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20 pages, 3263 KiB  
Article
Land Cover Transformations and Thermal Responses in Representative North African Oases from 2000 to 2023
by Tallal Abdel Karim Bouzir, Djihed Berkouk, Safieddine Ounis, Sami Melik, Noradila Rusli and Mohammed M. Gomaa
Urban Sci. 2025, 9(7), 282; https://doi.org/10.3390/urbansci9070282 - 18 Jul 2025
Viewed by 313
Abstract
Oases in arid regions are critical ecosystems, providing essential ecological, agricultural, and socio-economic functions. However, urbanization and climate change increasingly threaten their sustainability. This study examines land cover (LULC) and land surface temperature (LST) dynamics in four representative North African oases: Tolga (Algeria), [...] Read more.
Oases in arid regions are critical ecosystems, providing essential ecological, agricultural, and socio-economic functions. However, urbanization and climate change increasingly threaten their sustainability. This study examines land cover (LULC) and land surface temperature (LST) dynamics in four representative North African oases: Tolga (Algeria), Nefta (Tunisia), Ghadames (Libya), and Siwa (Egypt) over the period 2000–2023, using Landsat satellite imagery. A three-step analysis was employed: calculation of NDVI (Normalized Difference Vegetation Index), NDBI (Normalized Difference Built-up Index), and LST, followed by supervised land cover classification and statistical tests to examine the relationships between the studied variables. The results reveal substantial reductions in bare soil (e.g., 48.10% in Siwa) and notable urban expansion (e.g., 136.01% in Siwa and 48.46% in Ghadames). Vegetation exhibited varied trends, with a slight decline in Tolga (0.26%) and a significant increase in Siwa (+27.17%). LST trends strongly correlated with land cover changes, demonstrating increased temperatures in urbanized areas and moderated temperatures in vegetated zones. Notably, this study highlights that traditional urban designs integrated with dense palm groves significantly mitigate thermal stress, achieving lower LST compared to modern urban expansions characterized by sparse, heat-absorbing surfaces. In contrast, areas dominated by fragmented vegetation or seasonal crops exhibited reduced cooling capacity, underscoring the critical role of vegetation type, spatial arrangement, and urban morphology in regulating oasis microclimates. Preserving palm groves, which are increasingly vulnerable to heat-driven pests, diseases and the introduction of exotic species grown for profit, together with a revival of the traditional compact urban fabric that provides shade and has been empirically confirmed by other oasis studies to moderate the microclimate more effectively than recent low-density extensions, will maintain the crucial synergy between buildings and vegetation, enhance the cooling capacity of these settlements, and safeguard their tangible and intangible cultural heritage. Full article
(This article belongs to the Special Issue Geotechnology in Urban Landscape Studies)
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21 pages, 6655 KiB  
Article
Improving Oxidation Stability and Insulation Performance of Plant-Based Oils for Sustainable Power Transformers
by Samson Okikiola Oparanti, Issouf Fofana and Reza Jafari
Physchem 2025, 5(2), 23; https://doi.org/10.3390/physchem5020023 - 18 Jun 2025
Viewed by 406
Abstract
In power transformers, insulating liquids are essential for cooling, insulation, and condition monitoring. However, the environmental impact and biodegradability issues of traditional hydrocarbon-based liquids have spurred interest in green alternatives like natural esters. Despite their benefits, natural esters are highly prone to oxidation, [...] Read more.
