Search Results (980)

Organic phase change materials show potential for thermal energy storage, but their scalable implementation is limited by fixed phase change temperatures, molten leakage, and low thermal conductivity. To address the temperature constraint, a binary eutectic system of 1-tetradecanol and 1,10-decanediol is prepared, expanding the operational temperature range for building thermal management. Compositing the eutectic with expanded graphite yields a composite material that exhibits a low leakage and a markedly improved thermal conductivity of 4.642 W/(m·K), which is approximately 12 times that of the pure eutectic. The composite maintains distinct phase transition properties, with melting and solidification temperatures of 37.77 °C and 29.38 °C and corresponding latent heats of 218.80 J/g and 216.66 J/g. It also demonstrates a good cycling stability, retaining over 87% of the original latent heat after 2000 thermal cycles. While these findings remain valid under controlled conditions, further studies are required to evaluate their practical feasibility and long-term durability in real-world scenarios. This work establishes a systematic approach for fabricating composite phase change materials and provides a promising candidate for building thermal management applications. Full article

The emulsification of a molten fusible metal alloy in a liquid epoxy matrix with its subsequent curing is a novel way to create a highly concentrated phase-change material. However, numerous challenges have arisen. The high interfacial tension between the molten metal and epoxy resin and the difference in their viscosities hinder the stretching and breaking of metal droplets during stirring. Further, the high density of metal droplets and lack of suitable surfactants lead to their rapid coalescence and sedimentation in the non-cross-linked resin. Finally, the high differences in the thermal expansion coefficients of the metal alloy and cross-linked epoxy polymer may cause cracking of the resulting phase-change material. This work overcomes the above problems by using nanosilica-induced physical gelation to thicken the epoxy medium containing Wood’s metal, stabilize their interfacial boundary, and immobilize the molten metal droplets through the creation of a gel-like network with a yield stress. In turn, the yield stress and the subsequent low-temperature curing with diethylenetriamine prevent delamination and cracking, while the transformation of the epoxy resin as a physical gel into a cross-linked polymer gel ensures form stability. The stabilization mechanism is shown to combine Pickering-like interfacial anchoring of hydrophilic silica at the metal/epoxy boundary with bulk gelation of the epoxy phase, enabling high metal loadings. As a result, epoxy shape-stable phase-change materials containing up to 80 wt% of Wood’s metal were produced. Wood’s metal forms fine dispersed droplets in epoxy medium with an average size of 2–5 µm, which can store thermal energy with an efficiency of up to 120.8 J/cm³. Wood’s metal plasticizes the epoxy matrix and decreases its glass transition temperature because of interactions with the epoxy resin and its hardener. However, the reinforcing effect of the metal particles compensates for this adverse effect, increasing Young’s modulus of the cured phase-change system up to 825 MPa. These form-stable, high-energy-density composites are promising for thermal energy storage in building envelopes, radiation-protective shielding, or industrial heat management systems where leakage-free operation and mechanical integrity are critical. Full article

This study utilized capric acid (CA), lauric acid (LA), myristic acid (MA), palmitic acid (PA), and stearic acid (SA) as alternative feedstocks to conduct theoretical analyses on ten fatty acid-based ternary eutectic systems. By leveraging the Schrader equation, phase diagrams for each system were constructed, and their theoretical eutectic points were calculated. The CA-LA-MA (capric acid–lauric acid–myristic acid) ternary system was selected as a representative for experimental fabrication: differential scanning calorimetry (DSC) was employed to characterize its thermal properties, while Fourier transform infrared spectroscopy (FT-IR) and thermogravimetric analysis (TGA) were used to assess its functional group composition and thermal stability, respectively. Theoretical calculations indicate that the ten ternary eutectic systems exhibit melting temperatures ranging from 17.11 °C to 37.61 °C, with phase change latent heats spanning 167.8 J·g⁻¹ to 189.6 J·g⁻¹. For the CA-LA-MA system, experimental DSC results confirm that its eutectic melting temperature is 16.0 °C (accompanied by a phase change latent heat of 177.0 J·g⁻¹, with minor deviations from theoretical predictions attributed to reagent impurities and operational errors). TGA characterization further reveals that the CA-LA-MA mixture has an initial weight loss temperature (corresponding to ~1% mass loss) of 115.6 °C and an extrapolated onset weight loss temperature of 164.8 °C, confirming reliable thermal stability below 100 °C—consistent with its low-temperature application design. These results validate the consistency between theoretical predictions and experimental data, and demonstrate that fatty acid-based ternary eutectic mixtures are promising candidates for low-temperature thermal energy storage applications. Full article

