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Keywords = plastic injection molding

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23 pages, 5204 KiB  
Article
Evaluation of Polypropylene Reusability Using a Simple Mechanical Model Derived from Injection-Molded Products
by Tetsuo Takayama, Rikuto Takahashi, Nao Konno and Noriyuki Sato
Polymers 2025, 17(15), 2107; https://doi.org/10.3390/polym17152107 - 31 Jul 2025
Viewed by 299
Abstract
In response to growing global concerns about plastic waste, the development of efficient recycling technologies for thermoplastics has become increasingly important. Polypropylene (PP), a widely used commodity resin, is of particular interest because of the urgent need to establish sustainable material circulation. However, [...] Read more.
In response to growing global concerns about plastic waste, the development of efficient recycling technologies for thermoplastics has become increasingly important. Polypropylene (PP), a widely used commodity resin, is of particular interest because of the urgent need to establish sustainable material circulation. However, conventional mechanical property evaluations of injection-molded products typically require dedicated specimens, which involve additional material and energy costs. As described herein, we propose a simplified mechanical model to derive Poisson’s ratio and critical expansion stress directly from standard uniaxial tensile tests of molded thermoplastics. The method based on the true stress–true strain relationship in the small deformation region was validated using various thermoplastics (PP, POM, PC, and ABS), with results showing good agreement with those of the existing literature. The model was applied further to assess changes in mechanical properties of Homo-PP and Block-PP subjected to repeated extrusion. Both materials exhibited reductions in elastic modulus and critical expansion stress with increasing extrusion cycles, whereas Block-PP showed a slower degradation rate because of thermo-crosslinking in its ethylene–propylene rubber (EPR) phase. DSC and chemiluminescence analyses suggested changes in stereoregularity and radical formation as key factors. This method offers a practical approach for evaluating recycled PP and contributes to high-quality recycling and material design. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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9 pages, 1238 KiB  
Proceeding Paper
Optimization of Mold Changeover Times in the Automotive Injection Industry Using Lean Manufacturing Tools and Fuzzy Logic to Enhance Production Line Balancing
by Yasmine El Belghiti, Abdelfattah Mouloud, Samir Tetouani, Mehdi El Bouchti, Omar Cherkaoui and Aziz Soulhi
Eng. Proc. 2025, 97(1), 54; https://doi.org/10.3390/engproc2025097054 - 30 Jul 2025
Viewed by 187
Abstract
The main thrust of the study is the need to cut down the time taken for mold changes in plastic injection molding which is fundamental to the productivity and efficiency of the process. The research encompasses Lean Manufacturing, DMAIC, and SMED which are [...] Read more.
The main thrust of the study is the need to cut down the time taken for mold changes in plastic injection molding which is fundamental to the productivity and efficiency of the process. The research encompasses Lean Manufacturing, DMAIC, and SMED which are improved using fuzzy logic and AI for rapid changeover optimization on the NEGRI BOSSI 650 machine. A decrease in downtime by 65% and an improvement in the Process Cycle Efficiency by 46.8% followed the identification of bottlenecks, externalizing tasks, and streamlining workflows. AI-driven analysis could make on-the-fly adjustments, which would ensure that resources are better allocated, and thus sustainable performance is maintained. The findings highlight how integrating Lean methods with advanced technologies enhances operational agility and competitiveness, offering a scalable model for continuous improvement in industrial settings. Full article
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27 pages, 36926 KiB  
Article
Comparison of Additive Manufacturing and Injection Molding of Biocomposites Reinforced with Alkali-Treated Wood Flour Derived from Recycled Wooden Pallets
by Mehmet Demir, Nilgül Çetin and Nasır Narlıoğlu
Polymers 2025, 17(15), 2004; https://doi.org/10.3390/polym17152004 - 22 Jul 2025
Viewed by 392
Abstract
Biodegradable polymer composites offer promising alternatives to petroleum-based plastics, supporting the principles of a zero waste and circular economy. This study investigates the reinforcing potential of alkali-treated wood flour derived from recycled pine (Pinus brutia Ten.) and poplar (Populus alba L.) [...] Read more.
