Search Results (82)

Reducing surface roughness can enhance the mechanical properties of processed materials. The variation law of the aluminum alloy surface roughness induced by continuous-nanosecond combined laser (CL) with different continuous laser power densities and laser delay is investigated experimentally. A back propagation neural network (BPNN) coupled with a sparrow search algorithm (SSA) is employed to predict surface roughness. The nanosecond laser energy density, continuous laser power density and laser delay are input parameters, while the surface roughness is output parameter. The lowest surface roughness is achieved with completely paint film removed by the CL while the nanosecond laser energy density is 1.99 J/cm², the continuous laser power density is 2118 W/cm² and the laser delay is 1 ms. Compared to the original target and the target irradiated by nanosecond pulse laser (ns laser), the reductions in the surface roughness are 20.62% and 12.00%, respectively. The SSA-BPNN model demonstrates high prediction accuracy, with a correlation coefficient (R²) of 0.98628, root mean square error (RMSE) of 0.024, mean absolute error (MAE) of 0.020 and mean absolute percentage error (MAPE) of 1.30% on the test set. These results indicate that the SSA-BPNN demonstrates higher-precision surface roughness prediction with limited experimental data than BPNN. Furthermore, the findings confirm that the CL can effectively reduce surface roughness. Full article

Money Art is a growing contemporary practice where artists transform banknotes into unique visual works. While conceptually powerful, these artworks present significant conservation challenges due to their fragile substrates and complex material compositions. This study investigates the degradation behaviour of UniPosca acrylic markers applied on zero-euro banknotes, drawing on the techniques of artist RichardHTT, and explores bio-based protective strategies suitable for their preservation. Laboratory samples were prepared to replicate the original artwork and subjected to accelerated ageing. A multi-analytical approach was employed, including multispectral imaging, Fourier trasform infrared (FTIR) and Raman spectroscopy, and scanning electron microscopy (SEM-EDS) colorimetric analysis. Thickness and adhesion properties were assessed with contact micrometry and peel tests, while wettability was evaluated through static contact angle measurements. Four biopolymer coatings, chitosan and chitosan–nanocellulose films with varying CNC concentrations, were evaluated for their transparency, mechanical stability, and compatibility with the substrate. Results showed that painted areas, especially those with blue and black pigments, experienced marked degradation, while, after coating application, samples demonstrated improved chromatic stability, hydrophobicity, and adhesion. Importantly, all coatings were fully removable via enzymatic cleaning with α-amylase, confirming their reversibility. This research highlights the potential of chitosan-based biocomposites as conservation materials for non-traditional artworks and contributes to developing tailored, reversible strategies for contemporary art preservation. Full article

This study uses the melt compounding method to recycle polypropylene-based car bumper waste (PP-CBW) in order to produce nanocomposite films for mulch application. The nanocomposite films were compounded by mixing virgin linear low-density polyethylene (LLDPE) with PP-CBW at a constant ratio of 4:1 in the presence of different percentages of nanofillers. Nanocomposites reinforced with nanoclays were compatibilized with an anhydride grafted polyethylene (PE-g-MAH), at a constant compatibilizer-to-clay ratio equal to 3, to improve the adherence between the nonpolar matrix and the hydrophilic nanoclay and acrylic paint present in the car bumper. An extruder with a corotating twin screw was used to produce blends of different compositions. To create nanocomposite films, the mixtures were further processed in a blown film extruder. The effect of the presence of nanoclays on the barrier, thermal, and mechanical properties of the nanocomposite films was investigated. The dispersion of clay layers in the matrix was examined by atomic force microscopy (AFM). The results indicate that 3 wt% of clay loading maximized the tensile strength in the transverse direction (TD) and machine direction (MD). A 1 wt% clay loading increased the MD tear resistance by 66% and manifested an optimum dart impact strength. Significant improvements in thermal and barrier properties were also achieved in the presence of 3 wt% clay loading. Full article

