Search Results (13)

Accurately classifying petrol and diesel fuel using an image processing method is crucial for fuel-related industries such as petrol pumps, refineries, and fuel storage facilities. However, distinguishing between these fuels using traditional methods can be challenging due to their similar visual characteristics. This study aims to enhance the accuracy and robustness of existing fuel classification by utilizing the transfer learning-based finetuned pre-trained deep learning models and ensemble approaches. Specifically, we upgrade pre-trained deep models like ResNet152V2, InceptionResNetV2, and EfficientNetB7 by incorporating additional layers. Through transfer learning, these models are adapted to the specific task of classifying petrol and diesel fuels. To evaluate their performance, the upgraded deep model and an ensemble of these models are tested on a synthetic dataset. The results indicate that the ensemble of upgraded ResNet152V2, InceptionResNetV2, and EfficientNetB7 achieves recall, precision, f-score, and accuracy scores of 99.54%, 99.69%, 99.62%, and 99.67%, respectively. Moreover, a comparative analysis reveals that the upgraded models outperform state-of-the-art baseline models. Full article

In this entry, the possibility of the implementation of a biorefinery based on multiple raw materials (from agricultural wastes, vegetable oils, etc.) is covered, pointing out the available technology to interconnect different processes so that the atom economy of the process is as high as possible, reducing the environmental impact and improving the efficiency of the energy or products obtained. For this purpose, this model is based on previous works published in the literature. The role of biorefineries is becoming more and more important in the current environmental scenario, as there is a global concern about different environmental issues such as climate change due to GHG emissions, among others. In this sense, a biorefinery presents several advantages such as the use of natural raw materials or wastes, with high atom economy values (that is, all the products are valorized and not released to the environment). As a consequence, the concept of a biorefinery perfectly fits with the Sustainable Development Goals, contributing to the sustainable growth of different regions or countries, regardless of their stage of development. The aim of this entry is the proposal of a biorefinery based on multiple raw materials, using different technologies such as transesterification to produce both biodiesel and biolubricants, steam reforming to produce hydrogen from glycerol or biogas, hydrothermal carbonization of sewage sludge to produce hydrochar, etc. As a result, these technologies have potential for the possible implementation of this biorefinery at the industrial scale, with high conversion and efficiency for most processes included in this biorefinery. However, there are some challenges like the requirement of the further technological development of certain processes. In conclusion, the proposed biorefinery offers a wide range of possibilities to enhance the production of energy and materials (hydrogen, biodiesel, biolubricants, different biofuels, hydrochar, etc.) through green technologies, being an alternative for petrol-based refineries. Full article

One of the measures to reduce the carbon footprint of the Portland cement (PC) manufacturing process is through a wider use of supplementary cementitious and waste materials. The main objective of this work was to produce a new binder using two different waste materials: fly ash (FA) from thermal power plants and spent fluid catalytic cracking catalyst (sFCCC) from petrol refineries. In order to improve their reactivity, both FA and sFCCC were mechanically activated prior to the preparation of the binder. The new binder consisted mostly of the waste materials (70 mass %), with PC as a minor component (30 mass %). It was found that using sFCCC as the binder component accelerated cement hydration and the pozzolanic reaction. The new binder had a shorter setting time and a higher early strength than the binder prepared without sFCCC. Full article

