Search Results (1,273)

Biofouling is an issue of global significance that impairs marine infrastructure, causes increased fuel consumption and greenhouse gas emissions, and threatens biodiversity. Since the year 2000, self-polishing copolymer (SPC) coatings and fouling release coatings (FRCs) dominate the fouling protection coatings market. SPC technology is based on the controlled release of biocides using a mixture of acrylic and natural binders as a delivery system. FRC technology is based on PDMS providing surface properties that resist attachment of fouling organisms. FRCs often contain surface modifying agents, such as free silicone oils, to tune the physicochemical properties of the surface. However, the long-term efficacy of these agents and their migration and distribution in PDMS-based coatings have not been well studied. In this study, we employed time-of-flight secondary ion mass spectrometry (ToF-SIMS) combined with multivariate analysis to examine the distribution of silicone oils as a function of exposure to artificial seawater (ASW). The results show that pure PDMS-based coatings allow uniform distribution of silicone oils with robust behavior upon ASW exposure. In contrast, epoxy–PDMS-based coatings displayed phase separation of the oils, which strongly altered their surface chemistry. Our findings suggest that the modification of mobile oils is critical to the performance of marine antifouling coatings. Furthermore, the presence of other ingredients of commercial coating formulations strongly affected the distribution of mobile oils. This study lays the foundation for future systematic research aimed at developing predictive models to optimize fouling protection coatings for the marine industry. Full article

Heavy oil and extra-heavy oil represent mobility-limited petroleum resources because supramolecular associations of asphaltenes and resins, together with strong interfacial resistance, generate extremely high apparent viscosity. In recent years, nanotechnology has emerged as a promising approach for viscosity management and enhanced oil recovery (EOR). This review critically examines recent advances in nano-assisted viscosity reduction from a reservoir-operational perspective and organizes the literature into two field-relevant categories: metal-based and non-metal nano-systems. Metal-based nanoparticles (NPs) mainly promote catalytic aquathermolysis and related bond-cleavage and hydrogen-transfer reactions under hydrothermal conditions, enabling partial upgrading and persistent viscosity reduction during thermal recovery. In contrast, non-metal nano-systems—particularly silica- and graphene-oxide-derived materials—primarily operate through interfacial and structural regulation mechanisms at low or moderate temperatures. These effects include wettability alteration, interfacial-film stabilization, modification of asphaltene aggregation behavior, and the formation of dispersed-flow regimes such as Pickering-type emulsions that reduce apparent flow resistance in multiphase systems. Beyond summarizing nanomaterial types, this review emphasizes reservoir-scale considerations governing field applicability, including brine stability, NPs transport and retention in porous media, and formulation compatibility. Comparative analysis highlights the distinct operational windows of thermal catalytic nano-systems and cold-production nano-systems, providing a reservoir-oriented framework for designing nano-assisted viscosity-reduction technologies. Full article

Climate change has adversely affected grain production and quality of canola, the second-largest oilseed crop, which contributes 13–16% of total vegetable oil. Multiple biotic and abiotic stresses significantly limit canola production due to rapid climate change, and conventional breeding alone is insufficient to meet global demand. Therefore, several advanced biotechnologies have been developed to cope with this change. Among these, genetic modification, gene editing, and RNA interference are particularly significant for rapid cultivar development in a cost-effective, efficient, and convenient way. Recent findings in gene editing applications have revealed “prospective sites”, highlighting regions amenable to precise editing without compromising canola plant growth or development. Pan-genome analyses have further guided gene editing target selection, enabling the validation of key stress-resilience genes across diverse canola cultivars, while the CRISPR-epigenetic regulatory connection enables targeted control of gene expression and trait modulation. A hypothetical application of genomic selection is also suggested, which could complement gene editing to accelerate the development of superior cultivars. Accordingly, this review focuses on the latest studies of genetic modification, gene editing, and RNA interference to strengthen canola resilience under rapid climate change and discusses the major concerns. Taken together, these genome-editing strategies offer precise approaches for improving biotic and abiotic stress tolerance, although careful consideration of both off-target effects and regulatory compliance remains essential for their practical implementation in canola improvement. Full article