Existing office buildings in Australia contribute to 24% of the nation’s electricity consumption and 10% of greenhouse gas emissions, with energy use projected to rise by 84%. Meeting the 2050 sustainability target and United Nations (UN) 17 Sustainable Development Goals (SDGs) requires improving sustainability within existing office buildings. This systematic review examines net zero energy and climate resilience strategies in these buildings by analysing 74 studies from scholarly literature, government reports, and industry publications. The literature search was conducted across Scopus, Google Scholar, and Web of Science databases, with the final search in early 2025. Studies were selected based on keywords and research parameters. A narrative synthesis identified key technologies, evaluating the integration of net zero principles with climate resilience to enhance energy efficiency through HVAC modifications. Technologies like heat pumps, energy recovery ventilators, thermal energy storage, and phase change materials (PCMs) have been identified as crucial in reducing HVAC energy usage intensity (EUI). Lighting control and plug load management advancements are examined for reducing electricity demand. This review highlights the gap between academic research and practical applications, emphasising the need for comprehensive field studies to provide long-term performance data. Current regulatory frameworks influencing the net zero transition are discussed, with recommendations for policy actions and future research. This study links net zero performance with climate adaptation objectives for existing office buildings and provides recommendations for future research, retrofit planning, and policy development. Full article

Due to its high energy density, liquid Hydrogen is an essential fuel for both terrestrial energy systems and space propulsion. However, uncontrolled evaporation poses a challenge for cryogenic storage and transport technologies. Accurate modeling of evaporation remains difficult due to the multiscale menisci formed by the wetting liquid phase. Thin liquid films form near the walls of containers, ranging from millimeters to nanometers in thickness. Heat conduction through the solid walls enables high evaporation rates in this region. Discrepancies in the reported values of the accommodation coefficients (necessary inputs to models) further complicate evaporation calculations. In this study, we present a novel multiscale model for CFD simulations of evaporating Hydrogen menisci. Film profiles below 10 $\mu$m are computed by a subgrid model using a lubrication-type thin film equation. The microscale model is combined with a macroscale model above 10 $\mu$m. Evaporation rates are computed using a kinetic phase change model combined with in situ calculations of the accommodation coefficient using transition state theory. The submodels are implemented in Ansys Fluent^TM using User-Defined Functions (UDFs), and a method to establish two-way coupling is detailed. The modeling results are in good agreement with cryo-neutron experiments and show improvement over prior models. The model, including UDFs, is made available through a public repository. Full article

Nanoparticle-mediated photothermal conversion exploits the unique light-to-heat transduction properties of engineered nanomaterials to address challenges in energy, water, and healthcare. This review first examines fundamental mechanisms—localized surface plasmon resonance (LSPR) in plasmonic metals and broadband interband transitions in semiconductors—demonstrating how tailored nanoparticle compositions can achieve >96% absorption across 250–2500 nm and photothermal efficiencies exceeding 98% under one-sun illumination (1000 W·m⁻², AM 1.5G). Next, we highlight advances in solar steam generation and desalination: floating photothermal receivers on carbonized wood or hydrogels reach >95% efficiency in solar-to-vapor conversion and >2 kg·m⁻²·h⁻¹ evaporation rates; three-dimensional architectures recapture diffuse flux and ambient heat; and full-spectrum nanofluids (LaB₆, Au colloids) extend photothermal harvesting into portable, scalable designs. We then survey photothermal-enhanced thermal energy storage: metal-oxide–paraffin composites, core–shell phase-change material (PCM) nanocapsules, and MXene– polyethylene glycol—PEG—aerogels deliver >85% solar charging efficiencies, reduce supercooling, and improve thermal conductivity. In biomedicine, gold nanoshells, nanorods, and transition-metal dichalcogenide (TMDC) nanosheets enable deep-tissue photothermal therapy (PTT) with imaging guidance, achieving >94% tumor ablation in preclinical and pilot clinical studies. Multifunctional constructs combine PTT with chemotherapy, immunotherapy, or gene regulation, yielding synergistic tumor eradication and durable immune responses. Finally, we explore emerging opto-thermal nanobiosystems—light-triggered gene silencing in microalgae and poly(N-isopropylacrylamide) (PNIPAM)–gold nanoparticle (AuNP) membranes for microfluidic photothermal filtration and control—demonstrating how nanoscale heating enables remote, reversible biological and fluidic functions. We conclude by discussing challenges in scalable nanoparticle synthesis, stability, and integration, and outline future directions: multicomponent high-entropy alloys, modular photothermal–PCM devices, and opto-thermal control in synthetic biology. These interdisciplinary innovations promise sustainable solutions for global energy, water, and healthcare demands. Full article