The analysis of the corrosion phenomenon of the installations of the largest refinery in Romania confirmed the existence of its conditions, in the atmospheric distillation plants of crude oil, in the heat exchangers, and in the petrol and diesel hydrofining plants. However, the slightest effect of this phenomenon was found in the dome, the plates, and the exhaust pipes at the top of the distillation column, as well as in the reflux vessel of the atmospheric distillation plant. The main cause of the corrosion phenomenon and the increase in the corrosion areas of the material of the crude oil refining installations is the presence of hydrochloric acid, obtained after incorrect desalination (hydrolysis of calcium and magnesium chloride). To prevent this phenomenon, in laboratory conditions, we tested an antacid inhibitor (alkyl phenol) and a residual product (undistilled polyamine), with the role of supplementing the commercial inhibitor with a cheap product. The effectiveness of these additives was evaluated by introducing specimens made from the material taken from the refining column and from the reflux vessel into a solution of hydrochloric acid of various concentrations (5–15%). This solution was treated with the two corrosion inhibitors, the analysis of their effectiveness being performed at concentrations ranging between 0.05 and 0.2%. In addition, in this article, we deduced the equations of variation of the corrosion rate, depending on the working temperature of the refinery. Full article

Replacing fossil jet fuel with biojet fuel is an important step towards reducing greenhouse gas (GHG) emissions from aviation. To this end, Sweden has adopted a GHG mandate on jet fuel, complementing those on petrol and diesel. The GHG mandate on jet fuel requires a gradual reduction in the fuel’s GHG emissions to up to 27% by 2030. This paper estimates the potential production of biojet fuel in Sweden for six integrated production pathways and analyzes what they entail with regard to net biomass input and the amount of hydrogen required for upgrading to fuel quality. Integrated production of biofuel intermediates from forestry residues and by-products at combined heat and power plants as well as at the forest industry, followed by upgrading to biojet fuel and other transportation fuels at a petroleum refinery, was assumed in all the pathways. The potential output of bio-based transportation fuels was estimated to 90 PJ/y, including 22 PJ/y of biojet fuel. The results indicate that it will be possible to meet the Swedish GHG mandate for jet fuel for 2030, although it will be difficult to simultaneously achieve the GHG mandates for road transportation fuels. This highlights the importance of pursuing complementary strategies for bio-based fuels. Full article

Sources of contamination in a subsurface environment are petrol, diesel fuel, gasoline at oil refineries, underground storage tanks, transmission pipelines, and different industries. The permeable reactive barrier (PRB) is a promising technology to remediate groundwater in-situ. In this study, synthetic groundwater samples containing toluene are treated in three reactor columns by biological processes. PRB-1 consisted of sand and gravel as reactor media, microbial inoculum (bioaugmentation—BA), and nutrients (biostimulation—BS); PRB-2 consisted of sand and gravel as reactor media, microbial inoculum, nutrients, and 12 layers of nonwoven geotextile fabrics; and PRB-3 consisted of only sand and gravel as reactor media (natural attenuation—NA). This study was conducted to assess the impact of geotextile fabric filter, bioaugmentation, and biostimulation on toluene degradation efficiency. After 167 days of treatment, toluene biodegradation efficiencies varied between 88.2% and 93.8% for PRB 1, between 98.0% and 99.3% for PRB 2, and between 14.2% and 68.6% for PRB 3. The effluent toluene concentrations for PRB-2 were less than the guideline value (0.7 mg/L) of the World Health Organization. Reaction rate data were fitted with a first-order kinetic reaction rate model. This study showed that the toluene removal efficiency in the geotextile layered PRB combined with BA and BS process was significantly higher compared to the other processes tested. This lab-scale study introduced a new PRB configuration suitable for the remediation of sites contaminated with toluene. Full article

Energy-related greenhouse gas emissions dominate the carbon footprints of most product systems, where petroleum is one of the main types of energy sources. This is consumed as a variety of refined products, most notably diesel, petrol (gasoline) and jet fuel (kerosene). Refined product carbon footprints are of great importance to regulators, policymakers and environmental decision-makers. For instance, they are at the heart of current legislation, such as the European Union’s Renewable Energy Directive or the United States’ Renewable Fuels Standard. This study identified 14 datasets that report footprints for the same system, namely, petroleum refinery operations in Europe. For the main refined products, i.e., diesel, petrol and jet fuel, footprints vary by at least a factor of three. For minor products, the variation is even greater. Five different organs of the European Commission have estimated the refining footprints, where for the main products, these are relatively harmonic; for minor products, much less so. The observed variation in carbon footprints is due mainly to differing approaches to refinery modelling, especially regarding the rationale and methods applied to assign shares of the total burden from the petroleum refinery operation to the individual products. Given the economic/social importance of refined products, a better harmony regarding their footprints would be valuable to their users. Full article