Polyvinyl chloride (PVC) is widely used in engineering applications; however, its inherent thermal instability associated with dehydrochlorination limits its processing window and long-term performance. While blending with thermoplastic polyurethane (TPU) and plasticization are common strategies to improve flexibility, their combined influence on the thermal behavior and stability of PVC, particularly when bio-based plasticizers are employed, has not been thoroughly investigated. In this study, the thermal behavior and stability of PVC/TPU blends plasticized with glycerol diacetate monolaurate, a bio-based plasticizer derived from waste cooking oil, were investigated. Dynamic mechanical analysis (DMA) and Fourier transform infrared spectroscopy (FTIR) were used to examine segmental mobility and intermolecular interactions, while scanning electron microscopy (SEM) provided insight into microstructural organization. Thermal stability was evaluated through conductivity-based dehydrochlorination measurements, complemented by thermogravimetric and derivative thermogravimetric analyses (TGA/DTG) to assess degradation behavior. The results showed that neither TPU nor the bio-plasticizer alone improved the resistance of PVC to dehydrochlorination. In contrast, ternary PVC/TPU/bio-plasticizer blends exhibited a pronounced delay in HCl evolution, accompanied by a more homogeneous phase distribution and interaction-driven modification of the molecular environment. TGA/DTG analysis indicated that this stabilization arises from altered degradation kinetics rather than a simple shift in degradation onset. Overall, the findings clarify the thermal behavior of PVC-based blends and demonstrate a sustainable formulation approach for achieving flexible and thermally balanced PVC materials while reducing reliance on potentially toxic phthalate plasticizers. Full article

Sunflower oil is particularly prone to thermo-oxidative degradation due to its high content of polyunsaturated fatty acids, especially under high-temperature conditions. This study investigated the oxidative stability of sunflower oil heated at 180 °C for 4 and 8 h, focusing on the protective effect of silibinin oleate (SIL-O), a lipophilic polyphenolic derivative, compared to the synthetic antioxidant butylated hydroxytoluene (BHT). Oxidative changes were evaluated through peroxide value (PV), p-anisidine value (p-AV), and total oxidation value (TOTOX), while structural alterations were monitored using FTIR spectroscopy. Additionally, fatty acid composition was analyzed by GC-MS to assess compositional changes associated with oxidation. Thermal treatment led to increases in PV, p-AV, and TOTOX, indicating progressive oxidation, alongside a decrease in unsaturated fatty acids. FTIR analysis revealed characteristic changes, including a reduction in the unsaturation band (~3008 cm⁻¹), modifications in the ester carbonyl region (~1743 cm⁻¹), and the emergence of bands associated with cis–trans isomerization (~968–970 cm⁻¹). Strong correlations were observed between fatty acid degradation, FTIR indices, and oxidation parameters. Compared to the control, SIL-O inhibited oxidation in a dose-dependent manner. At 300 ppm, it outperformed BHT, demonstrating its potential as a natural antioxidant for enhancing the stability of sunflower oil during high-temperature processing. Full article

Zeolitic imidazolate framework-8 (ZIF-8) is one of the most extensively studied metal–organic frameworks due to its high surface area, tunable porosity, chemical stability, and intrinsic antimicrobial activity. Recent research has focused on engineering ZIF-8 through metal doping and surface functionalization to enhance its physicochemical performance and expand its applications in food safety and environmental systems. Metal-doped ZIF-8 incorporating Cu²⁺, Fe²⁺/Fe³⁺, Ag⁺, or Mn²⁺ improves reactive oxygen species generation, enables controlled metal-ion release, and promotes synergistic bactericidal mechanisms against both Gram-positive and Gram-negative pathogens. In parallel, surface modification using biopolymers such as hyaluronic acid, chitosan, alginate, and polyethylene glycol enhances colloidal stability, reduces cytotoxicity, modulates surface charge, and improves adhesion to food-contact surfaces, thereby enhancing coating stability and sustained antimicrobial activity. These combined strategies support the development of multifunctional nanoplatforms with improved dispersibility, controlled release behavior, and compatibility with food packaging, sanitization, and water treatment applications. From a sustainability perspective, ZIF-8-based systems offer the potential to reduce reliance on conventional chemical disinfectants, minimize chemical residues, and enable the integration of biodegradable polymer matrices for safer and more environmentally responsible antimicrobial solutions. This review summarizes recent advances in synthesis strategies, structure–property relationships, antimicrobial and antibiofilm mechanisms, and environmental safety considerations. Key challenges, including scalability, regulatory acceptance, stability, and long-term ecotoxicological impact, are discussed, along with perspectives on stimuli-responsive systems, essential oil encapsulation, and smart antimicrobial coatings. Full article