In power transformers, insulating liquids are essential for cooling, insulation, and condition monitoring. However, the environmental impact and biodegradability issues of traditional hydrocarbon-based liquids have spurred interest in green alternatives like natural esters. Despite their benefits, natural esters are highly prone to oxidation, limiting their broader use. This study explores a novel blend of two plant-based oils, canola oil and methyl ester derived from palm kernel oil, enhanced with two antioxidants, Tert-butylhydroquinone (TBHQ) and 2,6-Di-tert-butyl-4-methyl-phenol (BHT), to improve oxidation resistance. The performance of this antioxidant-infused oil was evaluated in terms of its interaction with Kraft paper insulation through accelerated thermal aging over periods of 10, 20, 30, and 40 days. Key properties, including the viscosity, breakdown voltage, conductivity, and FTIR spectra of oils, were analyzed before and after aging. Additionally, the degradation of the Kraft paper was investigated using scanning electron microscopy (SEM), optical microscopy, and dielectric strength tests. The results show that the antioxidant-treated oil exhibits significantly enhanced molecular stability, reduced viscosity, lower conductivity, and improved breakdown voltage (53.16 kV after 40 days). Notably, the oil mixture maintained the integrity of the Kraft paper insulation better than traditional natural esters, demonstrating superior dielectric properties and a promising potential for more sustainable and reliable power transformer applications. Full article
(This article belongs to the Section Electrochemistry)
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14 pages, 15617 KiB  
Article
Impact of Green Wall and Roof Applications on Energy Consumption and Thermal Comfort for Climate Resilient Buildings
by Cihan Turhan, Cristina Carpino, Miguel Chen Austin, Mehmet Furkan Özbey and Gulden Gokcen Akkurt
Urban Sci. 2025, 9(4), 105; https://doi.org/10.3390/urbansci9040105 - 1 Apr 2025
Viewed by 1332
Abstract
Nowadays, reducing energy consumption and obtaining thermal comfort are significant for making educational buildings more climate resilient, more sustainable, and more comfortable. To achieve these goals, a sustainable passive method is that of applying green walls and roofs that provide extra thermal insulation, [...] Read more.
Nowadays, reducing energy consumption and obtaining thermal comfort are significant for making educational buildings more climate resilient, more sustainable, and more comfortable. To achieve these goals, a sustainable passive method is that of applying green walls and roofs that provide extra thermal insulation, evaporative cooling, a shadowing effect, and the blockage of wind on buildings. Therefore, the objective of this study is to evaluate the impact of green wall and roof applications on energy consumption and thermal comfort in an educational building. For this purpose, a university building in the Csb climate zone is selected and monitored during one year, as a case study. Then, the case building is modelled in a well-calibrated dynamic building energy simulation tool and twenty-one different plant species, which are mostly used for green walls and roofs, are applied to the envelope of the building in order to determine a reduction in energy consumption and an increase in thermal comfort. The Hedera canariensis gomera (an ivy species) plant is used for green walls due to its aesthetic appeal, versatility, and functional benefits while twenty-one different plants including Ophiopogon japonicus (Mando-Grass), Phyllanthus bourgeoisii (Waterfall Plant), and Phoenix roebelenii (Phoenix Palm) are simulated for the green roof applications. The results show that deploying Hedera canariensis gomera to the walls and Phyllanthus bourgeoisii to the roof could simultaneously reduce the energy consumption by 9.31% and increase thermal comfort by 23.55% in the case building. The authors acknowledge that this study is solely based on simulations due to the high cost of all scenarios, and there are inherent differences between simulated and real-world conditions. Therefore, the future work will be analysing scenarios in real life. Considering the limited studies on the effect of different plant species on energy performance and comfort, this study also contributes to sustainable building design strategies. Full article
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14 pages, 4024 KiB  
Article
Characterization and Development of Ceramics with Inorganic Additives
by Mirza Awais, Asif Mansoor, Imran Shah, Murtaza Hussain and Muhammad Asif
Inventions 2024, 9(6), 121; https://doi.org/10.3390/inventions9060121 - 5 Dec 2024
Viewed by 1657
Abstract
Date palm tree (DPT) and pine tree (PT) needles in forests form a combustible mat, posing fire risks during summer in Pakistan that damage vegetation, wildlife habitats, and biodiversity and impact local livelihoods. In this article, sintered ceramic specimens were prepared at different [...] Read more.
