Sign in to use this feature.

Years

Between: -

Subjects

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Journals

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Article Types

Countries / Regions

remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline
remove_circle_outline

Search Results (8,276)

Search Parameters:
Keywords = ordinary

Order results
Result details
Results per page
Select all
Export citation of selected articles as:
21 pages, 680 KB  
Article
An Integrated Optimal Control Model for Simultaneous Tuberculosis Transmission and Stunting Prevention
by Rika Amelia, Nursanti Anggriani and Wan Muhamad Amir W. Ahmad
Mathematics 2026, 14(7), 1140; https://doi.org/10.3390/math14071140 (registering DOI) - 28 Mar 2026
Abstract
This study develops an integrated mathematical model to investigate the interaction between tuberculosis (TB) transmission and childhood stunting, which is aligned with the United Nations Sustainable Development Goals (SDG 3). The population is structured into two age groups (0–5 years and ≥5 years), [...] Read more.
This study develops an integrated mathematical model to investigate the interaction between tuberculosis (TB) transmission and childhood stunting, which is aligned with the United Nations Sustainable Development Goals (SDG 3). The population is structured into two age groups (0–5 years and ≥5 years), with stunting explicitly incorporated into the pediatric population to capture its potential influence on TB dynamics. The model is formulated as a system of ordinary differential equations and analyzed using equilibrium and stability analysis, with the basic reproduction number, R0. The disease-free equilibrium is locally asymptotically stable when R0 < 1, while an endemic equilibrium exists when R0 > 1. Sensitivity analysis indicates that the transmission rate (β), progression rate from latent to active infection (σ), and recovery rate (γ) are the most influential parameters affecting R0. These parameters are therefore selected as control variables in an optimal control framework to design effective intervention strategies. Numerical simulations show that the combined control strategy significantly reduces TB transmission, resulting in a reduction of more than 80% in active TB cases within a relatively short intervention period. The results suggest that integrated interventions targeting transmission, disease progression, and recovery are substantially more effective than single-measure strategies. This study provides a quantitative framework to support integrated public health policies addressing TB and childhood stunting simultaneously. Full article
(This article belongs to the Special Issue Mathematical Modelling of Epidemic Dynamics and Control)
20 pages, 1445 KB  
Article
International Trade and Environmental Sustainability Dynamics in SADC
by Jude Igyo Ali and Patricia Lindelwa Makoni
Sustainability 2026, 18(7), 3310; https://doi.org/10.3390/su18073310 (registering DOI) - 28 Mar 2026
Abstract
This paper examines how openness of international trade is dynamically related to environmental sustainability in sixteen member states of the Southern African Development Community (SADC) between 2000 and 2024, taking into consideration institutional quality factors, economic development, and structural factors. The study uses [...] Read more.
This paper examines how openness of international trade is dynamically related to environmental sustainability in sixteen member states of the Southern African Development Community (SADC) between 2000 and 2024, taking into consideration institutional quality factors, economic development, and structural factors. The study uses the Panel Fully Modified Ordinary Least Squares (FMOLS), Pedroni panel cointegration tests, and quantile regression to examine the determination of per capita CO2 emissions by using trade openness, GDP per capita, government effectiveness, energy use, natural resource rents, and urbanisation. The findings of cointegration prove a long-run equilibrium stability. FMOLS estimates show that trade openness positively but insignificantly increases the typically pooled long-run specifications through urbanisation and natural resource rents and negatively through GDP per capita, which is in line with the phase upper-Environmental Kuznets Curve. The outcome of quantile regression reveals a large distributional heterogeneity with the trade openness decreasing emissions only among high-emitting economies at the seventy-fifth and at the ninetieth percentile which is the imperative effect of the quantile technique demonstrating the need for country-differentiated trade and environmental policy across the SADC. Full article
Show Figures

