Search Results (121)

In this study, the atmospheric corrosion behavior of AZ31 magnesium alloy exposed in Sanya and Nansha for one year was investigated. While existing studies have characterized marine corrosion of magnesium alloys, the synergistic corrosion mechanisms under extreme tropical marine conditions (simultaneous high Cl⁻, rainfall, and temperature fluctuations) remain poorly understood—particularly regarding dynamic corrosion–product evolution. The corrosion characteristics and behavior of AZ31 magnesium alloy exposed in Sanya and Nansha were evaluated using X-ray photoelectron spectroscopy, X-ray diffraction, electrochemical measurements, scanning electron microscopy, and weight loss tests. The results showed that the main components of corrosion products were MgCO₃·xH₂O(x = 3, 5), Mg₅(CO₃)₄(OH)₂·4H₂O, Mg₂Cl(OH)₃·4H₂O, and Mg(OH)₂. The corrosion rate exposed in the Nansha was 26.5 μm·y⁻¹, which was almost two times than that in Sanya. Localized corrosion is the typical corrosion characteristic of AZ31 magnesium alloy in this tropical marine atmosphere. This study exposes the dynamic crack–regeneration mechanism of corrosion products under high-Cl⁻-rainfall synergy. The corrosion types of AZ31 magnesium alloy in this tropical marine atmosphere were mainly represented by pitting corrosion and filamentous corrosion. Full article

In this study, we investigated the electrochemical corrosion behavior and mechanisms of FeCrNi/WC alloys with varying contents of CTC-S (spherical WC) and CTC-A (angular WC) in a 3.5 wt.% NaCl solution, addressing the corrosion resistance requirements for stainless steel composites in marine environments. The electrochemical test results demonstrate that the corrosion resistance of the alloy initially increases with the CTC-A content, followed by a decrease, which is associated with the formation, stability, and rupture of the passivated film. Nyquist and Bode diagrams for electrochemical impedance spectroscopy confirm that the charge transfer resistance of the passivated film is the primary determinant of the composite’s corrosion performance. A modest increase in CTC-A contributes to the formation of a more heterogeneous second phase, providing a physical barrier and enhancing solid solution strengthening, and thus delaying the cracking and corrosion processes of the passivation film. However, excessive CTC-A content leads to significant dissolution of the alloy’s reinforcement phase and promotes decarburization, resulting in the formation of corrosion pits, craters, and cracks that compromise the passivation film and expose fresh alloy surfaces to further corrosion. When the CTC-A content is 10% and the CTC-S content is 30%, this combination results in minimal degradation in the corrosion performance (0.213 μA·cm²) while balancing the hardness and toughness of the alloy. Additionally, electrochemical evaluations reveal that incorporating angular CTC-A particles at 10 vol% effectively delays the breakdown of the passivation film by mitigating the interfacial galvanic coupling through enhancing the mechanical interlocking at the WC/FeCrNi interface. The CTC-A/CTC-S hybrid system exhibits a remarkable 62% reduction in the pitting propagation rate compared to composites reinforced solely with spherical WC, which is attributed to the preferential dissolution of angular WC protrusions that sacrificially suppress crack initiation at the phase boundaries. Full article

In open-pit bench pre-splitting blasting, the interaction of explosion-induced stress waves between blast holes is essential for safeguarding the rear rock mass. This study utilizes the caustic method to examine the propagation velocity of explosion-induced cracks, the stress intensity factor at the crack tip, and the final morphology of cracks between adjacent blast holes with varying delay times. Field pre-splitting blasting experiments were carried out to validate these effects. The experimental results reveal that, for short inter-hole delay times (0–12 μs), a “hook-like” crack intersection zone emerges between blast holes. Changes in delay time influence the patterns of crack propagation, leading to deviations in the propagation direction of cracks in subsequent blast holes due to the combined effects of stress waves and cracks from preceding holes. The fracture mechanism evolves from pure Mode I (tensile) to a mixed Mode I-II (tensile-shear). Vibration signals from the field blasting tests were analyzed using the variational mode decomposition (VMD) method. The findings indicate that optimized inter-hole delay times can reduce peak particle velocity (PPV) by 18.7–23.4% compared to simultaneous initiation, thereby significantly minimizing damage to the rear rock mass, a crucial factor for maintaining slope stability. Full article

