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Keywords = photo luminance

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23 pages, 44483 KiB  
Article
Morphological Background-Subtraction Modeling for Analyzing Traffic Flow
by Erik-Josué Moreno-Mejía, Daniel Canton-Enriquez, Ana-Marcela Herrera-Navarro and Hugo Jiménez-Hernández
Modelling 2025, 6(2), 38; https://doi.org/10.3390/modelling6020038 - 9 May 2025
Viewed by 1168
Abstract
Automatic surveillance systems have become essential tools for urban centers. These technologies enable intelligent monitoring that is both versatile and non-intrusive. Today, these systems can analyze various aspects, such as urban traffic, citizen behavior, and the detection of unusual activities. Most intelligent systems [...] Read more.
Automatic surveillance systems have become essential tools for urban centers. These technologies enable intelligent monitoring that is both versatile and non-intrusive. Today, these systems can analyze various aspects, such as urban traffic, citizen behavior, and the detection of unusual activities. Most intelligent systems utilize photo sensors to gather information and assess situations. They analyze data sequences from these photo sensors over time to detect moving objects or other relevant information. In this context, background modeling approaches are crucial for efficiently detecting moving objects by differentiating between the foreground and background, which serves as the basis for further analysis. Although current methods are effective, the dynamic nature of outdoor environments can limit their performance due to numerous external variables that affect the collected information. This paper introduces a novel algorithm that uses mathematical morphology to create a background model by analyzing texture information in discrete spaces, leading to an efficient solution for the background subtraction task. The algorithm dynamically adjusts to global luminance conditions and effectively distinguishes texture information to label the foreground and background using morphological filters. A key advantage of this approach is its use of discrete working spaces, which enables faster implementation on standard hardware, making it suitable for a variety of devices. Finally, our proposal is tested against reference datasets of surveillance and common background subtraction algorithms, demonstrating that our method adapts better to outdoor conditions, making it more robust in detecting different moving objects. Full article
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23 pages, 4866 KiB  
Article
Developing an Integrated Soft-Switching Bidirectional DC/DC Converter for Solar-Powered LED Street Lighting
by Saeed Danyali, Mohammadamin Shirkhani, Jafar Tavoosi, Ali Ghazi Razi, Mostafa M. Salah and Ahmed Shaker
Sustainability 2023, 15(20), 15022; https://doi.org/10.3390/su152015022 - 18 Oct 2023
Cited by 16 | Viewed by 2360
Abstract
In the current era marked by the growing adoption of renewable energy sources, the use of photovoltaic-powered LED streetlights, known for their enhanced efficiency and extended lifespan, is on the rise. This lighting solution encompasses essential components such as a photovoltaic (PV) panel, [...] Read more.
In the current era marked by the growing adoption of renewable energy sources, the use of photovoltaic-powered LED streetlights, known for their enhanced efficiency and extended lifespan, is on the rise. This lighting solution encompasses essential components such as a photovoltaic (PV) panel, an energy storage system, LED luminaires, and a controller responsible for supervising power distribution and system operations. This research introduces a novel approach involving a ZVS (zero-voltage switching) bidirectional boost converter to manage the interaction among the PV panel, LED lights, and battery storage within the system. To elevate system efficiency, a modified version of the conventional bidirectional boost converter is employed, incorporating an auxiliary circuit encompassing a capacitor, inductor, and switch. This configuration enables soft switching in both operational modes. During daytime, the converter operates in the buck mode, accumulating solar energy in the battery. Subsequently, at night, the battery discharges energy to power the LED lights through the converter’s boost operation. In this study, the PET (photo-electro-thermal) theory is harnessed, coupled with insights into heatsink characteristics and the application of a soft-switching bidirectional boost converter. This integrated approach ensures optimal driving of the LED lights at their ideal operating voltage, resulting in the generation of optimal luminous flux. The proposed LED lighting system is thoroughly examined, and theoretical outcomes are validated through simulations using the PSCAD/EMTDC version 4.2.1 software platform. Full article
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17 pages, 9527 KiB  
Article
Two Residual Attention Convolution Models to Recover Underexposed and Overexposed Images
by Noorman Rinanto and Shun-Feng Su
Symmetry 2023, 15(10), 1850; https://doi.org/10.3390/sym15101850 - 1 Oct 2023
Cited by 2 | Viewed by 1732
Abstract
Inconsistent lighting phenomena in digital images, such as underexposure and overexposure, pose challenges in computer vision. Many studies have developed to address these issues. However, most of these techniques cannot remedy both exposure problems simultaneously. Meanwhile, existing methods that claim to be capable [...] Read more.