Date palm tree (DPT) and pine tree (PT) needles in forests form a combustible mat, posing fire risks during summer in Pakistan that damage vegetation, wildlife habitats, and biodiversity and impact local livelihoods. In this article, sintered ceramic specimens were prepared at different weight concentrations (DPT5, DPT10, DPT20, and DPT 30 and PT5, PT10, PT20, and PT30) of date palm tree leaf ash and pine tree needle ash as secondary additives in ceramic manufacturing along with primary material kaolinite (China clay). Raw materials composition was analyzed using X-ray diffraction (XRD), taking loss on ignition, water absorption, bulk density, saturated surface dry density (SSD), weight per unit area, and thermal cycling as measurement indexes. The result indicates that loss on ignition increases while increasing the quantity of secondary additives and the maximum increase for DPT30 was 19.6% and for PT30, it was 22.1%. As the secondary additives increase, the water absorption rate also increases and the maximum increase for DPT30 and PT30 is 4.5%. Meanwhile, with the increase in secondary additives, the density decreased; for DPT 30, it was 1457.7 kg/m3 and for PT30, it was 1829.8 kg/m3. Thermal performance was investigated by heating and cooling cycles. It was observed that thermal performances increase with the increase in secondary additives. The results reveal this novel approach has the potential to form a ceramic and good properties can be achieved. The prepared specimens have the potential to be used in the fields of electronics, aerospace, construction, and building engineering, alleviating environmental strain, curbing the exhaustion of China clay reserves, and most importantly, lowering the risk of forest fires in Pakistan. Full article
(This article belongs to the Section Inventions and Innovation in Advanced Manufacturing)
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22 pages, 2753 KiB  
Article
Chemical Composition and Crystallization Behavior of Oil and Fat Blends for Spreadable Fat Applications
by Maureen Gerlei, Hugo Pierson, Marc Ponçot, Cyril J. F. Kahn and Michel Linder
Foods 2024, 13(20), 3305; https://doi.org/10.3390/foods13203305 - 18 Oct 2024
Cited by 4 | Viewed by 3183
Abstract
To meet the expectations of European consumers, who prioritize agro-environmental factors and local resources, the substitution of fats (palm, coconut, shea) and achieving a balanced fatty acid profile in spreadable fats are gaining more attention. The crystallization at 4 °C of a lipid [...] Read more.
To meet the expectations of European consumers, who prioritize agro-environmental factors and local resources, the substitution of fats (palm, coconut, shea) and achieving a balanced fatty acid profile in spreadable fats are gaining more attention. The crystallization at 4 °C of a lipid blend composed of rapeseed oil, anhydrous dairy fats, and emulsifiers was studied using a multi-scale approach (DSC and X-ray diffraction techniques) to understand the emergence of polymorphic structures. Although the addition of PUFA from rapeseed oil reduces the atherogenicity and thrombogenicity indices in the blend, controlling the cooling kinetics influences the shapes (needles and spherulites) and sizes of the crystalline structures (small crystals form at a cooling rate of 1 °C min−1, while larger crystals form at higher rates of 5 and 10 °C min−1). The crystallization behavior revealed differences in polymorphic forms at 4 °C in the blend, with a transition to different forms occurring more rapidly compared to dairy fat (stop-and-return method). The study shows crystalline coexistence (α, β′, and β) in a 2L lamellar structure, with the β′ form being predominant. This structure is ideal for formulating a spreadable product, offering good spreadability (SFC < 32% at 10 °C), mouthfeel, and nutritional benefits compared to butter. Full article
(This article belongs to the Section Food Physics and (Bio)Chemistry)
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13 pages, 1448 KiB  
Article
No Effect of Intermittent Palm or Sole Cooling on Acute Training Volume during Resistance Exercise in Physically Active Adults: A Summary of Protocols
by Rouven Kenville, Martina Clauß, Aleksander Arup, Patrick Ragert and Tom Maudrich
Sports 2024, 12(10), 281; https://doi.org/10.3390/sports12100281 - 16 Oct 2024
Cited by 1 | Viewed by 2022
Abstract
Intermittent palm (PC) and sole cooling (SC) are proposed ergogenic methods for enhancing exercise performance during high-intensity and fatiguing conditions. However, findings in the literature regarding its positive effect remain inconclusive. This study aimed at investigating the effects of intermittent PC and SC [...] Read more.
