Search Results (28)

This paper develops a shock-absorbing asphalt mixture for pedestrian pavements that mitigates the impact of normal walking on pedestrians’ bodies by incorporating crumb rubber from recycled tires to produce a soft mixture. This aims to reduce injuries to vulnerable road users, enable the rethinking of urban pavement designs, and address the major challenges facing societies, ultimately achieving more sustainable, resilient, and safer cities. To promote land sustainability, the designed asphalt mixture should be pervious, allowing water to infiltrate into the underlying soil. The development of the asphalt mixture followed an experimental methodology that involved formulating asphalt mixtures with conventional bitumen, polymer-modified bitumen, and bituminous emulsion. The shock-absorbing capability was evaluated by measuring the deformation of the asphalt mixture over time in response to a falling weight from a Light Falling Weight Deflectometer. Permeability capabilities were assessed through the permeability test. Subsequently, the asphalt mixture was characterized according to its macrotexture, friction, air void content, rutting resistance, and stiffness to assess its suitability as a walking surface material. Results indicate that increasing rubber content enhances deformation capacity and improves cushioning but reduces stiffness. Among the solutions, mixtures with polymer-modified bitumen and intermediate rubber content achieved the balance between impact attenuation and mechanical performance. Full article

The flexible micro-structured surface found in biological skins exhibits remarkable drag reduction properties, inspiring applications in the aerospace industry, underwater exploration, and pipeline transportation. To address the challenge of efficiently replicating such structures, this study presents a composite flexible polymer film with a bio-inspired micro-dimple array, fabricated via an integrated process of precision milling, polishing, and micro-injection molding using thermoplastic polyurethane (TPU). We systematically investigated the influence of key injection parameters on the shape accuracy and surface quality of the film. The experimental results show that polishing technology can significantly reduce mold core surface roughness, thereby enhancing film replication accuracy. Among the parameters, melt temperature and holding time exerted the most significant effects on shape precision PV and bottom roughness R_a, while injection speed showed the least influence. Under optimized conditions of a melt temperature of 180 °C, injection speed of 60 mm/s, holding pressure of 7 MPa, and holding time of 13 s, the film achieved a micro-structure shape accuracy of 13.502 μm and bottom roughness of 0.033 μm. Numerical simulation predicted a maximum drag reduction rate of 10.26%, attributable to vortex cushion effects within the dimples. This performance was experimentally validated in a flow velocity range of 0.6–2 m/s, with the discrepancy between simulated and measured drag reduction kept within 5%, demonstrating the efficacy of the proposed manufacturing route for flexible bio-inspired drag reduction film. Full article

Spacer fabrics are a breathable material option for wearable cushioning, but the cushioning performance is still not comparable to that of traditional elastomeric cushioning materials. The polymer-based connective structure of spacer fabrics largely affects fabric properties, compression, and mechanical performance, and this is a research gap that calls for the development of spacer fabrics with enhanced cushioning functions. This study develops a new square-wave inlay pattern and investigates the effects of the inlay structure and spatial frequency of the spacer course, as well as the effects of the silicone inlay on compression, impact force absorption, and vibration isolation of the spacer fabric. Twelve samples are designed and evaluated. The results show that the square-wave inlaid spacer fabric has higher energy absorption during compression. The square-wave pattern with a shorter transition distance between the front and back tuck stitches could increase the inclination angle close to a right angle, and extra tuck stitches on the surface float could secure the square-wave structure to enhance the impact force absorption ability. The increment in the spatial frequency of spacer courses provides a less stiff fabric with lower impact force absorption but higher vibration isolation ability. This study shows the innovative development of spacer fabric for enhancing cushioning properties. Full article

Background/Objectives: Compaction of sustained release coated pellets into tablets is associated with damage to the functional coat and loss in sustained release. The influences of precompression, trilayering, and tableting rate on the compaction of sustained release coated pellets into tablets are not well defined and were herein investigated to enhance the current limited understanding of these factors. Methods: Pellets coated with acrylic polymer (AC) or ethylcellulose (EC) were combined with filler material and compacted into multi-unit pellet system (MUPS) tablets prepared using different levels of precompression, as a trilayered MUPS tablet and at different tableting rates. The physical properties of the resulting MUPS tablets were evaluated. Trilayering was achieved by adding cushioning layers at the top and bottom of the MUPS tablet to avoid direct contact of pellets with punch surfaces. Results: With precompression, slightly stronger MUPS tablets were made compared to the tablets without precompression for EC pellets but not AC pellets. However, precompression led to a slight reduction in pellet coat damage for AC pellets but not EC pellets. Trilayering led to significant reductions in pellet coat damage and significant increases in tablet tensile strength. When EC pellets were lubricated with sodium stearyl fumarate, pellet coat damage was significantly lower. Increasing the tableting rate from 20 to 100 rpm did not result in increased pellet coat damage but in significantly weaker tablets due to the shorter dwell time. Conclusions: This study provides key insights on how compaction parameters and techniques could be altered to produce better MUPS tablets. Full article

