Search Results (12)

This paper analyses the notch effect in the fracture behaviour of acrylonitrile–styrene–acrylate (ASA) material manufactured by fused filament fabrication (FFF). The research is performed on 72 single-edge-notch bending (SENB) specimens containing U-notches with nominal notch radii varying from 0 mm (crack-like defects) up to 2.0 mm, and fabricated with three different raster orientations (0/90, 45/−45, 30/−60). Apparent fracture toughness values are obtained for the different conditions and the resulting notch effect is analysed through the Theory of Critical Distances. A fractographic analysis is also performed using Scanning Electron Microscopy (SEM) in order to justify the fracture (macroscopic) behaviour from the observed fracture micromechanisms. The notch effect observed in the three ASA raster orientations is very similar, and lower than that observed in other FFF polymeric alternatives (ABS, PLA). Full article

This paper describes a simple method to synthesize tough hydrogels from a highly cross-linked neutral network. It was found that applying alkaline hydrolysis to a highly cross-linked hydrogel synthesized from acrylamide (AAm) can increase its swelling ratio dramatically. Double-network (DN) hydrogels synthesized from polymerization of loosely cross-linked AAm networks inside a highly cross-linked AAm gel were not tough. However, repeating the same recipes with a second polymerization step to synthesize a DN hydrogel from a hydrolyzed highly cross-linked AAm gel resulted in tough hydrogels. Those gels exhibited finite tensile behavior similar to that of conventional DN hydrogels. Moreover, craze-like patterns were observed during tensile loading of a DN hydrogel synthesized from a hydrolyzed highly cross-linked first network and a loosely cross-linked second network. The patterns remained in the gel even after strain hardening at high stretch ratios. The craze-like pattern formation was suppressed by increasing the concentration of cross-linking monomer in the second polymerization step. Crack propagation in DN hydrogels synthesized using hydrolysis was also studied by applying a tensile load on notched specimens. Full article

Fibre Metal Laminates (FMLs) are very interesting materials due to their light weight coupled with their high stiffness, high fatigue resistance, and high damage tolerance. However, the presence of the polymeric matrix in the composite layers and of polymeric adhesive at the metal/composite interface can constitute an Achille’s heel for this class of materials, especially when exposed to a hot environment or water. Therefore, in the present article, aluminium/carbon fibre FML specimens were produced, aged by considering different hydrothermal conditions, and then, subjected to mechanical testing. The End-Notched Flexure (ENF) test was considered for this activity. It was found that the first ageing stage, consisting of submersion in saltwater, was very detrimental to the specimens, while the second stage, composed of high and low temperature cycles, showed an increase in the maximum load, probably due to a post-curing effect of the resin during the higher temperatures of the ageing cycles and to the dissolution of salt crystals during the subsequently ageing stages in distilled water. Full article

Arapaima scales possess a hierarchical structure capable of absorbing a considerable amount of energy before fracture. These natural dermal armors present significant potential in the sustainable development of cost-effective composites. This work aimed, for the first time, to analyze the impact resistance and ballistic performance of arapaima scale-reinforced epoxy composites and their potential application in multilayered armor systems (MAS). Composite plates were prepared with 20%, 30%, and 40 vol% of arapaima scales. Composite specimens were subjected to notched Izod impact and residual velocity stand-alone tests and their MAS through backface signature (BFS) tests, with their fracture surfaces studied using SEM. The Izod tests confirmed the effect of scales’ volume fraction on the energy absorbed by the composites, showing an increase with volume fraction. Residual velocity tests showed that composites with 30 vol% of scales resulted in the most significant improvement in absorbed energy. All MAS formulations presented BFS depths lower than the trauma limit specified by the NIJ standard. Fractographic analysis showed that the scales’ toughening mechanisms improved the composites’ energy absorption capacity. The experimental results substantiate the potential use of arapaima scales as a reinforcement agent in polymeric composites, with 30 vol% being the optimal volume fraction for energy-absorbing applications. Full article