Biodegradable polymer composites offer promising alternatives to petroleum-based plastics, supporting the principles of a zero waste and circular economy. This study investigates the reinforcing potential of alkali-treated wood flour derived from recycled pine (Pinus brutia Ten.) and poplar (Populus alba L.) waste wooden pallets in poly(lactic acid) (PLA) biocomposites. Wood flour was initially recovered through grinding and screening during recycling, followed by alkali treatment via a green chemistry approach to enhance interfacial bonding with the PLA matrix. The impact of alkali concentration and two fabrication methods—additive manufacturing (AM) and injection molding (IM)—on the properties of developed biocomposite materials was assessed through mechanical, physical, morphological, and thermal analyses. IM samples outperformed AM counterparts, with the IM PLA containing 30 wt% wood flour (alkali-treated with 10% solution) showing the highest mechanical gains: tensile (+71.35%), flexural (+64.74%), and hardness (+2.62%) compared to untreated samples. Moreover, the AM sample with 10 wt% wood flour and 10% alkali treatment showed a 49.37% decrease in water absorption compared to the untreated sample, indicating improved hydrophobicity. Scanning electron microscopy confirmed that alkali treatment reduced void content and enhanced morphological uniformity, while thermal properties remained consistent across fabrication methods. This work introduces a green composite using non-toxic materials and treatments, facilitating eco-friendly production aligned with zero waste and circular economy principles throughout the manufacturing lifecycle. Full article
(This article belongs to the Special Issue Polymer Composites: Structure, Properties and Processing, 2nd Edition)
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12 pages, 2558 KiB  
Article
Multi-Walled Carbon Nanotube (MWCNT)-Reinforced Polystyrene (PS) Composites: Preparation, Structural Analysis, and Mechanical and Thermal Properties
by Kadir Gündoğan and Damla Karaağaç
Polymers 2025, 17(14), 1917; https://doi.org/10.3390/polym17141917 - 11 Jul 2025
Viewed by 349
Abstract
Polystyrene (PS), a thermoplastic polymer, is used in many applications due to its mechanical performance, good chemical inertness, and excellent processability. However, it is doped with different nanomaterials for reasons such as improving its electrical conductivity and mechanical properties. In this study, carbon [...] Read more.
Polystyrene (PS), a thermoplastic polymer, is used in many applications due to its mechanical performance, good chemical inertness, and excellent processability. However, it is doped with different nanomaterials for reasons such as improving its electrical conductivity and mechanical properties. In this study, carbon nanotube (CNT)-added PS composites were produced with the aim of combining the properties of CNTs, such as their low weight and high tensile strength and Young’s modulus, with the versatility, processability, and mechanical properties of PS. In this study, multi-walled carbon nanotube (MWCNT)-reinforced polystyrene (PS) composites with different percentage ratios (0.1, 0.2, and 0.3 wt%) were prepared by a plastic injection molding method. The mechanical, microstructural, and thermal properties of the fabricated PS/MWCNT composites were characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FTIR) Spectroscopy, Atomic Force Microscopy (AFM) and Thermogravimetric Analysis (TGA) techniques. AFM analyses were carried out to investigate the surface properties of MWCNT-reinforced composite materials by evaluating the root mean square (RMS) values. These analyses show that the RMS value for MWCNT-reinforced composite materials decreases as the weight percentage of MWCNTs increases. The TGA results show that there is no change in the degradation temperature of the 0.1%- and 0.2%-doped MWCNT composites compared to pure polystyrene, but the degradation of the 0.3%-doped MWCNT composite is almost complete at a temperature of 539 °C. Among the PS/MWCNT composites, the 0.3%-doped MWCNT composite exhibits more thermal stability than pure PS and other composites. Similarly, the values of the percentage elongation and tensile strength of 0.3% MWCNT-doped composites was obtained as 1.91% and 12.174% mm2, respectively. These values are higher than the values of 0.1% and 0.2% MWCNT-doped composite materials. In conclusion, the mechanical and thermal properties of MWCNT-reinforced PS polymers provide promising results for researchers working in this field. Full article
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16 pages, 3150 KiB  
Article
Predictive ANN Modeling and Optimization of Injection Molding Parameters to Minimize Warpage in Polypropylene Rectangular Parts
by Juan Luis Gámez, Amparo Jordá-Vilaplana, Miguel Angel Peydro, Miguel Angel Selles and Samuel Sanchez-Caballero
J. Manuf. Mater. Process. 2025, 9(7), 236; https://doi.org/10.3390/jmmp9070236 - 9 Jul 2025
Viewed by 337
Abstract
Injection molding is a fundamental process for transforming plastics into various industrial components. Among the critical aspects studied in this process, volumetric contraction and warpage of plastic parts are of particular importance. Achieving precise control over warpage is crucial for ensuring the production [...] Read more.