Inconsistent lighting phenomena in digital images, such as underexposure and overexposure, pose challenges in computer vision. Many studies have developed to address these issues. However, most of these techniques cannot remedy both exposure problems simultaneously. Meanwhile, existing methods that claim to be capable of handling these cases have not yielded optimal results, especially for images with blur and noise distortions. Therefore, this study proposes a system to improve underexposed and overexposed photos, consisting of two different residual attention convolution networks with the CIELab color space as the input. The first model working on the L-channel (luminance) is responsible for recovering degraded image illumination by using residual memory block networks with self-attention layers. The next model based on dense residual attention networks aims to restore degraded image colors using ab-channels (chromatic). A properly exposed image is produced by fusing the output of these models and converting them to RGB color space. Experiments on degraded synthetic images from two public datasets and one real-life exposure dataset demonstrate that the proposed system outperforms the state-of-the-art algorithms in optimal illumination and color correction outcomes for underexposed and overexposed images. Full article
(This article belongs to the Special Issue Symmetry in Computational Intelligence and Applications)
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13 pages, 3326 KiB  
Article
Thin Luminous Tracks of Particles Released from Electrodes with A Small Radius of Curvature in Pulsed Nanosecond Discharges in Air and Argon
by Victor F. Tarasenko, Dmitry V. Beloplotov, Alexei N. Panchenko and Dmitry A. Sorokin
Surfaces 2023, 6(2), 214-226; https://doi.org/10.3390/surfaces6020014 - 14 Jun 2023
Cited by 6 | Viewed by 2160
Abstract
Features of the nanosecond discharge development in a non-uniform electric field are studied experimentally. High spatial resolution imaging showed that thin luminous tracks of great length with a cross-section of a few microns are observed against the background of discharge glow in air [...] Read more.
Features of the nanosecond discharge development in a non-uniform electric field are studied experimentally. High spatial resolution imaging showed that thin luminous tracks of great length with a cross-section of a few microns are observed against the background of discharge glow in air and argon. It has been established that the detected tracks are adjacent to brightly luminous white spots on the electrodes or in the vicinity of these spots, and are associated with the flight of small particles. It is shown that the tracks have various shapes and change from pulse to pulse. The particle tracks may look like curvy or straight lines. In some photos, they can change their direction of movement to the opposite. It was found that the particle’s track abruptly breaks and a bright flash is visible at the break point. The color of the tracks differs from that of the spark leaders, while the bands of the second positive nitrogen system dominate in the plasma emission spectra during the existence of a diffuse discharge. Areas of blue light are visible near the electrodes as well. The development of glow and thin luminous tracks in the gap during its breakdown is revealed using an ICCD camera. Physical reasons for the observed phenomena are discussed. Full article
(This article belongs to the Collection Featured Articles for Surfaces)
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15 pages, 3746 KiB  
Article
Research on Improved Retinex-Based Image Enhancement Method for Mine Monitoring
by Feng Tian, Tingting Chen and Jing Zhang
Appl. Sci. 2023, 13(4), 2672; https://doi.org/10.3390/app13042672 - 19 Feb 2023
Cited by 13 | Viewed by 2666
Abstract
An improved Retinex fusion image enhancement algorithm is proposed for the traditional image denoising methods and problems of halo enlargement and image overexposure after image enhancement caused by the existing Retinex algorithm. First, a homomorphic filtering algorithm is used to enhance each RGB [...] Read more.
