Search Results (21)

Microencapsulated phase-change materials (MPCMs) with excellent thermal properties for low-temperature cold storage were developed in this study. Using 1-decanol as the core and methyl methacrylate as the shell precursor, the effects of emulsifier type and ultrasonic emulsification conditions were investigated. Styrene-maleic anhydride copolymer served effectively as a protective colloid emulsifier, producing MPCMs with high enthalpy and a well-defined, uniform microstructure. Under optimal conditions of 5 wt% emulsifier content relative to the oil phase, an ultrasonic power of 375 W, and an emulsification time of 12 min, the MPCMs exhibited a phase-change enthalpy of 126.7 kJ/kg. To further improve the thermal properties, a binary eutectic mixture was prepared by combining 1-decanol and 1-tetradecane at an optimal molar ratio (51.1:48.9). This binary-core MPCM showed a higher storage enthalpy (144.3 kJ/kg), with an increase of 13.9% compared to the single-core material (1-decanol). It also exhibited improved microstructural uniformity due to the stabilizing role of 1-tetradecane. These optimized MPCMs demonstrate phase-transition temperatures particularly suitable for low-temperature thermal storage, providing a practical and innovative technical solution for cold-chain logistics and vaccine refrigeration applications. Full article

Oleogels must replicate the rheological behavior of saturated fats at processing and consumption temperatures to maintain their physical stability and sensory acceptance. Thus, multicomponent oleogels present a promising approach since oleogelators can exhibit structuring and melting at different temperatures. The aim of the study was to produce a mixture of ultra-chain-long esters capable of structuring and modulating rheological behavior in response to temperature exposure. Therefore, enzymatic transesterification between sorbitol and fully hydrogenated crambe oil (FHCO) was performed to produce a mixture of ultra-long-chain sorbitan esters (SB) for efficient structuring of sunflower oil. SB generated in a reaction medium consisting exclusively of ethanol (60 °C, 200 rpm, 1:1 molar ratio) was selected for its high sorbitol consumption (~95%). While SB oleogels exhibited higher gel strength at 5 °C, at 25 °C, FHCO oleogels were stiffer, showing the gradual melting of SB oleogels evaluated by temperature-dependent rheological analyses and thermal properties. Oleogelation inhibited hydroperoxide formation compared to sunflower oil over 30 days. Results highlight the potential of multicomponent oleogels based on ultralong-chain esters for healthier and more stable high-lipid products. Modulating rheological thermoresponsiveness ensures physical stability under refrigeration while providing a texture similar to saturated fats during spreading and swallowing. Full article

This study characterized the quality of hemp oil (HO) and pumpkin seed oil (PO) and their blends before and after 2 and 4 months of storage at refrigerated and room temperature, without access to light and oxygen. The analyses included determining the acid value, peroxide value, fatty acid (FA) composition, and FA distribution in triacylglycerol (TAG) molecules. Pressure differential scanning calorimetry (PDSC) was used to assess the oxidative stability of oils and their blends. This study also evaluated the nutritional potential of hemp oil and pumpkin seed oil blends, as atherogenicity, thrombogenicity, and health-promoting indices and hypocholesterolaemic/hypercholesterolaemic ratio were calculated. The tested samples differed in properties depending on the storage time and temperature. The optimal choice was a blend of 50% hemp oil (HO) and 50% pumpkin oil (PO). This mixture demonstrated the desired fatty acid composition, satisfactory acid and peroxide values, and a relatively good oxidation induction time during storage. Despite the unfavorable distribution of FAs in TAG molecules, it was characterized by a balanced ratio of n-3 to n-6 acids. It was also concluded that research on HO and PO mixtures should be continued due to the potential synergistic effect of their bioactive substances. Full article