Freshwater scarcity is increasing day by day and has already reached a threatening level, especially in remotely populated areas. One of the technological solutions to this rising concern could be the use of the solar-based humidification–dehumidification (SHDH) method for water desalination. This technology is a promising solution but has challenges such as solar intermittency. This challenge can be solved by integrating SHDH with the phase change material as a solar energy storage medium. Therefore, a novel nano-enhanced binary eutectic phase change material (NEPCM) was developed in this project. PCM consisting of 70 wt.% stearic acid (ST) and 30 wt.% suberic acid (SBU) with a varying concentration of silicon carbide (SiC) nanoparticles (NPs) (0.1 to 3 wt.%) was synthesized specifically considering the need of SHDH application. The systematic thermophysical characterization was conducted to investigate their energy storage capacity, thermal durability, and performance consistency over repeated cycles. DSC analysis revealed that the addition of SiC NPs preserved the thermal stability of the NEPCM, while the phase transition temperature remained nearly unchanged with a variation of less than 0.74%. The value of latent heat is inversely related to the nanoparticle concentration, i.e., from 142.75 kJ/kg for the base PCM to 131.24 kJ/kg at 3 wt.% loading. This corresponds to reductions in latent heat ranging between 0.98% and 8.06%. The FTIR measurement confirms that no chemical reactions or no new functional groups were formed. All original functional groups of ST and SBU remained intact, showing that incorporating the SiC NP to the PCM lead to physical interactions (e.g., hydrogen bonding or surface adsorption). The TGA analysis showed that the SiC NPs in the NEPCM act as supporting material, and its nano-doping enhanced the final degradation temperature and thermal stability. There was negligible change in thermal conductivity for nanoparticle loadings of 0.1% and 0.4%; however, it increased progressively by 5.2%, 10.8%, 23.12%, and 25.8% at nanoparticle loadings of 0.7%, 1%, 2%, and 3%, respectively, at 25 °C. Thermal reliability was analyzed through a DSC thermal cycling test which confirmed the suitability of the material for the desired applications. Full article

The development of integrated renewable energy and high-density thermal energy storage systems has been fueled by the need for environmentally friendly heating and cooling in buildings. In this paper, MiniStor, a hybrid thermochemical and phase-change material storage system, is presented. It is equipped with a heat pump, advanced electronics-enabled control, photovoltaic–thermal panels, and flat-plate solar collectors. To optimize energy flows, regulate charging and discharging cycles, and maintain operational stability under fluctuating solar irradiance and building loads, the system utilizes state-of-the-art power electronics, variable-frequency drives and modular multi-level converters. The hybrid storage is safely, reliably, and efficiently integrated with building HVAC requirements owing to a multi-layer control architecture that is implemented via Internet of Things and SCADA platforms that allow for real-time monitoring, predictive operation, and fault detection. Data from the MiniStor prototype demonstrate effective thermal–electrical coordination, controlled energy consumption, and high responsiveness to dynamic environmental and demand conditions. The findings highlight the vital role that digital control, modern electronics, and Internet of Things-enabled supervision play in connecting small, high-density thermal storage and renewable energy generation. This strategy demonstrates the promise of electronics-driven integration for next-generation renewable energy solutions and provides a scalable route toward intelligent, robust, and effective building energy systems. Full article

