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Keywords = plastic-strain control

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26 pages, 7199 KiB  
Article
Investigation of Fresh, Mechanical, and Durability Properties of Rubberized Fibre-Reinforced Concrete Containing Macro-Synthetic Fibres and Tyre Waste Rubber
by Nusrat Jahan Mim, Mizan Ahmed, Xihong Zhang, Faiz Shaikh, Ahmed Hamoda, Vipulkumar Ishvarbhai Patel and Aref A. Abadel
Buildings 2025, 15(15), 2778; https://doi.org/10.3390/buildings15152778 - 6 Aug 2025
Abstract
The growing disposal of used tyres and plastic waste in landfills poses a significant environmental challenge. This study investigates the potential of utilizing used tyre rubber and macro-synthetic fibres (MSFs) made from recycled plastics in fibre-reinforced rubberized concrete (RuFRC). Various percentages of tyre [...] Read more.
The growing disposal of used tyres and plastic waste in landfills poses a significant environmental challenge. This study investigates the potential of utilizing used tyre rubber and macro-synthetic fibres (MSFs) made from recycled plastics in fibre-reinforced rubberized concrete (RuFRC). Various percentages of tyre rubber shreds were used to replace coarse aggregates, calculated as 10%, 20%, and 30% of the volume of fine aggregates; fibre dosages (0%, 0.25%, 0.5%, 0.75%, and 1% by volume) were incorporated into the mix, and a series of physical, mechanical, and durability properties were evaluated. The results show that, as the fibre and rubber content increased, the slump of RuFRC decreased, with the lowest value obtained for concrete with 1% fibre and 30% rubber. The density of RuFRC decreases as the rubber percentage increases due to air voids and increased porosity caused by the rubber. The strength properties of RuFRC were found to decline with the increase in the rubber content, with mixes containing 30% rubber exhibiting reductions of about 60% in compressive strength, 27% in tensile strength, and 13% in flexural strength compared to the control specimen. Durability testing revealed that an increased rubber content led to higher water absorption, water penetration, and chloride ion permeability, with 30% rubber showing the highest values. However, lower rubber content (10%) and higher fibre dosages improved the durability characteristics, with water absorption reduced by up to 5% and shrinkage strains lowered by about 7%, indicating better compaction and bonding. These results indicate that RuFRC with moderate rubber and higher fibre content offers a promising balance between sustainability and performance. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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29 pages, 3167 KiB  
Article
A Comparative Evaluation of Polymer-Modified Rapid-Set Calcium Sulfoaluminate Concrete: Bridging the Gap Between Laboratory Shrinkage and the Field Strain Performance
by Daniel D. Akerele and Federico Aguayo
Buildings 2025, 15(15), 2759; https://doi.org/10.3390/buildings15152759 - 5 Aug 2025
Abstract
Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and [...] Read more.