Alkyd resins are still one of the most important classes of binders for paint systems. They are outstanding in terms of their versatility of formulations and applications, cost-effectiveness, and durability. Traditionally, they are synthesized using phthalic anhydride, polyalcohols with three or four functional groups (pentaerythritol, glycerol, and trimethylolpropane), and fatty acids or oils. In this study, new bio-alkyd resins were synthesized with the objective of increasing the bio-based content by substituting phthalic anhydride, thereby also enhancing the biodegradability of coatings. The newly synthesized alkyd resins, formulated with azelaic acid, were used to develop coatings incorporating additives while avoiding cobalt-based driers. Additional agents such as leveling, wetting, and anti-skinning agents, were also included. Paints were applied to wood substrates and dried at room temperature. The resulting films were characterized by pendulum hardness, transparency, and color by colorimetry, cross-cut test, contact angle, and gloss. Thermal properties were analyzed by Differential Scanning Calorimetry (DSC), and Total Organic Carbon (TOC) content and aerobic biodegradation were also evaluated. The resulting coating films exhibited good mechanical performance, with hardness values ranging from 132 to 148 Persoz oscillations and strong adhesion to wood substrates (smooth cross-cut edges, Class 0). Significant biodegradability (70% in less than 90 days) was demonstrated under composting conditions, which was considerably higher than that of a commercial reference alkyd coating (34.7%) under the same conditions. These findings suggest that the developed bio-alkyd coatings formulated with azelaic acid and DCO-FA without cobalt-based driers represent a promising alternative to conventional phthalic acid-based alkyds. These novel coatings move closer to fully bio-based formulations and offer enhanced biodegradability, making them a more sustainable option for coating applications. Full article

Inorganic materials used in passive radiative cooling have achieved a commendable level of performance through synthesis, yet they lack sustainability and environmental friendliness as they do not incorporate recycling. This study developed a novel passive radiative cooling (PRC) film utilizing calcium carbonate extracted from discarded oyster shells (D-CaCO₃) and polyurethane (PU) as the matrix. This sustainable approach leverages the unique properties of CaCO₃, such as high solar reflectance and strong infrared emissivity, to achieve significant cooling effects. The PU/D-CaCO₃ film absorbs only 22% of total solar light and exhibits a high emissivity of 95% in the atmospheric window, achieving temperatures up to 7 °C lower than the surrounding environment under 650 W/m² solar irradiance. Furthermore, field tests were conducted to verify the implementation of our optical strategy by analyzing the optical properties and FDTD simulations. Consequently, the PU/D-CaCO3 film outperformed conventional white paint and pure PU, demonstrating a maximum temperature difference of 7 °C. Additionally, the passive radiative cooling efficiency of the film was verified through theoretical calculations. The oyster-shell-derived CaCO₃ utilizes waste and contributes to carbon sequestration, aligning with sustainable and eco-friendly goals. This research demonstrates the potential of using marine-derived materials in passive cooling technologies, offering a path to reduce energy consumption and greenhouse gas emissions in cooling applications. The findings highlight the commercial viability and environmental benefits of PU/D-CaCO₃ films, marking significant progress in passive radiative cooling. Full article

The multi-layered and multi-material structures of a violin’s surface varnish film make it more challenging to comprehensively understand the patterns of sound quality changes during the coating process. Using an alcohol varnish coating technique on one or both sides of the wood, along with a combination of micro-morphology, material characterization, and vibration signal processing, this study traced and analyzed the changes in the acoustic vibration properties of Norway spruce wood during the coating process. The results showed that the acoustic characteristics of the coated wood tended to change in an unfavorable direction throughout the coating process, and the specific dynamic elastic modulus (E_sp) of the final single- and double-sided coating varied by −1.77% and −6.07%, respectively. The loss angle tangent (tanδ) had the opposite trend, with rates of change of 20.76% and 30.42%. The sizing and priming treatments in the pretreatment stage had some positive effects on the acoustic properties of the wood specimens. Additionally, significant changes in acoustic vibration performance parameters began to be highlighted at the color paint stage (p < 0.05). These insights provide reference data for the improvement of violin acoustic performance and the simplification of the coating process. Full article