An improved Retinex fusion image enhancement algorithm is proposed for the traditional image denoising methods and problems of halo enlargement and image overexposure after image enhancement caused by the existing Retinex algorithm. First, a homomorphic filtering algorithm is used to enhance each RGB component of the underground coal mine surveillance image and convert the image from RGB space to HSV space. Second, bilateral filtering and multi-scale retinex with color restoration (MSRCR) fusion algorithms are used to enhance the luminance V component while keeping the hue H component unchanged. Third, adaptive nonlinear stretching transform is used for the saturation S-component. Last, the three elements are combined and converted back to RGB space. MATLAB simulation experiments verify the superiority of the improved algorithm. Based on the same dataset and experimental environment, the improved algorithm has a more uniform histogram distribution than the multi-scale Retinex (msr) algorithm and MSRCR algorithm through comparative experiments. At the same time, the peak signal-to-noise ratio (PSNR), structural similarity (SSIM), standard deviation, average gradient, mean value, and colour picture information entropy of the images were improved by 8.28, 0.15, 4.39, 7.38, 52.92 and 2.04, respectively, compared to the MSR algorithm, and 3.97, 0.02, 34.33, 60.46, 26.21, and 1.33, respectively, compared to the MSRCR algorithm. The experimental results show that the image quality, brightness and contrast of the images enhanced by the improved Retinex algorithm are significantly enhanced, and the amount of information in the photos increases, the halo and overexposure in the images are considerably reduced, and the anti-distortion performance is also improved. Full article
(This article belongs to the Special Issue Artificial Intelligence Applications in Mining and Mineral Processing)
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14 pages, 3318 KiB  
Article
Biogenic Synthesis of Fluorescent Carbon Dots (CDs) and Their Application in Bioimaging of Agricultural Crops
by Akshay M. Pete, Pramod U. Ingle, Rajesh W. Raut, Sudhir S. Shende, Mahendra Rai, Tatiana M. Minkina, Vishnu D. Rajput, Valery P. Kalinitchenko and Aniket K. Gade
Nanomaterials 2023, 13(1), 209; https://doi.org/10.3390/nano13010209 - 3 Jan 2023
Cited by 16 | Viewed by 3814
Abstract
Fluorescent nanoparticles have a transformative potential for advanced sensors and devices for point-of-need diagnostics and bioimaging, bypassing the technical burden of meeting the assay performance requirements. Carbon dots (CDs) are rapidly emerging carbon-based nanomaterials. Regardless of their fate, they will find increasing applications. [...] Read more.
Fluorescent nanoparticles have a transformative potential for advanced sensors and devices for point-of-need diagnostics and bioimaging, bypassing the technical burden of meeting the assay performance requirements. Carbon dots (CDs) are rapidly emerging carbon-based nanomaterials. Regardless of their fate, they will find increasing applications. In this study, a simple approach for synthesizing CDs from fruit peels was developed. The CDs were fabricated from Annona squamosa (L.) peels using a carbonization technique through microwave-assisted hydrothermal digestion at temperatures around 200 °C. Synthesized CDs were detected using a UV transilluminator for the preliminary confirmation of the presence of fluorescence. UV–Vis spectrophotometry (absorbance at 505 nm) analysis, zeta potential measurement (−20.8 mV), nanoparticles tracking analysis (NTA) (average size: 15.4 nm and mode size: 9.26 nm), photoluminescence, and Fourier transform infrared (FT-IR) analysis were used to identify the capping functional groups on the CDs. The total quantum yield exhibited was 8.93%, and the field emission scanning electron microscopy (FESEM) showed the size range up to 40 nm. The germinating mung bean (Vigna radiata (L.)) seeds were incubated with biogenically synthesized CDs to check the absorption of CDs by them. The fluorescence was observed under a UV-transilluminator in the growing parts of seeds, indicating the absorption of CDs during the germination, development, and growth. These fluorescent CDs could be used as a bioimaging agent. This novel method of synthesizing CDs was found to be eco-friendly, rapid, and cost-effective. Full article
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19 pages, 5900 KiB  
Article
Milk-Derived Carbon Quantum Dots: Study of Biological and Chemical Properties Provides Evidence of Toxicity
by Hasan Shabbir, Konrad Wojtaszek, Bogdan Rutkowski, Edit Csapó, Marek Bednarski, Anita Adamiec, Monika Głuch-Lutwin, Barbara Mordyl, Julia Druciarek, Magdalena Kotańska, Piotr Ozga and Marek Wojnicki
Molecules 2022, 27(24), 8728; https://doi.org/10.3390/molecules27248728 - 9 Dec 2022
Cited by 28 | Viewed by 3525
Abstract
Carbon dots (CDs) are carbon-based zero-dimensional nanomaterials that can be prepared from a number of organic precursors. In this research, they are prepared using fat-free UHT cow milk through the hydrothermal method. FTIR analysis shows C=O and C-H bond presence, as well as [...] Read more.
