Search Results (31)

This study investigated ten potential toxic metals (PTMs) in six milk and dairy product types and evaluated food safety (TDI, RDA), human exposure (EDI), non-carcinogenic risk (THQ, HI), and contamination levels (CF, PLI). Based on total PTM load, products ranked as: children’s milk > yogurt > protein milk > milk > ayran > kefir. Aluminum (Al) showed the highest average concentration in all products except ayran, where manganese (Mn) was dominant. Cadmium (Cd), mercury (Hg), and lead (Pb) were consistently at the lowest levels. Except for chromium (Cr) exposure from children’s milk, all average and maximum EDI values stayed below TDI and RDA thresholds. Children’s milk had the highest non-carcinogenic risk, while yogurt, kefir, milk, and ayran may also pose potential risks when maximum HI values are considered. Although CF values varied across products, PLI results showed all products had high levels of PTM contamination. Given the widespread consumption of dairy across all age groups, especially by sensitive populations like children, monitoring and controlling PTM levels is crucial alongside ensuring nutritional quality. Full article

Understanding pollution levels, ecological health risks, and sources of potentially toxic metals (PTMs) in the soil from university campuses is critical for assessing environmental safety. Soil samples were collected from 12 locations across urban parks and green areas at Sohag University in Egypt. The samples were processed and analysed for heavy metals, including iron (Fe), manganese (Mn), cobalt (Co), nickel (Ni), chromium (Cr), lead (Pb), zinc (Zn), copper (Cu), and cadmium (Cd). Pollution levels were evaluated using indices such as the pollution index (PI), pollution load index (PLI), geo-accumulation index (I_geo), and enrichment factors (EFs). Among the pollution indices, the EFs showed the highest sensitivity in detecting anthropogenic contributions, particularly for Cd, Pb, and Cr. Spatial distribution maps and multivariate statistical analyses, including correlation matrix (CM), principal component analysis (PCA), and cluster analysis (CA), were applied to identify the relationships between PTMs and soil properties, and source apportionment was performed using positive matrix factorisation (PMF). The results indicated that Mn, Ni, and Co were primarily geogenic, whereas Pb, Zn, Cr, and Cd showed higher concentrations, suggesting moderate-to-significant anthropogenic pollution. Pb and Cd pose considerable ecological risks, whereas other metals such as Cr and Cu exhibit moderate ecological threats. The non-carcinogenic and carcinogenic risks to the students were within safe limits, as defined by United States Environmental Protection Agency (USEPA) threshold values. Source apportionment using PMF identified five main sources of PTMs: industrial and anthropogenic activities (30.0%), traffic emissions (25.0%), natural soil processes (20.0%), agricultural practices (15.0%), and mixed industrial traffic sources (10.0%). These findings emphasise the importance of controlling anthropogenic activities to ensure a safer campus environment. Full article

Multivariate and statistical tool advancements help to assess potential pollution threats, their geochemical distribution, and the competition between natural and anthropogenic influences, particularly on sediment contamination with potentially toxic metals (PTMs). For this, riverine sediments from 25 locations along urban banksides of the River Ravi, Pakistan, were collected and analyzed to explore the distribution, pollution, ecological, and toxicity risk indices of PTMs like Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Sn, Sr, V, and Zn using Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES) technique. Additionally, techniques such as X-ray Diffraction (XRD) and Scanning Electron Microscopy–Energy Dispersive X-ray Spectroscopy (SEM-EDS) were employed to investigate the mineralogical and morphological aspects. The results indicated that mean concentrations (mg kg⁻¹) of Cd (2.37), Cr (128), Hg (16.6), Pb (26.6), and Sb (2.44) were significantly higher than reference values given for upper continental crust (UCC) and world soil average (WSA), posing potential threats. Furthermore, the geochemical pollution indices showed that sediments were moderately polluted with Cd (I_geo = 2.37, EF = 12.1, and CF = 7.89) and extremely polluted with Hg (I_geo = 4.54, EF = 63.2, and CF = 41.41). Ecological and toxicity risks were calculated to be extremely high, using respective models, predominantly due to Hg (Er_i = 1656 and ITRI = 91.6). SEM-EDS illustrated the small extent of anthropogenic particles having predominant concentrations of Zn, Fe, Pb, and Sr. Multivariate statistical analyses revealed significant associations between the concentrations of PTMs and the sampling locations, highlighting the anthropogenic contributions linked to local land-use characteristics. The present study concludes that River Ravi sediments exhibit moderate levels of Cd and extreme pollution by Hg, both of which contribute highly to extreme ecological and toxicity risks, influenced by both natural and anthropogenic contributions. Full article

