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Search Results (3,560)

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Keywords = particle separation

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25 pages, 6038 KB  
Article
Design and Testing of a Soil-Removal Device for Peanut Harvesting in Saline–Alkali Soils: Using a Squeezing and Rubbing Method
by Zengcun Chang, Dongwei Wang, Yu Tian, Xu Li, Baiqiang Zuo, Haipeng Yan, Jiayou Zhang, Jialin Hou and Dongjie Li
Agriculture 2026, 16(7), 755; https://doi.org/10.3390/agriculture16070755 (registering DOI) - 28 Mar 2026
Abstract
In response to the pressing issues of unclear adhesion mechanisms during the soil-removal process in peanut harvesting, poor soil fragmentation quality, and difficulties in separating the pods from the soil. Based on TRIZ theory, this study has innovatively designed a separation device that [...] Read more.
In response to the pressing issues of unclear adhesion mechanisms during the soil-removal process in peanut harvesting, poor soil fragmentation quality, and difficulties in separating the pods from the soil. Based on TRIZ theory, this study has innovatively designed a separation device that relies on external forces, such as kneading and squeezing. A mechanical model of soil fragmentation and separation was developed. The key factors affecting the device’s operational performance were identified. Through theoretical analysis and discrete element simulation, this study elucidates the working principle by which the device crushes and separates soil particles using kneading and squeezing forces. Through analysis of one-factor and orthogonal experiments, the optimal operating parameter combination for the device was determined to be: a drum installation clearance of 104.7 mm, a rotational speed difference of 75.2 rpm, and a pattern roughness of Grade III (reticulated). The system’s performance metrics are a soil removal rate of 96.59% and a pod damage rate of 2.48%. Field tests have confirmed that the deviation from simulation results is minimal. The device’s performance meets the requirements of actual production. Full article
(This article belongs to the Section Agricultural Technology)
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13 pages, 1804 KB  
Article
Microfluidic Pre-Concentration of Metals from Fine Flotation Tailings
by Olesya Tyumentseva, Kaster Kamunur, Lyazzat Mussapyrova, Aisulu Batkal, Luisa Beisembayeva and Rashid Nadirov
Minerals 2026, 16(4), 355; https://doi.org/10.3390/min16040355 - 27 Mar 2026
Abstract
The large volumes of fine flotation tailings constitute a persistent challenge for the conventional treatment of minerals due to their wide particle size distribution and their low metal contents. In this work, the potential of passive inertial microfluidics for the selective redistribution of [...] Read more.
The large volumes of fine flotation tailings constitute a persistent challenge for the conventional treatment of minerals due to their wide particle size distribution and their low metal contents. In this work, the potential of passive inertial microfluidics for the selective redistribution of mineral particles from actual copper flotation tailings is studied. A suspension of tailings was treated in a rectangular microfluidic channel in a laminar regime, without an external magnetic field or sheath flux. The solid fractions obtained were characterized in terms of particle size distribution, phase composition and element content. The microfluidic treatment induced a systematic distribution of the particles between the output fractions. The central fraction was enriched with coarser particles, the median particle size increasing from about 15 µm in the feed to about 20 µm, and had high concentrations of Cu, Fe, Ag and Zn, with enrichment factors reaching 2.0 to 2.7 depending on the element. On the other hand, the lateral fraction was mainly composed of finer particles (D50 ≈ 13 µm) and depleted in metalliferous phases. The elemental mass balance confirmed that the observed enrichment results from selective redistribution rather than from a loss of material. These results indicate that the separation of the particles cannot be explained solely by size effects and are consistent with a preferential migration of the denser and metal-rich particles towards stable inertial focusing trajectories. Full article
(This article belongs to the Section Mineral Processing and Extractive Metallurgy)
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20 pages, 6707 KB  
Article
Membrane Fouling Mechanisms in the Microfiltration of Oat Protein–β-Glucan Complexes
by Tianyu Zheng, Songlin Wen, Yi Wu, Pengyu Shuai, Delong Hou and Yao Jin
Membranes 2026, 16(4), 116; https://doi.org/10.3390/membranes16040116 - 27 Mar 2026
Viewed by 126
Abstract
This work investigated the membrane fouling mechanisms during the microfiltration of oat protein–β-glucan complexes. Microfiltration experiments were conducted under various pH conditions, protein-to-polysaccharide ratios, and ionic strengths. The fouling behavior was analyzed using multiple membrane fouling models to systematically elucidate the relationships among [...] Read more.
