Search Results (1,654)

As a typical mountain ecosystem in the western Tianshan Mountains, the Ili River Valley possesses abundant vegetation resources. Soil nematodes are effective biological indicators for evaluating soil micro-food webs. Nevertheless, the response mechanisms of nematode community structure to distinct vegetation types, especially native trees and forest-edge shrubs, remain poorly understood in this region. In this study, two dominant tree species (Picea schrenkiana and Malus sieversii) and two forest-edge shrub species (Berberis heteropoda and Berberis sibirica) were investigated. We analyzed the composition, diversity, and energy structure of rhizosphere soil nematodes and further compared their differences among plant species. The results indicated that tree rhizospheres had significantly higher amounts of nitrate nitrogen ($\mathrm{N}{\mathrm{O}}_3^{-}$-N and microbial biomass carbon (MBC), along with a lower amount of extractable organic carbon/extractable total nitrogen (EOC:ETN) than shrub rhizospheres (p < 0.05). Picea schrenkiana (PS) exhibited greater root carbon storage, higher root biomass, and a higher root carbon-to-nitrogen ratio (RC:RN) than Berberis heteropoda (BH) and Berberis sibirica (BS) (p < 0.05). The genus Chiloplacus dominated the nematode community across all four woody plants. The relative abundance of omnivore-predatory nematodes was markedly higher in shrubs (BH and BS) than in trees (PS and MS). The soil food webs of PS and MS were degraded, whereas shrub food webs were in a transitional state between structured and degraded habitats. Shrubs presented a higher maturity index, structural metabolic footprint, and energy flux of omnivore-predatory nematodes, but a lower energy flux of bacterivorous nematodes. Additionally, PS had the highest nematode carbon use efficiency (NCUE) and the lowest energy flux uniformity (U). $\mathrm{N}{\mathrm{O}}_3^{-}$-N extractable total nitrogen (ETN), soil organic carbon (SOC), and root traits were the primary factors driving variations in nematode communities and carbon indicators. Therefore, nematode carbon indicators closely associated with soil carbon and nitrogen cycling have the potential to serve as sensitive auxiliary biological metrics for evaluating material cycling and energy flow in pure forests and shrub ecosystems. This study provides empirical support for the assessment of regional ecosystem stability. Full article

This study evaluates the environmental performance of 34 single-engine light utility helicopters across five operational phases: ground idle departure, ground idle arrival, takeoff, approach, and landing-takeoff (LTO). A hybrid multi-criteria decision-making (MCDM) framework integrating interval type-2 fuzzy sets with the Analytic Hierarchy Process (AHP), VIKOR, and TOPSIS was applied to ensure robust and reliable assessment. Six criteria: shaft horsepower (SHP), fuel flow, hydrocarbon (HC), carbon monoxide (CO), particulate matter (PM), and nitrogen oxides (NOx) were considered to capture both engine performance and environmental impact, with relative importance determined through AHP. VIKOR generated a compromise ranking, while TOPSIS validated the results. The analysis revealed that the HUGHES 500 (DDA250-C18, A34), HUGHES 501 (DDA250-C20B, A29), and BELL 206B-1 (DDA250-C20, A32) engines achieved the best environmental performance due to low fuel consumption and reduced emissions across NOx, PM, HC, and CO. In contrast, engines such as K-1200 (T53 17A-1, A1) and BELL UH-1H (T53 L13, A2) performed the poorest, with high fuel flow and elevated emissions. Sensitivity analysis showed minimal changes in rankings when the NOx weight was varied, confirming the robustness of the framework. These results highlight that emissions and fuel efficiency are more critical than engine power in determining environmental sustainability. Full article

This study investigated spring water in the core area and buffer zone of the Shibing Dolomite Karst World Heritage Site using one-year monthly monitoring, hydrochemistry, nitrate dual isotopes, and the MixSIAR model. The buffer zone spring exhibits shallow fissure-conduit flow with rapid hydrological response, anthropogenic nitrate dominance (>62%), nitrification as the main process, and limited denitrification. Its nitrate concentration shows seasonal peaks. In contrast, the core area spring is recharged by deep fissure water, with natural nitrate sources (>80%), stable nitrate levels (5–7.4 mg/L), and potential local denitrification. Nitrogen export in the buffer zone increases 4.5 times in the rainy season (NO₃⁻ accounting for 93% of TN). The core area shows higher TN export flux per unit area (3.34 vs. 0.4 g/m²/a) and greater DON proportion. Nitrogen export far exceeds that from rocky desertified areas, suggesting that dissolved nitrogen leaching drives karst rocky desertification evolution. Full article

