Search Results (191)

Lanthanide rare earth elements possess significant promise for material applications owing to their distinctive optical and magnetic characteristics, as well as their versatile coordination capabilities. This study introduced a lanthanide-functionalized magnetic nanocellulose composite (NNC@Fe₃O₄@La(OH)₃) for effective phosphorus/nitrogen (P/N) ligand separation. The hybrid material employs the adaptable coordination geometry and strong affinity for oxygen of La³⁺ ions to show enhanced DNA-binding capacity via multi-site coordination with phosphate backbones and bases. This study utilized cellulose as a carrier, which was modified through carboxylation and amination processes employing deep eutectic solvents (DES) and polyethyleneimine. Magnetic nanoparticles and La(OH)₃ were subsequently incorporated into the cellulose via in situ growth. NNC@Fe₃O₄@La(OH)₃ showed a specific surface area of 36.2 m²·g⁻¹ and a magnetic saturation intensity of 37 emu/g, facilitating the formation of ligands with accessible La³⁺ active sites, hence creating mesoporous interfaces that allow for fast separation. NNC@Fe₃O₄@La(OH)₃ showed a significant affinity for DNA, with adsorption capacities reaching 243 mg/g, mostly due to the multistage coordination binding of La³⁺ to the phosphate groups and bases of DNA. Simultaneously, kinetic experiments indicated that the binding process adhered to a pseudo-secondary kinetic model, predominantly dependent on chemisorption. This study developed a unique rare-earth coordination-driven functional hybrid material, which is highly significant for constructing selective separation platforms for P/N-containing ligands. Full article

The utilisation of edible insects for human nutrition is a long-standing practice in many parts of the globe, and is being gradually introduced into countries without an entomophagic tradition as well. These unconventional sources of protein of animal origin have arisen as a sustainable alternative to other animal protein sources, such as meat. This review intends to present the compilation of data in the scientific literature on the chemical composition and nutritional value of the bee brood of A. mellifera species and subspecies as edible foods. For this, a comprehensive search of the scientific literature was carried out using the databases ScienceDirect, Scopus, Pub-Med, BOn, and SciELO. Appropriate keywords were used for the search to reach the research works that addressed the topics of the review. The results showed that bee brood has considerable quantities of protein, fat and carbohydrates. The most abundant amino acids are leucine and lysine (these two being essential amino acids) and aspartic acid, glutamic acid, and proline (these three being non-essential amino acids). As for the fatty acids, bee broods contain approximately equal fractions of saturated and monounsaturated fatty acids, while the polyunsaturated fatty acids are negligible. The dietary minerals present in higher quantities are potassium, phosphorus, and magnesium, and the most abundant vitamins are vitamin C and niacin; choline is also present, although it is not a true vitamin. Although bee brood from A. mellifera has potential for human consumption as a nutrient-rich food, there are still many aspects that need to be further studied in the future, such as safety and hazards linked to possible regular consumption. Full article

Cover cropping has emerged as a pivotal sustainable agronomic practice aimed at enhancing soil health and sustaining crop productivity. To quantify its effects across diverse agroecosystems, we conducted a meta-analysis of 1877 paired observations from 114 studies (1980–2025) comparing cover cropping with bare fallow during fallow periods in major cereal systems across China. Cover cropping significantly reduced soil bulk density by 6.1% and increased key soil nutrients including total nitrogen (+13.1%), total phosphorus (+15.6%), hydrolysable nitrogen (+9.3%), available phosphorus (+11.1%), available potassium (+12.4%), soil organic matter (+11.7%), and microbial biomass carbon (+41.1%). Leguminous cover crops outperformed non-legumes in enhancing nitrogen availability, reflecting biological nitrogen fixation. Mixed-species cover crop mixtures showed superior benefits over monocultures, likely due to complementary effects on nutrient cycling and soil structure. Soil texture and initial soil organic carbon significantly moderated these outcomes. Furthermore, although overall soil pH remained stable, cover cropping exhibited a clear buffering effect, tending to regulate soil pH toward neutrality. Meta-regression analyses revealed a diminishing positive effect on total nitrogen (TN), available potassium (AK), and microbial biomass carbon (MBC) with an extended duration of cover cropping, suggesting potential saturation effects. These results underscore the context-dependent efficacy of cover cropping as a strategy for soil quality enhancement. Optimizing cover crop implementation should integrate the consideration of inherent soil characteristics, baseline fertility, and species composition to maximize agroecosystem resilience and sustainability. Full article