This article assesses the potential of using a diamond-like carbon coating doped with tungsten, a-C:H:W (WC/C), on the sliding pairs of refrigeration compressors. The ability of WC/C coating to provide low wear and a low coefficient of friction was experimentally verified in a specific refrigeration compressor operating environment (lubrication with oil diluted with refrigerant) and under extreme operating conditions (starved lubrication with a small amount of oil). Conditions of starved lubrication with a substance of reduced lubricity promote a temperature increase and high mechanical (friction) stresses on the surface of the sliding pairs. These situations can hinder the effective operation of WC/C coatings. Comparative wear tests were carried out for S235JR steel samples with and without WC/C coating. It was found that the samples with the WC/C coating had the lowest wear values and the lowest friction coefficients (approximately 0.06). A low coefficient of friction suggests that even a small amount of oil (one drop) is likely sufficient to achieve mixed lubrication conditions between the tested sliding surfaces and reduce material loss. The tested WC/C coating can protect sliding friction pairs in refrigeration compressors under extreme operating conditions caused by a lack of oil. Less friction reduces the need for energy to drive the refrigeration compressor. Additionally, the significance of this research is highlighted by the fact that the wear tests were conducted using R452A, a novel, eco-friendly refrigerant. Full article

Oil lubricates the contact between the orbiting and stationary scroll in the refrigerant scroll compressor, while the sealing between the scrolls is achieved through the refrigerant vapour pressure in the sealed back pressure chamber. The back pressure should be adjusted using the refrigerant oil two-phase flow from the oil separator at the compressor discharge to the back pressure chamber and the refrigerant oil flow from the back pressure chamber to the compressor suction side. Both of the flows are conducted through connecting tubes with corresponding high-pressure and low-pressure nozzles with small diameters. Models for predicting the refrigerant oil critical and subcritical flows through the nozzles were developed and applied in enable the prediction of the back pressure. The models are original, because the slip between the oil and the refrigerant as well as the refrigerant solubility in the oil are taken into account. The critical flow model is validated against the experimental data that are available in the literature. The back pressure is predicted by equating the mass flow rates of refrigerant and oil two-phase mixtures through the high- and low-pressure nozzles. The results show that the critical flow takes place through the high-pressure nozzle, while the subcritical flow through the low-pressure nozzle can also exist in cases with a small pressure difference between the back pressure chamber and the compressor suction side. The refrigerant solubility in the oil has a small influence on the critical and subcritical refrigerant oil mixture mass flow rates, while the influence on the back pressure is more pronounced. Full article

The effect of essential oils (EOs) incorporated in their vapor phase combined with lactic acid immersion pretreatment was studied on fresh refrigerated chicken breast shelf life. Among the several EOs assayed, the in vitro results obtained from the vapor diffusion test allowed mustard, oregano, and garlic EOs to be selected due to their higher antimicrobial activity. In addition, it was possible to determine the EO minimum inhibitory concentrations against Pseudomonas aeruginosa and Escherichia coli and to identify EO binary mixtures showing synergistic or additive effects. Based on the obtained results, a ternary mixture constituted by 0.073, 0.292, and 0.146 µL/mL of headspace of mustard, oregano, and garlic, respectively, was proposed for its application to chicken breasts. The ternary mixture inhibitory action was confirmed in vitro against P. aeruginosa and E. coli. Furthermore, the presence of numerous compounds with recognized antimicrobial and antioxidant activity was found in its volatile phase through gas chromatography. When applying an EO mixture in its vapor phase in combination with 1.0% v/v of lactic acid immersion pretreatment on refrigerated chicken breast, a decrease in mesophilic microorganisms’ growth rate as well as in lipid oxidation was observed. Moreover, in a preliminary sensory test, the treated chicken breast was found to be acceptable to consumers and showed no significant differences compared to untreated chicken. In conclusion, the combined use of lactic acid immersion and EOs in their vapor phase was an effective alternative to increase chicken breast shelf life. Full article