Rapid pavement repair demands materials that combine accelerated strength gains, dimensional stability, long-term durability, and sustainability. However, finding materials or formulations that offer these balances remains a critical challenge. This study systematically evaluates two polymer-modified belitic calcium sulfoaluminate (CSA) concretes—CSAP (powdered polymer) and CSA-LLP (liquid polymer admixture)—against a traditional Type III Portland cement (OPC) control under both laboratory and realistic outdoor conditions. Laboratory specimens were tested for fresh properties, early-age and later-age compressive, flexural, and splitting tensile strengths, as well as drying shrinkage according to ASTM standards. Outdoor 5 × 4 × 12-inch slabs mimicking typical jointed plain concrete panels (JPCPs), instrumented with vibrating wire strain gauges and thermocouples, recorded the strain and temperature at 5 min intervals over 16 weeks, with 24 h wet-burlap curing to replicate field practices. Laboratory findings show that CSA mixes exceeded 3200 psi of compressive strength at 4 h, but cold outdoor casting (~48 °F) delayed the early-age strength development. The CSA-LLP exhibited the lowest drying shrinkage (0.036% at 16 weeks), and outdoor CSA slabs captured the initial ettringite-driven expansion, resulting in a net expansion (+200 µε) rather than contraction. Approximately 80% of the total strain evolved within the first 48 h, driven by autogenous and plastic effects. CSA mixes generated lower peak internal temperatures and reduced thermal strain amplitudes compared to the OPC, improving dimensional stability and mitigating restraint-induced cracking. These results underscore the necessity of field validation for shrinkage compensation mechanisms and highlight the critical roles of the polymer type and curing protocol in optimizing CSA-based repairs for durable, low-carbon pavement rehabilitation. Full article
(This article belongs to the Special Issue Study on Concrete Structures—2nd Edition)
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15 pages, 1539 KiB  
Article
Microplastics Induce Structural Color Deterioration in Fish Poecilia reticulata Mediated by Oxidative Stress
by Hong-Yu Ren, Huan-Chao Ma, Rui-Peng He, Cong-Cong Gao, Bin Wen, Jian-Zhong Gao and Zai-Zhong Chen
Fishes 2025, 10(8), 382; https://doi.org/10.3390/fishes10080382 - 5 Aug 2025
Abstract
Microplastics (MPs) can affect fish health by inducing oxidative stress, but their impact on structural coloration remains poorly understood. This study investigated the effects of environmentally relevant concentrations (16 and 160 μg/L) of MPs and nanoplastics (NPs) exposure on growth, oxidative stress and [...] Read more.
Microplastics (MPs) can affect fish health by inducing oxidative stress, but their impact on structural coloration remains poorly understood. This study investigated the effects of environmentally relevant concentrations (16 and 160 μg/L) of MPs and nanoplastics (NPs) exposure on growth, oxidative stress and structural coloration in blue strain guppy fish (Poecilia reticulata). Results showed exposure to 160 μg/L MPs significantly reduced specific growth rate of fish compared to controls. Plastic accumulation followed a dose-dependent pattern, especially within gut concentrations. Oxidative stress responses differed between MPs and NPs: 160 μg/L MPs decreased SOD activity in skin and reduced GSH levels, while 160 μg/L NPs increased MDA levels in gut tissues, indicating severe lipid peroxidation. Structural coloration analysis revealed exposure to 160 μg/L MPs decreased lightness and increased yellowness, demonstrating reduced blue coloration. This was accompanied by an increase in skin uric acid content, suggesting that guanine conversion might occur to combat oxidative stress. These findings demonstrate that MPs, particularly at high concentrations, impair growth and induce oxidative stress in guppies. To counteract stress, guanine in iridophores may be converted into uric acid, leading to a decline in structural coloration. This study is the first to reveal that MPs disrupt structural coloration of fish, providing new insights into the ecological risks of plastic pollution on aquatic organisms. Full article
(This article belongs to the Special Issue Impact of Climate Change and Adverse Environments on Aquaculture)
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21 pages, 5966 KiB  
Article
Study on Mechanism and Constitutive Modelling of Secondary Anisotropy of Surrounding Rock of Deep Tunnels
by Kang Yi, Peilin Gong, Zhiguo Lu, Chao Su and Kaijie Duan
Symmetry 2025, 17(8), 1234; https://doi.org/10.3390/sym17081234 - 4 Aug 2025
Abstract
Crack initiation, propagation, and slippage serve as the key mesoscopic mechanisms contributing to the deterioration of deep tunnel surrounding rocks. In this study, a secondary anisotropy of deep tunnels surrounding rocks was proposed: The axial-displacement constraint of deep tunnels forces cracks in the [...] Read more.