Figure 1

18 pages, 460 KB  
Article
Lower Bounds for the Asymptotic Relative Efficiency of Huber Regression
by Xiaoyi Wang and Le Zhou
Mathematics 2026, 14(7), 1138; https://doi.org/10.3390/math14071138 (registering DOI) - 28 Mar 2026
Abstract
Huber regression serves as a prominent robust alternative to ordinary least squares (OLS), particularly in the presence of heavy-tailed error distributions. While the asymptotic relative efficiency (ARE) of Huber regression is well documented for the standard normal distribution, its worst-case efficiency across the [...] Read more.
Huber regression serves as a prominent robust alternative to ordinary least squares (OLS), particularly in the presence of heavy-tailed error distributions. While the asymptotic relative efficiency (ARE) of Huber regression is well documented for the standard normal distribution, its worst-case efficiency across the class of all continuous and symmetric error distributions remains an important theoretical question. In this paper, we establish positive lower bounds for the ARE of Huber regression relative to OLS. By strategically selecting the robustification parameter based on the moments or quantiles of the error distribution, we first prove that the ARE is uniformly bounded away from zero across all continuous and symmetric error distributions. This result guarantees a baseline level of efficiency for Huber regression, sharing a similar theoretical spirit with the celebrated lower bound of the Wilcoxon rank estimator. Utilizing the empirical process theory, we further establish that the relative efficiency of Huber regression remains unchanged if the theoretical tuning parameter is replaced by an estimator with a suitable convergence rate. Simulation studies are conducted to examine the performance of Huber regression under the proposed tuning strategies. Full article
(This article belongs to the Special Issue Computational Statistics and Data Analysis, 3rd Edition)
16 pages, 1695 KB  
Article
Wave Absorption in a Two-Dimensional Medium Using Peridynamic Differential Operator and Perfectly Matched Layers
by Reza Alebrahim and Riccardo Panciroli
Mathematics 2026, 14(7), 1134; https://doi.org/10.3390/math14071134 (registering DOI) - 28 Mar 2026
Abstract
In this study, the nonlocal theory of peridynamics (PD) is adopted to simulate elastic wave propagation in an infinite plate. To realistically represent an unbounded domain and suppress artificial wave reflections at computational boundaries, the perfectly matched layer (PML) technique is incorporated into [...] Read more.
In this study, the nonlocal theory of peridynamics (PD) is adopted to simulate elastic wave propagation in an infinite plate. To realistically represent an unbounded domain and suppress artificial wave reflections at computational boundaries, the perfectly matched layer (PML) technique is incorporated into the peridynamic framework. A refined non-ordinary state-based peridynamic (RNOSB-PD) formulation is developed in which the peridynamic differential operator is employed to accurately capture wave kinematics and stress responses. The proposed model is validated through numerical simulations of wave propagation, where displacement field is examined within both the physical domain and the absorbing layers. The results demonstrate that the peridynamic PML effectively attenuates outgoing waves without generating spurious reflections, leading to responses that closely replicate those of an infinite plate. This study confirms the robustness and accuracy of the RNOSB-PD–PML approach and highlights its potential for simulating wave phenomena in unbounded or large-scale solid mechanics problems involving nonlocal effects. Full article
Show Figures