The expansion device is the critical component of micro-to-small scale organic Rankine cycle (ORC) systems, substantially affecting system efficiency and cost. Low isentropic efficiency and lubrication requirements are the main issues associated with using volumetric expanders in ORC systems. Despite lubrication contributing to reducing internal leakages in an expander, it may compromise the performance of the ORC system by adversely affecting the evaporator’s thermal capacity. This study tests a recently developed and modified revolving vane expander (M-RVE) in a micro-scale ORC test rig by implementing an adjustable oil mass flow rate. The impact of the lubricant oil on the performance of the M-RVE prototype is investigated within a wide range of oil circulation rates (OCR). The results demonstrate a negligible improvement in the filling factor for OCRs higher than 1%. Moreover, the shaft power is not considerably sensitive to OCR, while the calculated isentropic efficiency of the expander improves with OCR. Furthermore, the impact of the lubricant oil on the performance of the evaporator is studied, assuming the exact OCR as the expander and measured temperature and pressure similar to the pure refrigerant for the lubricant-refrigerant mixture in the evaporator. The study shows that the evaporator capacity is penalized with OCR, especially for values higher than 1%. Hence, an OCR of about 1% is a good compromise, and it can be used as a guideline for designing revolving vane expanders for micro-scale ORC systems without a dedicated lubricant oil circuit. Full article

These days, the low efficiency of solar-based thermal power plants results in uneconomical performance and high-cost uncompetitive industries compared with conventional fossil fuels. In order to overcome such issues, a novel combined cooling–power–heating (trigeneration) system is proposed and analyzed in this paper. This system uses an ammonia–water binary mixture as a working fluid and a solar heat source to produce diverse types of energy for a multi-unit building in a sustainable fashion. In addition to the basic cooling–power cogeneration cycle, a flashing chamber that will boost the flow rate of refrigerant without any additional heat supply is employed. By developing a mathematical model, the system performance is analyzed using varying parameters of solar irradiation, hot oil temperature, process heat pressure, and ambient temperature to investigate the influence on electrical power, cooling capacity, refrigeration exergy, energy utilization factor (EUF), and system exergy efficiency. Increasing direct normal irradiation (DNI) from 500 W/m² to 1000 W/m² reduces the system EUF and exergy efficiency from 53.62% to 43.12% and from 49.02% to 25.65%, respectively. Both power and refrigeration exergy increase with increasing DNI and ambient temperature, while heating exergy remains constant. It is demonstrated that of 100% solar energy supplied, 46.03% is converted into energetic output and 53.97% is recorded as energy loss. The solar exergy supplied is distributed into 8.34% produced exergy, 29.78% exergy loss, and the remaining 61.88% is the destructed exergy. The highest destruction of solar exergy (56.89%) occurs in the central receiver. Full article

This paper reports on the development of new emulsion gels containing a mixture of olive, chia and algae oil emulsified with soy protein isolate and stabilized by two different cold gelling agents, gelatin (EGEL) and chitosan (ECHIT), and to evaluate their potential use as pork backfat replacers in cooked pork patties. Reformulated patties were produced by half and full pork backfat replacement and compared to normal fat patties and reduced fat content patties made by replacing half of the added fat with water. Color parameters, pH and thermal stability of the emulsion gels were determined at processing and after 10 days of refrigerated storage. Proximate composition, fatty acid profile, technological properties and sensory attributes were evaluated after patty processing, while color parameters, pH and lipid oxidation were monitored in patties during 15 days of refrigerated storage (4 °C). Reformulated patties showed significant improvements of the lipid profile (lower saturated fatty acid content and n-6/n-3 ratio and higher long-chain polyunsaturated fatty acid content) as compared to the controls. In terms of technological properties, chitosan was more effective than gelatin as a stabilizer of the emulsion gel. All reformulated patties showed a good evolution of lipid oxidation during storage and acceptable sensory attributes. Full article