This work investigated the membrane fouling mechanisms during the microfiltration of oat protein–β-glucan complexes. Microfiltration experiments were conducted under various pH conditions, protein-to-polysaccharide ratios, and ionic strengths. The fouling behavior was analyzed using multiple membrane fouling models to systematically elucidate the relationships among the particle characteristics, rheological behaviors, and membrane fouling. When the pH was adjusted to 7.8, the multimodal particle size distribution of the complexes promoted the formation of a loosely structured cake layer on the membrane surface, accompanied by partial obstruction of membrane pore entrances. On the contrary, the complexes, shown as having a monomodal particle size distribution and similar particle size to the membrane pore, formed compact cake layers and strong membrane fouling resistance. At pH 4.8, protein hydrophobic aggregation generated large particulate clusters that formed a loose cake layer during microfiltration, resulting in a decrease in membrane fouling resistance. Increasing the β-glucan content reduced membrane resistance through enhancing steric hindrance and hydrophilicity. This research provides a theoretical foundation for optimizing membrane separation process parameters in the production of diversified oat-based products. Full article
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29 pages, 79167 KB  
Article
Development and Comparative Analysis of Vortex Generators for Boundary Layer and Separation Control on the Suction Side of Wind Turbine Blades
by Andrei V. Chukalin, Oleg V. Savelov and Ruslan V. Fedorov
Energies 2026, 19(7), 1637; https://doi.org/10.3390/en19071637 - 26 Mar 2026
Viewed by 218
Abstract
Vortex generators (VGs) are considered in this study as an effective means of controlling the boundary-layer structure and suppressing flow separation on the suction sides of wind turbine blades. An original geometry of a surface-mounted VG has been developed and experimentally investigated, providing [...] Read more.
Vortex generators (VGs) are considered in this study as an effective means of controlling the boundary-layer structure and suppressing flow separation on the suction sides of wind turbine blades. An original geometry of a surface-mounted VG has been developed and experimentally investigated, providing a stable modification of the near-wall flow over a wide range of incoming flow velocities. The aerodynamic effect is attributed to the formation of spatially diverging vortex structures that enhance momentum transfer from the outer flow region toward the near-wall layer, thereby increasing the energy level of the boundary layer. This results in an extension of the attached-flow region and an increase in the mean flow velocity over the suction side of the airfoil by up to 6.5%. The proposed configuration enables a 15% increase in the installation spacing of surface-mounted VGs without loss of control efficiency. Experimental investigations were carried out in a subsonic aerodynamic facility using the Particle Image Velocimetry (PIV) method at free-stream velocities of up to 30 m/s. The obtained data will be used for the development and validation of a mathematical model intended for parametric studies of the influence of surface-mounted VGs on various wind turbine blade airfoils under a wide range of atmospheric turbulence conditions. Full article
(This article belongs to the Special Issue New Trends in Wind Energy and Wind Turbines)
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14 pages, 5416 KB  
Article
Lamellar Dilation in (AB)-g-A Copolymacromer Melts: A Dissipative Particle Dynamics Study
by Jihoon Park and June Huh
Polymers 2026, 18(7), 798; https://doi.org/10.3390/polym18070798 - 26 Mar 2026
Viewed by 199
Abstract
Homopolymer addition is a widely used strategy to dilate the microdomain spacing of block copolymers, yet the attainable dilation is often limited by macrophase separation in conventional blends at elevated homopolymer loading. In this work, we investigate an architectural route to suppress macrophase [...] Read more.