Figure 1

23 pages, 2875 KB  
Article
Effects of High Moisture Corn Feeding on Weight Performance, Serum Immune Indices, Rumen Fermentation, and Metabolomics in Kazakh Rams
by Buweiaizhaer Maimaitimin, Tong Li, Subinuer Abuduli, Kadeliya Abudureyimu, Linhai Song, Liang Yang, Wei Shao and Wanping Ren
Animals 2026, 16(7), 1030; https://doi.org/10.3390/ani16071030 - 27 Mar 2026
Abstract
This study aimed to investigate the effects of feeding high-moisture corn (HMC) on weight performance, serum immune and antioxidant indices, rumen fermentation, microbial community, and metabolomics in Kazakh rams. A total of 32 healthy Kazakh rams were randomly divided into a control group [...] Read more.
This study aimed to investigate the effects of feeding high-moisture corn (HMC) on weight performance, serum immune and antioxidant indices, rumen fermentation, microbial community, and metabolomics in Kazakh rams. A total of 32 healthy Kazakh rams were randomly divided into a control group (CT, diet with only ordinary crushed corn) and an experimental group (GS, diet with 50% ordinary crushed corn + 50% HMC), following a 7-day adaptation period and a 120-day trial period. Results showed that the F/G was significantly lower in the GS group than in the CT group (p < 0.05). FBW, net weight gain and ADG increased by 4.58%, 8.69%, and 8.70%, respectively, while ADFI decreased by 7.04% (p > 0.05). Regarding serum immune indices, IgA in the GS group was significantly higher at 40 d (p < 0.01), and IgM was significantly higher at 40, 80, and 120 d (p < 0.05). For antioxidant indices, the SOD activity in the GS group was significantly higher than that in the CT group at 120 d (p < 0.01). The CAT activity in the GS group was significantly higher at 40, 80, and 120 d (p < 0.01). Among rumen fermentation parameters, the concentration of butyric acid in the GS group was significantly lower than in the CT group (p < 0.01). Microbial diversity analysis indicated no significant differences in Alpha- and Beta-diversity of rumen microorganisms between the two groups. However, the relative abundance of Firmicutes_A at the phylum level was significantly higher in the GS group (p < 0.05), and the abundance of Cryptobacteroides was significantly higher than in the CT group (p < 0.01). Rumen metabolomic analysis identified a total of 1357 differential metabolites, among which 1130 showed significant differences, with 459 upregulated and 671 downregulated. These were mainly enriched in pathways such as Glutathione metabolism, Beta-alanine metabolism, Sphingolipid metabolism, and lysine degradation. In conclusion, feeding HMC can improve feed conversion efficiency and weight performance in Kazakh rams, regulate the structure of dominant rumen microorganisms, and enhance immune and antioxidant capacities. Full article
Show Figures

Figure 1

16 pages, 354 KB  
Article
Symbolic Method for Solving Nonlocal Boundary Value Problems for Systems of Ordinary Loaded Integro-Differential Equations
by Efthimios Providas, Ioannis N. Parasidis and Jeyhun E. Musayev
Mathematics 2026, 14(7), 1128; https://doi.org/10.3390/math14071128 - 27 Mar 2026
Abstract
A symbolic method is presented for examining the solvability and constructing the exact solution to boundary value problems for systems of linear ordinary loaded differential equations and loaded integro-differential equations with nonlocal boundary conditions. The method uses the inverse of the differential operator [...] Read more.
A symbolic method is presented for examining the solvability and constructing the exact solution to boundary value problems for systems of linear ordinary loaded differential equations and loaded integro-differential equations with nonlocal boundary conditions. The method uses the inverse of the differential operator involved in the system of loaded differential or integro-differential equations. A solvability criterion based on the determinant of a matrix and an exact analytical matrix-form solution formula are presented. For the implementation of the method into computer algebra system software, two algorithms are provided. The effectiveness of the method is demonstrated by solving several problems. The theoretical and practical results obtained complement the existing literature on the subject. Full article
(This article belongs to the Special Issue Applications of Differential Equations in Sciences)
27 pages, 2530 KB  
Article
On Wind Effects in a Hyperbolic Advection–Reaction–Diffusion Forest Fire Model: Analytical Solutions, Stability, and Bifurcation Analysis
by Elena V. Nikolova, Gergana N. Nikolova and Tsvetomir Ch. Pavlov
Mathematics 2026, 14(7), 1118; https://doi.org/10.3390/math14071118 - 26 Mar 2026
Viewed by 105
Abstract
We revisit a hyperbolic wildfire model based on reaction–diffusion dynamics with relaxation effects and extend it by incorporating an advection transport term that accounts for wind-driven fire spread. After a planar two-dimensional reformulation and non-dimensionalization of the model, the analysis is restricted to [...] Read more.
We revisit a hyperbolic wildfire model based on reaction–diffusion dynamics with relaxation effects and extend it by incorporating an advection transport term that accounts for wind-driven fire spread. After a planar two-dimensional reformulation and non-dimensionalization of the model, the analysis is restricted to the minimal ignition regime characterized by the presence of a logistic reaction term governing the evolution of the fire-affected tree fraction. The focus of the study is to assess the influence of the effective wind velocity on the propagation dynamics of the fire-affected tree fraction. For this purpose, analytical solutions of the extended wildfire model are derived by applying the Simple Equations Method (SEsM) in its (1,1) variant using a Riccati-type ordinary differential equation as a simple equation. The obtained families of exact solutions describe physically relevant transition fronts connecting fire-unaffected and fully fire-affected states, or vice versa. Numerical simulations of the derived analytical solutions are performed to demonstrate how the internal front thickness and the profile morphology depend on the specific variant of the Riccati-type solution and on the magnitude of the effective wind velocity. A phase-plane stability and bifurcation analysis of the reduced traveling wave system is carried out. Hopf bifurcation thresholds with respect to the effective wind velocity parameter are identified, revealing transitions between monotone front propagation and oscillatory regimes. A regime map is constructed in the parameter plane spanned by the effective wind velocity and the traveling wave speed. This regime diagram delineates regions of qualitatively different propagation behavior, including monotone advancing fronts, possible oscillatory regimes, and regimes in which traveling wave fronts cease to exist. Full article
(This article belongs to the Special Issue Advances in Nonlinear Analysis: Theory, Methods and Applications)
Show Figures