Open-cell PU foams have a wide range of industrial applications due to their excellent cushioning, impact protection, packaging, thermal insulation, and sound reduction benefits. The foams absorb impact energy while deforming under compressing and are ideal for applications with severe and repeated loading conditions. Enhancing and improving their compressive durability is a vital area of ongoing research. We investigated the effect of incorporating shear-stiffening polymers (SSPs) and shear-thickening fluids (STFs) on the compression properties of open-cell foams. Rheological properties of STFs and SSPs prepared for incorporation into the foams confirmed the shear-thickening and shear-stiffening characteristics. Quasi-static compression tests performed at different speeds (6, 60, 120, 180, and 240 mm/s), as well as load-unload compression tests (6 and 24 mm/s), showed that the SSP-filled foam exhibited the most pronounced improvement in the elastic, plateau, and densification regions compared to the neat foam. While the STF-filled foam also improved performance over the neat foam, its advantages over the SSP-filled foam were less pronounced. The performance of the SSP-filled foam improved with increasing compression speeds, while the performance of the STF-filled foam remained relatively stable between 60 and 240 mm/s of load-unload tests. Post-test compression evaluations showed that neat and STF-filled foams quickly regained their original shape, while SSP-filled foams required more time before recovery. This research shows that combining SSP and STF smart materials with open-cell foams substantially improves their compressive performance, especially at high compression rates and load-unloading scenarios, increasing their functional life. Full article

This article demonstrates that machine fires caused by a belt transmission are a fundamental and current research problem. The aim of this work is to identify the hazards during thermal decomposition and combustion of a transmission with a toothed belt, used as a drive or conveyor belt to synchronise mechanisms. The analysis distinguished belts in a polyurethane or rubber cushion with a Kevlar, steel, or polyurethane cord. The belts’ composite structure can be a source of unpredictable emissions and toxic substances of varying concentrations and compositions during thermal decomposition and combustion. To evaluate the compared belts, a testing methodology was used to determine the toxicometric indicators (W_LC50SM), according to which it was possible to assess the toxicity of the thermal decomposition and combustion products following EU standards. The analysis was carried out based on the recorded emissions of chemical compounds during the thermal decomposition and combustion of polymer materials at three different temperatures (450, 550, and 750 °C). The least favourable toxicometric indicators (W_LC50SM) are found in rubber cushion belts, which are very toxic (about 13 g/m³) and toxic (about 40 g/m³) materials. The results show that thermoplastic polyurethane cushion belts are moderately toxic materials, with a W_LC50SM index ranging from 411 g/m³ to 598 g/m³. Full article

Silicon stands out as an exceptionally viable anode material, distinguished by its substantial capacity, plentiful natural reserves, eco-friendliness, and favorable low working potential. Nonetheless, the material’s pronounced volume fluctuations readily induce particle fragmentation, detachment of active components, and repeated disruption of the solid electrolyte interphase (SEI) layer. These factors contribute to a shortened cycle life and rapid capacity fading, thus hindering its practical application. The carbon composite approach can efficiently counteract these issues by capitalizing on silicon’s high capacity and employing carbon as a cushioning agent to diminish volume swelling, thus enhancing the deployment of silicon-based anode materials. This paper offers an exhaustive examination of the lithiation processes involved in Si/C anodes and delves into the strategic utilization of diverse carbon materials, including graphite, graphene, graphdiyne, carbon nanotubes, carbon fibers, MXenes, pitch, heteroatom-doped polymers, biomass-derived carbon, carbon-containing gas-derived carbon, MOFs, and g-C₃N₄ to advance the application of silicon in lithium-ion battery (LIB) anodes. Overall, this paper concentrates on summarizing the current research status and technological advancement and juxtaposes the merits and demerits of various carbon sources in Si/C anodes, thus providing a comprehensive assessment and forward-looking perspective on their future development. Full article

