Search Results (29)

Solid oxide fuel cells (SOFCs) are attracting attention as an eco-friendly power source because they show high power density. However, SOFC requires a high-temperature environment of 800 °C or higher, and accordingly, the problem of thermal stability of the material constituting SOFC has been raised. On the other hand, low-temperature solid oxide fuel cells (LT-SOFCs) research is steadily progressing to improve the electrochemical performance at low temperatures by improving the oxygen reduction reaction of the cathode by applying a cathode interlayer of various materials. In this study, LT-SOFCs were manufactured and electrochemically evaluated using praseodymium oxide (PrO_x) as a cathode interlayer. Scandium Stabilized Zirconia (ScSZ) pellets were used as electrolyte support for LT-SOFC, and PrO_x was deposited by various thicknesses as a cathode interlayer on ScSZ pellets by a sputtering process. Pt and Ni were deposited under the same process conditions for the cathode and anode, respectively. To analyze the thin-film characteristics of the PrO_x cathode interlayer, SEM (Scanning Electron Microscopy), X-ray Diffraction (XRD), and XPS (X-ray Photoelectron Spectroscopy) were analyzed. The electrochemical characteristics of LT-SOFCs were evaluated by electrochemical impedance spectroscopy (EIS). Hydrogen was supplied to the anode at the flow rate of 50 sccm, and the performance of LT-SOFC was evaluated at 500 °C by exposing the cathode to the atmosphere. Full article

In recent years, the world scientific community has shown increasing interest in rare earth metals in general and their nanoparticles in particular. Medicine and pharmaceuticals are no exception in this matter. In this review, we have considered the main opportunities and potential applications of rare earth metal (gadolinium, europium, ytterbium, holmium, lutetium, dysprosium, erbium, terbium, thulium, scandium, yttrium, lanthanum, europium, neodymium, promethium, samarium, praseodymium, cerium) nanoparticles in biomedicine, with data ranging from single reports of effects found in vitro to numerous independent in vivo studies, as well as a number of challenges to their potential for wider application. The main areas of application of rare earth metals, including in the future, are diagnosis and treatment of malignant neoplasms, therapy of infections, as well as the use of antioxidant and regenerative properties of a number of nanoparticles. These applications are determined both by the properties of rare earth metal nanoparticles themselves and the need to search for new approaches to solve a number of urgent biomedical and public health problems. Oxide forms of lanthanides are most often used in biomedicine due to their greatest biocompatibility and nanoscale size, providing penetration through biological membranes. However, the existing contradictory or insufficient data on acute and chronic toxicity of lanthanides still make their widespread use difficult. There are various modification methods (addition of excipients, creation of nanocomposites, and changing the morphology of particles) that can reduce these effects. At the same time, despite the use of some representatives of lanthanides in clinical practice, further studies to establish the full range of pharmacological and toxic effects, as well as the search for approaches to modify nanoparticles remain relevant. Full article

In this study, the performance and durability of polymer electrolyte membrane fuel cells (PEMFCs) were improved using a Pt-Pr₆O₁₁ composite electrode fabricated through a co-sputtering technique. Platinum (Pt), widely used as the catalyst material in PEMFCs, often faces stability issues under various electrical load conditions. These issues require greater efforts to enhance PEMFC durability. Various approaches, including replacement of catalyst supports with electrically stable materials (such as metal oxides) or adoption of core-shell and alloy structures to stabilize Pt, have been attempted. In this research, a thin film electrode combining Pr₆O₁₁ and Pt was fabricated. Pr₆O₁₁, a lanthanide oxide, enhances the oxygen reduction reaction (ORR) through strong interactions with Pt, and its multi-valence state contributes to improved durability. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were employed to analyze the composition, morphology, and chemical characteristics of the electrodes. I-V curves and electrochemical impedance spectroscopies (EIS) were measured to evaluate electrochemical properties of fuel cells. A cyclic voltammetry (CV) test was conducted to calculate the electrochemical surface area of the cell. As a result, the incorporation of Pr₆O₁₁ improved the pristine cell performance by 7.6% and increased performance after degradation testing by 121% compared to Pt-only cases. This demonstrates the effectiveness of the Pt-Pr₆O₁₁ composite in enhancing both the initial performance and the durability of PEMFCs. Full article