Figure 1

22 pages, 6211 KB  
Article
Mechanism of Activation and Mechanical Properties of Alkali-Activated Material Derived from GGBFS/FA Activated by Carbide Slag
by Zhong Wang, Shujie Chen, Xiaoyan Zheng, Xia Huang, Tengfei Fu, Chao Feng, Demei Yu and Hengchun Zhang
Materials 2026, 19(7), 1313; https://doi.org/10.3390/ma19071313 - 26 Mar 2026
Viewed by 224
Abstract
Ground granulated blast furnace slag (GGBFS)-based cementitious materials, known for their high strength and good fluidity, present an eco-friendly, low-carbon alternative to ordinary Portland cement (OPC). However, the high cost of activators poses a significant challenge, accounting for over 50% of alkali-activated material [...] Read more.
Ground granulated blast furnace slag (GGBFS)-based cementitious materials, known for their high strength and good fluidity, present an eco-friendly, low-carbon alternative to ordinary Portland cement (OPC). However, the high cost of activators poses a significant challenge, accounting for over 50% of alkali-activated material production costs. This study uses carbide slag (CS), a byproduct of polyvinylchloride (PVC) production, as an activator, along with other solid wastes such as GGBFS and fly ash (FA) as precursors to develop a novel, low-carbon alkali-activated material binder made entirely from solid waste. Various mixtures with different proportions of CS and GGBFS were prepared, and their workability and strength were tested at different ages. Additionally, the hydration characteristics and microstructure of the samples were analyzed using XRD, TG-DTG, FTIR, heat of hydration tests, and SEM-EDS. Results show that calcium hydroxide in CS activates the pozzolanic activity of GGBFS and FA, improving the strength as the proportion of CS increases. At the 5% CS content, the 7 days compressive strength of the GGBFS-based alkali-activated material increased by 79.7% compared to a 2% CS content. However, adding CS reduces the workability of the polymer slurry, with a spread decrease of 168.5 mm and 161.5 mm as the CS content increases from 2% to 8%. The inclusion of CS also increases the rate and total heat released during hydration, with the optimal performance observed at 5% CS. While FA incorporation reduces strength, it enhances slurry workability and reduces heat release during hydration. The strength development is attributed to the formation of AFt, C-S-H gel, C-(A)-S-H gel, and hydrocalumite-like hydrates. Full article
(This article belongs to the Section Construction and Building Materials)
Show Figures

Figure 1

21 pages, 3712 KB  
Article
Dynamical Analysis and Soliton Solutions of the Truncated M-Fractional FitzHugh–Nagumo Equation
by Beenish and Abdulaziz Khalid Alsharidi
Fractal Fract. 2026, 10(4), 213; https://doi.org/10.3390/fractalfract10040213 - 25 Mar 2026
Viewed by 115
Abstract
In this paper, we investigate the (1 + 1)-dimensional nonlinear truncated M-fractional FitzHugh–Nagumo model. The main objective is to analyze the dynamical behavior and obtain exact solutions for the model. First, a fractional transformation is applied to convert the governing partial differential equation [...] Read more.
In this paper, we investigate the (1 + 1)-dimensional nonlinear truncated M-fractional FitzHugh–Nagumo model. The main objective is to analyze the dynamical behavior and obtain exact solutions for the model. First, a fractional transformation is applied to convert the governing partial differential equation into an ordinary differential equation. Subsequently, a Galilean transformation is employed to reduce the resulting equation to a dynamical system. The bifurcation structure and chaotic dynamics of the model are then examined. The presence of chaos is further confirmed through the phase portrait, basin of attraction, return map, Lyapunov exponent, permutation entropy, Poincaré map, power spectrum, attractor, fractal dimension, multistability, time analysis, and recurrence plot. In addition, the sensitivity of the system to the initial conditions is analyzed. Finally, exact solutions for the model are constructed using the unified Riccati equation expansion method. The obtained results are illustrated using two-dimensional, three-dimensional, and contour plots. Full article
Show Figures