Homopolymer addition is a widely used strategy to dilate the microdomain spacing of block copolymers, yet the attainable dilation is often limited by macrophase separation in conventional blends at elevated homopolymer loading. In this work, we investigate an architectural route to suppress macrophase separation while retaining homopolymer-driven dilation: a covalently hybridized bottlebrush copolymer (CH-BBC), a copolymacromer-like bottlebrush architecture in which symmetric AB diblock side chains and A-type homopolymer side chains are covalently grafted to a common backbone. Using dissipative particle dynamics (DPD) simulations, we directly compare the phase behavior of CH-BBC melts with that of composition-matched blends of symmetric AB diblocks and A-type homopolymers. Across the explored window, CH-BBC exhibits microphase morphologies and disorder without an observable two-phase region, whereas the corresponding blends show extensive two-phase coexistence at elevated homopolymer loading. Lamellar analysis and one-dimensional density decompositions further reveal that CH-BBC enables substantially larger microphase dilation and stronger selective swelling of the A-rich domain because tethered A-type homopolymer segments preferentially occupy and dilate the A-rich domain interior while diblock A segments remain localized near interfaces. Full article
(This article belongs to the Special Issue Phase Behavior in Polymers: Morphology and Self-Assembly: 2nd Edition)
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22 pages, 8228 KB  
Article
Bridging Interfaces and Morphology: A Mesoscale Dynamics Framework for Predicting Percolation in Organic Solar Cells
by Estela Mayoral-Villa and Alfonso R. García-Márquez
Energies 2026, 19(7), 1624; https://doi.org/10.3390/en19071624 - 25 Mar 2026
Viewed by 182
Abstract
The dynamic self-assembly and phase separation of donor–acceptor blends are processes that dictate the nanoscale morphology in organic solar cells. Here, we employ a fluidics-inspired framework, integrating dissipative particle dynamics simulations with percolation theory, to investigate the morphogenesis of two non-fullerene systems: P3HT-PPerAcr [...] Read more.
The dynamic self-assembly and phase separation of donor–acceptor blends are processes that dictate the nanoscale morphology in organic solar cells. Here, we employ a fluidics-inspired framework, integrating dissipative particle dynamics simulations with percolation theory, to investigate the morphogenesis of two non-fullerene systems: P3HT-PPerAcr and P3HT-PFTBT. We analyze monomeric and homopolymer blends, and copolymer macrostructures, focusing on how key parameters such as temperature and polymer chain flexibility govern the dynamic evolution towards percolating networks. Our simulations captured the fundamental fluidic behavior and universal scaling near the critical percolation threshold (χc). The critical exponent β revealed distinct universality classes dictated by system compatibility and flexibility: monomeric and flexible homopolymer blends below the critical temperature (Tc) exhibit mean field behavior (β ≈ 1). In contrast, monomeric systems above χc and flexible copolymers below χc display 3D percolation behavior (β ≈ 0.45). In the case of flexible copolymeric macromolecules, above percolation threshold a quasi-bidimensional behavior emerge with (β ≈ 0.1). Notably, semi-rigid and rigid homopolymeric and copolymeric linear architectures induce a dimensional crossover, yielding quasi-2D (β ≈ 0.14) and quasi-1D (β ≈ 0.0) morphologies. These findings establish a direct link between tunable fluidic interactions, chain dynamics, and the emergence of optimal bicontinuous percolation networks. Full article
(This article belongs to the Section A2: Solar Energy and Photovoltaic Systems)
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13 pages, 2119 KB  
Article
Using Bayes’ Rule for Analysis of Microfluidic Particle and Cluster Sorting
by Elham Akbari, Esra Yilmaz, Christelle N. Prinz, Jason P. Beech and Jonas O. Tegenfeldt
Micromachines 2026, 17(4), 396; https://doi.org/10.3390/mi17040396 (registering DOI) - 25 Mar 2026
Viewed by 188
Abstract
Deterministic lateral displacement (DLD) and related microfluidic sorting devices are typically evaluated based on the size distributions of particles collected at each outlet, even though the more relevant measure of performance is the probability that a particle of a given size ends up [...] Read more.
