Search Results (352)

Against the backdrop of global energy transition and strict environmental regulations, supercritical carbon dioxide (scCO₂) fracturing and oil displacement technologies have emerged as pivotal green approaches in shale gas exploitation, offering the dual advantages of zero water consumption and carbon sequestration. However, the inherent low viscosity of scCO₂ severely restricts its sand-carrying capacity, fracture propagation efficiency, and oil recovery rate, necessitating the urgent development of high-performance thickeners. The current research on scCO₂ thickeners faces a critical trade-off: traditional fluorinated polymers exhibit excellent philicity CO₂, but suffer from high costs and environmental hazards, while non-fluorinated systems often struggle to balance solubility and thickening performance. The development of new thickeners primarily involves two directions. On one hand, efforts focus on modifying non-fluorinated polymers, driven by environmental protection needs—traditional fluorinated thickeners may cause environmental pollution, and improving non-fluorinated polymers can maintain good thickening performance while reducing environmental impacts. On the other hand, there is a commitment to developing non-noble metal-catalyzed siloxane modification and synthesis processes, aiming to enhance the technical and economic feasibility of scCO₂ thickeners. Compared with noble metal catalysts like platinum, non-noble metal catalysts can reduce production costs, making the synthesis process more economically viable for large-scale industrial applications. These studies are crucial for promoting the practical application of scCO₂ technology in unconventional oil and gas development, including improving fracturing efficiency and oil displacement efficiency, and providing new technical support for the sustainable development of the energy industry. This study innovatively designed an amphiphilic modified amino silicone oil polymer (MA-co-MPEGA-AS) by combining maleic anhydride (MA), methoxy polyethylene glycol acrylate (MPEGA), and amino silicone oil (AS) through a molecular bridge strategy. The synthesis process involved three key steps: radical polymerization of MA and MPEGA, amidation with AS, and in situ network formation. Fourier transform infrared spectroscopy (FT-IR) confirmed the successful introduction of ether-based CO₂-philic groups. Rheological tests conducted under scCO₂ conditions demonstrated a 114-fold increase in viscosity for MA-co-MPEGA-AS. Mechanistic studies revealed that the ether oxygen atoms (Lewis base) in MPEGA formed dipole–quadrupole interactions with CO₂ (Lewis acid), enhancing solubility by 47%. Simultaneously, the self-assembly of siloxane chains into a three-dimensional network suppressed interlayer sliding in scCO₂ and maintained over 90% viscosity retention at 80 °C. This fluorine-free design eliminates the need for platinum-based catalysts and reduces production costs compared to fluorinated polymers. The hierarchical interactions (coordination bonds and hydrogen bonds) within the system provide a novel synthetic paradigm for scCO₂ thickeners. This research lays the foundation for green CO₂-based energy extraction technologies. Full article

Glass Fiber-Reinforced Polymer (GFRP) bars are becoming increasingly common in structural engineering applications due to their superior material properties, mainly their resistance to corrosion due to their metallic nature in comparison to steel reinforcement and their improved durability in alkaline environments compared to CFRP and BFRP reinforcement. However, GFRP bars also suffer from a few limitations. One of the main issues that affects the performance of GFRP reinforcing bars is their bond with concrete, which may differ from the bond between traditional steel bars and concrete. However, despite the wide attention of researchers, there has not been a critical review of the recent research progress on bond behavior between GFRP bars and concrete. The objective of this paper is to provide an overview of the current state of research on bond in GFRP-reinforced concrete in an attempt to systematize the existing scientific knowledge. The study summarizes experimental investigations that directly measure bond strength and investigates the different factors that influence it. Additionally, an overview of the analytical and empirical models used to simulate bond behavior is then presented. The findings indicate the dependence of the bond on several factors that include bar diameter, bar surface, concrete strength, and embedment length. Additionally, it was concluded that both traditional and more recent bond models do not explicitly account for the effect of different factors, which highlights the need for improved bond models that do not require calibration with experimental tests. Full article