Carbon dots (CDs) are carbon-based zero-dimensional nanomaterials that can be prepared from a number of organic precursors. In this research, they are prepared using fat-free UHT cow milk through the hydrothermal method. FTIR analysis shows C=O and C-H bond presence, as well as nitrogen-based bond like C-N, C=N and –NH2 presence in CDs, while the absorption spectra show the absorption band at 280 ± 3 nm. Next, the Biuret test was performed, with the results showing no presence of unreacted proteins in CDs. It can be said that all proteins are converted in CDs. Photo luminance spectra shows the emission of CDs is 420 nm and a toxicity study of CDs was performed. The Presto Blue method was used to test the toxicity of CDs for murine hippocampal cells. CDs at a concentration of 4 mg/mL were hazardous independent of synthesis time, while the toxicity was higher for lower synthesis times of 1 and 2 h. When the concentration is reduced in 1 and 2 h synthesized CDs, the cytotoxic effect also decreases significantly, ensuring a survival rate of 60–80%. However, when the synthesis time of CDs is increased, the cytotoxic effect decreases to a lesser extent. The CDs with the highest synthesis time of 8 h do not show a cytotoxic effect above 60%. The cytotoxicity study shows that CDs may have a concentration and time–dependent cytotoxic effect, reducing the number of viable cells by 40%. Full article
(This article belongs to the Special Issue Functional Carbon Quantum Dots: Synthesis and Applications)
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18 pages, 4082 KiB  
Article
Numerical and Experimental Analysis of Shear Stress Influence on Cellular Viability in Serpentine Vascular Channels
by Khemraj Deshmukh, Saurabh Gupta, Kunal Mitra and Arindam Bit
Micromachines 2022, 13(10), 1766; https://doi.org/10.3390/mi13101766 - 18 Oct 2022
Cited by 7 | Viewed by 3302
Abstract
3D bioprinting has emerged as a tool for developing in vitro tissue models for studying disease progression and drug development. The objective of the current study was to evaluate the influence of flow driven shear stress on the viability of cultured cells inside [...] Read more.
3D bioprinting has emerged as a tool for developing in vitro tissue models for studying disease progression and drug development. The objective of the current study was to evaluate the influence of flow driven shear stress on the viability of cultured cells inside the luminal wall of a serpentine network. Fluid–structure interaction was modeled using COMSOL Multiphysics for representing the elasticity of the serpentine wall. Experimental analysis of the serpentine model was performed on the basis of a desirable inlet flow boundary condition for which the most homogeneously distributed wall shear stress had been obtained from numerical study. A blend of Gelatin-methacryloyl (GelMA) and PEGDA200 PhotoInk was used as a bioink for printing the serpentine network, while facilitating cell growth within the pores of the gelatin substrate. Human umbilical vein endothelial cells were seeded into the channels of the network to simulate the blood vessels. A Live-Dead assay was performed over a period of 14 days to observe the cellular viability in the printed vascular channels. It was observed that cell viability increases when the seeded cells were exposed to the evenly distributed shear stresses at an input flow rate of 4.62 mm/min of the culture media, similar to that predicted in the numerical model with the same inlet boundary condition. It leads to recruitment of a large number of focal adhesion point nodes on cellular membrane, emphasizing the influence of such phenomena on promoting cellular morphologies. Full article
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1 pages, 197 KiB  
Abstract
Public Lighting Recognition System Based on Colored Reflection Index and Computational Machine Learning
by Francisco Fambrini, Diogo Gará Caetano, Rangel Arthur and Yuzo Iano
Eng. Proc. 2022, 21(1), 56; https://doi.org/10.3390/engproc2022021056 - 13 Sep 2022
Viewed by 1008
Abstract
Identifying which type of lamp is installed on each public lighting pole and evaluating its luminous power is important because the new light-emitting diodes (LED)-type models are much more economical in terms of energy, and energy distribution companies need to know the consumption [...] Read more.