To address the cross-sensitivity and non-linear coupling issues caused by the coexistence of hydrogen, carbon monoxide, ammonia, and nitrogen dioxide in industrial environments, a flow-through quantitative detection system based on a MEMS gas sensor array was designed and constructed. The steady-state peak sampling method was employed for feature extraction from high-dimensional time-series data, and regression prediction models were developed using a traditional BP neural network and BP neural networks optimized by four swarm intelligence algorithms (ALA, AOO, SFOA, and SDO). The experimental results indicate that the intelligent optimization algorithms excel in decoupling the “cross-response” phenomenon, with all optimized models outperforming the traditional BP network. Among them, the SDOBP (Sledge Dog Optimizer-BP) model demonstrated the best overall performance, achieving the highest accuracy in carbon monoxide and hydrogen detection, with the Root Mean Square Error for hydrogen reduced to 2.17, an 84.2% improvement over the traditional model. The system achieves high-precision quantitative inversion of multi-component gases in complex environments, providing an effective means for industrial environmental safety monitoring. Full article

A 14-year-old spayed female Maltese dog presented with hematuria, pollakiuria, decreased urine volume per voiding, and prolonged urination time, and was diagnosed with multifactorial urinary obstruction involving suspected trigonal neoplasia and extensive urolithiasis affecting the kidneys, ureters, bladder, and urethra. Diagnosis was based on serum biochemical analysis, radiography, and ultrasonography, which revealed diffuse urolithiasis, urethral involvement, and a trigonal mass consistent with a suspected neoplastic lesion. Due to the multifocal nature of obstruction, surgical management was considered impractical. The patient underwent urethral stent placement as a minimally invasive palliative intervention. Following the procedure, rapid restoration of urine flow was achieved, and significant improvement in renal parameters, including blood urea nitrogen and creatinine, was observed within 3 days. During follow-up, the stent remained well positioned without migration. Although transient deterioration, including hydronephrosis and increased renal parameters, was noted at day 52, subsequent improvement was observed by day 64, suggesting a dynamic course of obstruction. This case demonstrates that urethral stenting can be an effective treatment option for managing complex, multifactorial lower urinary tract obstruction in dogs, providing rapid clinical improvement and sustained urinary patency. However, progressive changes in the upper urinary tract may occur, emphasizing the importance of comprehensive evaluation and continuous monitoring. Full article

To address the problems of short-circuit flow and dead zones, complicated operation and control caused by intermittent influent, and the mismatch between aeration rate and oxygen demand in the Cyclic Activated Sludge System (CASS), a novel Multi-Compartment Fixed-Biofilm Cyclic Activated Sludge System (MCFCASS) was developed. This system operated in continuous-flow mode, and the aeration rate of each compartment was redistributed using a mathematical model. The results show that the plug flow ratio of the MCFCASS reactor increased from 18.75% to 31.25% compared with the CASS reactor. After aeration rate redistribution, the average total nitrogen (TN) removal efficiency of the MCFCASS reactor rose from 83.34% to 86.80%, and the effluent TN concentration consistently met the Grade I-A limit (15 mg/L) specified in the Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB 18918-2002). The average removal efficiencies of chemical oxygen demand (COD) and ammonium nitrogen (NH₄⁺-N) increased from 91.58% and 93.39% to 92.98% and 94.57%, respectively. Microbial community analysis revealed that after aeration rate redistribution, the relative abundances of Pseudomonadota, Bacteroidota, and Bacillota in the pre-reaction zone of MCFCASS were 39.17%, 17.78%, and 10.33%, respectively. In addition, the abundances of some functional bacterial groups in the first and fourth compartments of the main reaction zone shifted adaptively in response to the aeration rate redistribution, consistent with the trends in pollutant removal contributions in these compartments. Hierarchical clustering and principal coordinate analysis (PCoA) further indicated that aeration rate redistribution influenced the microbial community structure. The above laboratory-scale optimization results may provide a preliminary reference for aeration control and improvement of denitrification performance in similar processes. Full article