The current publication deals with the fracture toughness of polymeric multi-layer materials. In detail, the crack initiation and growth, crack arrest, and crack re-initiation of a multi-layer material are examined. The aim is to develop a numerical model for crack initiation and incremental crack growth of a three-layer single edge notched bending specimen that features one brittle layer in a plastically deforming matrix. Crack initiation and crack propagation are modeled using the finite fracture mechanics concept and the energy concept, respectively. No delamination is accounted for and the crack grows in one plane. The experimental observation of a crack initiating in the brittle layer (at 61.4 ± 2.2 N) while the initial crack is blunting can be reproduced well with the numerical model (at 63.6 N) with a difference of <3.6%. The model is ready to be used for different layups to predict toughening mechanisms and damage tolerances in multi-layer materials. Full article

The aim of this paper is to assess the size and geometry effects on the mode I notch fracture toughness of polymeric samples containing rounded-tip V-shaped (RV) notches (V-notch with a finite radius at the notch tip). First, using a large number of fracture tests on an RV-notched Brazilian disk and semi-circular bending polymeric samples with four different sizes, the size-dependent values of the notch fracture toughness are obtained. Then, the mean stress criterion is modified for characterizing the size-dependency of notch fracture toughness in polymeric samples. The resulting modified mean stress criterion considers higher order terms of the stress field when calculating the fracture process zone length around the tip of the defect. Additionally, the critical distance r_c is assumed to be associated with the specimen size and a formula containing fitting parameters is utilized for considering this trend of r_c. The comparison between the values of notch fracture toughness obtained from experiments and those predicted by the modified mean stress criterion shows that the suggested approach can provide accurate estimations of size-dependent values of notch fracture toughness in polymeric specimens containing RV notches. Full article

The aim of this study was to compare three different light-curing-units (LCUs) and determine their effectiveness in the adhesive cementation of indirect composite restorations when a light-curing resin cement is used. Two resin composites were selected: Enamel Plus HRI (Micerium) and AURA (SDI). Three thicknesses (3 mm, 4 mm and 5 mm) were produced and applied as overlays and underlays for each resin composite. A standardized composite layer was placed between underlay and overlay surfaces. Light curing of the resin-based luting composites was attained through the overlay filters using LCUs for different exposure times. All specimens were allocated to experimental groups according to the overlay thickness, curing unit and curing time. Vickers Hardness (VH) notches were carried out on each specimen. Data were statistically evaluated. The curing unit, curing time and overlay thickness were significant factors capable of influencing VH values. The results showed significantly decreased VH values with increasing specimen thickness (p < 0.05). Significant differences in VH values were found amongst the LCUs for the various exposure times (p < 0.05). According to the results, a time of cure shorter than 80 s (with a conventional quartz–tungsten–halogen LCU) or shorter than 40 s (with a high-power light-emitting diode (LED) LCU) is not recommended. The only subgroup achieving clinically acceptable VH values after a short 20 s curing time included the 3 mm-thick overlays made out of the AURA composite, when the high-power LED LCU unit was used (VH 51.0). Composite thickness has an intense effect on polymerization. In clinical practice, light-cured resin cements may result in insufficient polymerization for high thickness and inadequate times. High-intensity curing lights can attain the sufficient polymerization of resin cements through overlays in a significantly shorter time than conventional halogen light. Full article

This work analyzes, both theoretically and experimentally, the fracture process of square specimens weakened by keyhole notches and subjected to compressive stresses. Two materials are covered: general-purpose polystyrene (GPPS) and poly(methyl methacrylate) (PMMA). Firstly, the load-carrying capacity (LCC) of the specimens is determined experimentally. Then, by using the equivalent material concept (EMC) for compressive conditions coupled with the maximum tangential stress (MTS) and the mean stress (MS) criteria, the LCC of the notched specimens is predicted. The results show that by using the approach proposed in the present investigation, not only can the critical loads in the keyhole notched polymeric specimens be precisely predicted, but also the corresponding compressive critical stress of the two mentioned polymers can be successfully estimated. Full article