Intermittent palm (PC) and sole cooling (SC) are proposed ergogenic methods for enhancing exercise performance during high-intensity and fatiguing conditions. However, findings in the literature regarding its positive effect remain inconclusive. This study aimed at investigating the effects of intermittent PC and SC compared to no cooling (NC) on acute training volume during resistance exercise, particularly focusing on the total number of repetitions (TR) performed. Three separate randomized crossover protocols, incorporating commonly practiced resistance exercises (Protocol 1: pullups; Protocol 2: pushups; Protocol 3: leg extensions), were conducted, enrolling healthy, physically active adults (overall sample: n = 41 (12 female), age: 23.9 ± 4.0 years (mean ± SD), height: 174.4 ± 9.5 cm, body mass: 69.3 ± 12.4 kg). During Protocol 3, tympanic temperature (TT), rate of perceived exertion (RPE), and electromyography (EMG) of quadriceps muscles were additionally assessed for SC. PC resulted in less TR compared to NC in Protocol 1 (p < 0.001). Protocol 2 and 3 did not reveal significant ergogenic benefits of PC or SC compared to NC (p > 0.05). Furthermore, SC had no effect on TT, RPE, or EMG amplitudes (all p > 0.05). The inconsistent findings suggest that intermittent PC and SC might have limited effectiveness in enhancing training volume during resistance exercise in physically active adults. Future research should examine various resistance training protocols under controlled conditions, and incorporate comprehensive physiological measurements to elucidate the potential benefits and mechanisms of intermittent cooling in resistance exercise contexts. Full article
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22 pages, 5560 KiB  
Article
Prediction of the Temperature Field in a Tunnel during Construction Based on Airflow–Surrounding Rock Heat Transfer
by Guofeng Wang, Yongqiao Fang, Kaifu Ren, Fayi Deng, Bo Wang and Heng Zhang
Buildings 2024, 14(9), 2908; https://doi.org/10.3390/buildings14092908 - 14 Sep 2024
Cited by 3 | Viewed by 1519
Abstract
It is important to determine the ventilation required in the construction of deep and long tunnels and the variation law of tunnel temperature fields to reduce the numbers of high-temperature disasters and serious accidents. Based on a tunnel project with a high ground [...] Read more.
It is important to determine the ventilation required in the construction of deep and long tunnels and the variation law of tunnel temperature fields to reduce the numbers of high-temperature disasters and serious accidents. Based on a tunnel project with a high ground temperature, with the help of convection heat transfer theory and the theoretical analysis and calculation method, this paper clarifies the contribution of various heat sources to the air demand during tunnel construction, and reveals the important environmental parameters that determine the ventilation value by changing the construction conditions. The results show that increasing the fresh air temperature greatly increases the required air volume, and the closer the supply air temperature is to 28 °C, the more the air volume needs to be increased. The air temperature away from the palm face is not significantly affected by changes in the supply air temperature. Adjusting the wall temperature greatly accelerates the rate of temperature growth. The supply air temperature rose from 15 to 25 °C, while the tunnel temperature at 800 m only increased by 1.5 °C. Over a 50 m range, the wall temperature rose from 35 to 60 degrees Celsius at a rate of 0.0842 to 0.219 degrees Celsius per meter. The total air volume rises and the surface heat transfer coefficient decreases as the tunnel’s cross-section increases. For every 10 m increase in the tunnel diameter, the temperature at 800 m from the tunnel face drops by about 0.5 °C. Changing the distance between the air duct and the tunnel face has little influence on the temperature distribution law. The general trend is that the farther the air duct outlet is from the tunnel face, the higher the temperature is, and the maximum difference is within the range of 50 m~250 m from the tunnel face. The maximum difference between the air temperatures at 12 m and 27 m is 0.79 °C. The geological structure and geothermal background have the greatest influence on the temperature prediction of high geothermal tunnels. The prediction results are of great significance for guiding tunnel construction, formulating cooling measures, and ensuring construction safety. Full article
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14 pages, 2562 KiB  
Article
Utilizing Date Palm Leaf Biochar for Simultaneous Adsorption of Pb(II) and Iodine from Aqueous Solutions
by Essam R. I. Mahmoud, Hesham M. Aly, Noura A. Hassan, Abdulrahman Aljabri, Asim Laeeq Khan and Hashem F. El-Labban
Processes 2024, 12(7), 1370; https://doi.org/10.3390/pr12071370 - 1 Jul 2024
Cited by 3 | Viewed by 1686
Abstract
This study addresses the environmental and health hazards posed by Pb(II) and iodine, two significant contaminants. The objective was to explore the adsorption of these substances from aqueous solutions using biochar derived from the leaf midribs of the date palm through a slow [...] Read more.