Injection molding is a fundamental process for transforming plastics into various industrial components. Among the critical aspects studied in this process, volumetric contraction and warpage of plastic parts are of particular importance. Achieving precise control over warpage is crucial for ensuring the production of high-quality components. This research explores optimizing injection process parameters to minimize volumetric contraction and warpage in rectangular polypropylene (PP) parts. The study employs experimental analysis, MoldFlow simulation, and Artificial Neural Network (ANN) modeling. MoldFlow simulation software provides valuable data on warpage, serving as input for the ANN model. Based on the Backpropagation Neural Network algorithm, the optimized ANN model accurately predicts warpage by considering factors such as part thickness, flow path distance, and flow path tangent. The study highlights the importance of accurately setting injection parameters to achieve optimal warpage results. The BPNN-based approach offers a faster and more efficient alternative to computer-aided engineering (CAE) processes for studying warpage. Full article
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19 pages, 4947 KiB  
Article
Injection Molding Simulation of Polycaprolactone-Based Carbon Nanotube Nanocomposites for Biomedical Implant Manufacturing
by Krzysztof Formas, Jarosław Janusz, Anna Kurowska, Aleksandra Benko, Wojciech Piekarczyk and Izabella Rajzer
Materials 2025, 18(13), 3192; https://doi.org/10.3390/ma18133192 - 6 Jul 2025
Viewed by 449
Abstract
This study consisted of the injection molding simulation of polycaprolactone (PCL)-based nanocomposites reinforced with multi-walled carbon nanotubes (MWCNTs) for biomedical implant manufacturing. The simulation was additionally supported by experimental validation. The influence of varying MWCNT concentrations (0.5%, 5%, and 10% by weight) on [...] Read more.
This study consisted of the injection molding simulation of polycaprolactone (PCL)-based nanocomposites reinforced with multi-walled carbon nanotubes (MWCNTs) for biomedical implant manufacturing. The simulation was additionally supported by experimental validation. The influence of varying MWCNT concentrations (0.5%, 5%, and 10% by weight) on key injection molding parameters, i.e., melt flow behavior, pressure distribution, temperature profiles, and fiber orientation, was analyzed with SolidWorks Plastics software. The results proved the low CNT content (0.5 wt.%) to be endowed with stable filling times, complete mold cavity filling, and minimal frozen regions. Thus, this formulation produced defect-free modular filament sticks suitable for subsequent 3D printing. In contrast, higher CNT loadings (particularly 10 wt.%) led to longer fill times, incomplete cavity filling, and early solidification due to increased melt viscosity and thermal conductivity. Experimental molding trials with the 0.5 wt.% CNT composites confirmed the simulation findings. Following minor adjustments to processing parameters, high-quality, defect-free sticks were produced. Overall, the PCL/MWCNT composites with 0.5 wt.% nanotube content exhibited optimal injection molding performance and functional properties, supporting their application in modular, patient-specific biomedical 3D printing. Full article
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11 pages, 2074 KiB  
Article
The Influence of Filtration on the Results of Measurements Made with Optical Coordinate Systems
by Wiesław Zaborowski, Adam Gąska, Wiktor Harmatys and Jerzy A. Sładek
Appl. Sci. 2025, 15(13), 7475; https://doi.org/10.3390/app15137475 - 3 Jul 2025
Viewed by 261
Abstract
This article presents research and a discussion on the proper use of filtration in optical measurements. Measurements were taken using a Werth multisensory machine using a Werth Zoom optical sensor. During optical measurements, the filtration option can be used. The manufacturer defines filters [...] Read more.