This work deals with the coating properties of synthetic latices comprising two kinds of polymers, specifically polyacrylate and polypyrrole, which were simultaneously formed by semi-continuous emulsion polymerization using a “one-pot” synthesis strategy. In this procedure, both the emulsion polymerization of acrylate monomers and the oxidative polymerization of pyrrole occurred concurrently in one reactor. Polyacrylate latices differing in polypyrrole loading were prepared by applying various dosages of pyrrole, specifically 0, 0.25, and 0.50, based on the fraction of acrylate monomers. The effect of the in situ incorporated polypyrrole component (having the nature of submicron composite polypyrrole-coated polyacrylate latex particles) on the physico-mechanical properties and chemical resistance of the resulting heterogeneous coating films was investigated. The interaction of incorporated polypyrrole and anti-corrosion pigments (see ZnS, Zn₃(PO₄)₂, ZnFe₂O₄, MoS₂, and ZnO) on the corrosion resistance of coatings was evaluated by using the electrochemical linear polarization technique. The polyacrylate latex prepared with the lowest polypyrrole loading (achieved by polymerizing 0.25 wt. % of pyrrole related to acrylic monomers) was found to be the optimum binder for waterborne anticorrosive coatings based on their properties and protective function. Their compatibility with the selected types of pigments was studied for these latex binders. In addition, their influence on the anti-corrosion efficiency of polyacrylate paint films was evaluated using the linear polarization electrochemical technique. For high corrosion resistance, the ZnS and MoS₂ pigments, showing compatibility with polyacrylate latices containing the polypyrrole component, proved to be advantageous. Full article

This research investigated the selected properties of nanocellulose films intended to serve as protective patches on fissured surfaces of wooden artefacts. The effects of their plasticisation with glycerol and functionalisation with selected silanes ((3-Glycidyloxypropyl)trimethoxysilane, and Methyltrimethoxysilane) were also determined. The obtained pure cellulose nanopapers (CNPs) had a homogeneous and compact structure but were very brittle, stiff, and wavy. Functionalisation with silanes made their structure more packed and reduced their equilibrium moisture content by 87–96%, depending on the type and concentration of the silane. Silane functionalisation also slightly improved nanopapers’ resistance to moulds. Plasticisation with glycerol provided CNPs with higher flexibility and resistance to fracture and made them flatter and smoother, reducing the wettability of their surfaces but increasing their hygroscopicity (EMC values increased 1.7–3.5 times for pure CNPs and 5–33 times for functionalised CNPs) and vulnerability to mould infestation. All prepared nanopapers can be easily glued to the wood surface and colour-matched using a nitro wood stain, oil paint or waterborne acrylic paint. The research showed that cellulose nanopapers modified with silanes and plasticised with glycerol seem to be a promising solution for protecting the cracked surface of wooden artefacts against further degradation due to external conditions. Full article

In the last few years, the role of science in Cultural Heritage has assumed greater significance since diagnostics have become essential for the characterization of artworks. The development of conservation strategies involves growing the study of artworks and the knowledge of the materials used against the degradation plaguing the painted surfaces. This work focuses on the investigation of the degradation processes involving paintings on canvas, in particular delamination and progressive deterioration of the painted surfaces. The main causes of the degradation are attributable to the formation of metal soaps, which originate from the interaction between binders and pigments; as a result, the process leads to the progressive fracturing of the paint film. Using various characterization techniques allowed us to acquire information on the structural and morphological properties of the binder resins and study the binder/pigment interaction during the degradation process to understand the quantity and quality of the acid sites present in the binders and, consequently, the potential reactivity with the cationic part of the pigments. The binders were also analyzed within paint layers in contact with zinc oxide to study the interactions and the possible formation of new species as metal soaps and metal oxalates that can modify the boundary among the painting layers and, consequently, the appearance of the artwork and its artistic value. Modifications after UV and thermal aging processes were observed using Infrared spectroscopy and thermogravimetric analysis. Zinc soap formation was observed after 7 h of a UV aging process and was correlated to the acidity of the resins. Full article