Fracture mechanics are of high interest for the engineering design and structural integrity assessment of polymeric materials; however, regarding highly ductile polymers, many open questions still remain in terms of fully understanding deformation and fracture behaviors. For example, the influence of the constraint and specimen size on the fracture behavior of polymeric materials is still not clear. In this study, a polymeric material with an elastic plastic deformation behavior (ABS, acrylonitrile butadiene styrene) is investigated with regard to the influence of constraint and specimen size. Different single-edge notched bending (SENB) specimen sizes with constant geometrical ratios were tested. The material key curve was used to investigate differences in the constraint, where changes for small and large specimen sizes were found. Based on a size-independent crack resistance curve (J–R curve), two apparent initiation parameters (J_0.2 and J_bl) were determined, namely, the initiation parameter J_ini (based on the crack propagation kinetics curve) and the initiation parameter J_I,lim (based on an ESIS TC 4 draft protocol). It was found that J_0.2 and J_bl could be used as crack initiation parameters whereby J_ini and J_I,lim are indicative of the onset of stable crack growth. Full article

In this paper, the fracture of notched polymeric specimens under compressive stresses was investigated both experimentally and theoretically. In the experimental section, to determine the load-carrying capacity (LCC) of U-notched specimens made of general-purpose polystyrene (GPPS) and polymethyl-methacrylate (PMMA) polymers, tests were performed on notched square samples under compression, i.e., negative mode I loading. In the observation of the nonlinear behavior of the two polymers in the standard compressive tests, for the first time, the equivalent material concept (EMC) was used under compressive loading to theoretically estimate the critical stresses of the two polymers, which were shown to be significantly different from the ultimate strengths obtained from the standard compression tests. By linking the EMC to the maximum tangential stress (MTS) and mean stress (MS) criteria, the LCC of the notched specimens was predicted. The outcomes are twofold: First, MTS, MS, EMC–MTS, and EMC–MS criteria provide accurate predictions of the experimental critical loads observed in the U-notched polymeric specimens; second, the combination of the EMC with the MTS and MS criteria, allow such predictions to be obtained without any need for experimental calibration. Full article

In this work, the fracture mechanics properties of polyamide (PA) specimens manufactured by the selective laser sintering (SLS) technology are investigated, in which an embedded crack-like notch was inserted in the design and produced during the additive manufacturing (AM) phase. To cover a wide variety of mode I/II mixity levels, the inclined asymmetrical semicircular specimen subjected to three points loading (IASCB) was employed. The investigation was carried out by analyzing the full displacement field in the proximity of the crack tip by means of the digital image correlation (DIC) technique. To characterize the material, which exhibits a marked elastic-plastic behavior, the quantity J-integral was evaluated by two different methods: the first one exploits the full fields measured by the DIC, whereas the second one exploits the experimental load–displacement curves along with FEM analysis. The DIC methodology was experimentally validated and proposed as an alternative method to evaluate the J-integral. It is especially suited for conditions in which it is not possible to use the conventional LDC method due to complex and possibly unknown loading conditions. Furthermore, results showed that the AM technique could be used effectively to induce cracks in this type of material. These two aspects together can lead to both a simplification of the fracture characterization process and to the possibility of dealing with a wider number of practical, real-world scenarios. Indeed, because of the nature of the additive manufacturing process, AM crack-like notches can be sintered even having complex geometry, being three-dimensional and/or inside the tested structure. Full article

Nowadays, laminated composites are widely used in the aerospace sector. All laminates have interply/interlaminar interfaces even if they are made using automated processes. The interfaces act as the areas of weaknesses and the potential crack initiation regions. Hence, any enhancement in the crack initiation and propagation resistance is always sought after. Usage of polymeric thin films is one of the promising and viable ways to achieve this. It is also easy to incorporate micro-thin films into any automation process. In the present study, different customized thin films that are compatible with Glass/BMI composites are fabricated. Fracture toughness tests in Mode I (opening mode), Mode II (sliding mode) and Mixed Mode I/II are conducted respectively using Double Cantilever Beam (DCB), End Notch Flexure (ENF) and Mixed Mode Bending (MMB) test specimens. This paper discusses the manufacturing of compatible micro-thin films. The various challenges faced during the manufacturing and incorporation of thin films are presented. The results of the various fracture toughness tests are examined. Mechanisms through which the different films help in resisting the crack initiation and propagation are deliberated and discussed. The incorporation of this technique in Automated Fiber Placement (AFP) is also discussed. Full article