Figure 1

12 pages, 254 KB  
Article
Can Wormhole Spacetimes in Unimodular Gravity Be Supported by Ordinary Matter? A General Proof of the Exotic Matter Requirement
by Mauricio Cataldo, Norman Cruz and Patricio Salgado
Axioms 2026, 15(4), 244; https://doi.org/10.3390/axioms15040244 - 25 Mar 2026
Viewed by 184
Abstract
We establish a general no-go theorem demonstrating that all traversable wormhole configurations in Unimodular Gravity necessarily require exotic matter. The proof relies solely on the geometric flaring-out condition, b′(r0) ≤ 1, which directly implies that ρ(r0 [...] Read more.
We establish a general no-go theorem demonstrating that all traversable wormhole configurations in Unimodular Gravity necessarily require exotic matter. The proof relies solely on the geometric flaring-out condition, b′(r0) ≤ 1, which directly implies that ρ(r0) + pr(r0) ≤ 0 at the throat. This condition represents a violation of the Null Energy Condition and, consequently, of the Weak and Strong Energy Conditions, independently of the particular choice of shape function, redshift function, or equation of state. This result holds for both tidal and zero-tidal-force configurations, showing that the requirement of exotic matter is a fundamental geometric consequence of the traversability condition rather than an artifact of specific solution choices. Therefore, Unimodular Gravity shares this fundamental constraint with General Relativity. Full article
(This article belongs to the Special Issue Complex Variables in Quantum Gravity)
30 pages, 1235 KB  
Article
Double-Edged Influencing Mechanisms of Digital Empowerment on Rural Environmental Governance: Evidence from China
by Yajing Zhang, Jingfeng Yuan and Weijian Jin
Land 2026, 15(4), 527; https://doi.org/10.3390/land15040527 - 24 Mar 2026
Viewed by 174
Abstract
With the increasing prevalence of digital technology, the inherent influencing mechanisms by which digital empowerment fosters rural environmental governance remain a critical area of inquiry. However, existing research neglects the dual effects of digital technology on rural environmental governance from the aspect of [...] Read more.
With the increasing prevalence of digital technology, the inherent influencing mechanisms by which digital empowerment fosters rural environmental governance remain a critical area of inquiry. However, existing research neglects the dual effects of digital technology on rural environmental governance from the aspect of stakeholders’ engagement. To address this gap, this study develops an integrated framework to investigate not only the direct impact of digital empowerment on rural environmental governance but also the mediating roles of stakeholders’ engagement and governance mechanisms, alongside the moderating role of perceived technology anxiety. Grounded in theoretical frameworks and extensive literature reviews, this study analyzes data from Jiangsu province in 2025 using an Ordinary Least Squares (OLS) model. The baseline regression results reveal that digital empowerment significantly promotes rural environmental governance, even after endogeneity analysis. Moreover, the results of the mediation effect show that digital empowerment enhances the level of rural environmental governance by accelerating stakeholders’ engagement and improving governance mechanisms. Furthermore, the moderating effect results imply that perceived technology anxiety may inhibit the negative effect of digital empowerment on rural environmental governance. Additionally, regional disparities exist in the influences of digital empowerment on rural environmental governance, with rural areas in Southern Jiangsu exhibiting a more pronounced effect compared to other regions. Full article
Show Figures