The Beijiang River Basin is an important ecological security protection area and water source supply area in Guangdong Province. This study assesses the spatiotemporal distribution characteristics of watershed water quality based on on-site monitoring data and multivariate statistical analysis. The results indicate that PO₄³⁻P concentrations peak during the flood season, whereas pH, NO₃⁻-N, and total nitrogen (TN) reach their highest levels during the autumn normal-flow period. Spatially, water quality follows a gradient of upstream > downstream > midstream, with the midstream region identified as the primary zone of water quality degradation. Future non-point source (NPS) pollution characteristics in the Beijiang River Basin are influenced by land use/cover change (LUCC) and climate change, showing significant variation across Shared Socioeconomic Pathway (SSP) scenarios. Under SSP126, precipitation increases at the slowest rate, with a peak annual value of 1599.77 mm during 2031–2040 and an average basin temperature of 19.61 °C. In contrast, SSP245 exhibits a marked increase in precipitation, reaching 1802.92 mm by 2061–2070. Under SSP585, annual precipitation rises to 2200.04 mm, with temperatures approximately 0.5 °C higher than those under SSP126. Simulations based on the improved ESP-PLUS model indicate that, under the natural development scenario (NDS), expansion of construction land increases urban runoff pollution by 32.97%. Under the economic development scenario (EDS), 1023 km² of ecological land is lost, significantly weakening pollution interception capacity, while construction land increases by 26.01%. In contrast, the coordinated development scenario (CDS) reduces ecological land loss by more than 60% compared to EDS through balanced development and conservation, thereby maintaining the basin’s pollutant purification function. Overall, future nitrogen and phosphorus loads in the watershed are projected to first decrease and then increase. Accordingly, differentiated management strategies are recommended, emphasizing the coordinated development of economic growth and ecological protection, and providing a scientific basis for controlling NPS pollution under changing climatic conditions. Full article

As climate change and air pollution problems become more serious around the world, regulations to reduce greenhouse gas emissions are being tightened. The International Maritime Organization (IMO) has adopted measures to limit sulfur oxides and nitrogen oxides generated by ships. Due to the continuous use of fossil fuels, carbon dioxide emissions are increasing rapidly, which is acting as a major cause of global warming and climate change. Currently, the carbon neutrality policy to reduce greenhouse gases emitted by ships is expanding, and the use of alternative energy from marine fuels is increasing worldwide. The shipbuilding industry is actively introducing eco-friendly ships that use liquefied natural gas (LNG) fuels, and the importance of equipment such as the Fuel Gas Supply System (FGSS), which can supply eco-friendly energy, is growing. In this study, we designed a Gas Valve Unit (GVU), one of the FGSS components, and analyzed the internal flow of the GVU by performing computational fluid dynamics (CFD) simulations. Full article

Constructed wetlands offer a sustainable, decentralized solution for wastewater treatment and reuse in Morocco. This study evaluated mesocosm-scale advanced vertical flow constructed wetlands (AVFCWs) incorporating locally sourced reactive media to assess phosphate mining residues as a novel substrate. Accordingly, four configurations were compared: a sand-based control (CW-A) and three amended systems combining pozzolan with phosphate mining residues (CW-B), clay (CW-C), and biochar (CW-D), operated in batch mode under hydraulic retention times (HRTs) of 24, 48, and 72 h. The incorporation of reactive media significantly improved treatment efficiency, with CW-D achieving high removal efficiencies across most parameters. COD and TSS removal reached 80% and 88%, respectively, while nitrogen removal exceeded 82% in optimal configurations. Phosphorus removal reached 76% in CW-B and 88% in CW-C. The removal of Cd and Cu exceeded 85% in all systems, with phosphate mining residues demonstrating strong potential for metal immobilization. However, despite these high removal efficiencies, the treated effluent did not meet Moroccan reuse standards for cadmium and fecal coliforms, indicating that single-stage AVFCWs are insufficient for safe agricultural reuse and require additional polishing steps. Extended HRT improved AVFCWs’ performance, but increased water loss, reaching up to 28% due to evapotranspiration. Hence, phosphate mining residues emerge as a promising substrate, pending further optimization, while supporting circular economy objectives. Full article

Mercury ion, a highly toxic and bioaccumulative heavy metal pollutant, poses significant risks to human health and ecosystems even at trace concentrations. Therefore, the development of highly sensitive and selective analytical methods for mercury ions is critically important to safeguard environmental integrity and human health. In this work, 4-mercaptopyridine-functionalized gold nanoparticles (4-MPY-AuNPs) were synthesized and subsequently immobilized onto quartz slides to fabricate a localized surface plasmon resonance (LSPR) sensor. Exploiting the selective coordination interaction between the pyridyl nitrogen atoms of 4-MPY and Hg²⁺, this LSPR sensor enables highly specific detection of Hg²⁺. Moreover, injecting a trace amount of 4-mercaptopyridine-functionalized AuNPs into the flow cell triggers the in situ formation of a surface-confined AuNP–Hg²⁺–AuNP sandwich architecture, thereby enhancing the sensor’s sensitivity. Under the optimized conditions, the proposed method exhibited a linear dynamic range of 1 × 10⁻⁹–6 × 10⁻⁷ mol L⁻¹, with a correlation coefficient (R²) of 0.9917 and a limit of detection (LOD) of 3.2 × 10⁻¹⁰ mol L⁻¹; the LOD of this method is one order of magnitude lower than the LODs reported in contemporary Hg²⁺ detection methods. This method exhibits high selectivity, sensitivity, cost-effectiveness, and is label-free, thereby demonstrating significant potential for environmental applications. Full article