The simplex strategies of fertilizer management and problems caused by simultaneous precipitation and high-temperature (SPH) climate were the main factors that led to yield loss and quality decline in the continuous cropping of tea chrysanthemum (Dendranthema morifolium ‘Jinsi Huang’). In this study, with sustainable biofertilizers being proposed as a potential solution. However, their effects under such constraints are underexplored. In this study, we compared different proportions of a sustainable dark tea biofertilizer, made with two commonly used fertilizers, by their contributions to the morphological, photosynthetic, and flowering traits of D. morifolium ‘Jinsi Huang’. The results showed that increasing the dark tea biofertilizer application to 4.5 kg·m⁻² significantly enhanced the soil alkali hydrolyzed nitrogen (596.53% increase), available phosphorus (64.11%), and rapidly available potassium (75.56%) compared to the levels in yellow soil. This nutrient enrichment in soil caused D. morifolium ‘Jinsi Huang’ to produce more leaves (272.84% increase) and flower buds (1041.67%), along with a strengthened photosynthetic capacity (higher Fv/Fm values and light saturation point). These improvements alleviated the photoinhibition caused by SPH climate conditions, ultimately leading to significantly higher contents of chlorogenic acid (38.23% increase) and total flavonoids (80.28%) in the harvested flowers compared to the control group. Thus, dark tea biofertilizer is a cost-effective and efficient additive for growing tea chrysanthemum in SPH regions due to improving soil quality and causing nutritional and functional components to accumulate in harvest flowers, which greatly promotes the commercial value of rural revitalization industries centered around tea chrysanthemum. Full article

Wine production generates by-products that require proper management and reuse to minimize their environmental impact. Grape pomace, a by-product of winemaking, holds significant nutritional and bioactive potential. This study evaluated the nutritional and antioxidant profiles of pomace from Isabella grapes (La Plata, Argentina) and Cabernet grapes (Veneto, Italy). Both varieties contain high levels of dietary fiber, especially Cabernet. However, Cabernet showed lower protein and lipid levels than Isabella. Calcium, potassium, and phosphorus were the major minerals in both by-products. Isabella exhibited a higher content of essential polyunsaturated fatty acids, particularly α-linoleic acid, while Cabernet shows a greater proportion of saturated and monounsaturated fatty acids. Additionally, Isabella exhibited significantly higher levels of caffeic acid derivatives (506.4 vs. 38.2 mg/kg dry weight), catechin (1613.2 vs. 294.8 mg/kg dry weight), epicatechin (1229.2 vs. 230.3 mg/kg dry weight), and total anthocyanins (2649 vs. 607.5 mg kuromanin/kg dry weight), as well as a greater total polyphenol content and antioxidant activity compared to Cabernet. These results highlight grape pomace’s potential as a valuable functional ingredient. Full article

Assessing available phosphorus (P) in paddy fields is challenging due to waterlogging-induced reducing conditions. This study tested the applicability of the Truog, Bray 2, and Mehlich 3 extraction methods in both air-dried and incubated soils, as well as the ascorbic-acid-reduced Bray 2 (AR Bray 2), which simulates reducing conditions, for evaluating rice growth under P fertilization. In addition, to investigate the chemical characteristics of the extraction methods, active Al and Fe and P sequential extractions were measured. Soil samples from four representative regions in Yamagata Prefecture were used. Pot cultivation tests using ‘Haenuki’ and ‘Tsuyahime’ cultivars were conducted with varying P fertilizer levels. Variations in P availability across soil types were influenced by levels of active Al and Fe. Sequential extractions identified NaHCO₃-P and NaOH-P fractions as important for P availability. Bray 2 in both soils and AR Bray 2 were the most effective methods, showing a strong saturating exponential correlation with rice growth and P uptake, whereas Mehlich 3 and Truog showed weaker correlations. Bray 2 and AR Bray 2 show potential but require further evaluation for practical application due to the small number of soils. Future efforts should prioritize developing methods that account for P dynamics under reducing conditions, thereby improving P management strategies and supporting sustainable rice production. Full article