The design of automobile chassis structures is fundamentally linked to the optimization of mass and structural robustness. While conventional chassis structures predominantly utilize metals, achieving further mass reduction and enhanced rigidity necessitates the adoption of composite sandwich materials, typically comprising carbon fiber-reinforced polymer (C.F.R.P.) laminate skins bonded to an aluminum honeycomb core. This study focuses on presenting a framework methodology for minimizing the mass of a race car chassis by calculating an optimal baseline lamination sequence through the modification of the composite material parameters on either side of the aluminum core, using an optimization algorithm (O.A.), finite element (F.E.) analysis, composite mechanics theory, and failure criteria. Optimal solutions were derived by varying the laminae orientation and sequence parameters under two scenarios: unconstrained and constrained laminae angles. The optimization results indicate that the proposed lamination scheme reduces mass by 12.36 kg (41.66%) compared to the original lamination, with constraints imposed on laminae angles having no significant impact on the ultimate optimal outcome. Full article

High permeance combined with high salt/dye separation efficiency is a prerequisite for achieving zero-liquid-discharge treatment of saline textile wastewater by membrane technology. Thin-film nanocomposite (TFN) membranes incorporating porous nanoparticles offer a promising route to overcome the permeability–selectivity trade-off of conventional polymer membranes. In this study, a vacuum-assisted method was used to co-blend ZIF-67 and SiO₂ nanoparticles, while branched polyethyleneimine (PEI) served as a cross-linking bridge, resulting in a high-performance TFN membrane for salt/dye separation. Acting as a molecular connector, PEI coordinated with ZIF-67 through metal–amine complexation and simultaneously formed hydrogen bonds with surface hydroxyl groups on SiO₂, thereby linking ZIF-67 and SiO₂. The resulting membrane exhibited good hydrophilicity and excellent dye separation performance (water flux = 359.8 L m⁻² h⁻¹ bar⁻¹; Congo Red rejection = 99.2%) as well as outstanding selectivity in dye/salt mixtures (Congo Red/MgCl₂ selectivity of 1094). The optimal ZIF@SiO₂-PEI membrane maintained stable dye rejection over a wide range of trans-membrane pressures, initial concentrations, and pH values. These results reveal the huge potential of applying the ZIF@SiO₂-PEI TFN membranes for resource recovery in sustainable textile wastewater systems. Full article

Wave gliders’ power system shafts face complex conditions. To enhance their operational stability, it is crucial to study PTFE, a polymer material that could replace traditional metals. This study added carbon fiber (CF), titanium carbide (Ti-C), and both to a PTFE matrix. The impact of seawater immersion on water absorption and the mechanical properties was examined, as well as friction and wear characteristics under constant amplitude cyclic (CAC) loading and seawater lubrication. The results indicated that while Ti-C boosts PTFE matrix hardness, its poor binding with the PTFE matrix leads to high water absorption in Ti-C/PTFE (PTFE-3), causing a significant decrease in the mechanical properties post-immersion and poor friction and wear performance. In contrast, CFs and the PTFE matrix have good interfacial bonding and greatly improve the resistance of the PTFE matrix to cyclic loading and seawater immersion. Therefore, CF/PTFE (PTFE-2) shows good mechanical and tribological properties. Moreover, incorporating a certain amount of CFs into Ti-C enhances its adhesion to the PTFE matrix, reducing the occurrence three-body wear and allowing Ti-C to fully utilize its high hardness. Thus, the combination of Ti-C and CFs markedly improves PTFE’s mechanical and tribological properties under cyclic loading and in seawater. Full article