In the present study, fatigue performance of 6061-T6 and 6082-T6 commercially available extruded aluminum alloys in dry air and 3.5 wt% NaCl-saturated environment was investigated and compared. It was found that the aggressive chloride environment accelerated fatigue failure by up to an order of magnitude compared to laboratory air. Furthermore, alloy 6061-T6 shows more predictable fatigue life, having less scatter in its time to failure in a corrosive environment. The presence of localized pitting corrosion, particularly in Fe-rich intermetallic phases, provides initiation sites for fatigue cracks, leading to premature failure in both alloys. The corrosion fatigue cracks dominantly propagate through the grain interiors rather than along grain boundaries, indicating a tendency to transgranular crack propagation mechanisms. The effect of different loading frequencies (10 Hz and 0.2 Hz) on the corrosion fatigue life of 6061-T6 alloy showed a slightly enhanced fatigue life at the higher frequency. It was also found that alloy 6061-T6 was susceptible to pitting corrosion in NaCl-saturated environments with concentrations ranging between 0.5 wt% and 3.5 wt% without exhibiting significant changes in fatigue life. Full article

This study investigates the synergistic effects of pulsed heat load and helium plasma irradiation on the surface damage evolution of high-purity tungsten, a candidate plasma-facing material (PFM) for future fusion reactors. Using a self-developed linear plasma device, tungsten samples were exposed to controlled single-pulse heat loads (32–124 MW·m⁻²) and helium plasma fluxes (7.76 × 10²²–2.40 × 10²³ ions·m⁻²·s⁻¹). SEM and XRD analyses revealed a progressive damage mechanism involving helium bubble formation, pit collapse, coral-like nanostructure evolution, and melting-induced restructuring. These surface changes were accompanied by grain refinement, lattice contraction, and peak shifts in the (110) diffraction plane. Mechanical testing showed a flux-dependent variation in hardness, with initial hardening followed by softening due to crack propagation. Surface reflectivity significantly declined with increasing load, indicating severe optical degradation. This work demonstrates the nonlinear coupling between thermal and irradiation effects in tungsten, offering new insights into damage accumulation under realistic reactor conditions. The findings highlight the dominant role of transient heat loads in driving structural and property changes and emphasize the importance of accounting for synergistic effects in material design. These results provide essential experimental data for optimizing PFMs in divertor and first-wall applications and suggest directions for future research into cyclic loading, long-term exposure, and microstructural recovery mechanisms. Full article

This study investigates the failure of a 750A dual-insulated pipeline, where cracks developed along the weld joints during heat supply resumption at the district heating facility. A comprehensive analysis was conducted through visual inspection, mechanical testing, microstructural characterization, finite element analysis (FEA), and electrochemical corrosion testing. The results indicate that cracks were generated in the heat-affected zone (HAZ), primarily caused by galvanic corrosion and thermal expansion-induced stress accumulation. Open circuit potential (OCP) measurements in a 3 M NaCl solution confirmed that the HAZ was anodic, leading to the most vulnerable position to corrosion. Furthermore, localized electrochemical tests were conducted for respective microstructural regions within the HAZ. The results reveal that coarse-grained HAZ exhibited the lowest corrosion potential, giving rise to preferential corrosion, promoting pit formation, and serving as initiation sites for stress concentration and crack propagation. FEA simulations demonstrate that pre-existing microvoids in the HAZ act as stress concentration sites, undergoing a localized stress exceeding 475 MPa. These findings emphasize the importance of controlling microstructural stability and mechanical integrity in welded pipelines, particularly in corrosive environments subjected to thermal stresses. Full article

