Search Results (45)

With the continuous and rapid development of global industries, issues such as offshore oil spills, leakage of organic chemicals, and the direct discharge of industrial oily sewage have caused serious damage to the ecological environment and water resources. Efficient oil–water separation is widely recognized as the solution. However, there is an urgent need to address the difficulties in treating thin oil films on the water surface and the low separation efficiency of existing oil–water separation materials. In view of this, this study aims to investigate high-efficiency oil–water separation materials for thin oil films. Four types of oil–water separation materials with different materials are designed to treat thin oil films on the water surface. The effects of factors such as oil film thickness, pressure, and temperature on the oil–water separation performance of these materials are studied. The viscosities of kerosene and diesel oil are tested, and the adsorption and separation effects of the oil–water separation materials on different oil products and oily organic solvents are examined. In addition, the long-term stability of the movable and portable oil–water separation components is verified. The results show that the oil-absorbing sponge-based oil–water separation membrane has an excellent microporous structure and surface roughness, endowing the membrane surface with excellent hydrophobicity and lipophilicity, and exhibiting good oil–water separation performance. The filtration flux of oil increases with the increase in pressure and temperature. It has good adsorption and separation performance for different oil products and oily organic solvents. Moreover, it maintains stable operation performance during the 12-month long-term oil–water separation process for kerosene and diesel oil. Full article

Oil spills in ports are particular cases of oil pollution in water environments that call for specific monitoring measures. Apart from the ecological threats that they pose, their proximity to human activities and the financial losses induced by disturbed port activities add to the need for immediate action. However, in ports, established methods based on short-wave infrared sensors might not be applicable due to the relatively low thickness of the oil layer, and satellite images suffer from insufficient spatial resolution, given the agglomeration of objects in ports. In this study, a lightweight ultraviolet (UV) camera was exploited in both controlled experiments and a real port environment to estimate the potential and limitations of UV imagery in detecting oil spills, in comparison to RGB images. Specifically, motivated by the scarce research literature on this topic, we set up experiments simulating oil spills with various oil types, different viewing angles, and under different weather conditions, such that the separability between oil and background (water) could be better understood and objectively assessed. The UV camera was also used to detect real-world oil spills in a port environment after installing it on a vessel for continuous monitoring. Various separability metrics between water and oil, computed in both scenarios (controlled experiments and port environment), show that the UV cameras have better potential than RGB in detecting oil spills in port environments. Full article

The frequent occurrence of marine oil spills underscores the need for efficient methods to identify spilled substances and analyze their thickness. Traditional models based on Laser-Induced Fluorescence (LIF) technology often focus on a single functionality, limiting their ability to simultaneously perform qualitative and quantitative analyses. This study introduces a novel LIF-based spectral analysis method that integrates a self-designed detection system and a multi-task framework, the Wavelet CNN-sLSTM-KAN-Enhanced Transformer (WaveConv-sLSTM-KET). By combining a Wavelet Transform CNN block, a scalar LSTM block, and a Kolmogorov–Arnold Network-Enhanced Transformer block, the framework enables simultaneous oil-type identification and thickness prediction without preprocessing or fully connected layers. It achieves high classification accuracy and precise regression for oil film thicknesses (50 µm–0.5 mm). Its reliability, real-time operation, and lightweight structure address limitations of conventional methods, offering a promising solution for non-destructive, efficient oil spill detection. Full article

In this study, the ANSYS 2020R1 software simulation is employed to examine the diffusion process of oil leakage and the underground water solute transport law in the Dashagou Yellow River crossing section of the oil pipeline. The simulation results demonstrate that under identical leakage pressure conditions, diesel fuel leakage in powdery, sandy soil is diminished, the emergency window is extended, and the corresponding leakage risk is reduced. In addition, the leakage rate of crude oil is slower than that of diesel oil. After 850 days of downward migration of approximately 190 m, the pollutant reaches quasi-static equilibrium in the big sand ditch. The results of the surface water oil spill analysis demonstrated that the oil film on the river surface migrated for 100 min after the spill, with a thickness that remained between 0.02 and 0.05 mm and a concentration that approached equilibrium. Full article