Deterministic lateral displacement (DLD) and related microfluidic sorting devices are typically evaluated based on the size distributions of particles collected at each outlet, even though the more relevant measure of performance is the probability that a particle of a given size ends up in a specific outlet. Here, we use Bayes’ rule to infer these size-dependent routing probabilities from experimentally accessible measurements of outlet size distributions, inlet size distributions, and outlet subpopulations. Using a DLD array designed to separate microspheres and microsphere clusters, we determine the probabilities that particles of different sizes are directed to each outlet and define a probabilistic critical size (DC) at which particles are equally likely to follow a zigzag and a displacement trajectory. Based on this, we calculate key performance metrics, purity, and yield. Our results demonstrate high-quality separations and show that routing probabilities provide a general and robust framework for benchmarking microfluidic sorting devices beyond traditional outlet-based analyses. Full article
(This article belongs to the Section A:Physics)
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8 pages, 4028 KB  
Brief Report
Progress in Industrialization of Tungsten Fiber-Reinforced Tungsten Composites
by Yiran Mao, Ute Wilkinson, Jan Willem Coenen, Daniel Wilkinson, Johann Riesch and Christian Linsmeier
J. Nucl. Eng. 2026, 7(2), 24; https://doi.org/10.3390/jne7020024 - 25 Mar 2026
Viewed by 244
Abstract
Plasma-facing materials (PFMs) for future fusion reactors require advanced mechanical and thermal properties to withstand the extreme challenges of high heat flux, plasma exposure, and neutron irradiation. Tungsten is one of the most suitable materials for use as a PFM in the divertor [...] Read more.
Plasma-facing materials (PFMs) for future fusion reactors require advanced mechanical and thermal properties to withstand the extreme challenges of high heat flux, plasma exposure, and neutron irradiation. Tungsten is one of the most suitable materials for use as a PFM in the divertor region. However, considering the high thermal loading/thermal stress combining plasma exposure and neutron irradiation/embrittlement, one of the major concerns for tungsten in PFMs is its intrinsic brittleness. To avoid cracking and components failure, tungsten toughening has been widely investigated, including the development of tungsten fiber-reinforced tungsten composites (Wf/W) using an extrinsic toughening mechanism, which could provide damage resilience against neutron embrittlement. Recently, a type of aligned long-fiber Wf/W (L-Wf/W) based on a powder metallurgical fabrication process was developed, demonstrating advanced fracture toughness while retaining other application-relevant properties. For L-Wf/W, the relatively easy production process suggests the feasibility and basis of industrialization. This work reports on the initial progress in industrializing L-Wf/W, with a focus on adapting the lab sintering process to a sintering process with industrial partner (Dr. Fritsch Sondermaschinen GmbH) and optimizing the process parameters. To improve the sinterability of tungsten and achieve higher density, various tungsten powders were explored, including commercial W powders, bimodal mixtures of different particle sizes, and granulated W powders. At the dedicated yttria interface, the thickness of yttria coating on the fibers was also optimized to ensure effective separation between the fibers and the matrix. Series of samples were produced with different dimensions up to 100 mm × 100 mm × 4 mm. After optimization, samples with 93% density and desired pseudo-ductility were prepared. Similarly to production in the lab, a major challenge in this work involved balancing the densification of the tungsten matrix with controlling fiber recrystallization and mitigating damage to the yttria interface. Full article
(This article belongs to the Special Issue Fusion Materials with a Focus on Industrial Scale-Up)
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28 pages, 6219 KB  
Review
A Review of Laser Welding for Particle-Reinforced Aluminum Matrix Composites and Steel
by Peiyang Fang, Longbo Chen, Yida Zeng, Zhiyong Li, Yan Wang, Guangping Wang, Xin Hong and Longfei Zeng
Coatings 2026, 16(3), 392; https://doi.org/10.3390/coatings16030392 - 23 Mar 2026
Viewed by 230
Abstract
Particle-reinforced aluminum matrix composite (AMC)/steel hybrid structures present considerable benefits for lightweight design and enhanced product performance. This article provides a systematic overview of research advances from 2003 to 2024 on laser welding of particle-reinforced AMCs to steel, with particular emphasis on the [...] Read more.