Forest ecosystems and urban parks are an integral part of the natural environment and the natural system of a city, where they form a mosaic of habitats resulting from the variation in soil cover due to human activities. The study was conducted in urban forests in five urban parks in Upper Silesia (southern Poland) and investigated the chemical properties and content of potentially toxic metals (PTMs) in the topsoil, which had an average thickness of 15 cm for all samples. The soil reaction ranged from acidic (pH = 4.7–5.1, in KCl) to slightly acidic (pH = 5.6, to neutral—6.6–7.2) at most sites. The organic carbon (OC) content was relatively high at all sites, ranging from 1.19 to 14.3%, with the highest total nitrogen (Nt) content being 0.481%. The average total phosphorus (Pt) content in the parks ranged from 310 mg kg⁻¹ to 684 mg kg⁻¹, while the highest values were 1840 mg kg⁻¹. The total Cr, Cu, Co and Ni content was within acceptable limits, while the Zn, Pb, Cd, As, Sr and Ba exceeded acceptable standards. In terms of content, Zn dominated the PTMs at each site (Zn > Pb > Ba > Sr > Cu > Cr > As > Ni > Cd > Co), while Ba and Pb alternated in taking second place (Zn > Ba > Pb > Sr > Cu > Cr > Ni > As > Co > Cd). Environmental indicators, such as the geoaccumulation index (Igeo), enrichment factor (EF) and potential ecological risk index (RI), showed that the analyzed soils are highly contaminated with PTMs. Among the sources of pollution in the urban forest are low emissions from coal combustion, industrial activities, water runoff from streets and proximity to transportation routes. Identification of PTM levels in urban parks will provide valuable information on the behavior of these metals, which is important in sustainable development and can help evaluate the local spatial development plans of urbanized areas. Full article

The aim of the study was to assess the impact of the specialization of agricultural production on selected parameters of soil health, i.e., soil organic carbon content (SOC), soil acidification, soil nutrient status, i.e., total nitrogen content (N_T), available forms of phosphorus, potassium, and magnesium, and microelements content, as well as the content of selected potentially toxic metals (PTMs). For the study, 18 farms located in the Masovian Voivodeship in Central Poland were selected. They were grouped into six types, and each type was represented by three farms. The study included organic farms; farms specializing in: crop, vegetable, poultry, dairy cattle, and pigs production. A total of 144 soil samples were analyzed. The results showed that the specialization of agricultural production and fertilizer management had a significant impact on most of the tested soil health parameters, except SOC and N_T content. Despite the high organic fertilizer doses introduced into soils in poultry (170 kg N per hectare as poultry manure) and pig farms (150 kg N per hectare as pig manure), there was no significant influence of these amendments on SOC content. This may indicate low organic carbon sequestration potential in some Polish agricultural soils. Organic farms had the lowest levels of plant nutrients in the tested soil samples, which may limit soil productivity. All the tested soils were strongly acidified, which could restrict both production and regulatory soil functions. Based on the synthetic index of soil fertility (SSFI), vegetable and poultry farms were characterized by very high fertility, while crop, dairy cattle, and pig farms fell into the medium fertility class. Organic farms were in the lowest fertility class. However, the study suggests that the SSFI may not be the best indicator for assessing soil fertility and health; therefore, further research is needed. Full article