An oil spill at sea represents a catastrophic environmental event resulting from the release of oil into marine ecosystems. These incidents pose substantial risks to marine biodiversity, wildlife habitats, and coastal populations, often engendering enduring and widespread repercussions. Cleaning up oil spills is costly due to logistical challenges. The accurate measurement of spill characteristics like the volume, thickness, and area of the spill is crucial before deploying cleanup crews to optimize resource allocation and reduce expenses. The main objective of this research is to use computer vision to detect oil spills and estimate its thickness, helping in decision-making processes to clean up the spill area. The system architecture proposed in this study integrates a drone equipped with a camera module to inspect sea areas and capture images. These images are processed using a deployed computer vision segmentation model to detect oil spills and estimate oil thickness. Predicted results help in decision making via a dedicated application by applying predefined criteria to determine the thickness of the spill, which further help in taking actions for the removal of oil spills. The computer vision model developed in this research could detect and estimate oil thickness with an mAP of 91%. The proposed system in this study uses instance segmentation to detect and segment oil spills in drone footage. This computer vision-based approach accurately identifies and outlines oil spill areas, aiding in the selection of efficient cleanup strategies. Real-time monitoring and assessment capabilities enable quick decision making and effective response measures. Full article

There is a heightened risk of an oil spill occurring in the Arctic, as climate change driven sea ice loss permits an increase in Arctic marine transportation. The ability to detect an oil spill and monitor its progression is key to enacting an effective response. Microwave scatterometer systems may be used detect changes in sea ice thermodynamic and physical properties, so we examined the potential of C-band polarimetric radar for detecting diesel fuel beneath a thin sea ice layer. Sea ice physical properties, including thickness, temperature, and salinity, were measured before and after diesel addition beneath the ice. Time-series polarimetric C-band scatterometer measurements monitored the sea ice evolution and diesel migration to the sea ice surface. We characterized the temporal evolution of the diesel-contaminated seawater and sea ice by monitoring the normalized radar cross section (NRCS) and polarimetric parameters (conformity coefficient (μ), copolarization correlation coefficient (ρco)) at 20° and 25° incidence angles. We delineated three stages, with distinct NRCS and polarimetric results, which could be connected to the thermophysical state and the presence of diesel on the surface. Stage 1 described the initial formation of sea ice, while in Stage 2, we injected 20L of diesel beneath the sea ice. No immediate response was noted in the radar measurements. With the emergence of diesel on the sea ice surface, denoted by Stage 3, the NRCS dropped substantially. The largest response was for VV and HH polarizations at 20° incidence angle. Physical sampling indicated that diesel emerged to the surface of the sea ice and trended towards the tub edge and the polarimetric scatterometer was sensitive to these physical changes. This study contributes to a greater understanding of how C-band frequencies can be used to monitor oil products in the Arctic and act as a baseline for the interpretation of satellite data. Additionally, these findings will assist in the development of standards for oil and diesel fuel detection in the Canadian Arctic in association with the Canadian Standards Association Group. Full article

This paper presents an original approach to predicting oil slick movement and dispersion at the water surface. Special emphasis is placed on the impact of evolving hydro-meteorological conditions and the thickness of the oil spill layer. The main gap addressed by this study lies in the need for a comprehensive understanding of how changing environmental conditions and oil thickness interact to influence the movement and dispersion of oil slicks. By focusing on this aspect, this study aims to provide valuable insights into the complex dynamics of oil spill behaviour, enhancing the ability to predict and mitigate the environmental impacts of such incidents. Self-designed software was applied to develop and modify previously established mathematical probabilistic models for predicting changes in the shape of the oil trajectory. First, a semi-Markov model of the process is constructed, and the oil thickness is analysed at the sea surface over time. Next, a stochastic-based procedure to forecast the horizontal movement and dispersion of an oil slick in diverse hydro-meteorological conditions considering a varying oil layer thickness is presented. This involves determining the trajectory and movement of a slick domain, which consists of an elliptical combination of domains undergoing temporal changes. By applying the procedure and program, a short-term forecast of the horizontal movement and dispersion of an oil slick provided its trajectory at the Bornholm Basin of the Baltic Sea within two days. The research results obtained are preliminary prediction results, although the approach considered in this paper can help responders understand the scope of the problem and mitigate the effects of environmental damage if the oil discharge reaches sensitive ecosystems. Finally, further perspectives of this research are given. Full article