Identifying which type of lamp is installed on each public lighting pole and evaluating its luminous power is important because the new light-emitting diodes (LED)-type models are much more economical in terms of energy, and energy distribution companies need to know the consumption of public lighting energy. In Brazil, the following types of lamps exist in street lighting: incandescent, mercury vapor, sodium vapor, “mixed” lamps (composed of a mercury vapor arc tube in series with an incandescent tungsten filament), metal lamps and modern LED-type lamps. In this article, the authors describe the experimental results of the development of an automated system for recognizing lamps for public lighting based on the light pattern of each lamp, taking into account an innovative optic method, which uses the reproduction index of color (RIC) phenomenon and colored cards. Data collection in the field consisted of the task of driving a vehicle through public roads and obtaining several photos of the colored cards illuminated through the lamps of the poles and also through the use of a spectrophotometer, which is already traditionally employed for this application. Samples were obtained and used for training classifiers that use machine learning in order to identify the nature of the lamps. The tests were carried out on the city’s public roads at night, so the resulting tables also show the noise from interfering light sources (examples: lights from windows in houses and buildings, lights in stores, etc.), thus creating a very realistic scenario. The performance of the classifiers was evaluated through parameters used in artificial intelligence. Full article
(This article belongs to the Proceedings of The 9th International Symposium on Sensor Science)
16 pages, 24944 KiB  
Article
Spectrometry of the Urban Lightscape
by Christopher Small
Technologies 2022, 10(4), 93; https://doi.org/10.3390/technologies10040093 - 13 Aug 2022
Cited by 2 | Viewed by 2876
Abstract
NASA’s Gateway to Astronaut Photography of Earth contains over 30,000 photos of ~2500 cataloged urban lightscapes (anthropogenic night light) taken from the International Space Station. A subset of over 100 of these multispectral DSLR photos are of sufficient spatial resolution, sharpness and exposure [...] Read more.
NASA’s Gateway to Astronaut Photography of Earth contains over 30,000 photos of ~2500 cataloged urban lightscapes (anthropogenic night light) taken from the International Space Station. A subset of over 100 of these multispectral DSLR photos are of sufficient spatial resolution, sharpness and exposure to be potentially useful for broadband spectral characterization of urban lightscapes. Spectral characterization of multiple urban lightscapes can provide a basis for quantifying intra and interurban variability in night light brightness, color and extent, as well as the potential for change analyses. A comparative analysis of simulated atmospheric transmissivity from the MODTRAN radiative transfer model indicates that the spectral slopes of transmissivity spectra are relatively insensitive model atmospheres, with variations in atmospheric path length and aerosol optical depth primarily affecting the bias of the spectrum rather than the slope. A mosaic of 18 intercalibrated, transmissivity-compensated RGB photos renders a spectral feature space bounded by four clearly defined spectral endmembers corresponding to white, yellow and red light sources, with brightness modulated by a dark background endmember. These four spectral endmembers form the basis of a linear spectral mixture model which can be inverted to provide estimates of the areal fraction of each endmember present within every pixel field of view. The resulting spectral feature spaces consistently show two distinct mixing trends extending from the dark endmember to flat spectrum (white–yellow) and warm spectrum (orange) sources. The distribution of illuminated pixels is strongly skewed toward a lower luminance background of warm spectrum street lighting with brighter lights, generally corresponding to point sources and major thoroughfares. Full article
(This article belongs to the Section Environmental Technology)
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18 pages, 5967 KiB  
Article
Cysteamine-Gold Coated Carboxylated Fluorescent Nanoparticle Mediated Point-of-Care Dual-Modality Detection of the H5N1 Pathogenic Virus
by Kaliannan Durairaj, Duc Duong Than, Anh Thi Viet Nguyen, Hak Sung Kim, Seon-Ju Yeo and Hyun Park
Int. J. Mol. Sci. 2022, 23(14), 7957; https://doi.org/10.3390/ijms23147957 - 19 Jul 2022
Cited by 4 | Viewed by 3689
Abstract
Globally, point-of-care testing (POCT) is the most preferable on-site technique for disease detection and includes a rapid diagnostic test (RDT) and fluorescent immunochromatographic strip test (FICT). The testing kits are generally insufficient in terms of signal enhancement, which is a major drawback of [...] Read more.