Particle-reinforced aluminum matrix composite (AMC)/steel hybrid structures present considerable benefits for lightweight design and enhanced product performance. This article provides a systematic overview of research advances from 2003 to 2024 on laser welding of particle-reinforced AMCs to steel, with particular emphasis on the influence of laser welding parameters, shielding gas, and reinforcing particles on the mechanical properties of the welded joints. The mechanisms by which intermetallic compounds (IMCs) impair joint strength are thoroughly analyzed. Moreover, the effects of rare earth element additions on both mechanical properties and corrosion resistance of the joints are critically assessed, along with the coupling mechanism between rare earth elements and the reinforcement phase. Key insights from the literature reveal that regulating heat input can effectively suppress harmful interfacial reactions. Meanwhile, the synergistic incorporation of rare earth elements not only refines the grain structure and boosts mechanical strength, but also improves corrosion resistance through the formation of dense surface oxide films and grain boundary strengthening. This review underscores the innovative integration of interfacial reaction control with rare earth microalloying to achieve high-performance AMC/steel laser-welded joints—a distinct departure from prior studies that typically investigated these strategies separately. Full article
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20 pages, 12398 KB  
Article
Comparison of Surface Morphology and Topography of Additively Manufactured SS 316L Steel After AWJM in Dependence on Layer Orientation
by Radoslav Vandžura, Matúš Geľatko, Marek Čornanič, Vladimír Simkulet and František Botko
Materials 2026, 19(6), 1255; https://doi.org/10.3390/ma19061255 - 22 Mar 2026
Viewed by 226
Abstract
Additively manufactured stainless steels are gaining considerable attention in the production of complex components, especially in the aerospace, food production, energy, and biomedical industries. Machining and achieving the desired surface properties of such materials remains a challenge. Abrasive waterjet machining technology appears to [...] Read more.
Additively manufactured stainless steels are gaining considerable attention in the production of complex components, especially in the aerospace, food production, energy, and biomedical industries. Machining and achieving the desired surface properties of such materials remains a challenge. Abrasive waterjet machining technology appears to be one of the options due to the advantages it brings. Removing support structures and separating individual parts is also one of the possible applications of this technology. This study investigates the effects of process parameters for individual cut qualities (Q1–Q5) of abrasive waterjet on the surface properties of additively manufactured stainless steel (SS 316L) specimens, considering the different mechanical properties of the material due to the direction of layering of the material during its production. Experimental specimens were prepared by selective laser melting technology with parameters ensuring the best possible quality of the resulting part. The results of the study showed changes in the topography of the machined surface, especially in the roughness parameters. Scanning Electron Microscopy and Energy Dispersive X-ray Spectroscopy analysis proved the presence of fragmented abrasive particles in the cut areas. Full article
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15 pages, 23897 KB  
Article
Heat Transfer Coefficient Between Spherical Particles in Low-Conducting Fluid
by Andrei I. Malinouski, Oscar S. Rabinovich and Heorhi U. Barakhouski
Computation 2026, 14(3), 74; https://doi.org/10.3390/computation14030074 - 20 Mar 2026
Viewed by 133
Abstract
Calculation of heat transfer in granular materials is an important task for many applications, from thermal management in electronics to exploring celestial soils. Usually, an effective thermal-conductivity model is employed to predict heat flux in unstructured granular media, such as a packed bed. [...] Read more.