With the increasing global reliance on maritime oil transportation, oil spills pose significant environmental hazards to coastal ecosystems. This study presents a comprehensive quantitative framework for assessing oil spill risks along the Jiaozhou Bay coastline in China. The research begins with an analysis of historical spill data to construct representative oil spill simulation scenarios. The advanced MEDSLIK-II oil spill prediction model is then employed to simulate oil spill trajectories under these scenarios, focusing on key parameters such as oil thickness and mass to evaluate the hazard levels associated with each scenario. Subsequently, the Environmental Sensitivity Index (ESI) is utilized to assess the vulnerability of coastal zones, while Geographic Information System (GIS) techniques are employed for a spatial analysis and visualization of the results. The case study, covering a 26.87 km stretch of the Jiaozhou Bay coastline, reveals 10 high-risk zones with a total length of 8561.2 m. These areas are predominantly characterized by saltwater marshes, brackish water marshes, and inundated low-lying areas, with ESI rankings of 9 and 10, accounting for 24% of the 339 analyzed segments. The modeling results indicate that in the simulated scenarios, oil spills originating from the Huangdao Oil Port and Qianwan Port pose the greatest risks, with potential impacts extending up to 12 km and 15 km along the coastline, respectively. The study highlights the importance of considering multiple factors, including oil spill trajectories, coastal geomorphology, and ecological sensitivity, in comprehensive risk assessments. The proposed framework demonstrates potential for adaptation and application to other coastal regions facing similar oil spill risks, contributing to the advancement of coastal management practices worldwide. Full article

Different systems of fire protection coatings are used to protect the metal structures of stories and trestles at oil and gas facilities from low (when filling cryogenic liquids) and high temperatures (in case of the possible development of a hydrocarbon fire regime). This paper presents the results of experiments of fireproof coatings on an epoxy binder after the simulation of a liquefied hydrocarbons spill and subsequent development of a hydrocarbon fire regime at the object of protection and exposure of structures to a standard fire regime. According to the experimental results, the temperatures on the samples at the end of the cryogenic exposure were determined and the time from the beginning of the thermal exposure to the limit state of the samples at a hydrocarbon and standard temperature fire regime was determined. As a result, temperature–time curves in the hydrocarbon and standard fire regimes were obtained, showing good convergence with the simulation results. The solution of the inverse task of heat conduction using finite element modeling made it possible to determine the thermophysical properties of the formed foam coke at the end of the fire tests of steel structures with intumescent coatings. It was determined that an average of 12 mm of intumescent coating thickness is required to achieve a fire protection efficiency of 120 min and for the expected impact of the hydrocarbon fire regime, the coating consumption should be increased by 1.5–2 times compared to the coating consumption for the standard regime. Full article

In this work, we studied the potential of the visible, near-infrared, and shortwave infrared wavelength regions for monitoring oil spill incidents using optical reflectance. First, a simple physical model was designed for accurate oil thickness and volume estimation using optical reflectance. The developed method was made invariant to changes in acquisition and illumination conditions. In the next step, an algorithm based on an artificial neural network was designed to detect spilled oil. The training samples that are required to optimize the parameters of the network were generated by utilizing the proposed physical model. To validate the method, experiments were conducted in laboratory and outdoor scenarios for detection and thickness/volume estimation on four different oil types. In particular, we developed hyperspectral datasets of oil samples with varying thickness between 500 µm and 5000 µm acquired using two different sensors, an Agrispec spectrometer and an Imec snapscan shortwave infrared hyperspectral camera, in strictly controlled experimental settings. To demonstrate the potential of the proposed method in outdoor environments using solely the visible wavelength region, we monitored the evolution of artificially spilled oil in an outdoor scene with an RGB camera mounted on a drone. Full article

Remote sensing has been widely used for oil spill monitoring in open waters. However, research on remote sensing monitoring of oil spills in ice-infested sea waters (IISWs) is still scarce. The spectral characteristics of oil-contaminated sea ice (OCSI) and clean sea ice (CSI) and their differences are an important basis for oil spill detection using visible/near-infrared (VNIR) remote sensing. Such features and differences can change with the observation geometry, affecting the identification accuracy. In this study, we carried out multi-angle reflection observation experiments of oil-contaminated sea ice (OCSI) and proposed a kernel-driven bidirectional reflectance distribution function (BRDF) model, Walthall–Ross thick-Litransit-Lisparse-r-RPV (WaRoLstRPV), which takes into account the strong forward-scattering characteristics of sea ice. We also analyzed the preferred observation geometry for oil spill monitoring in IISWs. In the validation using actual measured data, the proposed WaRoLstRPV performed well, with RMSEs of 0.0031 and 0.0026 for CSI and OCSI, respectively, outperforming the commonly used kernel-driven BRDF models, Ross thick-Li sparse (R-LiSpr), QU-Roujean (Qu-R), QU-Lisparse R-r-RPV (Qu-LiSpr-RrRPV), and Walthall (Wa). The observation geometry with a zenith angle around 50° and relative azimuth ranging from 250° to 290° is preferred for oil spill detection in IISWs. Full article