In recent years, there has been a growing concern about the negative impact of unforeseen contaminants such as metals in commonly consumed food items, which pose a threat to human well-being. Therefore, it is of utmost importance to evaluate the levels of these contaminants to guarantee the safe consumption of these food items. The goal of the current research is to determine the levels of essential (EMs: Mg, Ca, Mn, Fe, Co, Cu, and Zn) and potentially toxic metals (PTMs: Al, Cr, Ni, As, Cd, and Pb) in various brands of wheat-based sweets. One hundred samples were collected and analysed via flame atomic absorption spectrometry (FAAS) and inductively coupled plasma–optical emission spectrometry (ICP-OES). Also, the current study was to investigate the distribution, correlation, and multivariate analysis of 13 metals (Mg, Ca, Mn, Fe, Co, Cu, Zn, Al, Cr, Ni, As, Cd, and Pb). Hierarchical cluster analysis (HCA) and principal component analysis (PCA) were used to interpret the metals’ association. The concentration (mg/kg) ranges of EMs were, in order, Mg (12.70–65.67), Ca (24.02–209.12), Mn (1.32–9.61), Fe (4.55–111.23), Co (0.32–8.94), Cu (2.12–8.61), and Zn (2.60–19.36), while the concentration (mg/kg) ranges of PTMs were, in order, Al (0.32–0.87), Cr (0.17–5.74), Ni (0.36–1.54), Cd (0.16–0.56), and Pb (0.14–0.92), and As was not detected in any sample under investigation. The HCA data revealed that Co, Al, and Ni form clusters with other metals. Sweets are prepared at high temperatures, and the elevated temperatures can increase the likelihood of Ni and Al leaching from stainless steel. Tolerable dietary intake (TDI) values for Ni were higher than the values established by the European Food Safety Authority (EFSA). The CR value found for the Ni and Cr was at the threshold level of cancer risk, if an amount of 25 g were to be used over a lifetime. In a nutshell, this study highlights the monitoring of EM and PTM levels in wheat-based sweets, and from a food safety perspective, the study is important for consumers of wheat-based sweets. Full article

Prenatal exposure to potentially toxic metals (PTM) may impair fetal growth (FG). We investigated the relationship between maternal exposure to lead (Pb), cadmium (Cd) and manganese (Mn) and birth weight (BW) of 74 newborns. Blood was collected during the second trimester of pregnancy to determine Pb (PbB) and Cd (CdB), while hair (MnH) and toenails (MnTn) were used for Mn. Samples were analyzed by graphite furnace atomic absorption spectrophotometry (GFAAS). Sociodemographic and BW data were collected from questionnaires and maternity records, respectively. The medians (P25th–P75th) of PbB, CdB, MnH, and MnTn were, respectively, 0.9 (0.5–1.8) µg/dL; 0.54 (0.1–0.8) µg/L; 0.18 (0.1–0.4) µg/g; and 0.65 (0.37–1.22) µg/g. The means (standard deviation) of birth weight according to sex were 3067 (426.3) and 3442 (431) grams, respectively, for girls and boys. MnTn presented an inverse correlation with the BW/gestational age ratio for girls (rho = −0.478; p = 0.018), suggesting the effect of sex modification. Although BW correlation with CdB was not statistically significant, hierarchical linear regression (beta = −2.08; 95% CI–4.58 to 0.41) suggested a fetotoxic effect. These results confirmed the threat PTMs may represent and the need for more extensive research to elucidate their role in inadequate FG in developing countries. Full article