This article presents research and a discussion on the proper use of filtration in optical measurements. Measurements were taken using a Werth multisensory machine using a Werth Zoom optical sensor. During optical measurements, the filtration option can be used. The manufacturer defines filters as “Dust”. They allow the machine operator to define the appropriate size depending on the type of inclusions or artifacts created in the production process. They can occur in processes such as punching on presses or production in the injection molding process of plastics. The presented research results and statistical analyses confirm the assumptions regarding the validity of using filters and their values. The use of filters with a higher value significantly affects the obtained results and forces the machine user to make a reasonable choice. Full article
(This article belongs to the Special Issue Advanced Studies in Coordinate Measuring Technique)
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17 pages, 6013 KiB  
Article
The Effect of Injection Molding Processing Parameters on Chrome-Plated Acrylonitrile Butadiene Styrene-Based Automotive Parts: An Industrial Scale
by Yunus Emre Polat, Mustafa Oksuz, Aysun Ekinci, Murat Ates and Ismail Aydin
Polymers 2025, 17(13), 1787; https://doi.org/10.3390/polym17131787 - 27 Jun 2025
Viewed by 574
Abstract
In recent years, plastic decorative materials have been used in the automotive industry due to their advantages such as being environmentally friendly, aesthetic, light and economically affordable. Plastic decorative materials can exhibit high strength and metallic reflection with metal coatings. Chrome plating is [...] Read more.
In recent years, plastic decorative materials have been used in the automotive industry due to their advantages such as being environmentally friendly, aesthetic, light and economically affordable. Plastic decorative materials can exhibit high strength and metallic reflection with metal coatings. Chrome plating is generally preferred in the production of decorative plastic parts in the automotive industry. In this study, the effect of injection molding processing parameters on the metal–polymer adhesion of chrome-plated acrylonitrile butadiene styrene (ABS) was investigated. The ABS-based front grille frames are fabricated by means of using an industrial-scale injection molding machine. Then, the fabricated ABS-based front grille frame was plated with chrome by means of the electroplating method. The metal–polymer adhesion was investigated as a function of the injection molding processing parameters by means of a cross-cut test and scanning electron microscope (SEM). As a result, it was determined that the optimal injection process parameters, a cooling time of 18 s, a mold temperature of 70 °C, injection rates of 45-22-22-20-15-10 mm/s, and packing pressures of 110-100-100 bar, were effective in enhancing polymer–metal adhesion for the ABS-based front grille frame. Full article
(This article belongs to the Special Issue Advances in Polymer Molding and Processing)
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18 pages, 2875 KiB  
Article
Potential Use of Residual Powder Generated in Cork Stopper Industry as Valuable Additive to Develop Biomass-Based Composites for Injection Molding
by Ismael Romero-Ocaña, Miriam Herrera, Natalia Fernández-Delgado and Sergio I. Molina
J. Compos. Sci. 2025, 9(7), 330; https://doi.org/10.3390/jcs9070330 - 26 Jun 2025
Viewed by 336
Abstract
This study presents the development of a sustainable composite material by incorporating by-products from the cork industry into acrylonitrile butadiene styrene (ABS), with the aim of reducing the environmental impact of plastic composites while maintaining their performance. ABS, a petroleum-based polymer, was used [...] Read more.