The praseodymium-doped indium zinc oxide (PrIZO) thin-film transistor (TFT) is promising for applications in flat-panel displays, due to its high carrier mobility and stability. Nevertheless, there are few studies on the mechanism of annealing on PrIZO films and the fabrication of flexible devices. In this work, we first optimized the annealing-process parameters on the glass substrate. As the annealing temperature rises, the film tends to be denser and obtains a lower surface roughness, a narrower optical-band gap and less oxygen-vacancy content. However, the μ-PCD test shows the 250 °C-annealed film obtains the least defects. And the PrIZO TFT annealed at 250 °C exhibited a desired performance with a saturation mobility (μ_sat) of 14.26 cm²·V⁻¹·s⁻¹, a subthreshold swing (SS) of 0.14 V·dec⁻¹, an interface trap density (D_it) of 3.17 × 10¹¹, an I_on/I_off ratio of 1.83 × 10⁸ and a threshold voltage (Vth) of −1.15 V. The flexible devices were prepared using the optimized parameters on the Polyimide (PI) substrate and subjected to static bending tests. After bending at a radius of 5 mm, the mobility of devices decreases slightly from 12.48 to 10.87 cm²·V⁻¹·s⁻¹, demonstrating the great potential of PrIZO for flexible displays. Full article

Ammonia synthesis is one of the most important chemical reactions. Due to thermodynamic restrictions and the reaction requirements of the current commercial iron catalysts, it is also one of the worst reactions for carbon dioxide emissions and energy usage. Ruthenium-based catalysts can substantially improve the environmental impact as they operate at lower pressures and temperatures. In this work, we provide a screening of more than 40 metals as possible promoter options based on a Ru/Pr₂O₃ catalyst. Cesium was the best alkali promoter and was held constant for the series of double-promoted catalysts. Ten formulations outperformed the Ru-Cs/PrO_x benchmark, with barium being the best second promoter studied and the most cost-effective option. Designs of experiments were utilized to optimize both the pretreatment conditions and the promoter weight loadings of the doubly promoted catalyst. As a result, optimization led to a more than five-fold increase in activity compared to the unpromoted catalyst, therefore creating the possibility for low-ruthenium ammonia synthesis catalysts to be used at scale. Further, we have explored the roles of promoters using kinetic analysis, X-ray Photoelectron Spectroscopy (XPS), and in situ infrared spectroscopy. Here, we have shown that the role of barium is to act as a hydrogen scavenger and donor, which may permit new active sites for the catalyst, and have demonstrated that the associative reaction mechanism is likely used for the unpromoted Ru/PrO_x catalyst with hydrogenation of the triple bond of the dinitrogen occurring before any dinitrogen bond breakage. Full article

The development of economical catalysts that exhibit both high activity and durability for chlorinated volatile organic compounds (CVOCs) elimination remains a challenge. The oxidizing and acidic sites play a crucial role in the oxidation process of CVOCs; herein, praseodymium (Pr) was introduced into CrOx catalysts via in situ pyrolysis of MIL-101(Cr). With the decomposition of the ligand, a mixed micro-mesoporous structure was formed within the M-Cr catalyst, thereby reducing the contact resistance between catalyst active sites and the 1,2-dichloroethane molecule. Moreover, the synergistic interaction between chromium and praseodymium facilitates O_β species and acidic sites, significantly enhancing the low-temperature catalytic performance and durability of the M-PrCr catalyst for 1,2-dichloroethane (1,2-DCE) oxidation. The M-30PrCr catalyst possess enhanced active oxygen sites and acid sites, thereby exhibiting the highest catalytic activity and stability. This study may provide a novel and promising strategy for practical applications in the elimination of 1,2-DCE. Full article

The thermal stability of oxyfluorotellurite glass systems, (65-x)TeO₂-20ZnF₂-12PbO-3Nb₂O₅-xPr₂O₃, doped with praseodymium was examined. The different concentrations of praseodymium oxide (x = 0.5 and 2 mol%) were applied to verify the thermal, optical and luminescence properties of the materials under study. The relatively high values of the Dietzel (ΔT) and Saad–Poulain (S or H′) thermal stability factors determined using a differential thermal analysis (DTA) indicate the good thermal stability of the glass matrix, which gradually improves with the content of the active dopant. The temperature dependence of optical spectra in the temperature range 300–675 K for the VIS–NIR region was investigated. The involved Pr³⁺ optical transition intensities and relaxation dynamic of the praseodymium luminescent level were determined. The ultrashort femtosecond pulses were utilized to examine a dynamic relaxation of the praseodymium luminescent levels. Although the measured emission of the Pr³⁺ active ions in the studied glass encompasses the quite broad spectral region, the observed luminescence may only be attributed to ³P_J excited states. As a result, the observed decrease in the experimental lifetime for the ³P₀ level along with the increasing activator content was identified as an intensification of the Pr–Pr interplay and the associated self-quenching process. The maximum relative sensitivities (S_r) estimated over a relatively wide temperature range are ~0.46% K⁻¹ (at 300 K) for FIR (I₅₃₀/I₄₉₇) and 0.20% K⁻¹ (at 600 K) for FIR (I₆₃₀/I₄₉₇), which seems to confirm the possibility of using investigated glasses in optical temperature sensors. Full article

