Search Results (94)

This paper presents a comprehensive review of the environmentally friendly management and reutilization of electronic waste (e-waste) plastics in flexible pavement construction. The discussion begins with an overview of e-waste management challenges and outlines key recycling approaches for converting plastic waste into asphalt-compatible materials. This review then discusses the types of e-waste plastics used for asphalt modification, their incorporation methods, and compatibility challenges. Physical and chemical treatment techniques, including the use of free radical initiators, are then explored for improving dispersion and performance. Additionally, in situations where advanced pretreatment methods are not applicable due to cost, safety, or technical constraints, the application of alternative approaches, such as the use of low-cost complementary additives, is discussed as a practical solution to enhance compatibility and performance. Finally, the influence of e-waste plastics on the conventional and rheological properties of asphalt binders, as well as the performance of asphalt mixtures, is also evaluated. Findings indicate that e-waste plastics, when combined with appropriate pretreatment methods and complementary additives, can enhance workability, cold-weather cracking resistance, high-temperature anti-rutting performance, and resistance against moisture-induced damage while also offering environmental and economic benefits. This review highlights the potential of e-waste plastics as sustainable asphalt modifiers and provides insights across the full utilization pathway, from recovery to in-field performance. Full article

This study focuses on the influence of prolonged ultraviolet (UV) irradiation on the mechanical properties and surface microstructure of glass fiber-reinforced plastics (GFRPs) and basalt fiber-reinforced plastics (BFRPs), which are widely used in construction and transport infrastructure. The relevance of the research lies in the need to improve the reliability of composite materials under extended exposure to harsh climatic conditions. Experimental tests were conducted in a laboratory UV chamber over 2000 h, simulating accelerated weathering. Mechanical properties were evaluated using three-point bending, while surface conditions were assessed via profilometry and microscopy. It was shown that GFRPs exhibit a significant reduction in flexural strength—down to 59–64% of their original value—accompanied by increased surface roughness and microdefect depth. The degradation mechanism of GFRPs is attributed to the photochemical breakdown of the polymer matrix, involving free radical generation, bond scission, and oxidative processes. To verify these mechanisms, FTIR spectroscopy was employed, which enabled the identification of structural changes in the polymer phase and the detection of mass loss associated with matrix decomposition. In contrast, BFRP retained up to 95% of their initial strength, demonstrating high resistance to UV-induced aging. This is attributed to the shielding effect of basalt fibers and their ability to retain moisture in microcavities, which slows the progress of photo-destructive processes. Comparison with results from natural exposure tests under extreme climatic conditions (Yakutsk) confirmed the reliability of the accelerated aging model used in the laboratory. Full article

As major bleaching continues to ravage reefs worldwide, there is an urgent need for active coral restoration. However, the high cost of such a project is inhibitive for many countries. Here, we introduce a cost-effective design for Acropora robusta and Acroporavalenciennesi coral gardening through fragmentation and direct transplantation. Implemented off Boundary Island, Hainan Province, China, the project demonstrated high coral survival rates (>94%) at a reduced cost of USD 2.50 per coral after 246 days, besides exhibiting an efficient outplanting rate at 30 coral h⁻¹ person⁻¹. Growth monitoring suggested that the transplanted Acropora spp. follow an exponential growth model over time. Initial fragment size did not seem to affect the growth rate of outplanted Acropora spp., although a weak negative correlation was found at day 246 for A. robusta. Finally, the design used in this study employs detachable steel grid nurseries and is plastics-free, ensuring sustainability and adaptability to different reef conditions, and thus providing a promising strategy for affordable coral reef restoration. Full article

Investigating the seismic damage mechanism of large underground complexes is essential for the safe development of urban underground space. This paper examines a five-story and three-span underground complex situated in a soft soil site. Shaking table tests were designed and conducted on both the free field and the soil–underground complex interaction system. The time–frequency evolution of the free field under various seismic motions was investigated. A combined experimental and numerical simulation approach was employed to examine the seismic response of the soil–underground complex interaction system. The structural deformation evolution, stress distribution, and development process of plastic damage under different seismic motions were analyzed. The results reveal that soft soil exhibits a significant energy amplification effect under far-field long-period ground motions. Structural deformation is mainly governed by horizontal shear. Under strong seismic excitation, plastic damage first initiates at the end of the bottom-story columns and extends to column-to-slab and wall-to-slab connections, where abrupt stiffness changes occur. Under the far-field long-period ground motion, the structural deformation, stress distribution, and plastic damage are significantly greater than those under the Shanghai artificial wave. These findings provide valuable insights for the seismic design of large underground complexes in soft soil sites. Full article