In a bid to investigate the optimum transportation method for offshore wind-produced hydrogen (H₂) and assess the feasibility of repurposing the existing oil and gas infrastructure for H₂ transmission, this paper assesses the existing H₂ transportation methods with a comprehensive review of the H₂ impact on the existing natural gas pipeline infrastructure. To establish the possibility of repurposing the existing natural gas (NG) pipelines for H₂ gas transport, this paper reviews the influential technical measures—composition, pressure, temperature, volumetric energy density, density, and pressure drop—to assess whether the characteristics of hydrogen gas are compatible with the natural gas pipeline infrastructure. Based on these reviews, it was found that the current NG pipeline pressure exacerbates the H₂ embrittlement; for the existing NG pipelines to be repurposed, the operating pressure should be reduced, and the pipeline material should be revised. It was found that higher strength steels can be re-used with major modifications, or the pipeline should be constructed from material grade X52 or below. Nevertheless, the fitness of the existing NG pipelines for H₂ transmission should be assessed on a case-by-case basis and other factors such as erosion, leakage, pressure cycling, monitoring (e.g., distributed fiber-optic sensing technology) and a rigorous assessment of welds and joints should also be considered. Full article

Plum pomace (PP), a key by-product of plum juice processing, is a rich yet underutilized source of dietary fiber. However, its high-value exploitation is severely limited by the lack of efficient extraction and modification technologies. This study optimized the extraction of soluble dietary fiber (SDF) and insoluble dietary fiber (IDF) from plum pomace (PP) via Design of Experiments (DOE), and evaluated their modification effects. Alkaline extraction was screened as the optimal method for IDF, and orthogonal experiments determined the optimal conditions: solid-to-liquid ratio 1:20 g/mL, 14 g/L NaOH, 60 °C, and 80 min, achieving a high extraction yield of 62.18%. For SDF, enzymatic extraction was superior, and response surface methodology (RSM) optimized the process to a solid-to-liquid ratio of 1:15.5, 1.0% enzyme dosage, 61.5 °C, and 92 min, with a yield of 29.3%. Physical, chemical, and biological modifications all significantly enhanced SDF’s water/oil-holding capacity, cholesterol/glucose adsorption capacity, and cation exchange capacity. Biologically modified SDF showed the most significant enhancement, with WHC of 5.58 ± 0.05 g/g, OHC of 4.38 g/g, CAC of 7.68 mg/g, and CEC of 3.28 mmol/g. These results provide technical support for the high-value utilization of PP and lay a foundation for its application in functional foods and nutraceuticals. Full article

The decarbonization of marine transport requires the wider use of alternative low-carbon fuels that can be applied in existing compression ignition (CI) engines without major modifications. Hydrotreated vegetable oil (HVO) is considered a promising renewable drop-in fuel due to its favorable physicochemical properties and high cetane number. This study investigates the influence of neat HVO and its blends with conventional diesel fuel on the combustion characteristics, energy, and emission indicators of a CI engine operating under different load conditions and exhaust gas recirculation (EGR) ratios. Experimental tests were carried out on a four-cylinder CI engine at constant speed and variable load using diesel fuel (D100), HVO100, and their blends (D80_HVO20 and D50_HVO50). In-cylinder pressure measurements and combustion analysis were performed using AVL instrumentation and AVL BOOST software. The results show that increasing the HVO fraction slightly advances combustion phasing and increases maximum in-cylinder pressure by approximately 4–5%. The use of HVO was found to reduce brake-specific fuel consumption by up to 3.4% and increase brake thermal efficiency by about 1.9%, although volumetric fuel consumption increases due to the lower fuel density. In addition, higher HVO content significantly reduces smoke opacity by up to 42% and decreases CO₂ emissions by 4.7–6.3%, while the influence on NO_x emissions depends on the applied EGR strategy. The results indicate that HVO and its blends can be effectively applied in CI engines; however, optimal performance and emission characteristics require appropriate calibration of EGR rate and fuel injection timing. Full article