This study presents the development of a sustainable composite material by incorporating by-products from the cork industry into acrylonitrile butadiene styrene (ABS), with the aim of reducing the environmental impact of plastic composites while maintaining their performance. ABS, a petroleum-based polymer, was used as the matrix, and maleic anhydride (MAH) with dicumyl peroxide (DCP) served as a compatibilizing system to improve interfacial adhesion with cork microparticles. Composites were prepared with 10% w/w cork in various particle sizes and characterized via FTIR, X-ray computed tomography, SEM, mechanical testing, and thermal analysis. The best performing formulation (CPC-125) showed a reduction of only ~16% in tensile modulus and ~7% in tensile strength compared with ABS-g-MAH, with a more pronounced decrease in strain at break (3.23% vs. 17.47%) due to the cork’s inherent rigidity. Thermogravimetric and calorimetric analysis confirmed that thermal stability and processing temperatures remained largely unaffected. These results demonstrate the feasibility of incorporating cork microparticles as a bio-based reinforcing filler in ABS composites, offering a promising strategy to reduce the use of virgin plastics in applications compatible with conventional injection molding. Full article
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48 pages, 7715 KiB  
Review
Next-Generation Bioplastics for Food Packaging: Sustainable Materials and Applications
by Xiaokun Shi, Lijuan Cui, Chao Xu and Shuping Wu
Materials 2025, 18(12), 2919; https://doi.org/10.3390/ma18122919 - 19 Jun 2025
Viewed by 1676
Abstract
As the global plastic pollution problem intensifies and the environmental hazards of traditional petroleum-based plastics become increasingly significant, the development of sustainable alternative materials has become an urgent need. This paper systematically reviews the research progress, application status and future trends of new [...] Read more.
As the global plastic pollution problem intensifies and the environmental hazards of traditional petroleum-based plastics become increasingly significant, the development of sustainable alternative materials has become an urgent need. This paper systematically reviews the research progress, application status and future trends of new generation bioplastics in the field of food packaging. Bioplastics are categorized into three main groups according to their sources and degradability: biobased biodegradable materials (e.g., polylactic acid PLA, polyhydroxy fatty acid ester PHA, chitosan, and cellulose-based materials); biobased non-biodegradable materials (e.g., Bio-PE, Bio-PET); and non-biobased biodegradable materials (e.g., PBAT, PCL, PBS). Different processing technologies, such as thermoforming, injection molding, extrusion molding and coating technologies, can optimize the mechanical properties, barrier properties and freshness retention of bioplastics and promote their application in scenarios such as food containers, films and smart packaging. Although bioplastics still face challenges in terms of cost, degradation conditions and industrial support, promising future directions are found in the development of the large-scale utilization of non-food raw materials (e.g., agricultural waste, algae), nano-composite technology to enhance the performance, and the development of intelligent packaging functions. Through technological innovation and industry chain integration, bioplastics are expected to transform from an environmentally friendly alternative to a mainstream packaging material, helping to realize the goal of global carbon neutrality. Full article
(This article belongs to the Section Green Materials)
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22 pages, 4126 KiB  
Article
Investigation of Toy Parts Produced Using Injection Molding and FDM and Selection of the Best Manufacturing Method: A Multi-Criteria Approach
by Şeyda Değirmenci and Ali Osman Er
Appl. Sci. 2025, 15(12), 6725; https://doi.org/10.3390/app15126725 - 16 Jun 2025
Viewed by 363
Abstract
Three-dimensional (3D) printing has become a promising alternative to conventional methods in plastic part production, particularly for customized or low-volume applications such as toys. This study compares toy components produced by Fused Deposition Modeling (FDM) using polylactic acid (PLA) and acrylonitrile butadiene styrene [...] Read more.