Cementing operations are among the most critical steps in oil-well construction. When performed improperly, the integrity and useful life of the well can be significantly compromised. Light cement pastes are used to cement formations with a low fracture gradient to ensure zonal isolation and maintain the integrity of the casing. Extenders are additives used to reduce the density of cement pastes, ensuring that the paste has desirable properties before and after setting. This work aimed to evaluate the application of palygorskite clay as an additive in lightweight cement pastes for oil wells, highlighting how its fibrous morphology influences the microstructure and enhances the macroscopic properties of the hardened cement matrix. For this, the clay sample was initially characterized regarding its physicochemical properties using X-ray diffraction (XRD), X-ray fluorescence (XRF), thermogravimetry (TG), textural analysis (BET/N₂), and scanning electron microscopy (SEM). Lightweight pastes (1.56 g/cm³) were then formulated, varying the clay concentration by 1%, 3%, and 6% of the total mass. Cement pastes using bentonite were also formulated for comparison. Technological tests of atmospheric consistency, rheological behavior, free water, and stability were applied. It can be noted that the pastes formulated with palygorskite had lower viscosity, reflected in the reduced plastic viscosity and yield stress values, indicating easier flow behavior when compared with bentonite-based pastes. The pastes formulated with 6% palygorskite and 3% bentonite showed satisfactory stability and drawdown results. Therefore, applying palygorskite satisfies the minimum requirements for acting as an extending agent for lightweight cement pastes and is an option for application in oil-well cementing operations. Full article

To investigate the microscopic mechanism of aging-induced “dewetting” at the matrix/filler interface in Nitrate Ester Plasticized Polyether (NEPE) propellant, this study decoupled the aging process into two factors: crosslinking density evolution and nitrate ester decomposition. Molecular dynamics (MD) simulations were employed to construct all-component matrix models and matrix/filler interface models with varying aging extents. Key parameters including crosslinking density, mechanical properties, free volume fraction, diffusion coefficients of the matrix, as well as interfacial binding energy and radial distribution function (RDF) were calculated to analyze the effects of both aging factors on “debonding”. The results indicate the following: 1. Increased crosslinking density enhances matrix rigidity, suppresses molecular mobility, and causes interfacial binding energy to initially rise then decline, peaking at 40% crosslinking degree. 2. Progressive nitrate ester decomposition expands free volume within the matrix, improves binder system mobility, and weakens nitrate ester-induced interfacial damage, thereby strengthening hydrogen bonding and van der Waals interactions at the interface. 3. The addition of a small amount of bonding agent improved the interfacial bonding energy but did not change the trend of the bonding energy with aging. Full article

Plastic waste reduction has become a global priority, with consumer engagement playing a crucial role in the success of sustainability initiatives. This study examines the demographic and behavioral determinants of consumer engagement in plastic tableware reduction. Using survey data from Hong Kong residents and a Multivariate Analysis of Variance (MANOVA) approach, this study analyzes how age, gender, education, income, housing type, order frequency, opt-out effectiveness, and their interactions influence the four dimensions of engagement, namely plastic tableware opt-out behavior, support for government policies, support for plastic-free restaurants, and price sensitivity. The results indicate that age significantly affects plastic tableware reduction engagement, with order frequency and opt-out effectiveness moderating the effects of age and education. The study contributes to the literature by providing empirical insights into consumer-driven sustainability efforts and the role of behavioral factors in shaping engagement in plastic waste reduction. These findings offer valuable implications for policymakers and businesses promoting sustainable consumption practices. Full article

Physics-informed neural networks (PINNs) offer a mesh-free approach to solving partial differential equations (PDEs) with embedded physical constraints. Although PINNs have gained traction in various engineering fields, their adoption for railway bridge analysis remains under-explored. To address this gap, a systematic review was conducted across Scopus and Web of Science (2020–2025), filtering records by relevance, journal impact, and language. From an initial pool, 120 articles were selected and categorised into nine thematic clusters that encompass computational frameworks, hybrid integration with conventional solvers, and domain decomposition strategies. Through natural language processing (NLP) and trend mapping, this review evidences a growing but fragmented research landscape. PINNs demonstrate promising capabilities in load distribution modelling, structural health monitoring, and failure prediction, particularly under dynamic train loads on multi-span bridges. However, methodological gaps persist in large-scale simulations, plasticity modelling, and experimental validation. Future work should focus on scalable PINN architectures, refined modelling of inelastic behaviours, and real-time data assimilation, ensuring robustness and generalisability through interdisciplinary collaboration. Full article