This study addresses the environmental and health hazards posed by Pb(II) and iodine, two significant contaminants. The objective was to explore the adsorption of these substances from aqueous solutions using biochar derived from the leaf midribs of the date palm through a slow pyrolysis process. The pyrolysis was conducted in two stages within a vacuum furnace: initially at 300 °C for 1 h followed by overnight cooling, and then at 600 °C with a similar cooling process. The resulting biochar was characterized for its microstructural features and functional groups using scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. It exhibited a porous structure with large numbers of pores (20 to 50 μm in size) and functional groups including O-H, C-H, and C=C, which are integral to its adsorption capabilities. For the adsorption studies, a 100 ppm Pb(II) ion solution was treated with varying amounts of biochar (20, 40, 60, and 80 mg) for 24 h. In parallel, iodine adsorption was tested, with biochar quantities ranging from 0.1 to 0.4 g/50 mL. Both treatments were followed by filtration and analysis using atomic absorption spectroscopy to determine the remaining concentrations of Pb(II) and iodine. The study also explored the effect of varying incubation periods (up to 30 h) on iodine adsorption. The results were significant; 100% adsorption of Pb(II) was achieved with the addition of 60 mg of biochar per 10 mL of solution. In contrast, for iodine, a maximum adsorption of 39.7% was observed with 30 mg or 40 mg of biochar per 50 mL. These findings demonstrate the potential of date palm-derived biochar as an effective and sustainable material for the removal of Pb(II) and iodine from contaminated water, offering valuable insights for environmental remediation strategies. Full article
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12 pages, 4290 KiB  
Article
The Annual Effect of Landscapes on the Indoor Thermal Environment in Residential Areas—A Case Study in Southern Hunan
by Jiayu Li, Bohong Zheng, Xiao Chen and Lan Wang
Forests 2024, 15(7), 1099; https://doi.org/10.3390/f15071099 - 26 Jun 2024
Cited by 1 | Viewed by 1560
Abstract
Landscape elements are crucial to the quality of the built environment. Thermal comfort is one of the important paths through which landscape elements affect the quality of the built environment. Most studies investigate the impacts of the landscape on the outdoor thermal environment, [...] Read more.
Landscape elements are crucial to the quality of the built environment. Thermal comfort is one of the important paths through which landscape elements affect the quality of the built environment. Most studies investigate the impacts of the landscape on the outdoor thermal environment, while ignoring the impacts on the indoor environment. A residential area in Chenzhou, a typical city having a hot summer and cold winter climate, was taken as an example to reveal the effect on the indoor thermal environment of landscapes. The annual distribution of the indoor thermal environment was analyzed with the “Envi-met+IDW” model, which was created to evaluate the annual thermal impact. Analytical results show that, from the perspective of the annual cycle, the camphor tree has the best performance in regulating the indoor thermal environment, followed by water and the palm. Manila grass has a very weak impact on indoor thermal comfort throughout the year. Camphor trees, water, and palm extend the “acceptable temperature” by 523 h, 416 h, and 388 h respectively. However, the camphor tree also has the strongest cooling effect on indoor environments during winter, increasing the “heating demand temperature” by 289 h. Full article
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23 pages, 32973 KiB  
Article
From Nucleation to Fat Crystal Network: Effects of Stearic–Palmitic Sucrose Ester on Static Crystallization of Palm Oil
by Fien De Witte, Ivana A. Penagos, Davy Van de Walle, Andre G. Skirtach, Koen Dewettinck and Filip Van Bockstaele
Foods 2024, 13(9), 1372; https://doi.org/10.3390/foods13091372 - 29 Apr 2024
Cited by 4 | Viewed by 2423
Abstract
Palm oil (PO), a semi-solid fat at room temperature, is a popular food ingredient. To steer the fat functionality, sucrose esters (SEs) are often used as food additives. Many SEs exist, varying in their hydrophilic-to-lipophilic balance (HLB), making them suitable for various food [...] Read more.
