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Keywords = new capacitive load

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19 pages, 3483 KiB  
Article
Preparation of CF-NiO-PANI Electrodes and Study on the Efficiency of MFC in Recovering Potato Starch Wastewater
by Yiwei Han, Jingyuan Wang, Liming Jiang, Jiuming Lei, Wenjing Li, Tianyi Yang, Zhijie Wang, Jinlong Zuo and Yuyang Wang
Coatings 2025, 15(7), 776; https://doi.org/10.3390/coatings15070776 - 30 Jun 2025
Viewed by 230
Abstract
Microbial Fuel Cell (MFC) is a novel bioelectrochemical system that catalyzes the oxidation of chemical energy in organic waste and converts it directly into electrical energy through the attachment and growth of electroactive microorganisms on the electrode surface. This technology realizes the synergistic [...] Read more.
Microbial Fuel Cell (MFC) is a novel bioelectrochemical system that catalyzes the oxidation of chemical energy in organic waste and converts it directly into electrical energy through the attachment and growth of electroactive microorganisms on the electrode surface. This technology realizes the synergistic effect of waste treatment and renewable energy production. A CF-NiO-PANI capacitor composite anode was prepared by loading polyaniline on a CF-NiO electrode to improve the capacitance of a CF electrode. The electrochemical characteristics of the composite anode were evaluated using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), and the electrode materials were analyzed comprehensively by scanning electron microscopy (SEM), energy diffusion spectrometer (EDS), and Fourier transform infrared spectroscopy (FTIR). MFC system based on CF-NiO-PANI composite anode showed excellent energy conversion efficiency in potato starch wastewater treatment, and its maximum power density increased to 0.4 W/m3, which was 300% higher than that of the traditional CF anode. In the standard charge–discharge test (C1000/D1000), the charge storage capacity of the composite anode reached 2607.06 C/m2, which was higher than that of the CF anode (348.77 C/m2). Microbial community analysis revealed that the CF-NiO-PANI anode surface formed a highly efficient electroactive biofilm dominated by electrogenic bacteria (accounting for 47.01%), confirming its excellent electron transfer ability. The development of this innovative capacitance-catalytic dual-function anode material provides a new technical path for the synergistic optimization of wastewater treatment and energy recovery in MFC systems. Full article
(This article belongs to the Section Environmental Aspects in Colloid and Interface Science)
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10 pages, 28452 KiB  
Article
Highly Linear 2.6 GHz Band InGaP/GaAs HBT Power Amplifier IC Using a Dynamic Predistorter
by Hyeongjin Jeon, Jaekyung Shin, Woojin Choi, Sooncheol Bae, Kyungdong Bae, Soohyun Bin, Sangyeop Kim, Yunhyung Ju, Minseok Ahn, Gyuhyeon Mun, Keum Cheol Hwang, Kang-Yoon Lee and Youngoo Yang
Electronics 2025, 14(11), 2300; https://doi.org/10.3390/electronics14112300 - 5 Jun 2025
Viewed by 400
Abstract
This paper presents a highly linear two-stage InGaP/GaAs power amplifier integrated circuit (PAIC) using a dynamic predistorter for 5G small-cell applications. The proposed predistorter, based on a diode-connected transistor, utilizes a supply voltage to accurately control the linearization characteristics by adjusting its dc [...] Read more.