Oil pollutants, due to their toxicity, mutagenicity, and carcinogenicity, are considered a serious threat to human health and the environment. Petroleum hydrocarbons compounds, for instance, benzene, toluene, ethylbenzene, xylene, are among the natural compounds of crude oil and petrol and are often found in surface and underground water as a result of industrial activities, especially the handling of petrochemicals, reservoir leakage or inappropriate waste disposal processes. Methods based on the conventional wastewater treatment processes are not able to effectively eliminate oil compounds, and the high concentrations of these pollutants, as well as active sludge, may affect the activities and normal efficiency of the refinery. The methods of removal should not involve the production of harmful secondary pollutants in addition to wastewater at the level allowed for discharge into the environment. The output of sewage filtration by coagulation and dissolved air flotation (DAF) flocculation can be transferred to a biological reactor for further purification. Advanced coagulation methods such as electrocoagulation and flocculation are more advanced than conventional physical and chemical methods, but the major disadvantages are the production of large quantities of dangerous sludge that is unrecoverable and often repelled. Physical separation methods can be used to isolate large quantities of petroleum compounds, and, in some cases, these compounds can be recycled with a number of processes. The great disadvantage of these methods is the high demand for energy and the high number of blockages and clogging of a number of tools and equipment used in this process. Third-party refinement can further meet the objective of water reuse using methods such as nano-filtration, reverse osmosis, and advanced oxidation. Adsorption is an emergency technology that can be applied using minerals and excellent materials using low-cost materials and adsorbents. By combining the adsorption process with one of the advanced methods, in addition to lower sludge production, the process cost can also be reduced. Full article

Groundwater and soil pollution caused by (PAHs) spills, mostly from the oil industry and petrol stations in urban areas, represent a major environmental concern worldwide. However, infiltration into groundwater is decreasing due to the natural attenuation processes of PAHs in the vadose zone, which protect invaluable groundwater resources against contamination. This study was conducted to evaluate the effect of improper management of the petroleum industry on the groundwater and soil surrounding the petrol station and an oil refinery unit and, furthermore, to prepare the polluted risk intensity (PRI) map. Fifty-one soil samples and twenty-five water samples were analyzed for Light Non-aqueous Phase Liquid (LNAPLs), and one soil sample for Dense Non-Aqueous Phase Liquid (DNAPLs); furthermore, six soil samples analyzed for Tetraethyl Lead (TEL) analysis. The results showed that seventeen wells were polluted with LNAPLs and the soils were highly contaminated with different DNAPLs components and mainly was in the form of Polycyclic Aromatic Hydrocarbons (PAHs). Seven factors introduced to the GIS platform to produce PRI map, which is the distance to source, depth to water table, slope, lineaments, lithology, soil, and recharge rate. The final map revealed that the eastern and western parts of the study area are at a very high-risk level, whereas the center is at a very low to low-risk level. Full article

This paper discusses the problems associated with the implementation of Real Time Optimization/Model Predictive Control (RTO/MPC) systems, taking as reference the hydrogen distribution network of an oil refinery involving eighteen plants. This paper addresses the main problems related to the operation of the network, combining data reconciliation and a RTO system, designed for the optimal generation and redistribution of hydrogen, with a predictive controller for the on-line implementation of the optimal policies. This paper describes the architecture of the implementation, showing how RTO and MPC can be integrated, as well as the benefits obtained in terms of improved information about the process, increased hydrocarbon load to the treatment plants and reduction of the hydrogen required for performing the operations. Full article