Wood surface treatment aims to improve or reduce the surface activity of wood by physical treatment, chemical treatment, biological activation treatment or other methods to achieve the purpose of surface modification. After wood surface modification, the paint film adhesion performance, gluing performance, surface wettability, surface free energy and surface visual properties would be affected. This article aims to explore the effects of different modification methods on the adhesion of wood coating films. Modification of the wood surface significantly improves the adhesion properties of the paint film, thereby extending the service life of the coating. Research showed that physical external force modification improved the hydrophilicity and wettability of wood by changing its surface structure and texture, thus enhancing the adhesion of the coating. Additionally, high-temperature heat treatment modification reduced the risk of coating cracking and peeling by eliminating stress and moisture within the wood. Chemical impregnation modification utilized the different properties of organic and inorganic substances to improve the stability and durability of wood. Organic impregnation effectively filled the wood cell wall and increased its density, while inorganic impregnation enhanced the adhesion of the coating by forming stable chemical bonds. Composite modification methods combined the advantages of the above technologies and significantly improved the comprehensive properties of wood through multiple modification treatments, showing superior adhesion and durability. Comprehensive analysis indicated that selecting the appropriate modification method was key for different wood types and application environments. Full article

Acetone detection is of significant importance in various industries, from cosmetics to pharmaceuticals, bioengineering, and paints. Sensor manufacturing involves the use of different semiconductor materials as well as different metals for doping and functionalization, allowing them to achieve advanced or unique properties in different sensor applications. In the healthcare field, these sensors play a crucial role in the non-invasive diagnosis of various diseases, offering a potential way to monitor metabolic conditions by analyzing respiration. This article presents the synthesis method, using chemical solutions and rapid thermal annealing technology, to obtain Al-functionalized and Ni-doped copper oxide (Al/CuO:Ni) nanostructured thin films for biosensors. The nanocrystalline thin films are subjected to a thorough characterization, with examination of the morphological properties by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD) analysis. The results reveal notable changes in the surface morphology and structure following different treatments, providing insight into the mechanism of function and selectivity of these nanostructures for gases and volatile compounds. The study highlights the high selectivity of developed Al/CuO:Ni nanostructures towards acetone vapors at different concentrations from 1 ppm to 1000 ppm. Gas sensitivity is evaluated over a range of operating temperatures, indicating optimum performance at 300 °C and 350 °C with the maximum sensor signal (S) response obtained being 45% and 50%, respectively, to 50 ppm gas concentration. This work shows the high potential of developed technology for obtaining Al/CuO:Ni nanostructured thin films as next-generation materials for improving the sensitivity and selectivity of acetone sensors for practical applications as breath detectors in biomedical diagnostics, in particular for diabetes monitoring. It also emphasizes the importance of these sensors in ensuring industrial safety by preventing adverse health and environmental effects of exposure to acetone. Full article

A natural extract, i.e., urushiol, was employed to effectively cross-link and modify commercial wet-cured polyurethane acrylic resin. Comprehensive characterization of the paint film was performed using techniques such as FTIR, SEM, and TGA. The results indicated that the incorporation of urushiol significantly increased the cross-linking density of the resin, which in turn enhanced the film-forming properties, mechanical strength, and thermal stability of the paint film. Additionally, the study discovered that under isothermal conditions, the dynamic moduli (G′ and G″) of the paint film are related to the gel point frequency by a power law, aligning with the predictions of percolation theory. The application of the autocatalytic model has provided a novel approach to studying non-isothermal kinetic reactions, offering valuable insights for process optimization and further development of urushiol-based polyurethane. Full article