Globally, point-of-care testing (POCT) is the most preferable on-site technique for disease detection and includes a rapid diagnostic test (RDT) and fluorescent immunochromatographic strip test (FICT). The testing kits are generally insufficient in terms of signal enhancement, which is a major drawback of this approach. Sensitive and timely on-site POCT methods with high signal enhancement are therefore essential for the accurate diagnosis of infectious diseases. Herein, we prepare cysteamine-gold coated carboxylated europium chelated nanoparticle (Cys Au-EuNPs)-mediated POCT for the detection of the H5N1 avian influenza virus (AIV). Commercial nanoparticles were used for comparison. The spectral characteristics, surface morphologies, functional groups, surface charge and stability of the Cys AuNPs, EuNPs, and Cys Au-EuNPs were confirmed by UV-visible spectrophotometry, fluorescence spectrometry, transmission electron microscope with Selected area electron diffraction (TEM-SAED), Fourier-transform infrared spectroscopy (FTIR) and zeta potential analysis. The particle size distribution revealed an average size of ~130 ± 0.66 nm for the Cys Au-EuNPs. The Cys Au-EuNP-mediated RDT (colorimetric analysis) and FICT kit revealed a limit of detection (LOD) of 10 HAU/mL and 2.5 HAU/mL, respectively, for H5N1 under different titer conditions. The obtained LOD is eight-fold that of commercial nanoparticle conjugates. The photo luminance (PL) stability of ~3% the Cys Au-EuNPs conjugates that was obtained under UV light irradiation differs considerably from that of the commercial nanoparticle conjugates. Overall, the developed Cys Au-EuNPs-mediated dual-mode POCT kit can be used as an effective nanocomposite for the development of on-site monitoring systems for infectious disease surveillance. Full article
(This article belongs to the Section Molecular Pathology, Diagnostics, and Therapeutics)
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20 pages, 96730 KiB  
Article
The Potential of Moonlight Remote Sensing: A Systematic Assessment with Multi-Source Nightlight Remote Sensing Data
by Di Liu, Qingling Zhang, Jiao Wang, Yifang Wang, Yanyun Shen and Yanmin Shuai
Remote Sens. 2021, 13(22), 4639; https://doi.org/10.3390/rs13224639 - 17 Nov 2021
Cited by 6 | Viewed by 4579
Abstract
One recent trend in optical remote sensing is to increase observation frequencies. However, there are still challenges on the night side when sunlight is not available. Due to their powerful capabilities in low-light sensing, nightlight satellite sensors have been deployed to capture nightscapes [...] Read more.
