Search Results (1,118)

While the Ankom RF system facilitates efficient high-throughput in vitro fermentation studies, its high cost and limited flexibility constrain its broader applicability. To address these limitations, we developed and validated a low-cost, modular gas monitoring system (FerME), assembled from commercially available components. To evaluate its performance and reproducibility relative to the Ankom RF system (Ankom Technology, Macedon, NY, USA), in vitro rumen fermentation experiments were conducted under strictly controlled and identical conditions. Whole rumen contents were collected approximately 2 h post-feeding from individual mid- or late-lactation dairy cows and immediately transported to the laboratory. Each fermenter received 50 mL of processed rumen fluid, 100 mL of anaerobically prepared artificial saliva buffer, and 1.2 g of the donor cow’s diet. Bottles were sealed with the respective system’s pressure sensors, flushed with CO₂, and incubated in a 50 L water bath maintained at 39 °C. FerME (New Taipei City, Taiwan) and Ankom RF fermenters were placed side-by-side to ensure uniform thermal conditions. To assess the effect of filter bag use, an additional trial employed Ankom F57 filter bags (Ankom Technology, Macedon, NY, USA; 25 μm pore size). Trial 1 revealed no significant differences in cumulative gas production, volatile fatty acids (VFAs), NH₃-N, or pH between systems (p > 0.05). However, the use of filter bags reduced gas output and increased propionate concentrations (p < 0.05). Trial 2, which employed filter bags in both systems, confirmed comparable results, with the FerME system demonstrating improved precision (CV: 4.8% vs. 13.2%). Gas composition (CH₄ + CO₂: 76–82%) and fermentation parameters remained consistent across systems (p > 0.05). Importantly, with 12 pressure sensors, the total cost of FerME was about half that of the Ankom RF system. Collectively, these findings demonstrate that FerME is a reliable, low-cost alternative for real-time rumen fermentation monitoring and could be suitable for studies in animal nutrition, methane mitigation, and related applications. Full article

To study and quantify the impact of water storage on lake slope stability after the closure of an open-pit mine, we targeted slope control measures by large-scale parallel computing methods and strength reduction theory. This was based on a three-dimensional refined numerical model to simulate the evolution of slope stability under different water storage levels and backfilling management conditions, and to quantitatively assess the risk of slope instability through the spatial distribution of stability coefficients. This study shows that during the impoundment process, the slope stability has a nonlinear decreasing trend due to the decrease in effective stress caused by the increase in pore water pressure. When the water storage was at 0 m, the instability range is the largest, and the surface range is nearly 200 m from the edge of the pit; when the water level continued to rise to 50 m, the hydrostatic pressure of the pit lake water on the slope support effect began to appear, and the stability was improved, but there is still a wide range of unstable areas at the bottom. In view of the unstable area of the steep slope with soft rock in the north slope during the process of water storage, the management scheme of backfilling the whole bottom to −150 m was proposed, and the slope protection and pressure footing were formed by discharging the soil to −40 m in steps to improve the anti-slip ability of the slope. Full article

During the process of oil and gas drilling, due to the existence of pores or micro-cracks, drilling fluid is prone to invade the formation. Under the action of hydration expansion of clay in the formation and liquid pressure, wellbore instability occurs. In order to reduce the wellbore instability caused by drilling fluid intrusion into the formation, this study proposed a method of forming a dynamic hydrogen bond cross-linked network weak gel structure with modified nano-silica and P(AM-AAC). The plugging performance of the drilling fluid and the performance of inhibiting the hydration of shale were evaluated through various experimental methods. The results show that the gel composite system (GCS) effectively optimizes the plugging performance of drilling fluid. The 1% GCS can reduce the linear expansion rate of cuttings to 14.8% and increase the recovery rate of cuttings to 96.7%, and its hydration inhibition effect is better than that of KCl and polyamines. The dynamic cross-linked network structure can significantly increase the viscosity of drilling fluid. Meanwhile, by taking advantage of the liquid-phase viscosity effect and the physical blocking effect, the loss of drilling fluid can be significantly reduced. Mechanism studies conducted using zeta potential measurement, SEM analysis, contact angle measurement and capillary force assessment have shown that modified nano-silica stabilizes the wellbore by physically blocking the nano-pores of shale and changing the wettability of the shale surface from hydrophilic to hydrophobic when the contact angle exceeds 60°, thereby reducing capillary force and surface free energy. Meanwhile, the dynamic cross-linked network can reduce the seepage of free water into the formation, thereby significantly lowering the fluid loss of the drilling fluid. This research provides new insights into improving the stability of the wellbore in drilling fluids. Full article