This paper presents a highly linear two-stage InGaP/GaAs power amplifier integrated circuit (PAIC) using a dynamic predistorter for 5G small-cell applications. The proposed predistorter, based on a diode-connected transistor, utilizes a supply voltage to accurately control the linearization characteristics by adjusting its dc current. It is connected in parallel with an inter-stage of the two-stage PAIC through a series configuration of a resistor and an inductor, and features a shunt capacitor at the base of the transistor. These passive components have been optimized to enhance the linearization performance by managing the RF signal’s coupling to the diode. Using these optimized components, the AM−AM and AM−PM nonlinearities arising from the nonlinear resistance and capacitance in the diode can be effectively used to significantly flatten the AM−AM and AM−PM characteristics of the PAIC. The proposed predistorter was applied to the 2.6 GHz two-stage InGaP/GaAs HBT PAIC. The IC was tested using a 5 × 5 mm2 module package based on a four-layer laminate. The load network was implemented off-chip on the laminate. By employing a continuous-wave (CW) signal, the AM−AM and AM−PM characteristics at 2.55–2.65 GHz were improved by approximately 0.05 dB and 3°, respectively. When utilizing the new radio (NR) signal, based on OFDM cyclic prefix (CP) with a signal bandwidth of 100 MHz and a peak-to-average power ratio (PAPR) of 9.7 dB, the power-added efficiency (PAE) reached at least 11.8%, and the average output power was no less than 24 dBm, achieving an adjacent channel leakage power ratio (ACLR) of −40.0 dBc. Full article
(This article belongs to the Section Microwave and Wireless Communications)
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10 pages, 4638 KiB  
Communication
Optimized Ferrite Loading Strategy for Standing-Wave Antenna Miniaturization: A New Paradigm
by Tong Wu, Weisen Guo, Xiaodong Yang and Zhiya Zhang
Electronics 2025, 14(10), 1968; https://doi.org/10.3390/electronics14101968 - 12 May 2025
Viewed by 355
Abstract
This communication introduces a novel antenna miniaturization approach by strategically loading ferrites in distinct near-field regions. By identifying electric (E)- and magnetic (H)-field dominant zones in the antenna near-field, region-specific ferrites are strategically selected: high permittivity (εr) materials for E-field zones [...] Read more.
This communication introduces a novel antenna miniaturization approach by strategically loading ferrites in distinct near-field regions. By identifying electric (E)- and magnetic (H)-field dominant zones in the antenna near-field, region-specific ferrites are strategically selected: high permittivity (εr) materials for E-field zones and high permeability (µr) materials for H-field zones. This strategy maximizes miniaturization while minimizing losses and the increase in antenna weight resulting from ferrite loading. To validate this method, a bent inverted-F antenna was designed and measured. The experimental results demonstrate that loading ferrites in E-field regions reduces the operating frequency from 2555–2620 MHz to 2230–2293 MHz with 68% efficiency, 20% higher than traditional full-coverage loading. Equivalent circuit analysis further reveals that selective loading increases capacitance/inductance for miniaturization while suppressing losses. This work establishes a new paradigm for a functional-material-based antenna design and offers a new research route for the fabrication of functional materials, aligning with 5G/6G demands for compact, integrated, low-loss systems. Full article
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16 pages, 4161 KiB  
Article
Use of Capacitive Probes to Detect Asymmetry and Earth Fault in a Medium-Voltage Power Network
by Krzysztof Walczak and Aleksandra Schött-Szymczak
Energies 2025, 18(9), 2254; https://doi.org/10.3390/en18092254 - 28 Apr 2025
Viewed by 297
Abstract
The detection of short circuits in a medium-voltage (MV) network is a complex issue due to the way the neutral point works. An additional difficulty is the relatively large load asymmetry. The methods used so far include complex equipment (e.g., a system of [...] Read more.