To balance the quantity of heat generated and consumed, thermal energy storage systems are crucial for power plants and district heating systems. Particularly when phase transitions and pressure variations are not adequately covered in the existing literature, their work frequently takes place under complicated, changing temperature and fluid dynamic settings. The goal of this research is to create a thermodynamic model that incorporates the effects of steam condensation, steam injection, and heating failures to describe the transient behaviour of temperature and pressure in pressure vessels containing single-phase and two-phase fluids. To account for nonlinear, temperature-dependent steam properties, as well as initial and boundary constraints, the study proposes energy balance models for hot water and saturated steam cases. Numerical simulations evaluating sensitivity to parameter changes are presented alongside analytical solutions for isochoric and isobaric systems. The model also includes direct steam injection heating and the use of a heat exchanger. It explains the changes in temperature and pressure that occur in thermal energy storage systems over time, including significant events such as steam cushion collapse and condensate drainage. According to the sensitivity analysis, the main factors influencing the system’s safety limitations and transient dynamic phenomena are thermal power, heat exchanger capacity, and thermal insulation efficiency. The proposed thermodynamic model closes a major gap in the literature by providing reliable predictions of the transient behavior needed for the safe design and reliable operation of pressure vessels utilized for heat storage in district heating networks. This model can be used by engineers and researchers to optimize system design and steer clear of risky operational situations. Full article

The development of multifunctional polymer composites capable of both heat conduction and latent heat storage is of great interest for advanced thermal management applications. In this work, thermoplastic polyurethane (TPU) nanocomposites containing microencapsulated paraffin-based phase change materials (PCMs) and multi-walled carbon nanotubes (MWCNTs) were systematically investigated. The microstructure, thermal stability, specific heat capacity, thermal diffusivity and conductivity of these composites were analyzed as a function of the PCM and MWCNTs content. SEM observations revealed the homogeneous dispersion of PCM microcapsules and the presence of localized MWCNT aggregates in PCM-rich domains. Thermal diffusivity measurements indicated a monotonic decrease with increasing temperature for all compositions, from 0.097 mm²·s⁻¹ at 5 °C to 0.091 mm²·s⁻¹ at 25 °C for neat TPU, and from 0.186 mm²·s⁻¹ to 0.173 mm²·s⁻¹ for TPU with 5 vol.% MWCNTs. Distinct non-linear behavior was observed around 25 °C, i.e., in correspondence to the paraffin melting, where the apparent diffusivity temporarily decreased due to latent heat absorption. The trend of the thermal conductivity (λ) was determined by the competing effects of PCM and MWCNTs: PCM addition reduced λ at 25 °C from 0.162 W·m⁻¹·K⁻¹ (neat TPU) to 0.128 W·m⁻¹·K⁻¹ at 30 vol.% PCM, whereas the incorporation of 5 vol.% of MWCNTs increased λ up to 0.309 W·m⁻¹·K⁻¹. In PCM-containing nanocomposites, MWCNT networks efficiently bridged the polymer–microcapsule interfaces, creating continuous conductive pathways that mitigated the insulating effect of the encapsulated paraffin and ensured stable heat transfer even across the solid–liquid transition. A one-dimensional transient heat-transfer model confirmed that increasing the matrix thermal conductivity accelerates the melting of the PCM, improving the dynamic thermal buffering capacity of these materials. Therefore, these results underlined the potential of TPU/MWCNT/PCM composites as versatile materials for applications requiring both rapid heat dissipation and effective thermal management. Full article

The large-scale integration of renewable energy systems requires hydrogen storage technologies that can decouple energy production from energy utilization and allow for seasonal storage. Metal hydrides can offer higher volumetric energy density and operational safety than compressed H₂ but are limited by heat-transfer constraints that slow hydrogen absorption and desorption. This work investigates the performance of metal hydride–phase-change material hydrogen storage systems through advanced numerical modeling. Five reactor geometries are evaluated to quantify how longitudinal fins, transversal fins, helical fin structures, and graphite-enhanced composites influence heat removal, charge/discharge rates, and overall power density. Results show that longitudinal and transversal fins accelerate hydrogen absorption and desorption, reducing cycle times by up to 80.6%. The optimized finned helix configuration achieves the highest performance, with a power density of 2.55 kW/kg and charge/discharge powers of 6.75 kW and 13.25 kW, respectively. Expanded graphite further enhances kinetics in low-Biot-number designs, reducing cycle times by more than 30%. These findings provide design guidelines to maximize performance and efficiency of solid-state hydrogen storage for medium- and high-power applications. Full article