High-performance waterproof and breathable nanofiber membranes (WBNMs) are in great demand for various advanced applications. However, the fabrication of such membranes often relies on fluorinated materials or involves complex preparation processes, limiting their practical use. In this study, we present an innovative approach by utilizing silicon-containing polyurethane (SiPU) as a single-component, fluorine-free raw material to prepare high-performance WBNMs via a simple one-step electrospinning process. The electrospinning technique enables the formation of SiPU nanofibrous membranes with a small maximum pore size (d_max) and high porosity, while the intrinsic hydrophobicity of SiPU imparts excellent water-repellent characteristics to the membranes. As a result, the single-component SiPU WBNM exhibits superior waterproofness and breathability, with a hydrostatic pressure of 52 kPa and a water vapor transmission rate (WVTR) of 5798 g m⁻² d⁻¹. Moreover, the optimized SiPU-14 WBNM demonstrates outstanding mechanical properties, including a tensile strength of 6.15 MPa and an elongation at break of 98.80%. These findings indicate that the single-component SiPU-14 WBNMs not only achieve excellent waterproof and breathable performance but also possess robust mechanical strength, thereby enhancing the comfort and expanding the potential applications of protective textiles, such as outdoor apparel and car seats. Full article

A facile way to prepare Cu(OH)₂ inorganic nanofiltration membranes with neatly arranged multilayers has been developed based on the reaction of a sodium hydroxide solution and a copper ammonia solution at the liquid–liquid interfaces. The effects of the concentration, temperature, and time of the liquid–liquid reaction on membrane structure and pore sizes were studied by SEM, TEM, and X-ray diffraction. The growth mechanism of the membrane was discussed and the formation process model was proposed. It was found that the reaction temperature was a key factor in obtaining a Cu(OH)₂ monolayer, and this could be used to adjust the thickness and pore size of the monolayer. The as-prepared Cu(OH)₂ membranes exhibited excellent filtration performance with the pure water fluxes of 156.2 L·m⁻² h⁻¹ bar⁻¹ and retention rates of 100% for methylene blue (50 ppm) at a pressure of 0.1 MPa. This successfully opens up a new method of synthesizing multilayer nanoarrays’ Cu(OH)₂ structure for nanofiltration. Full article

The synergistic development of low-permeability reservoirs such as deep coalbed methane (CBM) and tight gas has emerged as a key technology to reduce development costs, enhance single-well productivity, and improve gas recovery. However, due to fundamental differences between coal seams and tight sandstones in their pore structure, permeability, water saturation, and pressure sensitivity, significant variations exist in their flow capacities and fluid production behaviors. To address the challenges of production allocation and main reservoir identification in the co-development of CBM and tight gas within deep gas-bearing basins, this study employs the transient multiphase flow simulation software OLGA to construct a representative dual-gas co-production well model. The regulatory mechanisms of the gas–liquid distribution, deliquification efficiency, and interlayer interference under two typical vertical stacking relationships—“coal over sand” and “sand over coal”—are systematically analyzed with respect to different tubing setting depths. A high-precision dynamic production allocation method is proposed, which couples the wellbore structure with real-time monitoring parameters. The results demonstrate that positioning the tubing near the bottom of both reservoirs significantly enhances the deliquification efficiency and bottomhole pressure differential, reduces the liquid holdup in the wellbore, and improves the synergistic productivity of the dual-reservoirs, achieving optimal drainage and production performance. Building upon this, a physically constrained model integrating real-time monitoring data—such as the gas and liquid production from tubing and casing, wellhead pressures, and other parameters—is established. Specifically, the model is built upon fundamental physical constraints, including mass conservation and the pressure equilibrium, to logically model the flow paths and phase distribution behaviors of the gas–liquid two-phase flow. This enables the accurate derivation of the respective contributions of each reservoir interval and dynamic production allocation without the need for downhole logging. Validation results show that the proposed method reliably reconstructs reservoir contribution rates under various operational conditions and wellbore configurations. Through a comparison of calculated and simulated results, the maximum relative error occurs during abrupt changes in the production capacity, approximately 6.37%, while for most time periods, the error remains within 1%, with an average error of 0.49% throughout the process. These results substantially improve the timeliness and accuracy of the reservoir identification. This study offers a novel approach for the co-optimization of complex multi-reservoir gas fields, enriching the theoretical framework of dual-gas co-production and providing technically adaptive solutions and engineering guidance for multilayer unconventional gas exploitation. Full article