This paper is devoted to the study of active and stable nickel catalysts for methane dry reforming based on Pr-doped ceria–zirconia obtained via the solvothermal continuous method. Studies on the physicochemical and catalytic properties of the 5%Ni/Ce_0.75Zr_0.25−xPr_xO₂ series have showed that Pr introduction leads to an increase in the amount of highly reactive oxygen in the oxide lattice. Praseodymium-based catalysts showed significantly higher reactant conversions. In addition to the nature of support, the method of nickel introduction was also studied; Ni was added both using impregnation and the one-pot procedure with mixed oxide preparation. The method of Ni addition was shown to have significant effect on the morphology of its particles and Ni-support interaction, and, respectively, on catalytic activity and coking stability. The 5%Ni/Ce_0.75Zr_0.15Pr_0.1O₂ catalyst prepared by one-pot method showed stable operation in the MDR reaction for 30 h at CO₂ and CH₄ conversions of ~40% and an H₂ yield of ~18% (T = 700 °C, τ = 10 ms). Full article

Our research contributes a new point of view on China’s rare earth dynamic risk spillover measurement; this was performed by combining complex network and multivariate nonlinear Granger causality to construct the time-varying connectedness complex network and analyze the formation mechanism using the impulse response. First, our empirical research found that for the dynamic characteristics of China’s rare earth market, due to instability, uncertainty, and geopolitical decisions, disruption can be captured well by the TVP-VAR-SV model. Second, except for praseodymium, oxides are all risk takers and are more affected by the impact of other assets, which means that the composite index and catalysts are main sources of risk spillovers in China’s rare earth trading complex network system. Third, from the perspective of macroeconomic variables, there are significant multivariate nonlinear impacts on the total connectedness index of China’s rare earth market, and they exhibit asymmetric shock characteristics. These findings indicate that the overall linkage of the risk contagion in China’s rare earth trading market is strong. Strengthening the interconnections among the rare earth assets is of important practical significance. Empirical results also provide policy recommendations for establishing trading risk protection measures under macro-prudential supervision. Especially for investors and regulators, rare earth oxides are important assets for risk mitigation. When rare earth systemic trading risk occur, the allocation of oxide rare earth assets can hedge part of the trading risk. Full article

The applications of thin-film transistors (TFTs) based on oxide semiconductors are limited due to instability under negative bias illumination stress (NBIS). Here, we report TFTs based on solution-processed In₂O₃ semiconductors doped with Pr⁴⁺ or Tb⁴⁺, which can effectively improve the NBIS stability. The differences between the Pr⁴⁺-doped In₂O₃ (Pr:In₂O₃) and Tb⁴⁺-doped In₂O₃ (Tb:In₂O₃) are investigated in detail. The undoped In₂O₃ TFTs with different annealing temperatures exhibit poor NBIS stability with serious turn-on voltage shift (ΔV_on). After doping with Pr⁴⁺/Tb⁴⁺, the TFTs show greatly improved NBIS stability. As the annealing temperature increases, the Pr:In₂O₃ TFTs have poorer NBIS stability (ΔV_on are −3.2, −4.8, and −4.8 V for annealing temperature of 300, 350, and 400 °C, respectively), while the Tb:In₂O₃ TFTs have better NBIS stability (ΔV_on are −3.6, −3.6, and −1.2 V for annealing temperature of 300, 350, and 400 ℃, respectively). Further studies reveal that the improvement of the NBIS stability of the Pr⁴⁺/Tb⁴⁺:In₂O₃ TFTs is attributed to the absorption of the illuminated light by the Pr/Tb4fⁿ—O2p⁶ to Pr/Tb 4fⁿ⁺¹—O2p⁵ charge transfer (CT) transition and downconversion of the light to nonradiative transition with a relatively short relaxation time compared to the ionization process of the oxygen vacancies. The higher NBIS stability of Tb:In₂O₃ TFTs compared to Pr:In₂O₃ TFTs is ascribed to the smaller ion radius of Tb⁴⁺ and the lower energy level of Tb 4f⁷ with a isotropic half-full configuration compared to that of Pr 4f¹, which would make it easier for the Tb⁴⁺ to absorb the visible light than the Pr⁴⁺. Full article

This research investigated recycling of manufacturing NdFeB magnet wastes in as-sintered and powder forms which contained high carbon via pyro-hydro metallurgy process. Effects of oxidative roasting on selective leaching of the magnet wastes were the main focus in comparison to recycling via whole leaching without oxidative roasting. The process started from oxidative roasting at 600 °C, sulfuric leaching, drying, roasting at 750 °C for powder and 800 °C for sintered wastes, water leaching, oxalic acid precipitation and calcination at 1000 °C to obtain neodymium oxides. Oxidative roasting was found to reduce carbon and resulted in neodymium and iron oxide formation with a minimum amount of neodymium iron oxide. This provided effective selective leaching of neodymium. For whole leaching, a significant loss of neodymium into leached residue was observed. Oxidative roasting-selective leaching provided significant recovery in the amount of 75.46% while whole leaching resulted in only 31.62 wt.% in the case of sintered waste. The final composition via oxidative roasting-selective leaching consisted of 68.11 wt.% neodymium, 19.83 wt.% praseodymium and 0.31 wt.% iron, while whole leaching resulted in a higher amount of iron at 1.20 wt.%. Similar results were obtained for powder magnet waste. Full article