Palm oil (PO), a semi-solid fat at room temperature, is a popular food ingredient. To steer the fat functionality, sucrose esters (SEs) are often used as food additives. Many SEs exist, varying in their hydrophilic-to-lipophilic balance (HLB), making them suitable for various food and non-food applications. In this study, a stearic–palmitic sucrose ester with a moderate HLB (6) was studied. It was found that the SE exhibited a complex thermal behavior consistent with smectic liquid crystals (type A). Small-angle X-ray scattering revealed that the mono- and poly-esters of the SE have different packings, more specifically, double and single chain-length packing. The polymorphism encountered upon crystallization was repeatable during successive heating and cooling cycles. After studying the pure SE, it was added to palm oil, and the crystallization behavior of the mixture was compared to that of pure palm oil. The crystallization conditions were varied by applying cooling at 20 °C/min (fast) and 1 °C/min (slow) to 0 °C, 20 °C or 25 °C. The samples were followed for one hour of isothermal time. Differential scanning calorimetry (DSC) showed that nucleation and polymorphic transitions were accelerated. Wide-angle X-ray scattering (WAXS) unraveled that the α-to-β′ polymorphic transition remained present upon the addition of the SE. SAXS showed that the addition of the SE at 0.5 wt% did not significantly change the double chain-length packing of palm oil, but it decreased the domain size when cooling in a fast manner. Ultra-small-angle X-ray scattering (USAXS) revealed that the addition of the SE created smaller crystal nanoplatelets (CNPs). The microstructure of the fat crystal network was visualized by means of polarized light microscopy (PLM) and cryo-scanning electron microscopy (cryo-SEM). The addition of the SE created a finer and space-filling network without the visibility of separate floc structures. Full article
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19 pages, 7957 KiB  
Article
A Field Investigation to Quantify the Correlation between Local and Overall Thermal Comfort in Cool Environments
by Xiaohong Liang, Yingdong He, Nianping Li, Yicheng Yin and Jinhua Hu
Buildings 2024, 14(4), 1171; https://doi.org/10.3390/buildings14041171 - 21 Apr 2024
Cited by 1 | Viewed by 1370
Abstract
The thermal comfort of local body parts is the essential factor that affects people’s health and comfort as well as a buildings’ energy. This study aims to (1) investigate the characteristics of the local thermal comfort of different body parts of occupants in [...] Read more.
The thermal comfort of local body parts is the essential factor that affects people’s health and comfort as well as a buildings’ energy. This study aims to (1) investigate the characteristics of the local thermal comfort of different body parts of occupants in real buildings in winter, (2) quantify the correlation between the amount of local body parts with coolness or discomfort and the overall subjective thermal responses, and (3) validate an easy-to-use local–overall thermal comfort model. A field investigation in the office and study rooms of a university was conducted in winter. The results indicate that the top five percentages of local coolness appeared in the feet (41.02%), the hands (26.58%), the calves (25.18%), the thighs (13.99%), and the head (9.72%) and that the top five percentages of local discomfort appeared in the feet (44.99%), the palms (28.2%), the calves (24.74%), the head (19.66%), and the thighs (16.35%). Moreover, when the whole body felt cool, at least four local body parts had cool sensations; when the whole body felt thermally uncomfortable, at least three local body parts had cool sensations; and when the whole body felt that the ambient environment was thermally unacceptable, at least seven local body parts had cool sensations. Meanwhile, the correlation between local discomfort and whole-body responses was different: when the whole body felt thermal uncomfortable, at least three local body parts had discomfort; and when the whole body felt that the ambient environment was thermally unacceptable, at least four local body parts had discomfort. Further, the local–overall thermal comfort model proposed by the authors exerted high accuracy in predicting overall thermal comfort. Full article
(This article belongs to the Special Issue Thermal Comfort in Built Environment: Challenges and Research Trends)
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18 pages, 4309 KiB  
Article
Analysing the Suitability of Using Different Biodegradable Fluids for Power Transformers with Thermally Upgraded Paper
by Cristina Méndez, Cristian Olmo, Ismael Antolín, Alfredo Ortiz and Carlos J. Renedo
Sustainability 2024, 16(8), 3259; https://doi.org/10.3390/su16083259 - 13 Apr 2024
Cited by 1 | Viewed by 1645
Abstract
Mineral oil has been used for many years in various electrical equipment, including transformers, as a cooling and insulation medium. However, its low biodegradability and poor performance in terms of fire protection have prompted the search for fluids to replace it, with vegetable [...] Read more.