Graphical abstract

37 pages, 5397 KB  
Article
Vibration Mitigation in a Pitch–Roll Ship Motion Under Multi-Parametric Excitations Using Proportional–Derivative Controllers
by Rageh K. Hussein, Yasmeen M. Mohamed, Ashraf Taha EL-Sayed and Galal M. Moatimid
Mathematics 2026, 14(7), 1100; https://doi.org/10.3390/math14071100 - 24 Mar 2026
Viewed by 209
Abstract
Vessel vibrations have serious safety risks and must be effectively mitigated. This study investigates the reduction in ship pitch–roll vibrations modeled as a two degrees of freedom of nonlinear spring–pendulum system subjected to multi-parametric excitation, using proportional–derivative controller. The main objective is to [...] Read more.
Vessel vibrations have serious safety risks and must be effectively mitigated. This study investigates the reduction in ship pitch–roll vibrations modeled as a two degrees of freedom of nonlinear spring–pendulum system subjected to multi-parametric excitation, using proportional–derivative controller. The main objective is to develop a rapid and efficient analytical approach to nonlinear vibration analysis. A non-perturbative approach is employed to transform weakly nonlinear oscillators of ordinary differential equations into equivalent linear ones without using Taylor expansions. He’s frequency formula plays a central role in this transformation. The resulting parametric solutions are validated using Mathematica Software (v13) and show a strong agreement with the original nonlinear model. The effects of various parameters on stability are examined. Theoretical analysis is conducted using the multiple time scales method to identify worst resonance conditions and derive frequency response equations. Stability near simultaneous sub-harmonic resonance is assessed using Routh–Hurwitz criterion. Numerical simulations based on the fourth-order Runge–Kutta method confirm the effectiveness of proportional–derivative control. Excellent agreement between analytical and numerical results demonstrates the accuracy, efficiency, and practical applicability of the proposed method. Full article
Show Figures

Figure 1

27 pages, 7143 KB  
Article
Research on Material Optimization of CSM Method Structures in Highly Weathered Strata
by Yifan Xie, Haitao Liu, Hao Wen, Chuangui Sun, Yong Chang, Qiang Feng, Lianzhen Zhang and Hongbo Wang
Materials 2026, 19(7), 1287; https://doi.org/10.3390/ma19071287 - 24 Mar 2026
Viewed by 104
Abstract
To address the challenges of low strength and poor impermeability of soil–cement walls formed with ordinary cement materials when applying the CSM (Cutter Soil Mixing) method in highly weathered strata, this study carried out structural optimization by combining the CSM method with H–section [...] Read more.
To address the challenges of low strength and poor impermeability of soil–cement walls formed with ordinary cement materials when applying the CSM (Cutter Soil Mixing) method in highly weathered strata, this study carried out structural optimization by combining the CSM method with H–section steel. This optimization effectively resolves issues such as low efficiency and high cost associated with the CSM method integrated with cement–filled piles. Meanwhile, using ordinary Portland cement as the base material, basalt fiber, sodium bentonite, and fly ash were added to investigate the influence of each component on the performance of the new composite. A novel CSM material suitable for highly weathered strata was developed, which exhibits excellent mechanical strength and impermeability. The optimal mix proportion of the soil–cement material was determined as follows: basalt fiber 0.5%, fly ash 15%, and sodium bentonite 3%. This research provides a quantitative basis for the efficient and economical application of the CSM method in highly weathered strata. Full article
Show Figures