Calculation of heat transfer in granular materials is an important task for many applications, from thermal management in electronics to exploring celestial soils. Usually, an effective thermal-conductivity model is employed to predict heat flux in unstructured granular media, such as a packed bed. However, a more advanced approach, the discrete element method (DEM), can capture the complex effects of mechanical loading and material mixtures on thermal transport coefficients, which traditional models struggle with. Pivotal for this approach is knowing the heat transfer coefficient between two adjacent particles. Currently, in most DEM-capable software, only particles in direct surface contact are considered to have non-zero heat conduction. We propose considering particles that are close to each other but don’t have a contact area with a non-zero surface area. We perform numerical modeling of the conductive heat transfer coefficient between equal spherical particles separated by media, assuming the fluid’s thermal conductivity is at least an order of magnitude lower. We use numerical solutions of differential equations to account for both thermal resistance within particles and through the gap between them. We found a simple generalized correlation for the heat transfer coefficient between particles and a general formula for the angular distribution of heat flux density across the particle surface. By employing a non-dimensional approach, the obtained formulas are constructed using non-dimensional parameters: the ratio of the particle’s thermal conductivity to that of the medium, and the ratio of the gap width between particles to their radius. The resulting formula is simple and convenient for DEM heat transfer calculations in packed and fluidized beds. Full article
(This article belongs to the Special Issue Computational Heat and Mass Transfer (ICCHMT 2025))
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31 pages, 7155 KB  
Article
Deep Learning-Based Synthesis, Classification and Analysis of Sedimentation Boundaries in Analytical Centrifugation Experiments
by Moritz Moß, Sebastian Boldt, Gurbandurdy Dovletov, Adjie Salman, Josef Pauli, Dietmar Lerche, Marco Gleiß, Hermann Nirschl, Johannes Walter and Wolfgang Peukert
Mach. Learn. Knowl. Extr. 2026, 8(3), 81; https://doi.org/10.3390/make8030081 - 20 Mar 2026
Viewed by 215
Abstract
Applications for machine learning (ML) and deep learning (DL) are constantly growing and have already been adopted in the field of particle measurement technology. Even though analytical (ultra-)centrifugation (AC/AUC) is a widely used technique for characterizing dispersed particle systems, ML and DL have [...] Read more.
Applications for machine learning (ML) and deep learning (DL) are constantly growing and have already been adopted in the field of particle measurement technology. Even though analytical (ultra-)centrifugation (AC/AUC) is a widely used technique for characterizing dispersed particle systems, ML and DL have not yet been applied in this area. Data evaluation and interpretation in AC/AUC can be challenging and often requires expert knowledge. DL models can help, but their development is limited by a lack of annotated training data. One solution is to generate and use synthetic data instead. In the first part of this study, a model was trained to synthesize data from experiments using a combination of Variational Autoencoder (VAE) and Generative Adversarial Networks (GANs). The results appear highly realistic. Novice users could distinguish real from synthetic samples with only 63% accuracy. Then, a classifier was trained on experimental AC data to categorize real-world examples based on their underlying separation kinetics, testing different DL architectures. After initial training, the models were further fine-tuned with synthetic AC data. ResNet34 models achieved the best performance with 94% accuracy, comparable to an AC expert (91%), while inexperienced users reached only 53%. In the second part of our study, a regression model was trained for the analysis of sedimentation coefficients. Therefore, various generative models were developed and evaluated for synthesizing AUC data based on numerically simulated sedimentation boundaries. The best results were achieved by combining VAE and GAN architectures with embedded physical constraints. However, the generative networks have so far led to additional smearing of the profiles, resulting in a broadening of the sedimentation coefficient distribution and indicating that further refinement is necessary. Full article
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15 pages, 5140 KB  
Article
Distribution and Enrichment of Heavy Metals in Fine-Grained Fractions of Crushed Electronic Waste
by Jitka Malcharcziková, Kateřina Skotnicová and Praveen Kumar Kesavan
Materials 2026, 19(6), 1222; https://doi.org/10.3390/ma19061222 - 19 Mar 2026
Viewed by 214
Abstract
The concentration of heavy metals in the environment has been steadily increasing, raising concerns about their adverse effects on ecosystems and human health. Fine-grained particulate matter is of particular concern due to its enhanced mobility, bioavailability, and potential for inhalation exposure. Facilities involved [...] Read more.