This study investigates the impact response of polymer foams commonly used in protective packaging, considering the fractal nature of their material microstructure. The research begins with static material characterization and impact tests on two low-density polyethylene foams. To capture the multiscale nature of the dynamic response behavior of two low-density foams to sustain impact loads, fractional differential equations of motion are used to qualitatively and quantitatively describe the dynamic response behavior, assuming restoring forces for each foam characterized, respectively, by a polynomial of heptic degree and by a trigonometric tangential function. A two-scale transform is employed to solve the mathematical model and predict the material’s behavior under impact loads, accounting for the fractal structure of the material’s molecular configuration. To assess the accuracy of the mathematical model, we performed impact tests considering eight dropping heights and two plate weights. We found good predictions from the mathematical models compared to experimental data when the fractal derivatives were between 1.86 and 1.9, depending on the cushioning material used. The accuracy of the theoretical predictions achieved using fractal calculus elucidates how to predict multiscale phenomena associated with foam heterogeneity across space, density, and average pore size, which influence the foam chain’s molecular motion during impact loading conditions. Full article

Concussions, a prevalent public health concern in the United States, often result from mild traumatic brain injuries (mTBI), notably in sports such as American football. There is limited exploration of smart-textile-based sensors for measuring the head impacts associated with concussions in sports and recreational activities. In this paper, we describe the development and construction of a smart textile impact sensor (STIS) and validate STIS functionality under high magnitude impacts. This STIS can be inserted into helmet cushioning to determine head impact force. The designed 2 × 2 STIS matrix is composed of a number of material layered structures, with a sensing surface made of semiconducting polymer composite (SPC). The SPC dimension was modified in the design iteration to increase sensor range, responsiveness, and linearity. This was to be applicable in high impact situations. A microcontroller board with a biasing circuit was used to interface the STIS and read the sensor’s response. A pendulum test setup was constructed to evaluate various STISs with impact forces. A camera and Tracker software were used to monitor the pendulum swing. The impact forces were calculated by measuring the pendulum bob’s velocity and acceleration. The performance of the various STISs was measured in terms of voltage due to impact force, with forces varying from 180 to 722 N. Through data analysis, the threshold impact forces in the linear range were determined. Through an analysis of linear regression, the sensors’ sensitivity was assessed. Also, a simplified model was developed to measure the force distribution in the 2 × 2 STIS areas from the measured voltages. The results showed that improving the SPC thickness could obtain improved sensor behavior. However, for impacts that exceeded the threshold, the suggested sensor did not respond by reflecting the actual impact forces, but it gave helpful information about the impact distribution on the sensor regardless of the accurate expected linear response. Results showed that the proposed STIS performs satisfactorily within a range and has the potential to be used in the development of an e-helmet with a large STIS matrix that could cover the whole head within the e-helmet. This work also encourages future research, especially on the structure of the sensor that could withstand impacts which in turn could improve the overall range and performance and would accurately measure the impact in concussion-causing impact ranges. Full article

Biodegradable foams are a potential substitute for most fossil-fuel-derived polymer foams currently used in the cushion furniture-making industry. Thermoplastic starch (TPS) and poly(butylene adipate-co-terephthalate) (PBAT) are biodegradable polymers, although their poor compatibility does not support the foam-forming process. In this study, we investigated the effect of polyethylene glycol (PEG) with or without silane A (SA) on the foam density, cell structure and tensile properties of TPS/PBAT blends. The challenges in foam forming were explored through various temperature and pressure values under supercritical carbon dioxide (CO₂) conditions. The obtained experimental results indicate that PEG and SA act as a plasticizer and compatibilizer, respectively. The 50% (TPS with SA + PEG)/50% PBAT blends generally produce foams that have a lower foam density and better cell structure than those of 50% (TPS with PEG)/50% PBAT blends. The tensile property of each 50% (TPS with SA + PEG)/50% PBAT foam is generally better than that of each 50% (TPS with PEG)/50% PBAT foam. Full article