Crack initiation, propagation, and slippage serve as the key mesoscopic mechanisms contributing to the deterioration of deep tunnel surrounding rocks. In this study, a secondary anisotropy of deep tunnels surrounding rocks was proposed: The axial-displacement constraint of deep tunnels forces cracks in the surrounding rock to initiate, propagate, and slip in planes parallel to the tunnel axial direction. These cracks have no significant effect on the axial strength of the surrounding rock but significantly reduce the tangential strength, resulting in the secondary anisotropy. First, the secondary anisotropy was verified by a hybrid stress–strain controlled true triaxial test of sandstone specimens, a CT 3D (computed tomography three-dimensional) reconstruction of a fractured sandstone specimen, a numerical simulation of heterogeneous rock specimens, and field borehole TV (television) images. Subsequently, a novel SSA (strain-softening and secondary anisotropy) constitutive model was developed to characterise the secondary anisotropy of the surrounding rock and developed using C++ into a numerical form that can be called by FLAC3D (Fast Lagrangian Analysis of Continua in 3 Dimensions). Finally, effects of secondary anisotropy on a deep tunnel surrounding rock were analysed by comparing the results calculated by the SSA model and a uniform strain-softening model. The results show that considering the secondary anisotropy, the extent of strain-softening of the surrounding rock was mitigated, particularly the axial strain-softening. Moreover, it reduced the surface displacement, plastic zone, and dissipated plastic strain energy of the surrounding rock. The proposed SSA model can precisely characterise the objectively existent secondary anisotropy, enhancing the accuracy of numerical simulations for tunnels, particularly for deep tunnels. Full article
(This article belongs to the Section Engineering and Materials)
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16 pages, 3316 KiB  
Article
Experimental Study on the Electromagnetic Forming Behavior of Pre-Painted Al 99.0 Sheet
by Dorin Luca, Vasile Șchiopu and Dorian D. Luca
J. Manuf. Mater. Process. 2025, 9(8), 259; https://doi.org/10.3390/jmmp9080259 - 3 Aug 2025
Viewed by 181
Abstract
Development of forming methods for surface-coated metals is a current concern due to their economic and environmental advantages. For a successful forming operation, it is necessary that both components, the substrate and the coating, are able to withstand stress without damage until the [...] Read more.
Development of forming methods for surface-coated metals is a current concern due to their economic and environmental advantages. For a successful forming operation, it is necessary that both components, the substrate and the coating, are able to withstand stress without damage until the final shape and dimensions are reached. This goal can be achieved through good knowledge of the elastic and plastic properties of the substrate and the coating, the compatibility between them, the appropriate surface treatment, and the rigorous control of technological forming parameters. Our study was carried out with flat specimens of pre-painted Al 99.0 sheet that were electromagnetically formed by bulging. Forming behavior was investigated as depending on the initial thickness of the substrate, on the aluminum sheet pretreatment, as well as on the plastic deformation path of the metal–paint structure. To verify the damage to the paint layer, tests with increasing strains were performed, and the interface between the metal and the coating layer was investigated by scanning electron microscopy. The obtained results indicate that electromagnetic forming of pre-painted sheets can be a feasible method for specific applications if the forming degree of the substrate is tightly correlated with the type of desired coating and with the pretreatment method used for the metal surface. Full article
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12 pages, 1939 KiB  
Article
Fe3+-Modulated In Situ Formation of Hydrogels with Tunable Mechanical Properties
by Lihan Rong, Tianqi Guan, Xinyi Fan, Wenjie Zhi, Rui Zhou, Feng Li and Yuyan Liu
Gels 2025, 11(8), 586; https://doi.org/10.3390/gels11080586 - 30 Jul 2025
Viewed by 165
Abstract
Fe3+-incorporated hydrogels are particularly valuable for wearable devices due to their tunable mechanical properties and ionic conductivity. However, conventional immersion-based fabrication fundamentally limits hydrogel performance because of heterogeneous ion distribution, ionic leaching, and scalability limitations. To overcome these challenges, we report [...] Read more.