Phases based on layered lanthanide nickelates are considered as promising electrode materials for various electrochemical devices, including solid oxide fuel cells and electrolysis cells. While such compounds may be prepared using either solid state or solution-assisted syntheses, each of these approaches entails certain problems. In the present work, we propose a novel approach for the simple and straightforward preparation of Pr₂NiO_4+δ-based materials. This approach involves co-melting of initial nitrate components, followed by high-temperature decomposition of the obtained mixture. The developed synthesis method exhibits a number of advantages over conventional techniques, enabling highly dispersed and single-phase powders to be obtained at a reduced synthesis temperature of 1050 °C. Therefore, the results of this work open new possibilities for the cost-effective preparation of Ruddlesden–Popper oxide phases. Full article

We report water-induced nanometer-thin crystalline indium praseodymium oxide (In-Pr-O) thin-film transistors (TFTs) for the first time. This aqueous route enables the formation of dense ultrathin (~6 nm) In-Pr-O thin films with near-atomic smoothness (~0.2 nm). The role of Pr doping is investigated by a battery of experimental techniques. It is revealed that as the Pr doping ratio increases from 0 to 10%, the oxygen vacancy-related defects could be greatly suppressed, leading to the improvement of TFT device characteristics and durability. The optimized In-Pr-O TFT demonstrates state-of-the-art electrical performance with mobility of 17.03 ± 1.19 cm²/Vs and on/off current ratio of ~10⁶ based on Si/SiO₂ substrate. This achievement is due to the low electronegativity and standard electrode potential of Pr, the high bond strength of Pr-O, same bixbyite structure of Pr₂O₃ and In₂O₃, and In-Pr-O channel’s nanometer-thin and ultrasmooth nature. Therefore, the designed In-Pr-O channel holds great promise for next-generation transistors. Full article

The activity of emission control catalysts must be improved in urban mode at low temperatures. One possible way is to tailor the metal-support interaction between platinum group metals (PGMs) and ceria to stabilize small clusters or single atoms, optimizing the utilization of costly PGMs. In this study, a small loading of Pd (<0.2 wt.%) was dispersed on Pr-rich cerium–zirconium–praseodymium mixed oxides (CZP45: Ce_0.45Zr_0.10Pr_0.45O_2−x). After the initial calcination at 800 °C, Pd was mainly in the form of dispersed isolated cations which were found to be efficient for low-temperature CO oxidation but inactive for propane combustion. Nevertheless, a pre-reduction step can trigger the formation of Pd nanoparticles and promote the propane oxidation. Pd nanoparticles, formed during the reduction step, coupled with the high oxygen mobility of CZP45, lead to outstanding catalytic activity for propane oxidation starting from 250 °C. However, the re-oxidation of Pd nanoparticles and their partial re-dispersion, promoted by the fast oxygen mobility of the mixed oxide, rapidly deactivate the catalysts in lean conditions. Full article

The impact of rare earth oxide (REO) concentration on the deposition process and selective recovery of the metal being deposited from a molten fluoride salt system was investigated by applying deposition of Nd and Pr and varying the concentration of REO added to the electrolyte. A ternary phase diagram for the liquidus temperature of the NdF₃-PrF₃-LiF system was constructed to better predict the optimal electrolyte constitution. Cyclic voltammetry was used to record three redox signals, reflecting the processes involving Nd(III)/Nd and Pr(III)/Pr transformations. A two-step red/ox process for Nd(III) ions and a single-step red/ox process for Pr(III) ions were confirmed by square-wave voltammetry. The cyclic voltammetry results indicated the possibility of neodymium and praseodymium co-deposition. In order to sustain higher co-deposition rates on the cathode and to avoid increased production of PFC greenhouse gases on the anode, a low-overpotential deposition technique was used for Nd and Pr electrodeposition from the electrolyte with varying Nd₂O₃ and Pr₆O₁₁ concentrations. Co-deposited neodymium and praseodymium metals were characterized by electron probe microanalysis (EPMA) and X-ray diffraction (XRD) analysis. After electrodeposition, concentration profiles of neodymium and praseodymium were recorded, starting from the cathode surface towards the electrolyte bulk. The working temperature of 1050 °C of the molten fluoride salt basic electrolyte, in line with the constructed phase diagram, was validated by improved co-deposition and led to a more effective deposition process. Full article