The in situ measurement of thick oil slick thickness (>0.5 mm) and area in real time in order to estimate the volume of an oil spill is very important for determining the oil spill response strategy and evaluating the oil spill disposal efficiency. In this article, a method is proposed to assess the volume of oil slicks by simultaneously measuring the thick oil slick thickness and area using ultrasonic inspection and image processing methods, respectively. A remotely operated vehicle (ROV), integrating two ultrasonic immersion transducers, was implemented as a platform to receive ultrasonic reflections from an oil slick. The oil slick thickness was determined by multiplying the speed of sound by the ultrasonic traveling time within the oil slick, which was calculated using the cross-correlation method. Images of the oil slick were captured by an optical camera using an airborne drone. The oil slick area was calculated by conducting image processing on images of the oil slick using the proposed image processing algorithms. Multiple measurements were performed to verify the proposed method in the laboratory experiments. The results show that the thickness, area and volume of a thick oil slick can be accurately measured with the proposed method. The method could potentially be used as an applicable tool for measuring the volume of an oil slick during an oil spill response. Full article

Oil spills on the sea surface have caused serious harm to the marine ecological environment and coastal environment. Oil film thickness (OFT) is an important parameter for estimating oil spills amount, and accurate quantification of OFT is of great significance for rapid response and risk assessment of oil spills. In recent years, thermal infrared remote sensing has been gradually applied to quantify the OFT. In this paper, the outdoor oil spill simulation experiments were designed, and the bright temperature (BT) data of different OFTs were obtained for 24 consecutive hours in summer and autumn. On the basis of the correlation analysis of OFT and bright temperature difference (BTD) between oil and water, the traditional regression fitting model, classical machine learning model, ensemble learning model, and deep learning model were applied to the inversion of OFT. At the same time, inversion results of the four models were compared and analyzed. In addition, the best OFT inversion time using thermal infrared was studied based on 24-h thermal infrared data. Additionally, the inversion results were compared with the measured results; the optimal OFT range detectable using thermal infrared was explored. The experimental results show that: (1) Compared with ensemble learning model, traditional regression fitting model, and classical machine learning model, Convolutional Neural Network (CNN) has the advantages of high stability while maintaining high-precision inversion, and can be used as the preferred model for oil film thickness inversion; (2) The optimal time for OFT detection is around 10:00 to 13:00 of the day, and is not affected by seasonal changes; (3) During the day, thermal infrared has good detection ability for OFT greater than 0.4 mm, and weak detection ability for thinner oil films; (4) At night, thermal infrared has certain detection ability for relatively thick oil film, but the accuracy is lower than that in the daytime. Full article

The electromagnetic (EM) scattering mechanism of dynamic oil spill–covered sea surface area is studied in this manuscript. Utilizing the theory of oil film diffusion combined with oil spill volume, a three–dimensional (3D) geometric model of dynamic oil spill–covered sea surface area is established. The changes of the geometric structure and statistical characteristics of the sea surface area under the influence of the oil film are also analyzed. The thinner the oil spill thickness, the more sensitive it is to the sea surface slope and wave height. The facet-based hybrid model and the multilayer dielectric scattering method are combined to measure the EM scattering on the sea surface when covered by dynamic oil spills. In addition, the hydrodynamic and tilt effect are discussed. The EM scattering mechanism of the dynamic oil spill–covered sea surface area is revealed, and the tilt modulation is greater than the hydrodynamic effect in the dynamic process of an oil spill. It provides an important reference for the remote sensing monitoring of oil. Full article

Marine oil spills can cause serious damage to marine ecosystems and biological species, and the pollution is difficult to repair in the short term. Accurate oil type identification and oil thickness quantification are of great significance for marine oil spill emergency response and damage assessment. In recent years, hyperspectral remote sensing technology has become an effective means to monitor marine oil spills. The spectral and spatial features of oil spill images at different levels are different. To accurately identify oil spill types and quantify oil film thickness, and perform better extraction of spectral and spatial features, a multilevel spatial and spectral feature extraction network is proposed in this study. First, the graph convolutional neural network and graph attentional neural network models were used to extract spectral and spatial features in non-Euclidean space, respectively, and then the designed modules based on 2D expansion convolution, depth convolution, and point convolution were applied to extract feature information in Euclidean space; after that, a multilevel feature fusion method was developed to fuse the obtained spatial and spectral features in Euclidean space in a complementary way to obtain multilevel features. Finally, the multilevel features were fused at the feature level to obtain the oil spill information. The experimental results show that compared with CGCNN, SSRN, and A2S2KResNet algorithms, the accuracy of oil type identification and oil film thickness classification of the proposed method in this paper is improved by 12.82%, 0.06%, and 0.08% and 2.23%, 0.69%, and 0.47%, respectively, which proves that the method in this paper can effectively extract oil spill information and identify different oil spill types and different oil film thicknesses. Full article