Identifying sustainable and efficient methods for the degradation of plastic waste in landfills is critical for the implementation of the Saudi Green Initiative, the European Union’s Strategic Plan, and the 2030 United Nations Action Plan, all of which are aimed at achieving a sustainable environment. This study assesses the influence of palm fronds (PFR) on the thermal degradation of polypropylene plastic (PP) using TGA/FTIR experimental measurements, thermo-kinetics, and machine learning convolutional deep learning neural networks (CDNN). Thermal degradation operations were conducted on pure materials (PFR and PP) as well as mixed (blended) materials containing 25% and 50% PFR, across degradation temperatures ranging from 25 to 600 °C and heating rates of 10, 20, and 40 °C·min⁻¹. The TGA data indicated a synergistic interaction between the agricultural waste (PFR) and PP plastic, with decreased thermal stability at temperatures below 500 °C, attributed to the hemicellulose and cellulose present in the PFR biomass. In contrast, at temperatures exceeding 500 °C, the presence of lignin retards the degradation of the PFR biomass and blends. Activation energy values between 81.92 and 299.34 kJ·mol⁻¹ were obtained through the application of the Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) model-free methods. The application of CDNN facilitated the extraction of significant features and labels, which were crucial for enhancing modeling accuracy and convergence. This modeling and simulation approach reduced the overall cost function from 41.68 to 0.27, utilizing seven hidden neurons, and 673,910 epochs in 13.28 h. This method effectively bridged the gap between modeling and experimental data, achieving an R² value of approximately 0.992, and identified sample composition as the most critical parameter influencing the thermolysis process. It is hoped that such findings may facilitate an energy-efficient pathway necessary for the thermal decomposition of plastic materials in landfills. Full article

By the late 1970s, plastics had emerged as the most widely used materials globally. The discovery, development, and processing of diverse polymeric materials have profoundly shaped modern life and driven the expansion of numerous industries. Given the widespread interest in the utilization of these materials, it has become increasingly imperative to design their life cycles from the outset. This approach aims to maximize their utility while minimizing their environmental footprint. This review aims to identify and analyze the key challenges in polymer processing applicable to both additive and formative manufacturing methods, emphasizing the relationship between processing and recycling within the framework of sustainability. Modern polymer processing techniques play a crucial role in enhancing the sustainability of polymer products by improving recycling potential (with consideration of polymer type, source, and additives), cost-effectiveness, carbon footprint, and key properties such as durability, lifespan, performance, and environmental impact. It will also explore the concept of the circular economy and its integration into modern processing methods, including extrusion, injection molding, and 3D printing. Additionally, current polymer recycling methods are analyzed with respect to their effectiveness, sustainability, and compatibility with the original materials. Moreover, the discussion emphasizes the benefits of a circular economy compared to a linear one by exploring the concepts of closed-loop and open-loop systems, along with their diverse applications depending on the material and the initial processing method employed. To ensure that humanity continues to benefit from polymer materials while striving for a waste-free environment, it is essential to integrate the principles of sustainable development from the very beginning. Full article

Age-strengthened aluminum alloys, as important lightweight structural materials, have significantly lower fatigue properties compared to non-age-strengthened aluminum alloys. In this study, the polycrystalline models containing precipitation-free zones (PFZ) were constructed by secondary development of the traditional polycrystalline model by modifying the mesh file. Polycrystalline finite element simulations of peak age-treated Al-7.02Mg-1.98Zn alloys were carried out with this model. The results demonstrate that the PFZ’s presence markedly reduces the alloy’s yield strength and a substantial stress concentration occurs adjacent to the PFZ, generating significant compressive stresses at the PFZ. Under cyclic loading, the maximum strain energy dissipation in the model containing the PFZ far exceeds that observed in the conventional polycrystalline model, and the strain energy dissipation observed in the PFZ is significantly higher than that at other locations. This indicates that the PFZ is the main region for fatigue crack initiation. In addition, the introduction of a rotation factor to simulate the inhomogeneous rotation within the grain reveals that the additional stress concentration in the PFZ introduced by the aluminum alloy-forming process further increases the fatigue crack initiation driving force. Full article

In this work, we designed a novel polyvinylidene fluoride (PVDF)@DNA solid polymer electrolyte, wherein DNA, as a plasticizer-like additive, reduced the crystallinity of the solid polymer electrolyte and improved its ionic conductivity. At the same time, due to its Lewis acid effect, DNA promotes the dissociation of lithium salts when interacting with lithium salt anions and can also fix the anions, creating more free lithium ions in the electrolyte and thus improving its ionic conductivity. However, owing to hydrogen bonding between DNA and PVDF, excess DNA occupies the lone pairs of electrons of the fluorine atoms on the PVDF molecular chains, affecting the conduction of lithium ions and the conductivity of the solid electrolyte. Hence, in this study, we investigated the effects of adding different DNA amounts to solid polymer electrolytes. The results show that 1% DNA addition resulted in the best improvement in the electrochemical performance of the electrolyte, demonstrating a high ionic conductivity of 3.74 × 10⁻⁵ S/cm (25 °C). The initial capacity reached 120 mAh/g; moreover, after 500 cycles, the all-solid-state batteries exhibited a capacity retention of approximately 71%, showing an outstanding cycling performance. Full article