This study investigates the fracture toughness of adhesive joints between carbon fiber-reinforced polymer composites (CFRP) and boron-alloyed high-strength steel under Mode I and II loading, based on linear elastic fracture mechanics (LEFM). Two adhesive types were examined: the excess resin from the prepreg composite, forming a thin layer, and a toughened structural epoxy (Sika Power-533), designed for the automotive industry, forming a thick layer. Modified double cantilever beam (DCB) and end-notched flexure (ENF) specimens were used for testing. The results show that using Sika Power-533 increases the critical energy release rate by up to 30 times compared to the prepreg resin, highlighting the impact of adhesive layer thickness. Joints with the thick Sika adhesive performed similarly regardless of whether uncoated or Al–Si-coated steel was used, indicating the composite/Sika interface as the failure point. In contrast, the thin resin adhesive layer exhibited poor bonding with uncoated steel, which detached during sample preparation. This suggests that, for thin layers, the resin/steel interface is the weakest link. These findings underline the importance of adhesive selection and layer thickness for optimizing joint performance in composite–metal hybrid structures. Full article

Metal-organic frameworks or MOFs are coordination polymers consisting of cationic metal centers liked by ligands. These coordination polymers have repeating entities that extend in one, two, or three dimensions through various Metal-ligand covalent bonds. The structural diversity of MOFs allows for the fine-tuning of properties like pore size, stability, and functionality, making them ideal for a wide range of industrial, environmental, and biomedical applications. Basolite C-300, HKUST-1 or [Cu₃(btc)₂(H₂O)₃], is one of the most studied three-dimensional porous frameworks. It is a commercially available MOF, easily produced under laboratory conditions. Its unique cubic structure, with multiple pore and adsorption sites, enhances its properties. This article reviews the conventional, new, and non-conventional methods of MOF and Basolite C-300 synthesis. In addition, the structural and spectral characterization of Basolite C-300 and its analogues is described, using spectroscopic and complementary multi-techniques to obtain fundamental knowledge about their structure. Finally, the applications of Basolite C-300 and similar MOFs are discussed, emphasizing their importance in industry and materials, technologies aimed at addressing global environmental and energy-related challenges, and biomedical applications. Full article

The increasing demand for sustainable construction materials has driven the exploration of alternatives to traditional cement-based concrete. In this context, this study investigates a cement-less material, specifically an alkali-activated or geopolymer concrete (GPC), which presents potential environmental benefits. The material has been characterized with respect to both its fresh and hardened properties, providing groundwork for future structural applications. A key focus of the research is the bond behavior between GPC and reinforcing bars, including both steel and non-metallic fiber-reinforced polymer (FRP) bars. The use of non-metallic bars is particularly relevant as they offer the potential to enhance the durability of structures by mitigating issues such as corrosion. Current research lacks comprehensive studies on factors affecting stress transfer at the GPC-reinforcing bar interface, such as bar diameter, bond length, and surface finish. This study aims to expand knowledge on the bond between GPC and steel/FRP rebars through experimental and analytical approaches. The tests, which included different bar types and bond lengths, showed that GPC exhibited similar bond behavior with steel and ribbed glass FRP bars in terms of bond strength and stress-slip curves. The results indicate that GPC exhibits comparable bond strength and stress-slip behavior when reinforced with either steel or ribbed glass FRP bars. Full article

Polymer electrolytes (PEs) provide enhanced safety for high–energy–density lithium metal batteries (LMBs), yet their practical application is hampered by intrinsically low ionic conductivity and insufficient electrochemical stability, primarily stemming from suboptimal Li⁺ solvation environments and transport pathways coupled with slow polymer dynamics. Herein, we demonstrate a molecular design strategy to overcome these limitations by regulating the Li⁺ solvation structure through the synergistic interplay of conventional Lewis acid–base coordination and engineered hydrogen bond (H–bond) networks, achieved by incorporating specific H–bond donor functionalities (N,N′–methylenebis(acrylamide), MBA) into the polymer architecture. Computational modeling confirms that the introduced H–bonds effectively modulate the Li⁺ coordination environment, promote salt dissociation, and create favorable pathways for faster ion transport decoupled from polymer chain motion. Experimentally, the resultant polymer electrolyte (MFE, based on MBA) enables exceptionally stable Li metal cycling in symmetric cells (>4000 h at 0.1 mA cm⁻²), endows LFP|MFE|Li cells with long–term stability, achieving 81.0% capacity retention after 1400 cycles, and confers NCM622|MFE|Li cells with cycling endurance, maintaining 81.0% capacity retention after 800 cycles under a high voltage of 4.3 V at room temperature. This study underscores a potent molecular engineering strategy, leveraging synergistic hydrogen bonding and Lewis acid–base interactions to rationally tailor the Li⁺ solvation structure and unlock efficient ion transport in polymer electrolytes, paving a promising path towards high–performance solid–state lithium metal batteries. Full article