Three-dimensional (3D) printing has become a promising alternative to conventional methods in plastic part production, particularly for customized or low-volume applications such as toys. This study compares toy components produced by Fused Deposition Modeling (FDM) using polylactic acid (PLA) and acrylonitrile butadiene styrene (ABS) filaments and those produced by traditional injection molding using ABS pellets. Unlike in many previous studies based on standardized test samples, a real toy part was evaluated in terms of compressive strength, dimensional accuracy, surface quality, and cost. Experimental results revealed that ABS parts produced by injection molding exhibited the highest compressive strength (3.93 kN), followed by PLA-FDM (2.97 kN) and ABS-FDM (0.95 kN). Similarly, injection-molded parts showed superior surface smoothness and dimensional accuracy. Cost analysis indicated that injection molding is economically viable only when production exceeds 735 pieces, while FDM becomes more attractive for smaller batches due to its low initial cost. A multi-criteria decision-making analysis using the TOPSIS method was conducted to integrate technical and economic factors. Results showed that injection molding is preferable for mass production, whereas PLA-FDM is more suitable for low-quantity, cost-sensitive scenarios. Full article
(This article belongs to the Section Additive Manufacturing Technologies)
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13 pages, 783 KiB  
Article
Multi-Objective Optimization of Injection Molding Process Parameters of Car Lamp Shell Based on Grey Correlation Analysis
by Ruixia Shan, Anqin Liu, Sen Jia, Changyou Liu and Wenguang Yang
Polymers 2025, 17(11), 1524; https://doi.org/10.3390/polym17111524 - 29 May 2025
Viewed by 347
Abstract
In order to improve the injection molding quality of the car lamp shell, orthogonal test, signal-to-noise ratio, gray correlation analysis, and CRITIC weight method were used to analyze the influence of mold temperature, melt temperature, injection time, velocity to pressure control, pressure holding [...] Read more.
In order to improve the injection molding quality of the car lamp shell, orthogonal test, signal-to-noise ratio, gray correlation analysis, and CRITIC weight method were used to analyze the influence of mold temperature, melt temperature, injection time, velocity to pressure control, pressure holding pressure and pressure holding time on the shrinkage index and the total deformation of warpage, and fully consider the difference and correlation between the evaluation parameters. The multi-objective optimization is transformed into single-objective optimization, and the optimal parameter set is obtained. The experimental results show that, compared with the initial analysis results, the indentation index of the headlight shell is reduced by 33.95%, the total warpage deformation is reduced by 13.99%, and the forming quality of the headlight shell is improved. The research results provide a theoretical reference value for multi-objective optimization of plastic injection molding process parameters. Full article
(This article belongs to the Section Polymer Processing and Engineering)
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12 pages, 5625 KiB  
Proceeding Paper
Molding Characteristics and Impact Strength of Polypropylene with Different Numbers of Recycling Cycles
by Hui-Mei Zheng, Jui-Chan Li, Yen-Kai Wang, Kai-Fu Liew and Hsin-Shu Peng
Eng. Proc. 2025, 92(1), 88; https://doi.org/10.3390/engproc2025092088 - 29 May 2025
Viewed by 340
Abstract
We analyzed the changes in the molding properties of polypropylene (PP) resin in the process of recycling after multiple plasticization, injection, and crushing processes. We also explored the changes in the material properties and characteristics with the ASTM-D256 impact test specimen and the [...] Read more.
We analyzed the changes in the molding properties of polypropylene (PP) resin in the process of recycling after multiple plasticization, injection, and crushing processes. We also explored the changes in the material properties and characteristics with the ASTM-D256 impact test specimen and the number of recycling cycles. After the material is injected and crushed, it is recycled to produce the material required for re-injection, and a pressure sensor is installed at the nozzle position to observe the effects of material properties and impact characteristics in recycling. Injecting and pulverizing PP several times results in looser molecular spacing, increasing the fluidity of the material. After several recycling cycles, the fluidity of the material gradually decreased. Its crystallinity fluctuated depending on the crystallinity and crystallization rates. Recycled PP materials in various molding processes were influenced by melt temperature, screw speed, back pressure, and injection speed, which also affected nozzle pressure and strength. As the melt temperature increased, the effect on the nozzle pressure and impact strength became more evident. Full article
(This article belongs to the Proceedings of 2024 IEEE 6th Eurasia Conference on IoT, Communication and Engineering)
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23 pages, 6564 KiB  
Article
Reusing Kaolin Residue from the Mining Industry to Produce PCL-Based Composites: Accelerating the Crystallization Process and Improving Mechanical Properties
by Carlos Bruno Barreto Luna, Jessika Andrade dos Santos Nogueira, José Vinícius Melo Barreto, Elieber Barros Bezerra, Fabiano Santana da Silva, Lorena Vanessa Medeiros Dantas, Renate Maria Ramos Wellen and Edcleide Maria Araújo
Int. J. Mol. Sci. 2025, 26(10), 4632; https://doi.org/10.3390/ijms26104632 - 13 May 2025
Viewed by 446
Abstract
The impact of adding 1%, 3%, and 5% by mass of kaolin residue (KR) was investigated regarding the mechanical, thermomechanical, and morphological properties, as well as the non-isothermal crystallization and melting kinetics of poly(ε-caprolactone) (PCL). The processing to obtain the PCL/KR composites was [...] Read more.