Introduction: Reconstructive plastic surgeons have made great strides in the field of breast reconstruction to achieve the best results for patients undergoing treatment for breast cancer. As microsurgical techniques have evolved, these patients can benefit from additional treatment modalities to optimize the results of the reconstruction. Free tissue transfer from alternative donor sites for breast reconstruction is routinely performed, which was not possible in the past. Neurotization is now possible to address the numbness and lack of sensation to the reconstructed breast. For those patients who develop lymphedema of the upper extremity as a result of their breast cancer care, supermicrosurgical options are now available to treat and even to prevent the development of lymphedema. This study presents a narrative review regarding the latest microsurgical advancements in autologous free flap breast reconstruction. Methods: A literature review was performed on PubMed with the key words “autologous free flap breast reconstruction”, “deep inferior epigastric perforator flap”, “transverse upper gracilis flap”, “profunda artery perforator flap”, “superior gluteal artery perforator flap”, “inferior gluteal artery perforator flap”, “lumbar artery perforator flap”, “breast neurotization”, “lymphovenous bypass and anastomosis”, and “vascularized lymph node transfer”. Articles that specifically focused on free flap breast reconstruction, breast neurotization, and lymphedema surgery in the setting of breast cancer were evaluated and included in this literature review. Results: The literature search yielded a total of 4948 articles which were screened. After the initial screening, 413 articles were reviewed to assess the relevance and applicability to the current study. Conclusions: Breast reconstruction has evolved tremendously in recent years to provide the most natural and cosmetically pleasing results for those patients undergoing treatment for breast cancer. As technology and surgical techniques have progressed, breast cancer patients now have many more options, particularly if they are interested in autologous reconstruction. These advancements also provide the possibility of restoring sensibility to the reconstructed breast as well as treating the sequela of lymphedema due to their cancer treatment. Full article

Inflammatory arthritis are common chronic inflammatory autoimmune diseases characterised by progressive, destructive inflammation of the joints leading to a loss of function and significant comorbidities; importantly, there are no cures and only 20% of patients achieve drug-free remission for over 2 years. Macrophages play a vital role in maintaining homeostasis, however, under the wrong environmental cues, become drivers of chronic synovial inflammation. Based on the current “dogma”, M1 macrophages secrete pro-inflammatory cytokines and chemokines, promoting tissue degradation and joint and bone erosion which over time lead to accelerated disease progression. On the other hand, M2 macrophages secrete anti-inflammatory mediators associated with wound healing, tissue remodelling and the resolution of inflammation. Currently, four subtypes of M2 macrophages have been identified, namely M2a, M2b, M2c and M2d. However, more subtypes may exist due to macrophage plasticity and the ability for repolarisation. Macrophages are highly plastic, and polarisation exists as a continuum with diverse intermediate phenotypes. This plasticity is achieved by a highly amenable epigenome in response to environmental stimuli and shifts in metabolism. Initiating treatment during the early stages of disease is important for improved prognosis and patient outcomes. Currently, no treatment targeting macrophages specifically is available. Such therapeutics are being investigated in ongoing clinical trials. The repolarisation of pro-inflammatory macrophages towards the anti-inflammatory phenotype has been proposed as an effective approach in targeting the M1/M2 imbalance, and in turn is a potential therapeutic strategy for IA diseases. Therefore, elucidating the mechanisms that govern macrophage plasticity is fundamental for the success of novel macrophage targeting therapeutics. Full article

Understanding short fatigue-crack propagation behavior is inevitable in the defect-tolerant design of structures. Short cracks propagate differently from long cracks, and the amount of crack closure plays a key role in the propagation behavior of short cracks. In the present paper, the buildup of fatigue-crack closure due to plasticity with crack extension from crack-like defects is simulated with a modified strip yield model, which leaves plastic stretch in the wake of the advancing crack. Crack-like defects are assumed to be closure-free and do not close even under compression. The effect of the size of crack-like defects on the growth and arrest of short cracks was systematically investigated and the cyclic R-curve derived. The cyclic R-curve determined under constant amplitude loading of multiple specimens is confirmed to be independent of the initial defect length. Load-shedding and ΔK-constant loading tests are employed to extend the cyclic R-curve beyond the fatigue limit determined under constant amplitude loading. The initiation stage of cracks is taken into account in R-curves when applied to smooth specimens. Full article