One recent trend in optical remote sensing is to increase observation frequencies. However, there are still challenges on the night side when sunlight is not available. Due to their powerful capabilities in low-light sensing, nightlight satellite sensors have been deployed to capture nightscapes of Earth from space, observing anthropomorphic and natural activities at night. To date, the mainstream of nightlight remote sensing applications has mainly focused on artificial lights, especially within cities or self-luminous bodies, such as fisheries, oil, offshore rigs, etc. Observations taken under moonlight are often discarded or corrected to reduce lunar effects. Some researchers have discussed the possibility of using moonlight as a useful illuminating source at night for the detection of nocturnal features on Earth, but no quantitative analysis has been reported so far. This study aims to systematically evaluate the potential of moonlight remote sensing with mono-spectral Visible Infrared Imaging Radiometer Suite/Day-Night-Band (VIIRS/DNB) imagery and multi-spectral photos taken by astronauts from the International Space Station (ISS), as well as unmanned aerial vehicle (UAV) night-time imagery. Using the VIIRS/DNB, ISS and UAV moonlight images, the possibilities of the moonlight remote sensing were first discussed. Then, the VIIRS/DNB, ISS, UAV images were classified over different non-self-lighting land surfaces to explore the potential of moonlight remote sensing. The overall accuracies (OA) and kappa coefficients are 79.80% and 0.45, 87.16% and 0.77, 91.49% and 0.85, respectively, indicating a capability to characterize land surface that is very similar to daytime remote sensing. Finally, the characteristics of current moonlight remote sensing are discussed in terms of bands, spatial resolutions, and sensors. The results confirm that moonlight remote sensing has huge potential for Earth observation, which will be of great importance to significantly increase the temporal coverage of optical remote sensing during the whole diurnal cycle. Based on these discussions, we further examined requirements for next-generation nightlight remote sensing satellite sensors. Full article
(This article belongs to the Section Urban Remote Sensing)
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19 pages, 2461 KiB  
Article
Pyrene-Benzimidazole Derivatives as Novel Blue Emitters for OLEDs
by Thenahandi Prasanthi Deepthika De Silva, Sang Gil Youm, Frank R. Fronczek, Girija Sahasrabudhe, Evgueni E. Nesterov and Isiah M. Warner
Molecules 2021, 26(21), 6523; https://doi.org/10.3390/molecules26216523 - 28 Oct 2021
Cited by 15 | Viewed by 3456
Abstract
Three novel small organic heterocyclic compounds: 2-(1,2-diphenyl)-1H-benzimidazole-7-tert-butylpyrene (compound A), 1,3-di(1,2-diphenyl)-1H-benzimidazole-7-tert-butylpyrene (compound B), and 1,3,6,8-tetra(1,2-diphenyl)-1H-benzimidazolepyrene (compound C) were synthesized and characterized for possible applications as blue OLED emitters. The specific molecular [...] Read more.
Three novel small organic heterocyclic compounds: 2-(1,2-diphenyl)-1H-benzimidazole-7-tert-butylpyrene (compound A), 1,3-di(1,2-diphenyl)-1H-benzimidazole-7-tert-butylpyrene (compound B), and 1,3,6,8-tetra(1,2-diphenyl)-1H-benzimidazolepyrene (compound C) were synthesized and characterized for possible applications as blue OLED emitters. The specific molecular design targeted decreasing intermolecular aggregation and disrupting crystallinity in the solid-state, in order to reduce dye aggregation, and thus obtain efficient pure blue photo- and electroluminescence. Accordingly, the new compounds displayed reasonably high spectral purity in both solution- and solid-states with average CIE coordinates of (0.160 ± 0.005, 0.029 ± 0.009) in solution and (0.152 ± 0.007, 0.126 ± 0.005) in solid-state. These compounds showed a systematic decrease in degree of crystallinity and intermolecular aggregation due to increasing steric hindrance, as revealed using powder X-ray diffraction analysis and spectroscopic studies. An organic light-emitting diode (OLED) prototype fabricated using compound B as the non-doped emissive layer displayed an external quantum efficiency (EQE) of 0.35 (±0.04)% and luminance 100 (±6) cd m−2 at 5.5 V with an essentially pure blue electroluminescence corresponding to CIE coordinates of (0.1482, 0.1300). The highest EQE observed from this OLED prototype was 4.3 (±0.3)% at 3.5 V, and the highest luminance of 290 (±10) cd m−2 at 7.5 V. These values were found comparable to characteristics of the best pure blue OLED devices based on simple fluorescent small-molecule organic chromophores. Full article
(This article belongs to the Special Issue Perovskite/Organic Light-Emitting Materials and Devices)
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22 pages, 30802 KiB  
Article
Simulating the Impact of Daytime Calibration in the Behavior of a Closed Loop Proportional Lighting Control System
by Aris Tsangrassoulis, Lambros Doulos and Angelos Mylonas
Energies 2021, 14(21), 7056; https://doi.org/10.3390/en14217056 - 28 Oct 2021
Cited by 7 | Viewed by 2052
Abstract
A daylighting control system that uses the closed loop proportional algorithm needs to be calibrated both during nighttime and daytime. The selection of the daytime calibration time can affect the behavior of the system and is usually performed when the ratio of the [...] Read more.