Safety concerns remain a bottleneck for the application of 2,4,6,8,10,12-hexanitro- 2,4,6,8,10,12-hexaazaisowurtzitane (CL-20)/1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane (HMX) cocrystal. Melamine–formaldehyde (MF) resin was chosen to fabricate CL-20/HMX cocrystal-based core–shell composites (CH@MF composites) via a facile in situ polymerization method. The resulted CH@MF composites were comprehensively characterized, and a compact core–shell structure was confirmed. The effects of the shell content on the properties of the composites were explored as well. As a result, we found that, except for CH@MF–2 with a 1% shell content, the increase in shell content led to a rougher surface morphology and more close-packed structure. The thermal decomposition peak temperature improved by 5.3 °C for the cocrystal enabled in 1.0 wt% MF resin. Regarding the sensitivity, the CH@MF composites exhibited a significantly reduced impact and friction sensitivity with negligible energy loss compared with the raw cocrystal and physical mixtures due to the cushioning and insulation effects of the MF coating. The formation mechanism of the core–shell micro-composites was further clarified. Overall, this work provides a green, facile and industrially potential strategy for the desensitization of energetic cocrystals. The CH@MF composites with high thermal stability and low sensitivity are promising to be applied in propellants and polymer-bonded explosive (PBX) formulations. Full article

Primary containers made of cyclic olefin polymer (COP) have recently gained attention since they may overcome several risks and shortcomings of glass containers as they exhibit a high break resistance, biocompatibility, and homogeneous heat transfer during lyophilization. On the downside, COP is more permeable for gases, which can lead to an ingress of oxygen into the container over time. Since oxidation is an important degradation pathway for monoclonal antibodies (mAbs), the continuous migration of oxygen into drug product containers should be avoided overall. To date, no long-term stability studies regarding lyophilizates in polymer vials have been published, potentially because of the unbearable gas permeability. In this study, we demonstrate that after lyophilization in COP vials and storage of these vials in aluminum pouches together with combined oxygen and moisture absorbers (“smart packaging”), oxidation of two lyophilized therapeutic antibodies was as low as in glass vials due to the deoxygenated environment in the pouch. Nevertheless, active removal of oxygen from the primary container below the initial level over time during storage in such “smart” secondary packaging was not achieved. Furthermore, residual moisture was controlled. Overall, the smart packaging reveals a promising approach for long-term stability of biopharmaceuticals; in addition to COP’s known benefits, stable, low oxygen and moisture levels as well as the protection from light and cushioning against mechanical shock by the secondary packaging preserve the sensitive products very well. Full article

With the development of societies, diabetic foot ulcers have become one of the most common diseases requiring lower extremity amputation. The early treatment and prevention of diabetic foot ulcers can considerably reduce the possibility of amputation. Using footwear to redistribute and relieve plantar pressure is one of the important measures for the treatment and prevention of diabetic foot ulcers. Thus, the evaluation and prediction of the distribution of plantar pressure play an important role in designing footwears. Herein, the finite element method was used to study plantar pressure under two kinds of foot models, namely, the skeletal structure foot model and the whole foot model, to explore the influence of human bones on the pressure of the soles of the feet and obtain accurate foot pressure. Simulation results showed that under the two models, the plantar pressure and the pressure from the footwear with ethylene vinyl acetate were all reduced. The total deformation demonstrated a slight increase. These stresses are very useful as they enable the design of suitable orthotic footwear that reduces the amount of stress in individuals with diabetic foot ulcers. Full article

Sports face guards (FGs) are devices that protect athletes from maxillofacial injury or ensure rapid return to play following orofacial damage. Conventional FGs are uncomfortable to wear owing to stuffiness caused by poor ventilation and often slip off due to increase in weight due to absorption of moisture from perspiration, lowering players’ performance. Herein, combinations of 3D-printed perforated acrylonitrile butadiene styrene (ABS) polymer sheets and 3D-knitted fabrics with honeycomb structures as cushioning materials were investigated to balance better wearing feel and mechanical properties. The flexural strength, weight, and shock absorption ability of, and air flow rate through, the ABS sheets with five different perforation patterns were evaluated and compared with those of conventional FG materials comprising a combination of polycaprolactone sheets for the medical splint and polychloroprene rubber for the cushioning material. The ABS sheets having 10% open area and 2.52 mm round holes, combined with knitted fabric cushioning, exhibited the requisite shock absorbing, higher air permeability, and lower weight properties than the conventional materials. Our results suggest that FGs fabricated using combinations of 3D-printed perforated ABS polymer sheets and 3D-knitted fabrics with honeycomb structures may impart enhanced wearing comfort for athletes. Full article