This study is focused on the environmental geochemistry of potentially toxic metals (PTMs)-bearing products and wastes in a mining area in Djebel Onk (NE Algeria) and their potential ecological and health risk assessment. Representative samples from (i) commercial products and (ii) grain size classes of wastes were mineralogically characterized using X-ray diffraction. The major and PTMs elements in the samples were chemically analyzed via ICP-AES and ICP-MS, respectively. The results reveal that the samples were mostly composed of carbonate fluorapatite (P₂O₅ > 24 wt %) and yielded PTM concentrations within the average range of phosphorites in neighboring countries and worldwide deposits as well. The concentrations of V, Cd, As, Ni, and Pb in the products were found to be within the acceptable values according to various standards, such as the Canadian and German Fertilizer Ordinance policies. Geochemically, PTMs distribution is linked to the main sub-composition of phosphate rock (apatite, clay, and dolomite). The Enrichment Factors (EF) display very-high-to-extremely-high enrichment of PTMs (Cr, Zn, As, Sr, Mo, Cd, Sb, Tl, Th, and U), while V, Co, Cu, Ni, Zr, Ga, Nb, and Pb show minor and moderate-to-high enrichments. Among all the PTMs, Cd, Tl, and U display a very high ecological risk (PERI) and contribute most to the total risk index (RI). The human health risk assessment of PTMs represented by the Hazard Index (HI) indicates that the non-carcinogenic risks are below the threshold values (HI < 1), while the HI values are higher for children than they are for adults. However, the cancer index (life time cancer risk) for Cr, Ni, As, and Cd for children and Cd for adults is greater than the acceptable threshold. These results are useful for phosphate beneficiation via removing these PTMs from the commercial product for efficient waste management. Full article

The present field-based study aimed to determine the levels of six potentially toxic metals (PTM)s (Cd, Cu, Fe, Ni, Pb, and Zn determined using a flame atomic-absorption spectrophotometer) using transplanted green-lipped mussel Perna viridis from a polluted site at Kampung Pasir Puteh (KPP) to unpolluted sites at Kampung Sungai Melayu (KSM) and Sungai Belungkor (SB) in the Johore Straits (SOJ), and to estimate the human health risks of the PTMs after the depuration periods. Interestingly, after 10 weeks of depuration in the two unpolluted sites, there were 55.6–88.4% and 51.3–91.7% reductions of the six PTMs after transplantation from KPP to SB and KSM, respectively. Lower risks of health assessments were recorded and judged on the present findings of significantly (p < 0.05) lower levels of safety guidelines, significantly (p < 0.05) lower values of target hazard quotient, and significantly (p < 0.05) lower values of estimated weekly intake, of all the six PTMs after 10 weeks of depuration of the transplanted polluted mussels to the two unpolluted sites in the SOJ. Thus, further reducing the noncarcinogenic risks of the PTMs to the consumers. From an aquacultural point of view, this depuration technique can be recommended to reduce the health risks of PTMs to mussel consumers. Full article

The present study aimed to assess the human health risks of six potentially toxic metals (PTMs) (Cd, Cu, Fe, Ni, Pb and Zn) in 21 populations of popular mangrove snails, Cerithidea obtusa, collected from Malaysia. In general, the concentrations (mg/kg wet weight) of Cd (0.03–2.32), Cu (11.4–35.2), Fe (40.9–759), Ni (0.40–6.14), Pb (0.90–13.4) and Zn (3.11–129) found in the snails in all populations were lower than the prescribed maximum permissible limits (MPL)s for Cd, Cu, Ni, Pb and Zn. However, in the investigated snail populations, Cd (14%), Pb (62%), Cu (19%), and Zn (10%) were found in exceedance of the MPL of the respective metal. The target hazard quotient (THQ) values in all populations for Cu, Ni, Fe and Zn were all found to be below 1.00. However, for the THQ values of Cd and Pb, two populations exceeded 1.00, while others were below the threshold level. The estimated weekly intake (EWI) of all six metals for all populations was only 0.03–4.65% of the provisional tolerable weekly intake. This conclusively indicates that, based on the EWI, there are no health risks of the six PTMs in the consumption of snails from Malaysia since the assessments are dependent on the consumers’ body weight and consumption rate. Nonetheless, the present results indicate that the amounts of snails consumed should be limited to minimize the potential health risks of PTMs to consumers. The relatively low and weak but positive correlations of Cu, Ni, Pb and Zn between C. obtusa and their habitat sediments indicate that C. obtusa can be a potential biomonitor for Cu, Ni, Pb and Zn. This is important for effective mangrove management from the perspective of the sustainable resources from the intertidal mangrove environment. Hence, the biomonitoring–health risk nexus of PTMs in mangrove snails is proposed in the present study. Full article

