. Full article

Span-wise homogeneous supersonic cavity flows display complicated structures due to shear layer breakdown, flow acoustic resonance, and even non-linear hydrodynamic-acoustic interactions. In practical applications, such as aircraft bays, the cavity is of finite width and has doors, both of which introduce distinctive phenomena that couple with the shear layer at the cavity lip, further modulating shear layer bifurcations and tonal mechanisms. In particular, asymmetric states manifest as ‘tornado’ vortices with significant practical consequences on the design and operation. Both inward- and outward-facing leading-wedge doors, resulting in leading edge shocks directed into and away from the cavity, are examined at select opening angles ranging from $22.5°$ to $90°$ (fully open) at Mach 1.6. The computational approach utilizes the Reynolds-Averaged Navier–Stokes equations with a one-equation model and is augmented by experimental observations of cavity floor pressure and surface oil-flow patterns. For the no-doors configuration, the asymmetric results are consistent with a long-time series DDES simulation, previously validated with two experimental databases. When fully open, outer wedge doors (OWD) yield an asymmetric flow, while inner wedge doors (IWD) display only mildly asymmetric behavior. At lower door angles (partially closed cavity), both types of doors display a successive bifurcation of the shear layer, ultimately resulting in a symmetric flow. IWD tend to promote symmetry for all angles observed, with the shear layer experiencing a pitchfork bifurcation at the ‘critical angle’ ($67.5°$). This is also true for the OWD at the ‘critical angle’ ($45°$), though an entirely different symmetric flow field is established. The first observation of pitchfork bifurcations (‘critical angle’) for the IWD is at $67.5°$ and for the OWD, $45°$, complementing experimental observations. The back wall signature of the bifurcated shear layer (impingement preference) was found to be indicative of the 3D cavity dynamics and may be used to establish a correspondence between 3D cavity dynamics and the shear layer. Below the critical angle, the symmetric flow field is comprised of counter-rotating vortex pairs at the front and back wall corners. The existence of a critical angle and the process of door opening versus closing indicate the possibility of hysteresis, a preliminary discussion of which is presented. Full article

Objectives: Sialic acid (SA), a naturally occurring compound abundantly found in birds’ nests, holds immense promise for skincare applications owing to its remarkable biological properties. However, its low bioavailability, poor stability, and limited skin permeability have constrained its widespread application. Methods: To overcome these challenges, SA was encapsulated within nanoliposomes (NLPs) by the high-pressure homogenization technique to develop an advanced and efficient transdermal drug delivery system. The skincare capabilities of this novel system were comprehensively evaluated across multiple experimental platforms, including in vitro cell assays, 3D skin models, in vivo zebrafish studies, and clinical human trials. Results: The SA-loaded NLPs (SA-NLPs) substantially improved the transdermal penetration and retention of SA, facilitating enhanced cellular uptake and cell proliferation. Compared to free SA, SA-NLPs demonstrated a 246.98% increase in skin retention and 1.8-fold greater cellular uptake in HDF cells. Moreover, SA-NLPs protected cells from oxidative stress-induced damage, stimulated collagen synthesis, and effectively suppressed the secretion of matrix metalloproteinases, tyrosinase activity, and melanin production. Additionally, zebrafish-based assays provided in vivo evidence of the skincare efficacy of SA-NLPs. Notably, clinical evaluations demonstrated that a 56-day application of the SA-NLPs-containing cream resulted in a 4.20% increase in L*, 7.87% decrease in b*, 8.45% decrease in TEWL, and 4.01% reduction in wrinkle length, indicating its superior brightening, barrier-repair, and anti-aging effects. Conclusions: This multi-level, systematic investigation strongly suggests that SA-NLPs represent a highly promising transdermal delivery strategy, capable of significantly enhancing the anti-aging, barrier-repair, and skin-brightening properties of SA, thus opening new avenues for its application in the fields of dermatology and cosmeceuticals. Full article

Microalgae proteins are increasingly recognized in the food and nutraceutical industries for their functional versatility and high nutritional value. Mild alkaline treatment is commonly used for cell wall degradation and intracellular protein solubilization, consequently enhancing the protein extraction yield. The findings of this study reveal that alkaline treatment alone, even at higher NaOH concentration (up to 0.3 M) and treatment time (up to 90 min), was ineffective (max. 2.4% yield) for the extraction of protein from Auxenochlorella protothecoides biomass. This challenge was significantly reduced through synergistic application of mechanical cell disruption using high-pressure homogenization (HPH) and alkaline solubilization. Single-pass HPH (35 k psi) alone without alkaline treatment led to 52.3% protein solubilization from wet biomass directly harvested from culture broth, while it was only 18.5% for spray-dried biomass. The combined effect of HPH and alkaline (0.1 M NaOH) treatment significantly increased protein extraction yield to 68.0% for a spray-dried biomass loading of 50 g L⁻¹. Through replacing spray-dried biomass with wet biomass, the requirement of NaOH was reduced by 5-fold to 0.02 M to achieve a similar yield of 68.1%. The process integration of HPH with the mild alkaline solubilization and utilization of wet biomass from culture broth showed high potential for industrialization of microalgae protein extraction. This method achieves high extraction yield while reducing alkaline waste and eliminating the need for energy-consuming drying of biomass, thereby minimizing the environmental impact. Full article