The duration of water immersion significantly affects the mechanical response of rock materials. This study investigated the weakly cemented sandstone from the Wulagen Open-pit Mine to examine how varying immersion times affected the mineral composition, micro-porous structure, and macro-mechanical properties of the sandstone. The current study aimed to explore the mechanisms underlying the degradation of the strength and deformability of sandstone due to prolonged water exposure. The analysis showed that immersion time notably influenced the pore structure as well as the mineralogical characteristics of weakly cemented sandstone. These changes were the primary factors leading to alterations in its mechanical properties and failure modes. Specifically, with increasing immersion time, clay minerals absorbed water and expanded, with the most significant expansion occurring between 30 and 60 days. This rapid internal crack growth led to an exponential decrease in compressive strength and elastic modulus, with the most significant decline occurring between 30 and 60 days. The failure mode of the sandstone transitioned from extensional fracture to shear failure. Acoustic emission analysis revealed that, in the dry state, tensile cracks were about three times more prevalent than shear cracks, while after 60 days of immersion, shear cracks accounted for over 80%. After 60 days of immersion, microscopic cracks were fully interconnected, and the mechanical properties of the sandstone showed minimal change, with shear failure becoming predominant. These experimental results provide theoretical guidance for preventing the collapse of slopes composed of weakly cemented rock under long-term immersion conditions. Full article

This study systematically analyzes the influence of the charge length-to-diameter ratio and stemming length on the radius and volume of blasting craters in coal and rock blasting crater tests to effectively address the challenge of achieving coal–rock separation in mixed blasting construction. In addition, it examines the energy distribution mechanism of blasting fragmentation and establishes characteristic equations for coal and rock blasting craters. Numerical simulations and blasting tests are conducted to investigate the casting effect of rock benches and the fragmentation characteristics of coal and rock benches under different charge structures. The results indicate that when the ratio of charge length to stemming length exceeds 0.91 and 0.74 for the coal and rock benches, respectively, the utilization rate of explosive energy for rock fragmentation gradually surpasses that for rock throwing. The charging structure is identified as a key factor in achieving coal–rock mixed blasting and separation mining. The explosive energy is effectively utilized with a bottom interval length of 2 m for rock benches and a stemming length ranging from 2.5 to 3 m for coal seams. This configuration raises the connectivity of rock damage cracks, improves the distribution of tensile cracks at the top of the coal seam, and prevents bulging or coal–rock interactions (blasting mixing) at the coal–rock interface. The findings demonstrate that the optimized charging structure effectively achieves separate mining in coal–rock mixed blasting, fulfilling the requirement of avoiding coal–rock mixing during blasting. The research provides valuable mining strategies and technical experience for achieving separate mining in coal–rock mixed blasting in open-pit coal mines and improving the recovery of thin coal seams. Full article

Microplastics (MPs) and antibiotics are widely detected in water bodies. However, the adsorption behavior and mechanism of different particle size polystyrene (PS) MPs on macrolide antibiotics under natural aging remain to be elucidated. In this study, potassium persulfate (K₂S₂O₈) was used to simulate the natural aging process of PS MPs. The adsorption behavior and mechanism of different size PS (80 and 400 μm) toward azithromycin (AZI), clarithromycin (CLA), and erythromycin (ERY) were investigated. Results of SEM showed that the surface roughness of aged PS MPs increased with the appearance of cracks, pits, and pores. XPS and FTIR analyses showed enhanced C=O functional groups in the aging process. The adsorption isotherm models revealed that the aging processes enhanced the AZI, CLA, and ERY adsorption tendency, as evidenced by the highest adsorption capacity for aged-80 μm (645, 665, 184 mg/kg) > original-80 μm (412, 420, 120 mg/kg), and aged-400 μm (280, 330, 110 mg/kg) > original-400 μm (197, 308, 100 mg/kg). Kinetic model fitting revealed that the adsorption process occurred in three stages: rapid, slow, and saturation. Adsorption kinetic curves for original and aged PS MPs conformed to the pseudo-second-order kinetic model. In contrast, the adsorption isotherm data fit the Langmuir model, indicating that the process primarily involved uniform monolayer chemical adsorption. Our findings provide insights into the substantial changes in the interactions between PS and macrolide antibiotics with aging processes. Full article