The present study was carried out to describe the characteristic features of potentially toxic metals (PTMs) in the soil of industrial city, Kolchugino–Vladimir Region–Russia. The mass fractions in mg/kg of Cu, Pb, Zn, and Cd were measured by atomic absorption spectrometer (AAS). Multivariate statistical analysis and hierarchical cluster analysis (HCA), were performed. The obtained results of the potentially toxic elements were mapped using ArcGIS. A total of four pollution indices were calculated to identify the areas with significant pollution associations. The data analysis showed that locations 14 (urban area) and 16 (non-ferrous metallurgy plant) contribute significantly to pollution. Maximum likelihood method was used to classify the land-use and land-cover (LULC). The analysis shows that locations 14 and 16 are belonging to the industrial area on LULC. Great attention should be paid to the control and regulation of waste disposal into the environment, which in turn, has an adversely impact on human health. By using the data, it could help to identify areas where waste control measures need to be implemented, such as increasing recycling or introducing more waste control legislation. It could also help to identify areas where waste control efforts have been successful. Data can be used by government, policymakers, and stakeholders for future planning and R&D activities. Full article

Exposure to potentially toxic metals (PTM) threatens maternal and child health. We investigated the determinants of exposure to lead (Pb), cadmium (Cd), arsenic (As), and manganese (Mn) in 163 pregnant women from the Recôncavo Baiano, Brazil, enrolled in the DSAN-12M cohort. We measured these metals in biological samples (blood, toenails, and hair) and the Pb dust loading rates (RtPb) at their homes by graphite furnace atomic absorption spectrophotometry (GFAAS). Questionnaires were applied to collect sociodemographic and general habits data. Only 2.91% (n = 4) of the pregnant women had As levels above the detection limit. Few participants had levels above the recommended reference values for blood Pb (5.1; 95% CI: 2.1–10.1%), and Mn in hair or toenails (4.3; 95% CI: 2.3–10.1%). On the other hand, 61.1 (95% CI: 52.4–69.3%) had elevated blood Cd levels. After binary logistic regression, low socioeconomic status, domestic waste burning, being a passive smoker, multiparity, and renovating the house significantly increased the chances of having high levels of Mn, Pb, and Cd. We detected a worrying situation related to exposure to Cd, showing the urgency of implementing human biomonitoring in the general population, especially in situations of social vulnerability. Full article

The present study evaluated the potentials of phytoremediation and the biomonitoring of potentially toxic metals (PTMs) (Zn, Ni, Fe, Pb, and Cu) in the mangrove leaves of Rhizophora apiculata from the tropical mangrove ecosystem in the Sepang Besar River and Lukut River, Peninsular Malaysia. Overall, the present studies concluded that (a) the levels of essential Fe, Cu, and Zn in lamina are significantly (p < 0.05) higher than in MP, (b) the levels of Pb and Ni in MP are significantly (p < 0.05) higher than in lamina, (c) the lamina has better potential as a phytoremediator of Cu, Zn, and Fe, while MP is a better potential phytoremediator of Pb and Ni, (d) lamina is a potential biomonitoring agent of potentially toxic metals based on better correlation coefficients with the surface sedimentary geochemical fractions, and (e) metal uptake in the mangrove leaves and comparative levels of metals is low with reported studies. Specifically, based on bioconcentration factors (BCF), their most obtained values were considered low (<1), suggesting that R. apiculata can be considered as a low-efficiency plant for the bioaccumulation of PTM. However, the present findings also suggested that R. apiculata may be classified as a potential phytoremediator for Zn, Cu, Pb, and Ni in the leaves, as indicated by higher metal accumulation in the MP, with BCF_EFLE values > 1.0; BCF_AR > 1.0 for Cu, Pb, and Ni. The mangrove leaves are potential biomonitors of PTMs since positive correlations of PTMs were found between the leaves and their habitat surface sediments. Having been identified as a potential phytoremediator and biomonitor of PTMs, the present study emphasized the possibility of establishing a framework for managing the coastal aquatic ecosystems along the mangrove ecosystems of Sepang and Lukut. Full article