This research evaluated the recovery and reuse of dolomitic calcareous amendment saturated with nutrients adsorbed from hydroponic effluent as a soil improver and its impact on the agronomic performance of Phaseolus vulgaris. Initially, the dolomitic calcareous amendment (DCA) was saturated with nutrients from the hydroponic effluent through adsorption tests. The characterization of the DCA was conducted before and after nutrient saturation to verify its composition. Soil analysis was carried out prior to the trial, and a completely randomized experimental design was applied with four treatments and five replications, totaling 20 experimental units for each soil type (sandy and clayey): T1 (control), T2 (raw dolomitic calcareous amendment—DCA), T3 (saturated dolomitic calcareous amendment—DCAS), and T4 (granulated dolomitic calcareous amendment—DCAG). Agronomic performance parameters of Phaseolus vulgaris were assessed to determine nutrient availability to the plant: number of pods, pod length (cm), number of seeds per pod, and weight of 100 seeds (g). Data normality was verified using the Shapiro–Wilk test, and results were analyzed using ANOVA and mean comparisons through Tukey’s test (p < 0.05) using InfoStat software 2020I. Additionally, plant tissue was analyzed to determine nutrient absorption in the seeds, and both soil types were analyzed after harvest. Adsorption results indicated that the DCA retained phosphorus, manganese, calcium, and zinc. According to the characterization, DCA primarily consisted of calcium and magnesium carbonates; following the saturation process, an increase in carbonate groups was observed due to calcium adsorption from the hydroponic effluent. Results in both soil types showed no significant differences in pod number, pod length, or seeds per pod, except for the weight of 100 seeds in sandy soil, where T1, T2, and T3 differed significantly from T4. Based on references, the phosphorus content in the harvested seeds from T3 in sandy soil is classified as sufficient. The findings demonstrate the potential of recovering and reusing nutrients from hydroponic effluent using DCA and transforming it into a value-added agricultural input for soil improvement, presenting a promising alternative for more sustainable and efficient agriculture. Full article

The genetic diversity of banana plants (Musa spp.) can result in different phosphorus requirements, highlighting the importance of studies performed to optimize phosphate fertilization in order to improve the productivity and sustainability of banana plantations. This study assessed the effects of phosphate fertilization on the duration of the harvest season, bunch mass, soil fertility and foliar nutrition of BRS SCS Belluna banana plants. A replicated trial was performed in two consecutive harvests, with different phosphorus levels, i.e., 25, 50, 75, 100, 125 and 150% of the recommended level for the crop. Soil analyses included macro- and micronutrients, silicon, acidity, organic matter, cation exchange capacity and base saturation. Leaf tissue was analyzed for mineral content. Thermophosphate had different effects on soil fertility and leaf nutrients. Calcium and phosphorus in the soil increased linearly. In the leaf, a reduction in zinc content was mainly observed. The lower temperatures and accumulated rainfall that occurred during the second harvest season are related to a greater number of days between flowering and harvest and a lower bunch mass. These results could support fertilization programs aimed at ensuring the long-term sustainability of phosphorus nutrition in banana plantations. Full article

This study proposes and evaluates a two-step phosphorus (P) recovery strategy that combines chemical precipitation with adsorption to comply with the updated EU Urban Wastewater Treatment Directive (Directive (EU) 2024/3019), which sets stricter limits on nutrient discharge and promotes resource recovery. The objective was to enhance the P removal efficiency beyond that achieved by conventional precipitation. A laboratory-scale design of experiments was conducted using real wastewater with an initial P concentration of 10 mg P/L post-precipitation and was extended to 1 and 40 mg P/L to assess broader applicability. The optimal lab-scale conditions (30 cm bed height and 5 mL/min flow rate) resulted in a saturated bed fraction (FSB) of 0.425 and a breakthrough time of 126 min. The process was successfully scaled up to a column with a height of 60 cm and a diameter of 4 cm, achieving a higher FSB (0.764), improved adsorption capacity (84.1 mg P/kg), and reduced unused bed (40%). The integrated system maintained effluent P levels below 0.5–0.7 mg P/L for over 400 min, demonstrating regulatory compliance and operational reliability. These findings confirmed the feasibility and scalability of combining precipitation with adsorption for enhanced P recovery in wastewater treatment systems. Full article