Fe3+-incorporated hydrogels are particularly valuable for wearable devices due to their tunable mechanical properties and ionic conductivity. However, conventional immersion-based fabrication fundamentally limits hydrogel performance because of heterogeneous ion distribution, ionic leaching, and scalability limitations. To overcome these challenges, we report a novel one-pot strategy where controlled amounts of Fe3+ are directly added to polyacrylamide-sodium acrylate (PAM-SA) precursor solutions, ensuring homogeneous ion distribution. Combining this with Photoinduced Electron/Energy Transfer Reversible Addition–Fragmentation Chain Transfer (PET-RAFT) polymerization enables efficient hydrogel fabrication under open-vessel conditions, improving its scalability. Fe3+ concentration achieves unprecedented modulation of mechanical properties: Young’s modulus (10 to 150 kPa), toughness (0.26 to 2.3 MJ/m3), and strain at break (800% to 2500%). The hydrogels also exhibit excellent compressibility (90% strain recovery), energy dissipation (>90% dissipation efficiency at optimal Fe3+ levels), and universal adhesion to diverse surfaces (plastic, metal, PTFE, and cardboard). Finally, these Fe3+-incorporated hydrogels demonstrated high effectiveness as strain sensors for monitoring finger/elbow movements, with gauge factors dependent on composition. This work provides a scalable, oxygen-tolerant route to tunable hydrogels for advanced wearable devices. Full article
(This article belongs to the Section Gel Chemistry and Physics)
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22 pages, 4555 KiB  
Article
Elastic–Plastic Analysis of Asperity Based on Wave Function
by Zijian Xu, Min Zhu, Wenjuan Wang, Ming Guo, Shengao Wang, Xiaohan Lu and Ziwei Li
Materials 2025, 18(15), 3507; https://doi.org/10.3390/ma18153507 - 26 Jul 2025
Viewed by 226
Abstract
This paper proposes an improved wave function asperity elastic–plastic model. A cosine function that could better fit the geometric morphology was selected to construct the asperity, the elastic phase was controlled by the Hertz contact theory, the elastoplastic transition phase was corrected by [...] Read more.
This paper proposes an improved wave function asperity elastic–plastic model. A cosine function that could better fit the geometric morphology was selected to construct the asperity, the elastic phase was controlled by the Hertz contact theory, the elastoplastic transition phase was corrected by the hyperbolic tangent function, and the fully plastic phase was improved by the projected area theory. The model broke through the limitations of the spherical assumption and was able to capture the stress concentration and plastic flow phenomena. The results show that the contact pressure in the elastic phase was 22% higher than that of the spherical shape, the plastic strain in the elastoplastic phase was 52% lower than that of the spherical shape, and the fully plastic phase reduced the contact area error by 20%. The improved hyperbolic tangent function eliminated the unphysical oscillation phenomenon in the elastoplastic phase and ensured the continuity and monotonicity of the contact variables, with an error of <5% from the finite element analysis. Meanwhile, extending the proposed model, we developed a rough surface contact model, and it was verified that the wavy asperity could better match the mechanical properties of the real rough surface and exhibited progressive stiffness reduction during the plastic flow process. The model in this paper can provide a theoretical basis for predicting stress distribution, plastic evolution, and multi-scale mechanical behavior in the connection interface. Full article
(This article belongs to the Section Materials Simulation and Design)
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33 pages, 4531 KiB  
Article
Development of the Theory of Additional Impact on the Deformation Zone from the Side of Rolling Rolls
by Valeriy Chigirinsky, Irina Volokitina, Abdrakhman Naizabekov, Sergey Lezhnev and Sergey Kuzmin
Symmetry 2025, 17(8), 1188; https://doi.org/10.3390/sym17081188 - 25 Jul 2025
Viewed by 159
Abstract
The model explicitly incorporates boundary conditions that account for the complex interplay between sections experiencing varying degrees of reduction. This interaction significantly influences the overall deformation behavior and force loading. The control effect is associated with boundary conditions determined by the unevenness of [...] Read more.