Background/Objectives: Peri-implantitis often necessitates surgical intervention, with implantoplasty being proposed as a decontamination method in resective surgeries. This mechanical cleaning technique aims to halt disease progression by removing bacterial colonies. However, implantoplasty may compromise mechanical properties, reduce corrosion resistance, and lead to cytotoxic effects due to titanium particle release. This study aimed to evaluate the corrosion and mechanical resistance of implantoplasty-treated dental implants, with and without bacterial contamination. Methods: Twenty dental implants were divided into three groups: control (C), implantoplasty (IP), and implantoplasty with bacterial contamination (IPC) using Streptococcus aureus and Porphyromonas gingivalis. Scanning electron microscopy was used to assess surface morphology. Fatigue life curves were obtained using a Bionix servohydraulic machine, and electrochemical corrosion tests were conducted to measure corrosion potentials and intensities. Results: The IPC group demonstrated significantly lower fatigue resistance and higher susceptibility to corrosion compared to the control and IP groups. Fatigue life decreased by 21.7%, and corrosion current density (ICORR) increased from 0.025 μA/cm² (control) to 0.089 μA/cm² (IP) and 0.122 μA/cm² (IPC). Corrosion potential (ECORR) shifted from −380 mV (control) to −450 mV (IP) and −495 mV (IPC). Surface defects caused by bacterial colonization facilitated stress concentration and crack initiation during fatigue testing. Conclusions: Dental implants treated with implantoplasty and exposed to bacterial contamination exhibit significantly reduced mechanical and corrosion resistance. Bacterial activity exacerbates surface vulnerability, leading to titanium loss and pitting corrosion. These findings highlight the clinical implications of bacterial colonization on implantoplasty-treated surfaces. Full article

The present study aims to assess the impact of hot isostatic pressing (HIP) treatment on refractory high-entropy alloy (HEA) WTaMoNbV produced by the laser powder bed fusion (LPBF) process. This was carried out by examining the functional properties of this HEA in terms of mechanical and environmental performance. The microstructure of the tested HEA was evaluated using optical microscopy, scanning electron microscopy (SEM), and X-ray diffraction (XRD). Mechanical properties were examined via compression tests, while environmental behavior was evaluated by immersion tests and potentiodynamic polarization. The obtained results demonstrate that HIP treatment improved the alloy’s density from 11.27 to 11.38 g/cm³ and increased its ultimate compression strength by 11.5% (from 1094 to 1220 MPa). This modest favorable effect was attributed to the improvement in bulk properties by eliminating a large part of the sub-grain boundaries and reducing the amount of inherent printing defects, mainly in the form of internal cracking. The advantages offered by HIP were also manifested in surface quality improvement from N11 to N10 grades and enhanced environmental performance, reducing pitting density from 34,155 to 9677 pits/cm². Full article

Parallelepipeds specimens were made to further investigate the rockburst occurrence mechanism of ore pillars in underground mining units. The investigation was carried out with uniaxial compression systems and real-time testing systems, such as stress, video, and acoustic emission, combined with digital image correlation (DIC) and SEM electron microscope scanning technology, to systematically analyze the evolution of rockburst of ore pillars, strain field characteristics, acoustic emission characteristics, mesoscopic characteristics of the rockburst fracture, morphology of the bursting crater, and debris characteristics. The findings demonstrate that the pillar’s rockburst process went through four stages, including the calm period, the particle ejection period, the block spalling period, and the full collapse period. According to DIC digital image correlation technology, the development of cracks in the rock is not obvious during the calm period, but during the small particle ejection and block spalling periods, the microcracks started to form and expand more quickly and eventually reached the critical surface of the rock, resulting in the formation of a complete macro-rockburst rupture zone. During stage I of the test, the rate of acoustic emission events and energy was relatively low; from stages II to IV, the rate gradually increased; and in stage V, the rate of acoustic emission events and energy reached its maximum value at the precise moment the rock exploded, releasing all of its stored energy. The specimen pit section primarily exhibits shear damage and the fracture exhibits shear fracture morphology, while the ejecta body primarily exhibits tensile damage and the fracture exhibits tensile fracture morphology. The location of the explosion pit is distributed on the left and right sides of the middle pillar of the specimen, and the shape is a deep “V”. The majority of the rockburst debris is greater than 5 mm, and it mostly takes the shape of thin plates, which is comparable to the field rockburst debris’s shape features. Full article