Utilizing the nonlinear effects of black phosphorus (BP), the self-starting threshold and noise performance were optimized in a figure-9 mode-locked fiber laser configuration. Experimental results demonstrate that a mode-locked pulse output with a spectral bandwidth of 8.2 nm, center wavelength of 1033.5 nm, and repetition rate of 42 MHz is obtained. Compared with single-mechanism mode-locked lasers, the self-starting mode-locked threshold is reduced by 100 mW. Regarding noise characteristics, the signal-to-noise ratio (SNR) is enhanced to 68.4 dB and the phase noise is reduced to −115.6 dBc/Hz at 1 MHz to 10 MHz frequency offsets. The root mean square (RMS) of the output power is optimized to 0.9% and phase noise jitter is reduced to 1.9%. This work proves a novel approach to tackle the challenges of high self-starting thresholds and instability in mode-locked lasers. Full article

This study aims to advance the understanding of hydrogen embrittlement (HE) in low-carbon and low-alloy steels by developing a predictive framework for assessing fracture toughness (FT), a critical parameter for mitigating HE in hydrogen infrastructure. A machine learning (ML) model was constructed by analyzing data from relevant literature to evaluate the fracture toughness of steels exposed to hydrogen environments. Seven ML modeling techniques were initially considered, with four selected for detailed evaluation based on predictive accuracy. The chosen modeling techniques were k-nearest neighbors (KNN), random forest (RF), gradient boosting (GB), and decision tree regression (DT). The selected models were further evaluated for their predictive accuracy and reliability, and the best model was used to perform parametric studies to investigate the impact of relevant parameters on FT. According to the results, the KNN model demonstrated reliable predictive performance, supported by high R-squared values and low error metrics. Among the variables considered, hydrogen pressure and yield strength emerged as the most influential, with hydrogen pressure alone accounting for 32% of the variation in FT. The model revealed a distinct trend in FT behavior, showing a significant decline at low hydrogen pressures (0–6.9 MPa) and a plateau at higher pressures (>8 MPa), indicating a saturation point. Alloying element contents, specifically those of carbon and phosphorus, also played a notable role in FT prediction. Additionally, the study confirmed that low concentrations of oxygen (<200 ppm) mitigate HE in X70 steel, likely by limiting hydrogen uptake. FT predictions do not show noticeable variations with lower displacement rates (<0.1 mm/min), indicating the need for low-rate measurements for accurate ML model training. Full article

Background: Plant-based meat analogs (PBMAs) have attracted attention as alternatives to traditional meat. Methods: In this study, three beef products (BPs; BP-1, BP-2, BP-3) and three PBMA products (PPs; PP-1, PP-2, PP-3) purchased from a Korean market were evaluated for nutritional profile-based nutritional facts, such as proximate composition, total calories, and levels of mineral, cholesterol, sugar, fatty acids, and amino acids, and for sensory characteristics. Results: Cholesterol and vaccenic acid were detected only in the BP samples. The levels of crude lipids, zinc, palmitic acid, stearic acid, oleic acid, saturated fatty acids, monounsaturated fatty acids, threonine, and lysine, and the score for taste and flavor were higher for the BPs than for the PPs (p < 0.05). By contrast, the levels of carbohydrates, calcium, iron, magnesium, sodium, glucose, sucrose, total sugar, isoleucine, phenylalanine, and glutamic acid were higher for the PPs than for the BPs. The levels of protein, potassium, phosphorus, copper, aluminum, valine, leucine, histidine, and arginine did not differ significantly between the BPs and the PPs. Multivariate analysis indicated that palmitic acid influenced the differences in nutritional profiles between the BPs and the PPs. Additionally, discrepancies were observed between the measured and labeled values for total sugar in PP-1 and PP-3. Conclusions: These findings offer valuable insights for the development of processed meat products using beef and PBMAs and may help consumers make informed purchasing decisions through the provision of accurate and reliable nutritional information. Full article