This study investigates the degradation mechanisms of fiber-reinforced polymer (FRP) matrices in composite insulators under partial discharge (PD) conditions. The degradation products may further cause deterioration of the electrical and chemical resistance (ECR) glass fibers. Using pyrolysis–gas chromatography-mass spectrometry (PY-GC-MS) and high-performance liquid chromatography–tandem mass spectrometry (HPLC-MS-MS), the thermal degradation gas and liquid products of the degraded FRP matrix were analyzed, revealing the presence of organic acids. These acids form when the epoxy resin’s cross-linked bonds break at high temperatures, generating anhydrides that hydrolyze into carboxylic acids in the presence of moisture. The hydrolyzation process is accelerated by hydroxyl radicals produced during PD. The resulting carboxylic acids deteriorate the glass fibers within the FRP matrix by degrading surface coupling agents and reacting with the alkali metal–silica network, leading to the substitution and precipitation of metal ions. Organic acids, particularly carboxylic acids, were found to have a more severe deteriorating effect on glass fibers compared to inorganic acids, with high temperatures exacerbating this process. These findings provide critical insights into the deterioration mechanisms of FRP under operational conditions, offering valuable guidance for optimizing manufacturing processes and enhancing the longevity of composite insulators. Full article

Unsaturated macrolactones (UMs) have long attracted researchers’ attention due to a combination of a reactive ester fragment and C=C bond in their structures. UMs of natural origin are comparatively few in number, and the task of developing synthetic approaches to new UMs is relevant. Recent advances in the synthesis of UMs cannot be dissociated from the progress in design of metathesis catalysts, since this catalytic approach is an atom-economy alternative to conventional organochemical methods. In the present review, we summarized and discussed the use of ring-closing metathesis, catalyzed by Ru and Group 6 metal complexes, in the synthesis of Ums and the advantages and shortcomings of the catalytic approach to UMs in comparison with organochemical methods. In a separate section, the use of UMs in the synthesis of unsaturated polyesters, the functionalization of these (co)polymers, and the prospects for practical use of the material obtained are also presented. It is essential that the actual approaches to UMs are often based on the use of renewable feedstocks, thereby meeting Green Chemistry principles. Full article

Many studies have examined the ability of polymer-based gels or hydrogels to serve various purposes, particularly as absorbents. Several studies have reported that polyvinyl alcohol (PVA), with specific compositions and additives, is an absorbent and a decontamination material usable for heavy metals and radioactive substances. PVA has a high cost and is slowly degradable under anaerobic conditions. This study investigated the potential of natural materials, namely cassava starch, which is an environmentally friendly, non-toxic, and readily available gel-forming polymer that, notably, is inexpensive in Indonesia. The FTIR analysis showed a bond and polymer formation between cassava starch and glycerol. The cassava starch–glycerol–water mixture was applied to media such as glass, aluminum plates, and ceramics contaminated with heavy-metal stable ions which correspond to a radionuclide. The media, stored at room temperature for 24 h, becomes a film. According to the SEM and XRF results, the gel becomes a film that binds and absorbs metals when dried. The SEM results showed the presence of metals corresponding with the sources of contamination, and the XRF results showed that the quantity of metals absorbed was large. The cassava starch gel absorption results indicated the formation of an amorphous compound, as indicated by the XRF results. Based on all the analyses, the cassava starch–glycerol gel has enormous potential. It is almost equivalent to a PVA gel as an absorbent material and heavy-metal decontamination material, when used for radioactive decontamination on the material’s surface. Full article