Mechanical gears are essential in power transmission systems across various industrial applications. Their performance is critically influenced by residual stresses from manufacturing processes like induction hardening, case hardening, and shot peening. Surface compressive residual stresses enhance resistance to pitting fatigue, bending fatigue and crack propagation, improving overall hardness. In the present work, a Non-Destructive Thermographic method (Active thermography), based on measurement of the thermal diffusivity parameter, is presented to characterize the surface treatments applied to gears. Surface hardness was measured using a micro-hardness tester, and residual stresses were determined with an X-Ray diffractometer, showing variations due to surface treatments. The variation in the thermal diffusivity parameter, obtained using the Slope Method, was found to be an indicator of the surface treatments’ effectiveness. Full article

Red sandstone is widely distributed in southern China. Due to the significant difference in mechanical properties before and after hydration and its poor water stability, red sandstone often triggers landslide accidents. In this paper, red sandstone from an open pit slope in Jiangxi Province was taken as the research object. Two variables, namely the initial saturation degree (25%, 50%, 75%, and 100%) and the number of wetting–drying cycles (0, 10, 20, 30, and 40), were set. With the help of nuclear magnetic resonance, the Brazilian disc test, and fractal theory, the relationships among its meso-structure, macroscopic fracture mechanics characteristics, and deterioration mechanism were analyzed. The research results are as follows: (1) Wetting–drying cycles have a significant impact on the pore structure and fracture mechanics characteristics of red sandstone. Moreover, the higher the initial saturation degree, the more obvious the deterioration effect of the wetting–drying cycles on the rock mass. (2) After further subdividing the pores according to their size for research, it was found that sandstone is mainly composed of mesopores, and the deterioration laws of different types of pores after the wetting–drying cycles are different. The porosities of total pores and macropores increase, while the proportions of mesopores and micropores decrease. The fractal dimensions of macropores and total pores of each group of rock samples are all within the range of 2–3, and the fractal dimension value increases with the increase in the number of wetting–drying cycles, showing significant and regular fractal characteristics. Micropores and some mesopores do not possess fractal characteristics. The fractal dimension of rock samples basically satisfies the rule that the larger the pore diameter, the larger the fractal dimension and the more complex the pore structure. (3) Both the type I and type II fracture toughness of rock samples decrease with the increase in the number of cycles, and the decrease is the most significant when the initial saturation degree is 100%. After 40 cycles, the decreases in type I and type II fracture toughness reach 23.578% and 30.642%, respectively. The fracture toughness is closely related to the pore structure. The porosity and fractal dimension of rock samples and their internal macropores are linearly negatively correlated with the type II fracture toughness. The development of the macropore structure is the key factor affecting its fracture mechanics performance. (4) After the wetting–drying cycles, the internal pores of red sandstone continue to develop. The number of pores increases, the pore diameter enlarges, and the proportion of macropores rises, resulting in internal damage to the rock mass. When bearing loads, the expansion and connection of internal cracks intensify, ultimately leading to the failure of the rock mass. The research results can provide important reference for the stability analysis of sandstone slope engineering. Full article

The relationship between slabbing failure and rockburst has become a hot issue in rockburst research. In this paper, the experimental system of impact rockburst is used to conduct a simulation experiment of rockburst induced by slab failure on metamorphic sandstone samples taken from the deep-buried horseshoe-shaped tunnel in Gaoloushan, with “pan-shaped” rockburst pits on site and laboratory simulation experiments, which prove the rationality of the experimental results of rockburst. The quantitative analysis of the displacement field in the process of the slab buckling rockburst is carried out, which shows that the slab structure will undergo a long period of gestation before its formation, and the formation of the slab structure will accelerate the occurrence of rockburst. This type of rockburst has attenuation characteristics in the process of rockburst; in addition, the phenomenon of “slab buckling circle” is found. The generation of the “slab buckling circle” and the formation of slab buckling cracks are inconsistent, which is a time-lagged fracture in engineering. The relationship between the rupture parameters of rockburst disaster rock mass and time shows a compound exponential growth relationship, revealing that the mechanism of the slab buckling rockburst can be regarded as the result of the combined action of shear crack and tension crack, which plays a leading role, reflecting the characteristic of progressive fracture development. It is a typical progressive fracture-induced instability rockburst model, which is a strain-lag rockburst. Full article