Rapid socio-economic development and the impact of human activities have exerted tremendous pressure on the groundwater system of the Dawen River Basin (DRB), the largest tributary in the middle and lower reaches of the Yellow River. Hydrochemical studies on the DRB have largely centered on the upstream Muwen River catchment and downstream Dongping Lake, with some focusing solely on karst groundwater. Basin-wide evaluations suggest good overall groundwater quality, but moderate to severe contamination is confined to the lower Dongping Lake area. The hydrogeologically complex mid-reach, where the Muwen and Chaiwen rivers merge, warrants specific focus. This region, adjacent to populous areas and industrial/agricultural zones, features diverse aquifer systems, necessitating a thorough analysis of its hydrochemistry and origins. This study presents an integrated hydrochemical, isotopic investigation and EWQI evaluation of groundwater quality and formation mechanisms within the multiple groundwater types of the central DRB. Central DRB groundwater has a pH of 7.5–8.2 (avg. 7.8) and TDSs at 450–2420 mg/L (avg. 1075.4 mg/L) and is mainly brackish, with Ca²⁺ as the primary cation (68.3% of total cations) and SO₄²⁻ (33.6%) and NO₃⁻ (28.4%) as key anions. The Piper diagram reveals complex hydrochemical types, primarily HCO₃·SO₄-Ca and SO₄·Cl-Ca. Isotopic analysis (δ²H, δ¹⁸O) confirms atmospheric precipitation as the principal recharge source, with pore water showing evaporative enrichment due to shallow depths. The Gibbs diagram and ion ratios demonstrate that hydrochemistry is primarily controlled by silicate and carbonate weathering (especially calcite dissolution), active cation exchange, and anthropogenic influences. EWQI assessment (avg. 156.2) indicates generally “good” overall quality but significant spatial variability. Pore water exhibits the highest exceedance rates (50% > Class III), driven by nitrate pollution from intensive vegetable cultivation in eastern areas (Xiyangzhuang–Liangzhuang) and sulfate contamination from gypsum mining (Guojialou–Nanxiyao). Karst water (26.7% > Class III) shows localized pollution belts (Huafeng–Dongzhuang) linked to coal mining and industrial discharges. Compared to basin-wide studies suggesting good quality in mid-upper reaches, this intensive mid-reach sampling identifies critical localized pollution zones within an overall low-EWQI background. The findings highlight the necessity for aquifer-specific and land-use-targeted groundwater protection strategies in this hydrogeologically complex region. Full article

Channeling in cementing causes interlayer interference, severely restricting oilfield recovery. Existing channeling plugging agents, such as cement and gels, often lead to reservoir damage or insufficient strength. Oil-soluble resin (OSR) particles show great potential in selective plugging of channeling fractures due to their excellent oil solubility, temperature/salt resistance, and high strength. However, their application is limited by the efficient filling and retention in deep fractures. This study innovatively combines the OSR particle plugging system with the mature rapid filtration loss plugging mechanism in drilling, systematically exploring the influence of particle size and sorting on their filtration, packing behavior, and plugging performance in channeling fractures. Through API filtration tests, visual fracture models, and high-temperature/high-pressure (100 °C, salinity 3.0 × 10⁵ mg/L) core flow experiments, it was found that well-sorted large particles preferentially bridge in fractures to form a high-porosity filter cake, enabling rapid water filtration from the resin plugging agent. This promotes efficient accumulation of OSR particles to form a long filter cake slug with a water content <20% while minimizing the invasion of fine particles into matrix pores. The slug thermally coalesces and solidifies into an integral body at reservoir temperature, achieving a plugging strength of 5–6 MPa for fractures. In contrast, poorly sorted particles or undersized particles form filter cakes with low porosity, resulting in slow water filtration, high water content (>50%) in the filter cake, insufficient fracture filling, and significantly reduced plugging strength (<1 MPa). Finally, a double-slug strategy is adopted: small-sized OSR for temporary plugging of the oil layer injection face combined with well-sorted large-sized OSR for main plugging of channeling fractures. This strategy achieves fluid diversion under low injection pressure (0.9 MPa), effectively protects reservoir permeability (recovery rate > 95% after backflow), and establishes high-strength selective plugging. This study clarifies the core role of particle size and sorting in regulating the OSR plugging effect based on rapid filtration loss, providing key insights for developing low-damage, high-performance channeling plugging agents and scientific gradation of particle-based plugging agents. Full article