The concentration of heavy metals in the environment has been steadily increasing, raising concerns about their adverse effects on ecosystems and human health. Fine-grained particulate matter is of particular concern due to its enhanced mobility, bioavailability, and potential for inhalation exposure. Facilities involved in the mechanical processing of electronic waste (e-waste) represent a significant potential source of metal-containing fine particles. In this study, crushed e-waste components containing precious metals were separated into particle-size fractions ranging from 3.0 to 0.15 mm using a vibratory sieving system. The elemental composition of the individual fractions was determined by energy-dispersive X-ray fluorescence spectrometry (ED-XRF), while the spatial distribution of selected metals in fine fractions was further investigated using scanning electron microscopy combined with energy-dispersive X-ray spectroscopy (SEM–EDS). The results demonstrate that e-waste contains a wide range of heavy non-ferrous metals whose distribution is strongly dependent on particle size. A pronounced enrichment of metals was observed in the finest fractions, particularly below 0.25 mm. Compared to the coarse fraction (>3 mm), the zinc concentration increased by approximately one order of magnitude, while chromium, nickel, and cadmium exhibited increases of up to approximately 20-fold. Lead showed particularly high enrichment, reaching approximately 2 wt.% in the finest fraction (<0.15 mm), corresponding to nearly fiftyfold enrichment relative to the coarse fraction. Tin concentrations also increased markedly, in some cases by up to two orders of magnitude. Trace amounts of arsenic and selenium were detected in the finest fractions, whereas mercury was not detected. The combined ED-XRF and SEM–EDS results confirm that fine-grained e-waste fractions are the dominant carriers of hazardous metals and respirable particles generated during mechanical processing. These findings highlight the dual character of fine fractions as both a critical environmental and occupational risk and a potentially valuable secondary resource. The study emphasizes the importance of controlled handling, effective dust management, and targeted processing strategies to minimize human exposure while enabling efficient recovery of valuable metals from e-waste. Full article
(This article belongs to the Special Issue Sustainable and Functional Materials: From Design to Applications)
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19 pages, 3132 KB  
Article
Inorganic–Organic Hybrid Polymer for Fine-Rich Coal Slime Water Treatment: Performance and Interfacial Adsorption Mechanism on Kaolinite Aluminol Surface
by Jing Chang, Hang Zhao, Shizhen Liang, Xihao Feng, Jia Xue and Wei Zhao
Separations 2026, 13(3), 99; https://doi.org/10.3390/separations13030099 - 19 Mar 2026
Viewed by 195
Abstract
High-ash coal slime water, characterized by its stable colloidal suspension of fine kaolinite particles, poses a significant challenge in the coal preparation industry because it is hard to achieve efficient solid–liquid separation. While traditional coagulants and flocculants often suffer from limited bridging capabilities [...] Read more.