To address critical challenges in marine oil spill remediation, including limited penetration of high-viscosity crude oil and inefficient adsorbent recovery, it is imperative to develop environmentally friendly materials integrating high-efficiency adsorption, in situ viscosity reduction, and controllable recovery. In this study, a delignified corn pith (CPDL) with a three-dimensional porous structure was employed as a green matrix. Through constructing a Fe₃O₄/expansible graphite (EG)/polyvinylidene fluoride (PVDF) composite functional coating combined with silanization modification, a multifunctional biomass-based oil sorbent (Fe₃O₄/EG/PVDF-CPDL) was successfully fabricated. The material maintains the inherent porous architecture while forming a stable micro/nano-rough surface, exhibiting excellent superhydrophobicity with a water contact angle of approximately 155°, and demonstrating exceptional stability in harsh acidic/alkaline/saline environments and multiple cycles. Benefiting from the synergistic photothermal effect of Fe₃O₄ and EG, under one sun illumination (1 kW/m²), the material surface temperature rapidly reaches above 80 °C within 100 s, reducing the viscosity of high-viscosity crude oil by over 95% (from 1.39 × 10⁵ to approximately 6.0 × 10³ mPa·s), thereby enabling rapid penetration and adsorption within 50 s. Moreover, the composite coating significantly enhances mechanical performance, achieving a compressive strength of 320 kPa (approximately eight times higher than that of the pristine substrate), ensuring structural integrity during handling and compression recovery. Meanwhile, the material demonstrates precise directional manipulation and efficient recovery through external magnetic fields due to its superior magnetic responsivity. Experimental results reveal a broad-spectrum adsorption capacity (14.8–30.2 g/g) and separation efficiency exceeding 96% after 20 adsorption–desorption cycles. In summary, this work presents an innovative strategy with significant application potential for efficient and controllable remediation of marine oil spills, particularly high-viscosity crude oil, by integrating synergistic functions of porous adsorption, superhydrophobic corrosion resistance, photothermal viscosity reduction, mechanical reinforcement, and magnetic control. Full article

Among the naturally abundant clays in the Earth’s crust, montmorillonite (MMT), a member of the smectite group, stands out for its versatility. Its interesting properties can be further improved by chemical processing with inorganic acids and reaction temperatures close to boiling. In this study, a Brazilian polycationic MMT was treated with a low-concentration (2M) aqueous solution of hydrochloric acid at 60 and 70 °C for 5 h. The resulting modified clay was then employed in the purification of post-consumption oil (PCO), specifically soybean oil. The effect of the modification variables of the clay and also the purification parameters (time and temperature) were investigated, comparing the adsorptive and purification capacities of the modified MMT with those of the natural and a commercial clay sample. The characterization of the MMT (raw and modified) was carried out by bulk density, moisture content, plasticity limit, BET, SEM/EDS, XRD, and FTIR, whereas the characterization of the PCO, as-received and after purification, involved the analyses of apparent density, relative flow time, UV-Vis spectrophotometry, and acid value. The results show that light acid activation, especially at 70 °C, promoted a significant increase in the surface area up to 96% and the adsorption capacity of the clay. The oil purification showed good results in all tests, with the best condition being 70 °C for 24 h with the C70 clay. Thus, the satisfactory results represent an economy of time and energy. Full article

Background: Disease outbreaks remain a major constraint on aquaculture production, making vaccination essential for disease management in farmed fish. However, injectable oil-adjuvanted vaccines can be costly and may induce adverse inflammatory reactions and welfare concerns, motivating investigations into alternative injectable adjuvant materials. Methods: We conducted an in vivo safety evaluation of shear-thinning, amidated TEMPO-oxidized cellulose nanofiber (TO-CNF) hydrogels formulated with an inactivated Vibrio anguillarum bacterin. Formulations were administered intraperitoneally to Atlantic salmon (Salmo salar L.) using a common garden design with cohabitated treatment groups across triplicate tanks. Fish were monitored and sampled at pre-injection baseline and at 300-, and 600-degree days post-injection. Safety endpoints included mortality, macroscopic and histopathological outcomes, and growth evaluated relative to sham controls, unmodified TO-CNF, and a commercial oil-adjuvanted vaccine. Results: Amidated TO-CNF formulations were associated with increased mortality (up to 16–18% in higher reagent-loading groups) compared to commercial oil-adjuvanted vaccine, material, and sham controls. Affected fish exhibited adverse outcomes, including adhesions, proliferative lesions, ascites, edema, hemorrhage, and secondary opportunistic infections. In contrast, controls showed minimal mortality and pathology. Growth and immune response endpoints were variable and did not demonstrate consistent treatment-associated effects. Physicochemical analyses indicated differences in formulation stability and qualitative compositional differences across modification levels, but these were not quantified nor linked to specific causal mechanisms in this study. Conclusions: The amidated TO-CNF formulations tested here were associated with formulation-dependent safety risks under the conditions evaluated and are not yet suitable as injectable vaccine adjuvants in Atlantic salmon. These findings define important safety constraints for this material class and highlight the need for improved modification and purification strategies. More broadly, this work underscores the importance of establishing in vivo safety boundaries prior to efficacy optimization for emerging biomaterial-based vaccine adjuvants. Full article