The development of deep coalbed methane (buried depth > 2000 m) in the Yan’an block of Ordos Basin is limited by low permeability, the pore structure of the coal reservoir, and the gas–water occurrence relationship. It is urgent to clarify the key control mechanism of pore structure on gas migration. In this study, based on high-pressure mercury intrusion (pore size > 50 nm), low-temperature N₂/CO₂ adsorption (0.38–50 nm), low-field nuclear magnetic resonance technology, fractal theory and Pearson correlation coefficient analysis, quantitative characterization of multi-scale pore–fluid system was carried out. The results show that the multi-scale pore network in the study area jointly regulates the occurrence and migration process of deep coalbed methane in Yan’an through the ternary hierarchical gas control mechanism of ‘micropore adsorption dominant, mesopore diffusion connection and macroporous seepage bottleneck’. The fractal dimensions of micropores and seepage are between 2.17–2.29 and 2.46–2.58, respectively. The shape of micropores is relatively regular, the complexity of micropore structure is low, and the confined space is mainly slit-like or ink bottle-like. The pore-throat network structure is relatively homogeneous, the difference in pore throat size is reduced, and the seepage pore shape is simple. The bimodal structure of low-field nuclear magnetic resonance shows that the bound fluid is related to the development of micropores, and the fluid mobility mainly depends on the seepage pores. Pearson’s correlation coefficient showed that the specific surface area of micropores was strongly positively correlated with methane adsorption capacity, and the nanoscale pore-size dominated gas occurrence through van der Waals force physical adsorption. The specific surface area of mesopores is significantly positively correlated with the tortuosity. The roughness and branch structure of the inner surface of the channel lead to the extension of the migration path and the inhibition of methane diffusion efficiency. Seepage porosity is linearly correlated with gas permeability, and the scale of connected seepage pores dominates the seepage capacity of reservoirs. This study reveals the pore structure and ternary grading synergistic gas control mechanism of deep coal reservoirs in the Yan’an Block, which provides a theoretical basis for the development of deep coalbed methane. Full article

Rainfall infiltration is a key factor affecting the stability of the slope. To study the impact of rainfall on the instability mechanism and stability of slopes, this paper employs numerical simulation to establish a rainfall infiltration slope model and conducts a saturated–unsaturated slope flow and solid coupling numerical analysis. By combining the strength reduction method with the calculation of slope stability under rainfall infiltration, the safety factor of the slope is obtained. A comprehensive analysis is conducted from the perspectives of the seepage field, displacement field and other factors to examine the impact of heavy rainfall patterns and rainfall intensities on the instability mechanism and stability of the slope. The results indicate that heavy rainfall causes the transient saturation zone within the landslide body to continuously move upward, forming a continuous sliding surface inside the slope, which may lead to instability and sliding of the soil in the upper part of the slope toe. The heavy rainfall patterns significantly affect the temporal and spatial evolution of pore water pressure, displacement and safety factors of the slope. Pore water pressure and displacement show a positive correlation with the rainfall intensity at various times during heavy rainfall events. The pre-peak rainfall pattern causes the largest decrease in the safety factor of the slope, and the slope failure occurs earlier, which is the most detrimental to the stability of the slope. The rainfall intensity is inversely proportional to the safety factor. As the rainfall intensity increases, the decrease in the slope’s safety factor becomes more significant, and the time required for slope instability is also shortened. The results of this study provide a scientific basis for analyzing rainfall-induced slope instability and failure. Full article