Mineral oil has been used for many years in various electrical equipment, including transformers, as a cooling and insulation medium. However, its low biodegradability and poor performance in terms of fire protection have prompted the search for fluids to replace it, with vegetable oils being prominently considered. In this study, the dielectric, chemical, and physical properties of four vegetable oils obtained from different seeds (sunflower, rapeseed, soybean, and palm) and a biodegradable synthetic fluid are analysed throughout their lifespan in transformers. Their performances are compared with a traditional mineral oil to assess which one is more suitable for use in transformers employing this type of paper. To achieve this, the fluids were subjected to thermal ageing in combination with copper and a thermally upgraded kraft (TUK) paper, with its degradation controlled by measuring the degree of polymerisation. The results demonstrate that the origin of the vegetable oils affects their properties and degradation rates. It was found that most of the alternative fluids are suitable for use in transformers with the TUK paper and that they can increase their lifespan. Full article
(This article belongs to the Section Sustainable Engineering and Science)
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22 pages, 8785 KiB  
Article
Insights in the Structural Hierarchy of Statically Crystallized Palm Oil
by Fien De Witte, Ivana A. Penagos, Kato Rondou, Kim Moens, Benny Lewille, Daylan A. Tzompa-Sosa, Davy Van de Walle, Filip Van Bockstaele, Andre G. Skirtach and Koen Dewettinck
Crystals 2024, 14(2), 142; https://doi.org/10.3390/cryst14020142 - 30 Jan 2024
Cited by 7 | Viewed by 2532
Abstract
Palm oil (PO) is still widely used for the production of all types of food products. Due to its triacylglycerol (TG) composition, PO is semisolid at ambient temperature, offering possibilities for many applications. In order to tailor the fat crystal network for certain [...] Read more.
Palm oil (PO) is still widely used for the production of all types of food products. Due to its triacylglycerol (TG) composition, PO is semisolid at ambient temperature, offering possibilities for many applications. In order to tailor the fat crystal network for certain applications, it remains imperative to understand the structural build-up of the fat crystal network at the full-length scale and to understand the effect of processing conditions. In this study, PO was crystallized under four temperature protocols (fast (FC) or slow (SC) cooling to 20 °C or 25 °C) and was followed for one hour of isothermal time. A broad toolbox was used to fundamentally unravel the structural build-up of the fat crystal network at different length scales. Wide-angle and small-angle X-ray scattering (WAXS and SAXS) showed transitions from α-2L to β’-2L over time. Despite the presence of the same polymorphic form (β’), chain length structure (2L), and domain size, ultra-small-angle X-ray scattering (USAXS) showed clear differences in the mesoscale. For all samples, the lamellar organization was confirmed. Both cooling speed and isothermal temperature were found to affect the size of the crystal nanoplatelets (CNPs), where the highest cooling speed and lowest isothermal temperature (FC and 20 °C) created the smallest CNPs. The microstructure was visualized with polarized light microscopy (PLM) and cryo-scanning electron microscopy (cryo-SEM), showing clear differences in crystallite size, clustering, and network morphology. Raman spectroscopy was applied to confirm differences in triglyceride distribution in the fat crystal network. This study shows that both cooling rate and isothermal temperature affect the fat crystal network formed, especially at the meso- and microscale. Full article
(This article belongs to the Special Issue Feature Papers in Crystals 2023)
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22 pages, 9860 KiB  
Article
Thermally Future-Proofing Existing Libyan Housing Stock with Biobased Insulation Materials and Passive Measures: An Empirical and Numerical Study Using a Digital Twin
by Salwa Albarssi, Shan Shan Hou and Eshrar Latif
Buildings 2024, 14(1), 175; https://doi.org/10.3390/buildings14010175 - 10 Jan 2024
Cited by 2 | Viewed by 1977
Abstract
Thermal refurbishment and retrofitting building envelopes with passive measures such as the optimisation of opaque and transparent fabric performance may play a key role in reducing cooling and heating load and promoting building energy efficiency. Furthermore, to reduce the embodied carbon impact of [...] Read more.