The model explicitly incorporates boundary conditions that account for the complex interplay between sections experiencing varying degrees of reduction. This interaction significantly influences the overall deformation behavior and force loading. The control effect is associated with boundary conditions determined by the unevenness of the compression, which have certain quantitative and qualitative characteristics. These include additional loading, which is less than the main load, which implements the process of plastic deformation, and the ratio of control loads from the entrance and exit of the deformation site. According to this criterion, it follows from experimental data that the controlling effect on the plastic deformation site occurs with a ratio of additional and main loading in the range of 0.2–0.8. The next criterion is the coefficient of support, which determines the area of asymmetry of the force load and is in the range of 2.00–4.155. Furthermore, the criterion of the regulating force ratio at the boundaries of the deformation center forming a longitudinal plastic shear is within the limits of 2.2–2.5 forces and 1.3–1.4 moments of these forces. In this state, stresses and deformations of the plastic medium are able to realize the effects of plastic shaping. The force effect reduces with an increase in the unevenness of the deformation. This is due to a change in height of the longitudinal interaction of the disparate sections of the strip. There is an appearance of a new quality of loading—longitudinal plastic shear along the deformation site. The unbalanced additional force action at the entrance of the deformation source is balanced by the force source of deformation, determined by the appearance of a functional shift in the model of the stress state of the metal. The developed theory, using the generalized method of an argument of functions of a complex variable, allows us to characterize the functional shift in the deformation site using invariant Cauchy–Riemann relations and Laplace differential equations. Furthermore, the model allows for the investigation of material properties such as the yield strength and strain hardening, influencing the size and characteristics of the identified limit state zone. Future research will focus on extending the model to incorporate more complex material behaviors, including viscoelastic effects, and to account for dynamic loading conditions, more accurately reflecting real-world milling processes. The detailed understanding gained from this model offers significant potential for optimizing mill roll designs and processes for enhanced efficiency and reduced energy consumption. Full article
(This article belongs to the Special Issue Symmetry in Finite Element Modeling and Mechanics)
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17 pages, 8074 KiB  
Article
Cyclic Behavior Enhancement of Existing RC Bridge Columns with UHPC Jackets: Experimental and Parametric Study on Jacket Thickness
by Songtao Gu and Rui Zhang
Buildings 2025, 15(15), 2609; https://doi.org/10.3390/buildings15152609 - 23 Jul 2025
Viewed by 196
Abstract
Ultra-high-performance concrete (UHPC) jackets present a promising solution for enhancing the seismic resilience of seismically deficient reinforced concrete (RC) bridge columns. This study investigates jacket thickness optimization through integrated experimental and numerical analyses. Quasi-static cyclic tests on a control column and a specimen [...] Read more.
Ultra-high-performance concrete (UHPC) jackets present a promising solution for enhancing the seismic resilience of seismically deficient reinforced concrete (RC) bridge columns. This study investigates jacket thickness optimization through integrated experimental and numerical analyses. Quasi-static cyclic tests on a control column and a specimen retrofitted with a 30-mm UHPC jacket over the plastic hinge region demonstrated significant performance improvements: delayed damage initiation, controlled cracking, a 24.6% increase in lateral load capacity, 139.5% higher energy dissipation at 3% drift, and mitigated post-peak strength degradation. A validated OpenSees numerical model accurately replicated this behavior and enabled parametric studies of 15-mm, 30-mm, and 45-mm jackets. Results identified the 30-mm thickness as optimal, balancing substantial gains in lateral strength (~12% higher than other thicknesses), ductility, and energy dissipation while avoiding premature failure modes—insufficient confinement in the 15-mm jacket and strain incompatibility-induced brittle failure in the 45-mm jacket. These findings provide quantitative design guidance, establishing 30 mm as the recommended thickness for efficient seismic retrofitting of existing RC bridge columns. Full article
(This article belongs to the Section Building Materials, and Repair & Renovation)
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29 pages, 7048 KiB  
Article
Research on Synergistic Control Technology for Composite Roofs in Mining Roadways
by Lei Wang, Gang Liu, Dali Lin, Yue Song and Yongtao Zhu
Processes 2025, 13(8), 2342; https://doi.org/10.3390/pr13082342 - 23 Jul 2025
Viewed by 202
Abstract
Addressing the stability control challenges of roadways with composite roofs in the No. 34 coal seam of Donghai Mine under high-strength mining conditions, this study employed integrated methodologies including laboratory experiments, numerical modeling, and field trials. It investigated the mechanical response characteristics of [...] Read more.