Organic phase change materials (OPCMs) show immense application potential in solar energy storages owing to high energy storage capacity and latent heat efficiency. However, it is difficult to achieve prolonged energy storage due to the sensitivity of phase change to environmental temperature, and adding other substances will lead to a decrease in total energy density. Herein, azobenzene organic phase change composite (C₁₄Azo-MA) was designed and prepared by doping myristic acid (MA) with an azobenzene derivative (C₁₄Azo) featuring a carbon chain identical to that of the MA matrix. C₁₄Azo-MA was systematically characterized by UV–Visible absorption spectroscopy and differential scanning calorimetry. The results showed that the C₁₄Azo-MA retains the same isomerization properties as the C₁₄Azo dopant. C₁₄Azo-MA, due to its molecular photoisomerization and enhanced intermolecular interactions, establishes a new energy barrier and forms supercooling within C₁₄Azo-MA, thereby allowing the storage of thermal energy below the crystallization temperature of MA. Notably, the C₁₄Azo-MA exhibits a high energy density of 225.08 J g⁻¹, surpassing that of pure MA by 14.42%. This work holds significant potential for solar energy storage applications. Full article

The low thermal conductivity of phase-change materials (PCMs) remains a key limitation in latent heat thermal energy storage systems, leading to slow melting and incomplete energy recovery. To address this challenge, this study explores extended Y-Fin geometries as a novel heat transfer enhancement strategy within a concentric-tube latent heat thermal energy storage configuration. Six fin designs, derived from a baseline Y-shaped structure, were numerically compared to assess their influence on the melting and solidification behavior of stearic acid. A two-dimensional transient enthalpy–porosity model was developed and rigorously verified through grid, temporal, and residual convergence analyses. The results indicate that fin geometry plays a critical role in enhancing heat transfer within the PCM domain. The extended Y-Fin configuration achieved the fastest melting time, 28% shorter than the baseline Y-Fin case, due to improved thermal penetration and bottom-region accessibility. Additionally, the thermal performance was evaluated using nano-enhanced PCMs (10% Al₂O₃ and CuO in stearic acid) and paraffin wax. The addition of Al₂O₃ nanoparticles significantly improved thermal conductivity, while paraffin wax exhibited the shortest melting duration due to its lower melting point and latent heat. This study introduces an innovative fin architecture combining extended conduction paths and improved convective reach for efficient latent heat storage systems. Full article

In this work, three novel optimization algorithms—collectively referred to as the BxR algorithms—and their multi-objective versions, referred to as the MO-BxR algorithms, are applied to diverse heat transfer systems. Five representative case studies are presented: two single-objective problems involving a heat exchanger network and a jet-plate solar air heater; a two-objective optimization of Y-type fins in phase-change thermal energy storage units; and two three-objective problems involving TPMS–fin three-fluid heat exchangers and Tesla-valve evaporative cold plates for LiFePO₄ battery modules. The proposed algorithms are compared with leading evolutionary optimizers, including IUDE, εMAgES, iL-SHADEε, COLSHADE, and EnMODE, as well as NSGA-II, NSGA-III, and NSWOA. The results demonstrated improved convergence characteristics, better Pareto front diversity, and reduced computational burden. A decision-making framework is also incorporated to identify balanced, practically feasible, and engineering-preferred solutions from the Pareto sets. Overall, the results demonstrated that the BxR and MO-BxR algorithms are capable of effectively handling diverse thermal system designs and enhancing heat transfer performance. Full article

The utilization and transformation of heat have played pivotal roles in numerous significant stages of human societal evolution and advancement. Recently, more rigorous and precise requirements have been imposed on thermal functional materials for applications including microelectronic device cooling, personal thermal regulation in extreme environments, green building initiatives, flexible wearable electronics, and solar thermal collection. Thermal functional fibers offer advantages such as lightweight construction, versatile functional design, and integrated manufacturing capabilities. By modifying the composition, structure, and fabrication techniques of fibers, control over heat transfer, storage, and conversion processes can be optimized. This review underscores the latest developments in thermal functional fibers, emphasizing high thermal conductivity fibers, thermal insulation fibers, thermal radiation regulation fibers, phase-change thermal storage fibers, thermoelectric fibers, Joule heating fibers, photothermal conversion fibers, thermally actuated fibers, and multifunctional composite fibers. It elucidates how these various fibers enhance thermal performance through innovative material selection, fabrication methods, and structural design. Finally, the review discusses prevailing developmental trends, current challenges, and future directions in the design and fabrication of thermal functional fibers. Full article