Thermal refurbishment and retrofitting building envelopes with passive measures such as the optimisation of opaque and transparent fabric performance may play a key role in reducing cooling and heating load and promoting building energy efficiency. Furthermore, to reduce the embodied carbon impact of the building, the refurbishment measures need to consider the use of low-carbon building materials. This paper investigates ways to thermally future-proof typical Libyan houses using biobased materials. Several typical Libyan houses were monitored for one year to investigate the heating and cooling energy use and to thermally retrofit the building envelope. A digital twin was created in the DesignBuilder software using the real building data of one building for digital model calibration. Finally, multi-objective optimisation was carried out with low-impact biobased materials for insulation, including camel hair, sheep wool, and date palm fibre as well as using other optimisation variables such as shading and glazing types. The study reveals that thermally upgrading the building roof and wall with insulation materials and upgrading the windows with energy-efficient glazing and local shadings can achieve a reduction in cooling load from 53.51 kWh/m2/y to 40.8 kWh/m2/y. Furthermore, the heating load reduces from 19.4 kW/m2/y to 15 kW/m2/y without compromising the standard annual discomfort hours. Full article
(This article belongs to the Special Issue Future-Proofing Bio-Based Building Materials)
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15 pages, 8608 KiB  
Article
The Effects of Emulsifier Addition on the Functionalization of a High-Oleic Palm Oil-Based Oleogel
by Melissa Perez-Santana, Victor Cedeno-Sanchez, John C. Carriglio and Andrew J. MacIntosh
Gels 2023, 9(7), 522; https://doi.org/10.3390/gels9070522 - 27 Jun 2023
Cited by 8 | Viewed by 2405
Abstract
Alternatives to oils with high saturated fatty acid content are often liquid oils (high in unsaturated fatty acids) that have a modified structure created either through additives or processing. Emulsifiers are additives that can be used as structuring agents of liquid fats; this [...] Read more.
Alternatives to oils with high saturated fatty acid content are often liquid oils (high in unsaturated fatty acids) that have a modified structure created either through additives or processing. Emulsifiers are additives that can be used as structuring agents of liquid fats; this process results in products such as oleogels, which can broaden the applications of these oils. This study assessed and compared the effects of mono- and diglycerides at 3%, 5%, 7% and 10% w/w on the mechanical and thermal properties of high-oleic palm oil (HOPO) oleogels. HOPO was heated to 75 °C and mixed with mono- or diglycerides at those four concentrations. The thermomechanical properties of the melted oleogels were assessed using differential scanning calorimetry (DSC). The melted oleogels were cooled to final temperatures of 5 °C, 10 °C and 15 °C under identical cooling rates, after which a puncture test (via a texture analyzer) was used to assess their textures. Finally, polarized light microscopy was used to assess the mechanical changes induced through emulsifier addition. The results showed that the use of mono- and diglycerides significantly modified the thermal and mechanical properties of the oleogels. The addition of saturated monoglycerides promoted a higher-temperature nucleation stage that did not previously occur in HOPO. The onset crystallization temperature increased with the addition of diglycerides, promoting crystallization at higher temperatures of the high-melting fraction of HOPO. The hardness of the oleogel generally increased with emulsifier addition and a reduction of the temperature. The effect of the temperature on the hardness was significantly greater in the diglyceride oleogel than in the monoglyceride oleogel. This study shows that the addition of mono- and diglycerides allows companies to customize their formulations to achieve desired results that may not previously have been possible, thereby facilitating novel uses for these oils within the industry. Full article
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