Addressing the stability control challenges of roadways with composite roofs in the No. 34 coal seam of Donghai Mine under high-strength mining conditions, this study employed integrated methodologies including laboratory experiments, numerical modeling, and field trials. It investigated the mechanical response characteristics of the composite roof and developed a synergistic control system, validated through industrial application. Key findings indicate significant differences in mechanical behavior and failure mechanisms between individual rock specimens and composite rock masses. A theoretical “elastic-plastic-fractured” zoning model for the composite roof was established based on the theory of surrounding rock deterioration, elucidating the mechanical mechanism where the cohesive strength of hard rock governs the load-bearing capacity of the outer shell, while the cohesive strength of soft rock controls plastic flow. The influence of in situ stress and support resistance on the evolution of the surrounding rock zone radii was quantitatively determined. The FLAC3D strain-softening model accurately simulated the post-peak behavior of the surrounding rock. Analysis demonstrated specific inherent patterns in the magnitude, ratio, and orientation of principal stresses within the composite roof under mining influence. A high differential stress zone (σ1/σ3 = 6–7) formed within 20 m of the working face, accompanied by a deflection of the maximum principal stress direction by 53, triggering the expansion of a butterfly-shaped plastic zone. Based on these insights, we proposed and implemented a synergistic control system integrating high-pressure grouting, pre-stressed cables, and energy-absorbing bolts. Field tests demonstrated significant improvements: roof-to-floor convergence reduced by 48.4%, rib-to-rib convergence decreased by 39.3%, microseismic events declined by 61%, and the self-stabilization period of the surrounding rock shortened by 11%. Consequently, this research establishes a holistic “theoretical modeling-evolution diagnosis-synergistic control” solution chain, providing a validated theoretical foundation and engineering paradigm for composite roof support design. Full article
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24 pages, 7960 KiB  
Article
Creep Behavior and Deformation Mechanism of Aluminum Alloy: Integrating Multiscale Simulation and Experiments
by Weizheng Lu, Jianguo Wu, Jiajun Liu, Xiaoai Yi, Qiyue Zhang, Yang Chen, Jia Li and Qihong Fang
Symmetry 2025, 17(7), 1146; https://doi.org/10.3390/sym17071146 - 17 Jul 2025
Viewed by 238
Abstract
Aluminum (Al) alloys exhibit exceptional mechanical properties, seeing widespread use in various industrial fields. Here, we use a multiscale simulation method combining phase field method, dislocation dynamics, and crystal plasticity finite element method to reveal the evolution law of precipitates, the interaction mechanism [...] Read more.
Aluminum (Al) alloys exhibit exceptional mechanical properties, seeing widespread use in various industrial fields. Here, we use a multiscale simulation method combining phase field method, dislocation dynamics, and crystal plasticity finite element method to reveal the evolution law of precipitates, the interaction mechanism between dislocations and precipitates, and the grain-level creep deformation mechanism in 7A09 Al alloy under creep loading. The phase field method indicates that Al alloys tend to form fewer but larger precipitates during the creep process, under the dominant effect of stress-assisted Ostwald ripening. The dynamic equilibrium process of precipitate is not only controlled by classical diffusion mechanisms, but also closely related to the local strain field induced by dislocations and the elastic interaction between precipitates. Dislocation dynamics simulations indicate that the appearance of multiple dislocation loops around the precipitate during the creep process is the main dislocation creep deformation mechanism. A crystal plasticity finite element model is established based on experimental characterization to investigate the macroscopic creep mechanism. The dislocation climb is hindered by grain boundaries during creep, and high-density dislocation bands are formed around specific grains, promoting non-uniform plastic strain and leading to strong strain gradients. This work provides fundamental insights into understanding creep behavior and deformation mechanism of Al alloy for deep-sea environments. Full article
(This article belongs to the Section Engineering and Materials)
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15 pages, 5721 KiB  
Article
Temperature-Dependent Martensitic Transformation in Cold-Rolled AISI 304 Stainless Steel
by Jaka Burja, Jernej Lindič, Barbara Šetina Batič and Aleš Nagode
Crystals 2025, 15(7), 652; https://doi.org/10.3390/cryst15070652 - 16 Jul 2025
Viewed by 252
Abstract
This study investigates the influence of plastic deformation and temperature on the formation of mechanically induced martensite and the associated changes in hardness in AISI 304 austenitic stainless steel. Cold rolling was performed at three temperatures (20 °C, 0 °C, and −196 °C) [...] Read more.