Figure 1

15 pages, 9543 KB  
Article
A Novel Electrochemiluminescent Biosensor Based on Nitrogen-Doped Graphyne for Ultrasensitive Kanamycin Residue Detection in Milk and Honey Samples
by Yuxuan Liu, Tianzeng Huang, Yang Chen, Gaowa Xing, Hongmei Cao and Daixin Ye
Chemosensors 2026, 14(3), 76; https://doi.org/10.3390/chemosensors14030076 - 23 Mar 2026
Viewed by 174
Abstract
A novel sensitive and selective electrochemiluminescence (ECL) sensor using nitrogen-doped graphyne as the platform was proposed for kanamycin (KAN) detection. First, nitrogen-doped graphyne nanomaterial (1N-GY) with high conductivity was synthesized using a high-energy ball milling method. Compared with ordinary graphyne, the addition of [...] Read more.
A novel sensitive and selective electrochemiluminescence (ECL) sensor using nitrogen-doped graphyne as the platform was proposed for kanamycin (KAN) detection. First, nitrogen-doped graphyne nanomaterial (1N-GY) with high conductivity was synthesized using a high-energy ball milling method. Compared with ordinary graphyne, the addition of nitrogen atoms can improve the conductivity of the material and reduce the electronic migration energy barrier. Then it was used as a substrate material of the ECL sensor, not only increasing the conductivity of the biosensor but also improving the sensitivity of the ECL sensor by providing more immobilization space for the luminescent probe of Nafion-coated mesoporous silica adsorbed Ru(bpy)32+ (mSiO2@Nafion@Ru(bpy)32+). On this basis, mSiO2@Nafion@Ru(bpy)32+ functionalized DNA probes were used as luminescent and capture probes to specifically recognize different concentrations of KAN to produce ECL signals. Under optimal conditions, the proposed ECL sensor exhibited good linearity (10−12–10−6 M KAN) and a low detection limit of 1.08 pM. The prepared biosensor with good stability and selectivity successfully detected KAN in honey and milk samples, with spiked recovery rates ranging from 98% to 111.79%. This method not only expands the application of 1N-GY as a novel graphitic material in ECL biosensors but also provides an effective way to check antibiotics in dairy products. Full article
Show Figures

Figure 1

28 pages, 34091 KB  
Article
Effects of Titanium Gypsum and Flue Gas Desulfurization Gypsum on the Hydration and Mechanical Properties of Anhydrite–Phosphogypsum-Based Supersulfated Cement
by Youquan Xie, Li Yang, Xiaodong Li, Jiaqing Wang, Yanbo Li, Hao Zhou and Yueyang Hu
Materials 2026, 19(6), 1273; https://doi.org/10.3390/ma19061273 - 23 Mar 2026
Viewed by 219
Abstract
Supersulfated cement (SSC) is an environmentally friendly cementitious material with a low clinker content, in which industrial byproduct gypsum serves as the sulfate source, thereby enabling the valorization of solid waste. The hydration process, pore structure, microstructure, and hydration products were investigated using [...] Read more.
Supersulfated cement (SSC) is an environmentally friendly cementitious material with a low clinker content, in which industrial byproduct gypsum serves as the sulfate source, thereby enabling the valorization of solid waste. The hydration process, pore structure, microstructure, and hydration products were investigated using paste samples by means of isothermal calorimetry, X-ray diffraction (XRD), thermogravimetric analysis (TG–DTG), Fourier transform–infrared spectroscopy (FT-IR), mercury intrusion porosimetry (MIP), and scanning electron microscopy (SEM), while compressive strength was evaluated using mortar specimens. Compared with ordinary Portland cement (OPC), SSC offers clear advantages in reducing energy consumption and greenhouse gas emissions. In this study, the effects of titanium gypsum (TG) and flue gas desulfurization gypsum (FGD) on the hydration behavior, fluidity, mechanical properties, and microstructural evolution of an anhydrite (AH)–phosphogypsum (PG)-based SSC were systematically investigated. The results indicate that the incorporation of 11% TG and FGD mitigates the strong sulfate environment caused by the rapid dissolution of soluble AH, thereby regulating the hydration process. As the proportion of TG and FGD increased, the cumulative heat release within 72 h gradually decreased. When AH was completely replaced, the cumulative heat release of TG4 and FG4 decreased by approximately 19.7% and 28.6%, respectively. TG and FGD exhibited opposite effects on the fluidity of SSC while both promoting strength development. Among all mixtures, TG2 and FG2 showed the best performance, with the highest 28-day compressive strengths of 50.15 MPa and 51.95 MPa, respectively. Microstructural analysis reveals that differences in particle size distribution and dissolution kinetics among gypsums governed the sulfate release characteristics and slag activation mechanisms, thus leading to distinct hydration pathways, pore structure evolution, and microstructural densification. This study provides a theoretical basis for the efficient utilization of various industrial byproduct gypsums and offers important guidance for the controllable design of SSC performance. Full article
(This article belongs to the Special Issue Advances in Hydration Chemistry for Low-Carbon Cementitious Materials)
Show Figures

Graphical abstract

Back to TopTop