High-ash coal slime water, characterized by its stable colloidal suspension of fine kaolinite particles, poses a significant challenge in the coal preparation industry because it is hard to achieve efficient solid–liquid separation. While traditional coagulants and flocculants often suffer from limited bridging capabilities and distinct pH sensitivity, novel molecular architectures offer potential solutions. In this study, a star-shaped inorganic–organic hybrid flocculant (Al-PAM) was synthesized via in situ polymerization. Its flocculation performance and interfacial adsorption mechanism on the specifically targeted aluminol basal plane of kaolinite were systematically investigated and compared with Polyaluminum Chloride (PAC), Non-ionic Polyacrylamide (NPAM), and their combination (PAC + NPAM). Settling tests revealed that Al-PAM exhibited superior performance at a significantly lower dosage (10 mg∙L−1) compared to the PAC + NPAM binary reagent system. It achieved a rapid initial settling velocity and reduced the supernatant turbidity to 48.45 NTU, while maintaining a near-neutral pH favorable for water recycling. Furthermore, Quartz Crystal Microbalance with Dissipation (QCM-D) monitoring confirmed that Al-PAM forms a thick, viscoelastic, and irreversible adsorption layer on the Al2O3 substrate. The dissipation shifts (ΔD) revealed that the star-shaped architecture promotes distinct bridging and electrostatic adsorption, overcoming the limitation of linear polymers. This work elucidates the specific contribution of the alumina-surface interaction with flocculants and proposes an efficient strategy for treating refractory coal slime water. Full article
(This article belongs to the Special Issue Separation Technology in Mineral Processing)
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17 pages, 1932 KB  
Review
Nanoparticle-Based Approaches for Enhancing In Vitro Fertilization in Animal Reproduction
by Elżbieta Gałęska, Alicja Kowalczyk, Marko Samardžija, Gordana Gregurić Gračner, Marcjanna Wrzecińska, Jose Pedro Araujo, José Ángel Hernández Malagón, Mercedes Camiña, Ewa Czerniawska-Piątkowska and Zbigniew Dobrzański
Int. J. Mol. Sci. 2026, 27(6), 2747; https://doi.org/10.3390/ijms27062747 - 18 Mar 2026
Viewed by 234
Abstract
Nanotechnology, based on nanoparticles, has become an emerging interdisciplinary tool in reproductive biotechnology, offering innovative opportunities to improve fertilization efficiency and reproductive performance in farm animals. The purpose of this review is to provide an updated synthesis of current research on nanoparticle-based approaches [...] Read more.
Nanotechnology, based on nanoparticles, has become an emerging interdisciplinary tool in reproductive biotechnology, offering innovative opportunities to improve fertilization efficiency and reproductive performance in farm animals. The purpose of this review is to provide an updated synthesis of current research on nanoparticle-based approaches that enhance in vitro fertilization outcomes and other assisted reproductive technologies. The focus is on the biological mechanisms, potential benefits, and limitations of nanoparticle use in animal reproduction. Nanoparticles—including gold, silver, zinc oxide, selenium, and magnetic iron oxide—exhibit distinctive physicochemical properties that enable targeted interactions with gametes and reproductive cells. When used in semen extenders or culture media, nanoparticles improve sperm motility, acrosome and membrane integrity, and reduce oxidative stress and apoptosis. These effects contribute to enhanced fertilization rates and higher embryo developmental competence. In addition, nanoparticles can function as carriers for hormones, antioxidants, and growth factors, stabilizing reagents essential for oocyte maturation, sperm capacitation, and early embryo culture. The review also discusses nanopurification (selectively isolating and removing particles) and nanosorting (separating or organizing nanoscale objects) techniques that allow for non-invasive selection of viable gametes, and fluorescence- and magnet-assisted sorting systems that increase precision in sperm sexing. The mechanical aspects of nanoparticle–cell interactions are analyzed, emphasizing the influence of particle size, dose, and surface modification on both biological efficacy and cytotoxicity. Safety, toxicological concerns, and regulatory frameworks—including International Organization for Standardization (ISO) standards and European Commission recommendations—are critically reviewed to highlight the need for harmonized biocompatibility criteria. Although nanoparticle use in animal reproduction remains largely experimental, accumulated evidence demonstrates its potential to improve reproductive efficiency and reduce economic losses. Integrating nanoparticle-based systems with existing reproduction platforms may represent a transformative step toward sustainable and precision-driven livestock breeding. Full article
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