This study investigates the influence of plastic deformation and temperature on the formation of mechanically induced martensite and the associated changes in hardness in AISI 304 austenitic stainless steel. Cold rolling was performed at three temperatures (20 °C, 0 °C, and −196 °C) and various degrees of deformation (10–70%). Microstructural changes, including the formation of ε and α′ martensite, were characterized using X-ray diffraction (XRD) and electron backscatter diffraction (EBSD). The results confirm that martensitic transformation proceeds via the γ → ε → α′ sequence, with transformation rates and martensite fractions increasing at lower temperatures and higher strains. The stacking fault energy of 25.9 mJ/m2 favors this transformation pathway. Transformation rates of α′ martensite fractions significantly increased at lower temperatures and higher strains, 91.8% α′ martensite was observed at just 30% deformation at −196 °C. Hardness measurements revealed a strong correlation with martensite content: strain hardening dominated at lower deformations, while martensite formation became the primary hardening mechanism at higher deformations, especially at cryogenic temperatures. The highest hardness (551 HV) was observed in samples deformed to 70% at −196 °C. The findings provide insights into optimizing the mechanical properties of AISI 304 stainless steel through controlled deformation and temperature conditions. Full article
(This article belongs to the Special Issue Crystallization of High Performance Metallic Materials (2nd Edition))
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17 pages, 4663 KiB  
Article
Low-Cycle Fatigue Behavior of Nuclear-Grade Austenitic Stainless Steel Fabricated by Additive Manufacturing
by Jianhui Shi, Huiqiang Liu, Zhengping Liu, Runzhong Wang, Huanchun Wu, Haitao Dong, Xinming Meng and Min Yu
Crystals 2025, 15(7), 644; https://doi.org/10.3390/cryst15070644 - 13 Jul 2025
Viewed by 333
Abstract
The application of additive manufacturing technology in the field of nuclear power is becoming increasingly promising. The low-cycle fatigue behavior of Z2CN19-10 controlled-nitrogen-content stainless steel (SS) was investigated by fatigue equipment, scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and transmission electron microscopy [...] Read more.
The application of additive manufacturing technology in the field of nuclear power is becoming increasingly promising. The low-cycle fatigue behavior of Z2CN19-10 controlled-nitrogen-content stainless steel (SS) was investigated by fatigue equipment, scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), and transmission electron microscopy (TEM), including additive manufactured (AM) and forged materials. The results showed that the microstructure of the AM material exhibited anisotropy for the X, Y, and Z directions. The tensile and impact properties of the X, Y, and Z directions in AM material were similar. The fatigue life (Nf) of X- and Y-direction specimens was better than that of Z-direction specimens. The tensile, impact, and fatigue properties of all AM materials were lower than those of the forged specimens. The Z direction specimens of AM material showed the best plastic strain by the highest transition fatigue life (NT) during the fatigue strain amplitude at 0.3% to 0.6%. The forged specimens showed the best fatigue properties under the plastic strain amplitude control mode. Fatigue fracture surfaces of AM and forged materials exhibited multi- and single-fatigue crack initiation sites, respectively. This could be attributed to the presence of incompletely melted particles and manufacturing defects inside the AM specimens. The dislocation morphology of AM and forged fatigue specimens was observed to study the low-cycle fatigue behaviors in depth. Full article
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16 pages, 2521 KiB  
Article
Tuning the Gel Network Structure and Rheology of Acid-Induced Casein Gels via Thiol Blocking
by Thomas Pütz and Ronald Gebhardt
Int. J. Mol. Sci. 2025, 26(13), 6206; https://doi.org/10.3390/ijms26136206 - 27 Jun 2025
Viewed by 303
Abstract
This study systematically investigates how thiol–disulfide interactions influence the structure and mechanical properties of casein gels. Acid gels were prepared from suspensions of micellar casein (MC) powder that were heat-treated at 70 °C. Thiol groups were variably blocked with N-ethylmaleimide (NEM). The gels [...] Read more.