This paper introduces a new methodology that enables the production of polymer–metal parts through hybrid additive manufacturing. The approach combines fused filament fabrication (FFF) of polymers with adhesive bonding of metal inserts, applied during layer-by-layer construction. The work is based on unit cells designed and fabricated using eco-friendly materials—polylactic acid (PLA) and aluminum—which were subsequently analyzed for build quality and for mechanical performance under tensile lap-shear and three-point bending tests. The acquired knowledge in terms of optimal processing parameters for attaining strong polymer–metal bonds was then applied for the fabrication and testing of prototypes representing modular corner connectors for framing applications. Results on build quality demonstrate that issues, such as lumps and warping, can be solved by finetuning the 3D printing stages of the proposed methodology. In terms of destructive testing, significant improvements in the mechanical performance of PLA can be achieved, demonstrating the feasibility of the proposed methodology in integrating the lightweight properties of polymers with the stiffness of metals. This enables the development of innovative, sustainable and eco-friendly solutions that align with the growing demand for eco-friendly materials and processes in manufacturing. Full article

Precision micromilling is currently widely used for the fabrication of injection mold inserts for the mass production of microfluidic devices. However, for complex devices with micrometer-scale and high density of structures, micromilling results in high production times and costs for production runs of hundreds or thousands of units. Femtosecond laser (fs-laser) technology has emerged as a promising solution for high-precision micromachining. This study analyzes the potential of fs-laser micromachining for the fabrication of injection mold inserts for the large-scale production of thermoplastic microfluidic devices. For the evaluation of technology, a reference design was defined. The parameters of the fs-laser process were optimized to achieve high resolution of the structures and optimal surface quality, aiming to minimize production times and costs while ensuring the quality of the final part. The microstructures were replicated in two different grades of COC (Cyclic Olefin Copolymer) by injection molding. The dimensional tolerance of the structures and the surface finish achieved both in the insert and the polymer parts were characterized by scanning electron microscopy (SEM) and confocal microscopy. The surface quality of the final parts and its suitability for microfluidic fabrication were also assessed performing chemical bonding tests. The fs-laser machining process has shown great potential for the mass production of microfluidic devices. The developed process has enabled for a reduction of up to 90% in the fabrication times of the insert compared to micromilling. The parts exhibited very smooth surfaces, with roughness values (Sa) of 64.6 nm for the metallic insert and 71.8 nm and 72.9 nm for the COC E-140 and 8007S-04 replicas, respectively. The dimensional tolerance and the surface quality need to be improved to be competitive with the finishes achieved with precision micromilling. Nonetheless, there is still room for improvement considering the significant reduction in the production times through new laser processing strategies. Full article

SiC matrix composites are widely used in high-temperature structural components of aircraft engines and nuclear reactor materials because of their excellent properties such as their high modulus, high strength, corrosion resistance, and high-temperature resistance. However, the bonding of SiCf/SiC composites poses significant challenges in practical engineering applications, primarily due to residual stresses, anisotropy in composite properties, and the demanding conditions required for high-performance joints. This work reviews various bonding technologies for SiC ceramics and SiC matrix composites. These include solid-state diffusion bonding, NITE phase bonding, direct bonding without filling materials, MAX phase bonding, glass ceramic bonding, polymer precursor bonding, metal brazing bonding, and Si-C reaction bonding. Key results, such as the highest bending strength of 439 MPa achieved with Si-C reaction bonding, are compared alongside the microstructural characteristics of different joints. Additionally, critical factors for successful bonding, such as physical mismatch and metallurgical incompatibility, are discussed in detail. Future research directions are proposed, emphasizing the optimization of bonding techniques and evaluation of joint performance in harsh environments. This review provides valuable insights into advancing bonding technologies for SiC composites in aerospace and nuclear applications. Full article