The impact of adding 1%, 3%, and 5% by mass of kaolin residue (KR) was investigated regarding the mechanical, thermomechanical, and morphological properties, as well as the non-isothermal crystallization and melting kinetics of poly(ε-caprolactone) (PCL). The processing to obtain the PCL/KR composites was carried out through extrusion in a twin-screw extruder, followed by injection molding. This study investigated the events of first melting, fusion crystallization, and second melting using differential scanning calorimetry (DSC), with heating rates ranging from 5 to 25 °C/min. Additionally, models for the expanded Prout–Tompkins equation (BNA), the nth-order reaction with m-power autocatalysis by product (Cnm), and the Sestak and Berggren equation (SB) were tested. The PCL/KR composites exhibited an increase in the elastic modulus and the heat deflection temperature (HDT) compared to the pure PCL. Furthermore, high ductility was observed, as evidenced by the impact strength and elongation at break. The good distribution of KR in the PCL matrix was confirmed by scanning electron microscopy (SEM), which contributed to a more efficient crystallization process. The increase in KR content in the PCL matrix shifted the crystallization sigmoids to higher temperatures, acting as a nucleating agent, which reduced the energy barriers and increased the crystallization temperature by up to 5 °C. The melting events did not show significant changes with the addition of the KR. The results are important for the plastics processing industry, mainly due to the opportunity to add value to the waste and use it as an additive. Full article
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24 pages, 7153 KiB  
Article
A Comparative Study on the Compatibilization of Thermoplastic Starch/Polybutylene Succinate Blends by Chain Extender and Epoxidized Linseed Oil
by Ke Gong, Yinshi Lu, Alexandre Portela, Soheil Farshbaf Taghinezhad, David Lawlor, Shane Connolly, Mengli Hu, Yuanyuan Chen and Maurice N. Collins
Macromol 2025, 5(2), 24; https://doi.org/10.3390/macromol5020024 - 12 May 2025
Cited by 1 | Viewed by 1320
Abstract
The immiscibility of thermoplastic starch (TPS) and polybutylene succinate (PBS) complicates the thermal processing of these materials. This study provides the first comparative assessment of two compatibilizers with differing reaction mechanisms, Joncryl® ADR 4468 and epoxidized linseed oil (ELO), for the optimization [...] Read more.
The immiscibility of thermoplastic starch (TPS) and polybutylene succinate (PBS) complicates the thermal processing of these materials. This study provides the first comparative assessment of two compatibilizers with differing reaction mechanisms, Joncryl® ADR 4468 and epoxidized linseed oil (ELO), for the optimization of biobased TPS/PBS blends. A total of 13 batches, varying in compatibilizer and blend composition, were processed via hot melt extrusion and injection molding to produce pellets. Blends were analyzed using tensile and impact testing, differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), rheology, and scanning electron microscopy (SEM). The findings suggest that both compatibilizers can improve the compatibility of these blends, as evidenced by higher glass transition temperatures (Tg) compared to the reference batch (100-0-N/A). Joncryl® ADR 4468 batches exhibit superior tensile strength and Young’s moduli, while ELO batches demonstrate greater elongation at break. The enhanced processability observed in Joncryl® ADR 4468 is attributed to the increased polymer chain entanglement and molecular weight, whereas ELO facilitates greater chain mobility due to its plasticizing effect. These differences arise from the distinct mechanisms of action: Joncryl® ADR 4468 promotes chain extension and crosslinking, whereas ELO mainly enhances flexibility through plasticization. Overall, this study provides a comparative assessment of these compatibilizers in TPS/PBS blends, laying the groundwork for future investigations into optimizing compatibilizer concentration and blend composition. Full article
(This article belongs to the Collection Advances in Biodegradable Polymers)
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