This study systematically investigates how thiol–disulfide interactions influence the structure and mechanical properties of casein gels. Acid gels were prepared from suspensions of micellar casein (MC) powder that were heat-treated at 70 °C. Thiol groups were variably blocked with N-ethylmaleimide (NEM). The gels were characterized using stress–strain measurements, rheological analyses, and confocal microscopy. The stress–strain curves exhibited a biphasic behavior, with an initial linear elastic phase followed by a linear plastic region and a nonlinear failure zone. Compared to control samples, the addition of 100 mM NEM reduced the gel strength by 50%, while G′ and G″ increased by around 100%, unexpectedly. NEM-treated gels consist of uniformly sized building blocks coated with a whey protein layer. Strong physical interactions and dense packing enhance viscoelasticity under short deformations but reduce the compressive strength during prolonged loading. In contrast, control samples without NEM demonstrate weak viscoelasticity and increased compressive strength. The former is attributed to a broader particle size distribution from lower acid stability in the untreated gels, while the particularly high compressive strength of heat-treated gels additionally results from disulfide cross-links. The results show that thiol blocking and heating enable the targeted formation of acid casein gels with high shear stability but a low compressive strength. Full article
(This article belongs to the Collection Feature Papers in Materials Science)
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20 pages, 2594 KiB  
Article
Plasticity, Flow Liquefaction, and Cyclic Mobility in Liquefiable Soils with Low to Moderate Plasticity
by Carmine P. Polito and James R. Martin
CivilEng 2025, 6(2), 31; https://doi.org/10.3390/civileng6020031 - 12 Jun 2025
Cited by 1 | Viewed by 1048
Abstract
Over the past several decades, extensive research has advanced the understanding of liquefaction in clean sands and sand–silt mixtures under seismic loading. However, the influence of plastic (i.e., clayey) fines on the liquefaction behavior of sandy soils remains less well understood. This study [...] Read more.
Over the past several decades, extensive research has advanced the understanding of liquefaction in clean sands and sand–silt mixtures under seismic loading. However, the influence of plastic (i.e., clayey) fines on the liquefaction behavior of sandy soils remains less well understood. This study investigates how the quantity and plasticity of fines affect both the susceptibility to liquefaction and the resulting failure mode. A series of stress-controlled cyclic triaxial tests were conducted on sand specimens containing varying proportions of non-plastic silt, kaolinite, and bentonite. Specimens were prepared at a constant relative density with fines content ranging from 0% to 37%. Two liquefaction modes were examined: flow liquefaction, characterized by sudden and large strains under undrained conditions, and cyclic mobility, which involves gradual strain accumulation without complete strength loss. The results revealed a clear relationship between soil plasticity and liquefaction mode. Specimens containing non-plastic fines or fines with a liquid limit (LL) below 20% and a plasticity index (PI) of 0 exhibited flow liquefaction. In contrast, specimens with LL > 20% and PI ≥ 7% consistently displayed cyclic mobility behavior. These findings help reconcile the apparent contradiction between laboratory studies, which often show increased liquefaction susceptibility with plastic fines, and field observations, where clayey soils frequently appear non-liquefiable. The study emphasizes the critical role of plasticity in determining liquefaction type, providing essential insight for seismic risk assessments and design practices involving fine-containing sandy soils. Full article
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