Optimizing nutrient uptake efficiency (NUE) through an understanding of system-level dynamics and crop-specific physiological thresholds is essential for the resilience of North European vegetable production under shifting climatic conditions. This study evaluated the uptake and efficiency of macro- and secondary nutrients (N, P, K, Ca, Mg) in cabbage, carrot, red beet, and onion over a five-year period (2021–2025) in Latvia, comparing organic and integrated management systems. It was hypothesized that NUE on commercial farms is currently suboptimal due to standardized bulk applications and that systems integrating sustainable practices would demonstrate higher nutrient uptake efficiency than those relying exclusively on mineral fertilization. The results revealed a notable yield–input divergence, where increased fertilization rates failed to provide proportional yield gains, as evidenced by the lack of a strong linear relationship (R² < 0.07) and variable correlation coefficients (e.g., r = 0.52 for N in cabbage and r = −0.47 for Ca in carrot). These findings suggest that abiotic stressors and technical constraints may outweigh the influence of nutrient volume alone. This divergence was less pronounced in organic farming systems compared to integrated ones and varied notably by crop. Such species-specific responses indicate a complex role for mineral nutrition in root crops that requires further physiological investigation. No consistent differences in nutrient concentrations were observed between farming systems, indicating that inter-annual climatic variability is the dominant driver of nutrient dynamics. Furthermore, the integration of green manures and supplemental irrigation triggered extreme apparent system-level N-NUE values (exceeding 500% in some cases), reflecting the successful mineralization of legacy nitrogen and enhanced mass flow to the root zone. The study concludes that current fertilization methodologies in the Baltic region may lead to over-application. To ensure climate-resilient horticulture, management strategies must transition toward balancing ionic ratios (Ca:K) and synchronizing inputs with specific crop removal rates, rather than relying on standardized bulk applications. Full article

Hydrogen (H₂) storage in subsurface formations has recently gained attention as a promising large-scale energy storage solution. Although previous studies have revealed distinct displacement behaviors between H₂ and other gases such as nitrogen (N₂) and carbon dioxide (CO₂) in high-permeability sandstones, the mechanisms governing H₂ migration in tight formations remain largely unexplored. To provide experimental observations that may help improve the understanding of H₂ migration in tight reservoirs, we conducted H₂ flooding experiments on a tight sandstone sample from the Ordos Basin under pore fluid pressures of 0.5, 1, and 2 MPa. Dynamic core flooding processes were monitored using a low-field nuclear magnetic resonance (NMR) analysis system. The capillary number (Nc) in this work ranged from 1.7 × 10⁻⁹ to 3.4 × 10⁻⁹, indicating a capillarity-dominated flow. H₂ saturation in the tight sandstone increased from 41.9% to 53.3% and then to 57.7% with increasing pore fluid pressure. Under a pore fluid pressure of 0.5 MPa, H₂ initially displaced water in small pores (T₂ < 10.5 ms), leading to prolonged fluctuations in water content over 136 min before significant displacement occurred in large pores (10.5 ms < T₂ < 6579.3 ms). In contrast, at a pore fluid pressure of 2 MPa, the water in large pores was more significantly impacted, with a marked decrease in water saturation observed after 8 min of flooding. These findings provide direct experimental evidence of pressure-dependent and pore-scale selective displacement patterns of H₂ in tight sandstone, offering new insights into the fluid dynamics that control hydrogen injectivity and storage efficiency in low-permeability reservoirs. Full article