The evaluation of the wave-induced seabed stability such as liquefaction and shear failure is one of the factors that must be considered in the design of marine infrastructures. Due to the transformation within the porous medium, the wave-induced soil response manifests itself as a phase delay in the dynamic wave pressure on the seabed surface, which is referred to as “phase-lag”. In this study, the analytical solutions of wave-induced soil response in an infinite porous seabed are further examined to clarify the effects of phase-lags. Based on the coefficient of relative rigidity of the soil skeleton to the pore fluid ($R_k$), a simplified approximation is derived. The expressions of the phase-lags for wave-induced soil response are presented for various cases. Moreover, the phase-lag effects on instantaneous liquefaction and shear failure are analysed. Based on the parametric study, it is concluded the extreme phase-lag for wave-induced pore pressure increases with increasing $R_k$, the extreme phase-lag for horizontal effective stress and shear stress decrease with increasing $R_k$. Furthermore, the liquefaction zone and shear failure zone increase with increasing $R_k$. Full article

In order to accurately analyze the liquefaction and the reinforcement effect of saturated silty and sandy soils treated by dynamic compaction, a hydro-mechanically coupled explicit analysis method was proposed. The method, in combination with the cap model, was carried out using the Abaqus finite element software. Then, parametric analysis was carried out by means of the development and dissipation of excess pore water pressure, effective soil stress and the relative reinforcement degree. And the effects of the drop energy, tamper radius and soil permeability on the liquefaction zone and soil improvement of saturated soil were examined. The results demonstrated that the liquefaction zone and the effective reinforcement were determined by the drop energy rather than the permeability or tamper radius. A 2.5-times increase in drop energy can increase the maximum liquefaction depth by 1.1 m (4.6 m to 5.7 m) and the effective reinforcement depth (I_r ≥ 0.08) by 0.6 m (1.2 m to 1.8 m). It is recommended that the reinforcement effect should be improved by a lower drop energy with a low drop height and a heavy tamper in actual projects. It should also be noted that a smaller tamper radius was conducive to local soil improvement but also generated higher localized excess pore water pressures. Soil permeability critically controls liquefaction potential and excess pore water pressure dissipation. Low permeability soils experienced significant liquefaction depths and slower consolidation, whereas high permeability gravels (k = 10⁻² m/s) showed minimal liquefaction and great improvements in depth. To diminish the effect of the underground water, the gravel cushions should be used to drain pore water out before dynamic compaction. Full article

In response to the high-performance requirements of concrete materials under complex triaxial stress states and water-containing environments in marine engineering, this study focuses on water-containing basalt fiber-reinforced concrete (BFRC). Uniaxial compression and splitting tensile tests were conducted on specimens with different fiber contents (0.0%, 0.05%, 0.10%, 0.15%, and 0.20%) to determine the optimal fiber content of 0.1%. The compressive strength of the concrete with this fiber content increased by 13.5% compared to the control group without fiber, reaching 36.90 MPa, while the tensile strength increased by 15.9%, reaching 2.33 MPa. Subsequently, NMR and SEM techniques were employed to analyze the internal pore structure and micro-morphology of BFRC. It was found that an appropriate amount of basalt fiber (content of 0.1%) can optimize the pore structure and form a reticular three-dimensional structure. The pore grading was also improved, with the total porosity decreasing from 7.48% to 7.43%, the proportion of harmless pores increasing from 4.03% to 4.87%, and the proportion of harmful pores decreasing from 1.67% to 1.42%, thereby significantly enhancing the strength of the concrete. Further triaxial compression tests were conducted to investigate the mechanical properties of BFRC under different confining pressures (0, 3, and 6 MPa) and water contents (0%, 1%, 2%, and 4.16%). The results showed that the stress–strain curves primarily underwent four stages: initial crack compaction, elastic deformation, yielding, and failure. In terms of mechanical properties, when the confining pressure increased from 0 MPa to 6 MPa, taking dry sandstone as an example, the peak stress increased by 54.0%, the elastic modulus increased by 15.7%, the peak strain increased by 37.0%, and the peak volumetric strain increased by 80.0%. In contrast, when the water content increased from 0% to 4.16%, taking a confining pressure of 0 MPa as an example, the peak stress decreased by 27.4%, the elastic modulus decreased by 43.2%, the peak strain decreased by 59.3%, and the peak volumetric strain decreased by 106.7%. Regarding failure characteristics, the failure mode shifted from longitudinal splitting under no confining pressure to diagonal shear under confining pressure. Moreover, as the confining pressure increased, the degree of failure became more severe, with more extensive cracks. However, when the water content increased, the failure degree was relatively mild, but it gradually worsened with further increases in water content. Based on the CDP model, a numerical model for simulating the triaxial compression behavior of BFRC was developed. The simulation results exhibited strong consistency with the experimental data, thereby validating the accuracy and applicability of the model. Full article