The use of agro-industrial waste, such as wood ash or biomass ash, has been adopted as an alternative to synthetic fertilizers for providing nutrients to plants. This study aimed to evaluate the levels of primary and secondary macronutrients in soil cultivated with chrysanthemum under different types of fertilization management: organic, organomineral, and mineral, with and without liming. The experiment was conducted in a greenhouse for 185 days, using a randomized blocks design in a 5 × 2 factorial scheme: five fertilization types (incubated and unincubated wood ash, organomineral fertilizer, mineral fertilizer, and control) and two levels of liming (without liming and 70% base saturation) with five replicates. The soil used was Oxisol. The phosphorus, potassium, calcium, magnesium, and sulfur contents in the soil after cultivation were analyzed. There was a 77% increase in potassium in treatments with ash compared to treatments without ash. The corrected soil presented 173.2 mg dm⁻³ of potassium, compared to 153.6 mg dm⁻³ in the uncorrected soil, an increase of 11.6%. The calcium levels increased by 60% with the application of ash (incubated or not) and organomineral fertilizer, compared to soils without ash. Liming increased calcium by 1.12 cmol_c dm⁻³. Fertilizers with ash associated with liming resulted in higher magnesium levels. The sulfur content varied according to the fertilizer, with non-incubated ash showing the highest value (69.11 mg dm⁻³) compared to the control (11.08 mg dm⁻³), a difference of 83.96%. Organomineral fertilizer is an alternative for increasing the availability of macronutrients in the soil, allowing a second cropping cycle without the need to manage soil fertility, contributing to sustainable agriculture, encouraging the reuse of waste, and reducing the use of mineral fertilizers. Full article

This study assesses the current status of selected soil properties of an expanding equatorial agricultural region (Arauca, Colombia) across six landscapes, with the final focus being on evaluating overall soil quality. Field surveys, morphological descriptions, and laboratory analyses of 133 soil profiles were investigated. The landscapes include mountains (25 profiles), foothills (17), hills (11), alluvial plains (43), alluvial plains with dunes (21), and alluvial valleys (16). Soils are classified into six Reference Soil Groups (WRB FAO): Gleysols, Acrisols, Arenosols, Ferralsols, Leptosols, and Cambisols. The findings indicate high acidity, low fertility, and deficient exchangeable bases. Indeed, pH ranges from extremely acid to slightly acid (3.5–6.4), and exchangeable acidity saturation percentage (%SAI) values reach 100% in some areas. Soil textures vary from clay loam to sandy loam and clay. Nutrient contents are ranked in the order Cambisols > Gleysols > Arenosols > Ferralsols > Acrisols > Leptosols. Correlation analysis reveals that clay content positively influences the exchangeable basis percentage, while organic matter (OM) negatively correlates with the nutrients phosphorus, calcium, and magnesium. This study highlights that landscape position influences soil quality, with lower landscape positions having better quality than upper ones. These results provide insights into soil fertility and nutrient availability, which helps to predict suitable plant cultivation areas when increasing areas for agricultural use versus forestry in Arauca. The inclusion or maintenance of diverse tree species is a key element in maintaining the production of organic matter and, consequently, generating better soil quality. Full article

Extensive antibiotic use in swine production contaminates manure and wastewater with antibiotics. Discharging this waste into the environment, even after treatment, potentially fuels the spread of antibiotic resistance. This study investigated a full-scale swine wastewater treatment plant that combines coagulation–sedimentation, sand filtration, ozonation, activated carbon filtration, and a deaeration process. At each stage of this process, samples were collected and analyzed to determine their water quality parameters, antibiotic concentrations, and antibiotic resistance genes (ARGs). The experimental results showed coagulation–sedimentation effectively removed suspended solids (92.2%) and total phosphorus (96.9%). Ozonation significantly reduced antibiotic levels, including sulfamethazine by over 99.9%, although ARGs such as tetM, sul1, and sul2 were only removed at levels up to 95.9%. Interestingly, partial rebounds of sulfamethazine (438.9 μg/L) and marbofloxacin (0.40 μg/L) appeared in the final effluent, suggesting that desorption or operational factors (e.g., hydraulic fluctuation, filter media saturation, and pH) may affect the treatment process. In addition, strong correlations emerged between the levels of suspended solids and those of certain antibiotics (lincomycin, tiamulin), indicating particle-mediated sorption as a key mechanism. Even though ozonation and coagulation–sedimentation were found to contribute to the substantial removal of pollutants, the observed rebounds and residual ARGs highlight the need for optimized operational strategies and multi-barrier approaches to fully mitigate antibiotic contamination and inhibit the proliferation of resistant bacteria in swine wastewater. Full article