A standard problem in large tanks at oil refineries and petrol stations is that water and fuel usually occupy the same tank. This is undesirable and causes problems such as corrosion in the tanks. Normally, the water level in tanks is unknown, with the problems that this entails. We propose herein a method based on surface plasmon resonance (SPR) to detect in real time the interfaces in a tank which can simultaneously contain water, gasoline (or diesel) and air. The plasmonic sensor is composed of a hemispherical glass prism, a magnesium fluoride layer, and a gold layer. We have optimized the structural parameters of the sensor from the theoretical modeling of the reflectance curve. The sensor detects water-fuel and fuel-air interfaces and measures the level of each liquid in real time. This sensor is recommended for inflammable liquids because inside the tank there are no electrical or electronic signals which could cause explosions. The sensor proposed has a sensitivity of between 1.2 and 3.5 RIU⁻¹ and a resolution of between 5.7 × 10⁻⁴ and 16.5 × 10⁻⁴ RIU. Full article

The combustion of fossil fuels in the transport sector leads to an aggravation of the air quality along city roads and highways. Urban air quality is a serious problem nowadays as the number of vehicles increases on a yearly basis. With stricter Euro emission regulations, vehicle manufacturers are not meeting the imposed limits and are also disregarding the non-exhaust emissions. This paper highlights the relevance of non-exhaust emissions of passenger vehicles, both conventional (diesel and petrol) or electric vehicles (EV), on air quality levels in an urban environment in Belgium. An environmental life cycle assessment was carried out based on a real-world emission model for passenger cars and fuel refinery data. A cut-off was applied to the models to highlight what emissions, both from the refinery to the exhaust and electricity production for EV, do actually occur within Belgium’s borders. Results show that not much progress has been made from Euro 4 to 6 for conventional vehicles. Electric vehicles pose the best alternative solution as a more environmentally friendly means of transportation. The analysis results target policy makers with the intention that regulations and policies would be developed in the future and target the characterization of non-exhaust emissions from vehicles. These results indicate that EVs offer a valid solution for addressing the urban air quality issue and that non-exhaust emissions should be addressed in future regulatory steps as they dominate the impact spectrum. Full article

Fine airborne respirable particulates less than 10 micrometer (PM10) are considered one of the top environmental public health concerns, since they contain polycyclic aromatic hydrocarbons (PAHs) which are among the major carcinogenic compounds found in urban air. The objective of this study is to assess the genotoxicity of the ambient PM10 collected at 11 urban sites in Jeddah, Saudi Arabia. The PM10 extractable organic matter (EOM) was examined for its genotoxicity by the single cell gel electrophoresis (SCGE) comet assay and the Salmonella mutagenicity (Ames) test .Gas chromatography-mass spectrometry was used to quantify 16 PAH compounds in four sites. Samples from oil refinery and heavy diesel vehicles traffic sites showed significant DNA damage causing comet in 20-44% of the cells with tail moments ranging from 0.5-2.0 compared to samples from petrol driven cars and residential area, with comet in less than 2% of the cells and tail moments of < 0.02.In the Ames test, polluted sites showed indirect mutagenic response and caused 20-56 rev/ m³, mean while residential and reference sites caused 2-15 rev /m³. The genotoxicity of the EOM in both tests directly correlated with the amount of organic particulate and the PAHs concentrations in the air samples. The PAHs concentrations ranged between 0.83 ng/m³ in industrial and heavy diesel vehicles traffic sites to 0.18 ng /m³ in the residential area. Benzo(ghi)pyrene was the major PAH components and at one site it represented 65.4 % of the total PAHs. Samples of the oil refinery site were more genotoxic in the SCGE assay than samples from the heavy diesel vehicles traffic site, despite the fact that both sites contain almost similar amount of PAHs. The opposite was true for the mutagenicity in the Ames test. This could be due to the nature of the EOM in both sites. These findings confirm the genotoxic potency of the PM10 organic extracts to which urban populations are exposed. Full article