Mine tailings are a source of potentially toxic metals (PTMs) worldwide. Phytoremediation is a low-cost green technology that uses metal-tolerant plants to extract these contaminants and rehabilitate the soil. In mine tailing restoration efforts, it can be beneficial to introduce species that can facilitate the colonization of other plants (i.e., nurse plant syndrome). In this study, the phytoremediation and nursing potential of two species adapted to metalliferous soil, Aloe burgersfortensis and A. castanea, were evaluated for the first time. An experiment was performed with aloe plants grown in pots containing potting soil, platinum tailings, and gold tailings. Leaves were assessed for bioaccumulation of PTMs. Seeds of Bermuda grass and African daisy, two successional pioneers, were planted with the aloes and had their developmental parameters evaluated after 30 days. Allelopathic effects were also assessed, with seeds of the pioneer plants infused with root extracts of the aloes from the different soil treatments. A. castanea demonstrated greater potential for the bioaccumulation of Cd, Co, Mn, Ni, and Zn in the tailings. The presence of aloes benefited germination rates, leaf count, length, and plant biomass of grasses and daisies in the mine tailings, without significant allelopathic effects. Therefore, aloes—especially A. castanea—should be employed in the rehabilitation of metal-contaminated soils to extract metals and to aid the establishment of other species to enhance the phytoremediation processes. Full article

To investigate the leaching characteristics and potential environmental effects of potentially toxic metals (PTMs) from alum mine tailings in Lujiang, Anhui Province, soaking tests and simulated rainfall leaching experiments were conducted for two types of slag. PTMs comprising Cd, Cr, Cu, Mn, and Ni were detected in the slag. Cu and Cd contents exceeded the national soil risk screening values (GB 15618-2018). pH values of the two slag soaking solutions were negatively correlated with the solid:liquid ratio. pH values of the sintered slag soaking solutions with different solid:liquid ratios finally stabilized between 4.4 and 4.59, and those of the waste slag soaking solutions finally stabilized between 2.7 and 3.4. The concentrations of Cd, Cr, Cu, Mn, and Ni leached from waste slag were higher than those from sintered slag, and the dissolved concentrations of these PTMs in sintered slag were higher under rainfall leaching conditions than soaking conditions (the difference in Cr concentration was the smallest, 5.6%). The cumulative release of Cd, Cr, Cu, Mn, and Ni increased as the leaching liquid volume increased. The kinetic characteristics of the cumulative release of the five PTMs were best fitted by a double constant equation (R² > 0.98 for all fits). Single factor index evaluations showed that Mn and Ni were the PTMs with high pollution degrees (P_i for Mn and Ni exceed 1) in the leaching solutions. However, considering the biotoxicity of PTMs, the water quality index evaluations showed that the water quality of the sintered slag soaking solution, the waste slag soaking solution, and the sintered slag leachate was good, poor, and undrinkable, respectively. The health risk assessment showed that the total non-carcinogenic risk (HI) values in adults for both the sintered slag leachate and waste slag soaking solution exceeded the safe level of 1, with HI values of 3.965 and 2.342, respectively. The hazard quotient (HQ) for Cd was 1.994 for the sintered slag leachate, and Cd and Cr make up 50.29% and 15.93% of the total risk, respectively. Cr makes up 28.38% of the total risk for the waste slag soaking solution. These results indicate a high non-carcinogenic risk of exposure to Cd and Cr in the leaching solution used for drinking purposes. These findings may provide a reference for the evaluation and ecological control of PTM pollution in alum mining areas. Full article