The application of nanofluids for enhancing the heat transfer rate is widely used in various heat exchanger applications. The selection of oil as the base to prepare nanofluids significantly enhances the thermal performance, due to its high heat carrying capacity as compared to conventional base fluid. A review is performed of various heat exchanger conduits having base fluid as nanoparticles with oil. It is reported that the heat transfer rate of a heat exchanger is significantly increased with the use of oil-based nanofluids. The rate of heat transfer depends on the type of nanoparticle, its concentration and diameter, the base fluid, as well as factors like the mixture of more than two nanoparticles (hybrid nanofluids) and stability. A review is also performed of the thermal performance of the different nanofluids analyzed by various investigators. The heat transfer system reviewed in this work includes triangular, square, and circular conduits, as well as rib surface conduits. The review of various applications viz. solar thermal systems, heat exchangers, refrigerators, and engines, is carried out where the inclusion of the oil base is used. It is reported that the amalgamation of the nanomaterial with the oil as base fluid is a prolific technique to enhance thermal performance. The performance of the reviewed research work is comparatively analyzed for different aspects viz. thermal oil, mineral oil, hybrid, and conventional nanoparticles, concentration of nanoparticles, etc. The novelty of the present work is the determination of the effective performing oil-based nanofluid in various applications, to figure out the selection of specific mineral oil, thermal oil, nanoparticle concentration, and hybrid nanofluids. Full article

The presented results show that the presence of refrigerant significantly deteriorates the lubricating properties of compressor oil under starved lubrication conditions (with a small amount of oil). The change can be 40–120% compared to the properties of the oil alone. Additionally, in the group of oils that are substitutes (operational alternatives) compatible with a given refrigerant, the effect of the refrigerant on the lubricating properties varies. The differences can be as much as 25%. In order to evaluate and properly select compressor oils for the refrigerant, the lubricating properties should be tested in a mixture with the refrigerant under conditions similar to actual operation. Such an evaluation of lubricating properties is made possible by the author’s method of testing the wear of the block-on-ring friction node. The obtained rankings of lubricating properties for oils (due to the wear volume) can provide good guidelines for the suitable selection of a lubricant for refrigeration compressors (especially for new, environmentally friendly refrigerants, such as R452A). The research was carried out for mixtures of zeotropic refrigerants (R404A, R452A) with polyester oils (POE) and natural refrigerant (R600a) with mineral oils (MO). In each group of refrigerants, different mechanisms of oil–refrigerant mixture formation occur. Each refrigerant was tested with three different compressor oils recommended for each other for alternative uses in refrigeration systems. Full article

To mitigate the damage of oil spills, a filter modified with a hydrophilic and oleophobic coating is proposed for affordable and efficient oil separation and recovery from water. The sol–gel method was chosen to produce a colloidal suspension of titanium dioxide particles for its ease of production and its versatility in application for many different substrates, including paper and cloth fabric. After immersing the substrates into a titanium-containing solution, three techniques were applied to increase the production of titanium dioxide—microwave-assisted, refrigeration, and ultra-sonication. Contact angle tests were done to investigate the change in the filter’s oleophobicity. The titanium dioxide present on the surface of the filter was amorphous, but all treatment methods showed an improvement in oleophobicity. All treated filters improved oil filtration performance by up to eighty percent. The filters isolated motor oil from a mixture while allowing water to pass through. The coated filters also displayed photocatalytic activity by degrading methylene blue on its surface when exposed to sunlight, demonstrating the filter’s self-cleaning ability. For real-world applications, the filter can be supported by a stainless mesh for enhanced strength and durability. While being dragged through the water, the filter collects the surface oil, allowing water to pass through via gravity. Full article