This work focused on the Xinghua River, a typical urbanizing river, to investigate how different anthropogenic activities affect the composition, sources, and environmental impact of dissolved organic matter (DOM) during urbanization. Using fluorescence spectroscopy combined with multivariate statistics, we systematically explored DOM characteristics and their response to urbanization. A total of four fluorescent components were identified, including protein-like components C1 and C3, and humic-like components C2 and C4, with protein-like substances constituting the major fraction of DOM. Fluorescence indices indicated that DOM in the Xinghua River was primarily derived from autochthonous sources (FI > 1.9), with a low degree of humification reflecting the dominance of fresh organic matter input during urbanization. Spatial analysis revealed that from upstream to downstream, the source of DOM gradually shifted from autochthonous dominance to increased allochthonous input, accompanied by increasing trends in both protein-like and humic-like components, indicating an accumulative effect of anthropogenic activities along the river. 2D-COS further revealed that the transformation sequence of DOM components along the flow direction was C3 → C1 → C4 → C2, suggesting that tyrosine/tryptophan-like substances were the most sensitive to anthropogenic disturbance. Redundancy analysis identified total phosphorus (TP), total dissolved solids (TDS), and permanganate index (COD_Mn) as the key environmental factors influencing DOM distribution, highlighting the synergistic regulatory roles of nitrogen and phosphorus nutrients and organic pollution loads on DOM composition. This study not only elucidates the gradient effects of human activities on DOM in the Xinghua River but also provides a scientific basis for water management in urban rivers worldwide, particularly for zone-based control and source-oriented management. Full article

Atlantic salmon (Salmo salar) is highly perishable during refrigerated storage due to the formation of off-odor volatile compounds that limit shelf life and consumer acceptance. This study investigated the development of off-odor volatiles in Atlantic salmon fillets during refrigerated storage and evaluated how rearing conditions influence storage-induced volatile formation. Salmon reared under warm (20.3 ± 1.95 °C with continuous light) or cool (13.1 ± 0.85 °C with a 12 h light–12 h dark cycle) conditions were harvested, stored at 4 ± 1 °C, and analyzed at 0, 3, 7, 9, and 15 days using selected-ion flow-tube mass spectrometry (SIFT-MS). Refrigerated storage was the primary driver of volatile formation, with lipid-derived aldehydes and alcohols forming early, followed by additional oxidation products as deterioration progressed, and finally, terminal oxidation products. These findings demonstrate distinct temporal pathways of off-odor volatile formation during refrigerated storage, linking early-stage oxidation of polar lipids, mid-stage involvement of neutral lipids, and late-stage accumulation of terminal and microbial products. Protein-derived volatiles exhibited compound-specific behavior, with reactive sulfur- and nitrogen-containing compounds increasing early or mid-storage and microbial metabolites accumulating steadily over time. Environmentally derived off-odor compounds, including geosmin and 2-methylisoborneol, were progressively released during storage as lipid structures degraded. Warm-reared salmon consistently exhibited higher concentrations of lipid- and protein-derived volatiles, indicating greater oxidative and proteolytic susceptibility. Rearing conditions modulate the extent but not the progression of these spoilage mechanisms. This mechanistic understanding provides a basis for targeted strategies to control off-odor volatile compound development and improve refrigerated shelf life and sensory quality of Atlantic salmon. Full article

Large wastewater treatment plants (WWTP) are increasingly supplemented with quaternary treatment. Classical monitoring hereby relies mostly on the measurement of oxygen demand, micropollutants and the nutrients phosphorus and nitrogen. From a microbiological perspective, relevant parameters to assess treatment performance include the removal efficacies of the fecal gene load as a proxy of pathogenic risk, antibiotic resistance genes and the bacterial regrowth potential. For this purpose, a combination of flow cytometry and quantitative PCR, together with a viability assessment, was applied to characterize a full-scale pilot plant. The pilot plant comprised conventional treatment and MBR and ozonation for advanced treatment. The assessment of fecal gene load was based on the quantification of Bacteroidales of human origin, as these obligate anaerobic bacteria cannot replicate within wastewater treatment plants. Whereas conventional treatment resulted in only moderate removal of these parameters, quaternary treatment typically led to a much stronger decrease. MBR treatment contributed most strongly to the removal with an appr. 6 log reduction compared to the primary clarification effluent, corroborating its microbiological merit for wastewater treatment. In addition to removing microorganisms and their genetic content, data also suggested a 95% reduction in extracellular DNA. Ozonation further enhanced microbiological removal. From an analytical perspective, the study shows the added value of using a long amplicon qPCR approach together with sample treatment with a viability dye to minimize false-positive signals and to avoid underestimation of treatment performance. The chosen diagnostic approach shows promise in assessing the microbiological treatment efficacy of WWTPs and as a basis to decide on the microbiological necessity of treatment upgrades. Full article