A daylighting control system that uses the closed loop proportional algorithm needs to be calibrated both during nighttime and daytime. The selection of the daytime calibration time can affect the behavior of the system and is usually performed when the ratio of the illuminance of the ceiling sensor (SD,tc) to the illuminance at a point on the working plane (ED,tc) is relatively large without sunlight patches in the ceiling photo-sensor’s field of view (FOV). However, this requirement is not associated with a specific value and can be achieved under a wide range of conditions related to the sky luminance distribution. In the present work, four ceiling sensors with different field of views (FOVs) were examined in a typical north-facing office space. The effect of daytime calibration on the system’s performance was estimated through the calculation of lighting energy savings and the overdimming percentage. The results show that the effect of both the FOV of the ceiling sensor and the daytime calibration period is small except for the case of the sensor without cover, especially when it is close to the opening. In an attempt to quantify the SDtc/IDtc ratio, a new magnitude (RR) is proposed by dividing the illuminance ratios of the ceiling photo-sensor by that on the working surface during daytime and nighttime calibration. Thus, the daily calibration of the sensors with cover can be performed when RR > 1. Full article
(This article belongs to the Section G: Energy and Buildings)
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9 pages, 3309 KiB  
Article
Highly Stable Inverted CdSe/ZnS-Based Light-Emitting Diodes by Nonvacuum Technique ZTO as the Electron-Transport Layer
by Sajid Hussain, Fawad Saeed, Ahmad Raza, Abida Parveen, Ali Asghar, Nasrud Din, Zhang Chao, Jing Chen, Qasim Khan and Wei Lei
Electronics 2021, 10(18), 2290; https://doi.org/10.3390/electronics10182290 - 17 Sep 2021
Cited by 6 | Viewed by 3485
Abstract
CdSe/ZnS quantum dots (QDs) have attracted great consideration from investigators owing to their excellent photo-physical characteristics and application in quantum dot light-emitting diodes (QD-LEDs). The CdSe/ZnS-based inverted QD-LEDs structure uses high-quality semiconductors electron transport layers (ETLs), a multilayered hole transporting layers (HTLs). In [...] Read more.
CdSe/ZnS quantum dots (QDs) have attracted great consideration from investigators owing to their excellent photo-physical characteristics and application in quantum dot light-emitting diodes (QD-LEDs). The CdSe/ZnS-based inverted QD-LEDs structure uses high-quality semiconductors electron transport layers (ETLs), a multilayered hole transporting layers (HTLs). In QD-LED, designing a device structure with a minimum energy barrier between adjacent layers is very important to achieve high efficiency. A high mobility polymer of poly (9,9-dioctylfluorene-co-N-(4-(3-methylpropyl)) diphenylamine (TFB) was doped with 4,4′-bis-(carbazole-9-yl) biphenyl (CBP) with deep energy level to produce composite TFB:CBP holes to solve energy mismatch (HTL). In addition, we also improved the QD-LED device structure by using zinc tin oxide (ZTO) as ETL to improve device efficiency. The device turn-on voltage Vt (1 cd m−2) with ZTO ETL reduced from 2.4 V to 1.9 V significantly. Furthermore, invert structure devices exhibit luminance of 4296 cd m−2, current-efficiency (CE) of 7.36 cd A−1, and external-quantum efficiency (EQE) of 3.97%. For the QD-LED based on ZTO, the device efficiency is improved by 1.7 times. Full article
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