Pangasius (Pangasianodon hypophthalmus) minced muscle with 1 and 2% salt was treated with different high-pressure processing and thermal methods, including conventional heat-induced gels (HIGs), high-pressure processing (HPP) prior to cooking (PC), HPP prior to setting (PS), and setting prior to HPP (SP), to evaluate for their effects on the selected physicochemical properties. The results showed that the PC treatment produced gels with a significantly higher gel strength (496.72–501.26 N·mm), hardness (9.62–10.14 N), and water-holding capacity (87.79–89.74%) compared to the HIG treatment, which showed a gel strength of 391.24 N·mm, a hardness of 7.36 N, and a water-holding capacity of 77.98%. PC gels also exhibited the typical microstructure of pressure-induced gels, with a denser and homogeneous microstructure compared to the rough and loosely connected structure of HIGs. In contrast, SP treatment exhibited the poorest gel quality in all parameters, with gel strength ranging from 319.79 to 338.34 N·mm, hardness from 5.87 to 6.31 N, and WHC from 71.91 to 73.72%. Meanwhile, the PS treatment showed a comparable gel quality to HIGs. SDS-PAGE analysis revealed protein degradation and aggregation in HPP-treated samples, with a decrease in the intensity of myosin heavy chains and actin bands. Fourier-transform infrared spectroscopy (FTIR) analysis showed minor shifts in protein secondary structures, with the PC treatment showing a significant increase in α-helices (28.09 ± 0.51%) and a decrease in random coil content (6.69 ± 0.92%) compared to α-helices (23.61 ± 0.83) and random coil structures (9.47 ± 1.48) in HIGs (p < 0.05). Only the PC treatment resulted in a significant reduction in total plate count (TPC) (1.51–1.58 log CFU/g) compared to 2.33 ± 0.33 log CFU/g in the HIG treatment. These findings suggest that HPP should be applied prior to thermal treatments (cooking or setting) to achieve an improved gel quality in reduced-salt pangasius products. Full article

The Erentaolegai silver deposit is located within the Derbugan metallogenic belt in the eastern segment of the Central Asia–Mongolia giant orogenic belt. The ore bodies are primarily hosted in the volcanic rocks of the Middle Jurassic Tamulangou Formation of the Mesozoic. The mineralization process of the deposit is divided into three stages: Stage I: Pyrite–Quartz Stage; Stage II: Sulfide–Quartz Stage; Stage III: Quartz–Manganese Carbonate Stage. This paper discusses the ore-forming fluids, ore-forming materials, and deposit genesis of the Erentaolegai silver deposits using fluid inclusions microthermometry, laser Raman spectroscopy, and H-O-S isotope analyses. Fluid inclusion microthermometry and laser Raman spectroscopy analyses indicate that the Erentaolegai silver deposit contains exclusively fluid-rich two-phase fluid inclusions, all of which belong to the H₂O-NaCl system. Homogenization temperatures of fluid inclusions in the three stages (from early to late) ranged from 257 to 311 °C, 228 to 280 °C, and 194 to 238 °C, corresponding to salinities of 1.91 to 7.86 wt%, 2.07 to 5.41 wt%, and 0.70–3.55 wt% NaCl equivalent, densities of 0.75 to 0.83 g/cm⁻³, 0.80 to 0.86 g/cm⁻³ and 0.85 to 0.89 g/cm⁻³. The mineralization pressure ranged from 12.2 to 29.5 MPa, and the mineralization depth was 0.41 to 0.98 km, indicating low-pressure and shallow-depth mineralization conditions. H-O isotope results indicate that the ore-forming fluid is a mixture of magmatic fluids and meteoric water, with meteoric contribution dominating in the late stage. The δ³⁴S values of metallic sulfides ranged from −1.8 to +4.0‰, indicating that the metallogenic material of the Erentaolegai silver deposit was dominated by a deep magmatic source. This study concludes that meteoric water mixing and subsequent fluid cooling served as the primary mechanism for silver mineral precipitation. The Erentaolegai silver deposit is classified as a low-sulfidation epithermal silver deposit. Full article