Liquid often exists in the accumulator of the rotary compressor during the process of startup or defrost of air-conditioning systems. Too much liquid entering the compressor cylinder would result in excessive pressure caused by the liquid compression, which is a great threat to the compressor. The liquid return through the liquid-return hole is the key to ensure the stable operation of the compressor. In this paper, the liquid-return characteristics in the liquid-return holes of the accumulator, including the mass-flow rate, liquid velocity and pressure difference between the liquid-return holes, during the startup process of the R290 rotary compressor are numerically investigated. The numerical simulation using the fluent volume of fluid (VOF) method was experimentally validated with the error of 1.55%. The comparison of liquid-return characteristics using different refrigerants is conducted. Effects of refrigerant solubility in the oil, refrigerant/oil-mixture type, liquid-return-hole diameter and compressor frequency on the liquid-return characteristics and liquid shape trough the liquid-return hole are discussed. The results show that the surface tension and viscosity of the liquid are the main factors affecting the liquid-return speed. The liquid-return rate of the refrigerant R290 is slower than that of other refrigerants R22 and R410A. The liquid-return rate increases with the increase in the compressor frequency. We conclude that for air-conditioning systems using R290 as refrigerant, increasing the number of return holes or the hole diameter is necessary to improve the liquid-return characteristics of the compressor. This research will provide theoretical guidance for the optimization of liquid return of rotary compressors using new refrigerants. Full article

In this study, the heat transfer performance of high-viscosity polyol ester (POE) oil POEA-220 (220 cSt) with low-GWP (global warming potential) refrigerant R-1234ze(E) on enhanced GEWA-B5H tube was investigated at saturation temperatures of 10 °C, 0 °C, and −6 °C. The mass fraction of oil varied from 0.25% to 10%, and all the nucleate pool boiling data were measured at heat fluxes ranging from 10 kW/m² to 90 kW/m². The experimental results showed that the heat transfer performance of the R-1234ze(E)/POEA-220 mixtures were superior to the R-1234ze(E)/POEA-68 mixtures. At saturation temperatures of 0 °C and −6 °C, even a 10% mass fraction of the POEA-220 oil showed an enhancement in the HTC (heat transfer coefficient) compared to the pure refrigerant in the moderate heat flux range. On the other hand, for the R-1234ze(E)/POEA-68 mixtures, a 5% mass fraction of oil showed no enhancement in the HTC compared to pure refrigerant at the same saturation temperature. Moreover, at low saturation temperatures (0 °C and −6 °C), the enhancement in the HTC decreased with increasing mass fraction of low-viscosity oil POEA-68, whereas high-viscosity oil POEA-220 showed the highest enhancement in the HTC for a 5% mass fraction of oil at −6 °C saturation temperature compared to the pure refrigerant. The results indicate that for nucleate boiling, the effect of oil viscosity on heat transfer performance is negligible if it contains comparatively high thermal conductivity and low surface tension. In addition, the effect of surface aging on heat transfer performance for the GEAW-B5H tube with pure refrigerant was also reported. Full article

Active edible films and coatings incorporating antimicrobial agents such as essential oils are studied to improve the shelf-life of fresh foods. The aim of this work was to study a mixture of sodium caseinate-chitosan (SC:CH), added with mesoporous silica nanoparticles filled with oregano essential oil (MSN-OEO), to produce an active edible coating for Panela cheese and to evaluate its properties during refrigerated storage for 15 days. The OEO was extracted by hydrodistillation and was incorporated into the MSN. Films based on SC:CH of 4:1 and 8:1 ratios with and without MSN-OEO were produced and the mechanical, barrier, physicochemical and microbiological properties of the films were evaluated. The SC:CH 8:1 ratio (w/w) with MSN-OEO showed reduced mean particle size (764.8 ± 23.3 nm), and a stable solution (zeta potential = 29.9 ± 1.1 mV). The thickness and solubility were influenced by the incorporation of MSN-OEO making it thinner and less soluble. Panela cheese samples were coated by the spray method using the SC:CH 8:1 containing MSN-OEO film forming solution. The final pH of the control cheese was 0.5 units lower than that of the coated cheese, whereas final moisture loss of the control cheese was 4.2 times that of the coated cheese. The mesophilic aerobic bacteria and of molds and yeasts populations achieved a reduction of about 2 Log₁₀ UFC/g after 15 days of storage. Due to microbial growth delay, and little moisture loss, this active coating may improve the quality and safety of Panela cheese. Full article