This work aimed to assess the potential efficacy of a novel polysaccharides-based extract as a green consolidant for the pictorial layer on marble substrates. Understanding its properties could lead to determining whether it can ensure the correct conservation and transmission of the cultural heritage. Four different types of marble specimens were prepared with paint based on malachite (egg, tempera grassa, rabbit glue, and linseed oil as binders). Colorimetric analyses, peeling tests, SEM-EDS, and FTIR spectroscopy were used to test the properties of the consolidant. Results reveal that no aesthetic changes occur when using the extract on painted surfaces and that the cohesive properties of most pictorial films increase after its application, confirming the consolidating effect. In conclusion, the use of an innovative green product for the restoration of marble-painted surfaces can be considered a possible good solution for consolidating treatment. Through this initial explorative research, we suggest an innovative approach to the protection of cultural heritage that doesn’t cause harm to both the restorer’s health and the environment. Full article

In order to prepare chitosan-coated pomelo peel flavonoid microcapsules with antibacterial properties, chitosan was used as the wall material for the purpose of coating the core material, pomelo peel flavonoids. The pH of the microcapsule crosslinking reaction was 7.5, the mass ratio of the microcapsule core material to the wall material was 1:1, and the concentration of the emulsifier was 1%. The microcapsules obtained under these preparation conditions exhibited superior performance, morphology, and dispersion. Additionally, the yield and coating rates were recorded at 22% and 50%, respectively. To prepare the paint film, the microcapsules were added into the coatings at varying concentrations of 0%, 3.0%, 6.0%, 9.0%, 12.0%, and 15.0%. The antibacterial efficacy of the paint film for both bacteria was progressively enhanced with the incorporation of microcapsules. The antibacterial efficacy against Staphylococcus aureus was observed to be higher than that against Escherichia coli. As the content of microcapsules increased, the color difference in the paint film increased, the gloss loss rate increased, and the light transmission rate reduced. The tensile property and elongation at break reduced, and the roughness increased. At a microcapsule content of 6.0%, the paint film exhibited superior overall performance, with an antibacterial efficacy against Escherichia coli and Staphylococcus aureus of 46.3% and 56.7%, respectively. The color difference was 38.58. The gloss loss rate was 41.0%, the light transmission rate was 90.4%, and the paint film exhibited a large elastic region, with an elongation at break of 21.5% and a roughness of 1.46 μm. Full article

The present work investigates the physicochemical stability of spray paints when irradiated with artificial solar light (at spectral range 300–800 nm). This research highlights the importance of understanding the materials used in street art and public murals, recognising them as a significant component of contemporary cultural heritage. By examining the stability and degradation of spray paints toward solar light exposure, the study aims to contribute to the preservation of contemporary murals, which reflect current social and cultural narratives. A physicochemical approach was employed for the study of spray paints’ physical and thermal properties, as well as the effect of specific photochemical ageing reactions/processes. The photochemical ageing results were compared with reference (unaged) samples. Specifically, a multi-technique approach was applied using stereo microscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM), contact angle measurement, colorimetry, glossimetry, differential scanning calorimetry (DSC), UV-Vis spectroscopy, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), and pyrolysis-GC/MS (Py-GC/MS). The photodegradation of the spray paints occurred from the first 144 h of solar light irradiation, resulting in changes in morphology, colour, gloss, roughness, and wettability. Regarding photochemical stability, ageing seems to affect the binders more than the synthetic organic pigments and the inorganic fillers. In particular, acrylic binders showed small chemical changes, whereas the alkyd, nitrocellulose, and styrene binders underwent severe chemical modification. The results suggest that simulated daylight irradiation prompts the migration of additives toward the surface of the spray paint films. In addition, the results of the analyses on the white spray paints in comparison with the coloured paints (from the same manufacturer) showed that there seems to be an active distinct photoageing mechanism involving titanium dioxide, but the whole issue needs further investigation. Full article