The dynamic non-equilibrium effect (DNE) describes the non-unique character of saturation–capillary pressure relationships observed under static, steady-state, or monotonic hydrodynamic conditions. Macroscopically, the DNE manifests as variations in soil hydraulic characteristic curves arising from varying hydrodynamic testing conditions and is fundamentally governed by soil matrix particle size distribution. Changes in the DNE across porous media with discrete particle size fractions are investigated via stepwise drying experiments. Through quantification of saturation–capillary pressure hysteresis and DNE metrics, three critical signatures are identified: (1) the temporal lag between peak capillary pressure and minimum water saturation; (2) the pressure gap between transient and equilibrium states; and (3) residual water saturation. In the four experimental sets, with the finest material (Test 1), the peak capillary pressure consistently precedes the minimum water saturation by up to 60 s. Conversely, with the coarsest material (Test 4), peak capillary pressure does not consistently precede minimum saturation, with a maximum lag of only 30 s. The pressure gap between transient and equilibrium states reached 14.04 cm H₂O in the finest sand, compared to only 2.65 cm H₂O in the coarsest sand. Simultaneously, residual water saturation was significantly higher in the finest sand (0.364) than in the coarsest sand (0.086). The results further reveal that the intensity of the DNE scales inversely with particle size and linearly with wetting phase saturation (Sw), exhibiting systematic decay as Sw decreases. Coarse media exhibit negligible hysteresis due to suppressed capillary retention; this is in stark contrast with fine sands, in which the DNE is observed to persist in advanced drying stages. These results establish pore geometry and capillary dominance as fundamental factors controlling non-equilibrium fluid dynamics, providing a mechanistic framework for the refinement of multi-phase flow models in heterogeneous porous systems. Full article

The deep carbonate reservoirs in the Tarim Basin, Xinjiang, China, are widely developed with multi-scale complex reservoir spaces such as fractures, pores, and karst caves under the coupling of abnormal high pressure, diagenesis, karst, and tectonics and have strong heterogeneity. Among them, fracture–cavity carbonate reservoirs are one of the main reservoir types. Revealing the petrophysical characteristics of fracture–cavity carbonate reservoirs can provide a theoretical basis for the log interpretation and geophysical prediction of deep reservoirs, which holds significant implications for deep hydrocarbon exploration and production. In this study, based on the mineral composition and complex pore structure of carbonate rocks in the Tarim Basin, we comprehensively applied classical petrophysical models, including Voigt–Reuss–Hill, DEM (Differential Effective Medium), Hudson, Wood, and Gassmann, to establish a fracture–cavity petrophysical model tailored to the target block. This model effectively characterizes the complex pore structure of deep carbonate rocks and addresses the applicability limitations of conventional models in heterogeneous reservoirs. The discrepancies between the model-predicted elastic moduli, longitudinal and shear wave velocities (Vp and Vs), and laboratory measurements are within 4%, validating the model’s reliability. Petrophysical template analysis demonstrates that P-wave impedance (Ip) and the Vp/Vs ratio increase with water saturation but decrease with fracture density. A higher fracture density amplifies the fluid effect on the elastic properties of reservoir samples. The Vp/Vs ratio is more sensitive to pore fluids than to fractures, whereas Ip is more sensitive to fracture density. Regions with higher fracture and pore development exhibit greater hydrocarbon storage potential. Therefore, this petrophysical model and its quantitative templates can provide theoretical and technical support for predicting geological sweet spots in deep carbonate reservoirs. Full article