Amidst the high global reliance on petroleum, this study addresses energy inefficiency in beam-pumping units used for oil extraction. We developed a tubular solid–liquid triboelectric nanogenerator (TENG) based on fluorinated polydimethylsiloxane (PDMS) films. Self-assembled surface modification with fluorosilane molecular chains enhanced charge transfer, achieving a 2.7-fold increase with 13F-PDMS. The enclosed tubular design utilizes periodic liquid-electrode contact to generate a volumetric effect. Experiments investigated the influence of liquid composition and device configuration on performance. Using a 1.69 mol/L FeCl₃ solution with four series-connected units, the TENG reached 29 V and 263 nA, powering 150 LEDs. This demonstrates its potential for harvesting reciprocating mechanical energy from pumping units to reduce operational energy consumption. Full article

The wettability of nanopores in shale reservoirs is a critical factor governing the phase behavior and flow characteristics of light hydrocarbon fluids such as shale gas and shale oil. Controllable hydrophobic modification of silica-based materials is essential to accurately replicate oil–wet conditions under laboratory conditions. In this study, an orthogonal experimental design was used to systematically investigate the effects of two silane coupling agents, $\gamma$-methacryloxypropyltrimethoxysilane (KH570) and trimethylchlorosilane (TMCS), on surface hydrophobicity under varying modification temperatures, concentrations, reaction duration, and base materials. Three representative silica-based substrates with distinct particle sizes were subsequently subjected to hydrophobic treatment under optimized conditions. The results demonstrate that substrate surface characteristics significantly influence modification efficacy. High specific surface area was found to result in high hydrophobicity. The long-chain, multifunctional molecular architecture of KH570 proved advantageous for substrates with sparse surface reactive sites. These findings underscore that the compatibility between the molecular structure of the silane coupling agent and the physicochemical properties of the substrate surface is pivotal for achieving efficient hydrophobization. This work provides theoretical guidance for the tailored control of hydrophobic modification of silica-based materials and establishes a foundation for accurately simulating in situ oil–wet environments in laboratory studies. Full article

Synergistic diagenetic evolution of sandstones and shales significantly impacts the quality of associated tight oil and shale oil reservoirs. Using integrated petrographic (thin sections, fluorescence thin sections, scanning electron microscopy with energy dispersive spectroscopy), mineralogical (X-ray diffraction), geochemical (stable carbon–oxygen isotopes, electron microprobe), organic petrologic, and petrophysical analyses, combined with basin burial and thermal history reconstruction, this study investigates the mechanisms and processes of synergistic diagenesis in the tight sandstone-shale assemblages of the 7th and 8th Members of the Yanchang Formation (Middle-Late Triassic) in the western Zhidan area, Ordos Basin, China. Controlled by basin evolution, the interbedded sandstones and shales, under shared burial-thermal conditions, exhibit strong synergy in four coupled processes: compaction, clay mineral evolution, shale fluid expulsion coupled with sandstone carbonate cementation, and shale hydrocarbon expulsion coupled with sandstone secondary porosity generation. This “fluid supply-response modification” relationship strongly influences diagenetic pathways and reservoir space evolution in sandstones, leading to variable reservoir quality among different sandstone-shale assemblages. Thicker-bedded sandstones interbedded with thinner-bedded shales represent potential targets for high-quality tight sandstone reservoirs. These findings provide a possible theoretical and methodological basis for identifying high-quality tight sandstone reservoirs in lacustrine-deltaic sandstone-shale assemblages. Full article