The detection of short circuits in a medium-voltage (MV) network is a complex issue due to the way the neutral point works. An additional difficulty is the relatively large load asymmetry. The methods used so far include complex equipment (e.g., a system of voltage transformers) for use mainly in power stations. The detection of short circuits deep in the network is therefore difficult, and this could facilitate the process of fault localization and limit the areas that should be disconnected for the time of fault removal. This article presents the new concept of using a system of capacitive probes as a simple and cheap tool that allows for the detection of a short circuit in an MV network based on the assessment of the zero-voltage component. This component is considered to be one of the basic starting criteria for various types of specialist earth-fault protections. Appropriately placed capacitive probes—through the existence of capacitive coupling with phase conductors—record the voltages of individual phases, including the total resultant voltage, which is the criterion for detecting a short circuit in the system. An important advantage of using such a solution is that capacitive probes allow for voltage measurement and assessment of line asymmetry in a non-contact and, therefore, safe manner. The presented concept has been tested in the laboratory and supported by simulation studies. The modeling of the system was based on the parameters of real structures used in overhead lines, recreated in laboratory conditions. Obtaining positive results of the simulation studies—primarily the appropriate sensitivity of short-circuit detection, confirmed in the laboratory—allows for the creation of a prototype of the device and the commencement of field tests, which will be the subject of further work conducted by the authors. Full article
(This article belongs to the Special Issue Innovation in High-Voltage Technology and Power Management)
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23 pages, 7767 KiB  
Article
Novel Real-Time Acoustic Power Estimation for Dynamic Thermoacoustic Control
by Eduardo Pilo de la Fuente, Jaime Gros, María Antonia Simón Rodríguez, Ana-Isabel Velasco and Carmen Iniesta
Appl. Sci. 2025, 15(5), 2838; https://doi.org/10.3390/app15052838 - 6 Mar 2025
Viewed by 631
Abstract
This paper presents a new procedure for the real-time processing and analysis of data from thermoacoustic systems. The approach focuses on continuously acquiring and adjusting measurements of acoustic wave pressure, enabling the instantaneous estimation of acoustic power. This is crucial for real-time control [...] Read more.
This paper presents a new procedure for the real-time processing and analysis of data from thermoacoustic systems. The approach focuses on continuously acquiring and adjusting measurements of acoustic wave pressure, enabling the instantaneous estimation of acoustic power. This is crucial for real-time control and decision-making, especially in applications that require rapid power estimation, such as the control loop implementation in thermoacoustic engines, where conditions are constantly changing and dynamic adaptation is essential. Two methods for estimating the power delivered to the load are proposed: (method 1) instantaneous power evaluation, which calculates the power consumed by the resistance in the resistance–capacitance (RC) load, and (method 2) one-period average power calculation using the well-established two-microphones method. These methods are validated with both different synthetic signals and experimental measurements. The results reveal that the new method provides real-time accurate estimations of the power delivered to the acoustic load and, thus, has shown potential for control-based applications. Full article
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16 pages, 3941 KiB  
Article
Facile Synthesis of Sandwich-Type Porous Structured Ni(OH)2/NCNWs/rGO Composite for High Performance Supercapacitor
by Xiaosen Duan, Mingyu Dou, Lingyang Liu, Long Zhang, Xianrui Bai, Ruixin Yang, Hengyi Wang and Jianmin Dou
Molecules 2025, 30(5), 1119; https://doi.org/10.3390/molecules30051119 - 28 Feb 2025
Cited by 1 | Viewed by 659
Abstract
Nickel hydroxide has ultra-high energy storage capacity in supercapacitors, but poor electrical conductivity limits their further application. The use of graphene to improve its conductivity is an effective measure, but how to suppress the stacking of graphene and improve the overall performance of [...] Read more.
Nickel hydroxide has ultra-high energy storage capacity in supercapacitors, but poor electrical conductivity limits their further application. The use of graphene to improve its conductivity is an effective measure, but how to suppress the stacking of graphene and improve the overall performance of composite materials has become a new challenge. In this work, a well-designed substrate of N-doped carbon nanowires with reduced graphene oxide (NCNWs/rGO) was fabricated by growing polypyrrole (PPy) nanowires between GO nanosheets layers and then calcining them at high temperatures. This NCNWs/rGO substrate can effectively avoid the stacking of rGO nanosheets, and provides sufficient sites for the subsequent in situ growth of Ni(OH)2, forming a uniform and stable Ni(OH)2/NCNWs/rGO composite material. Benefiting from the abundant pores, high specific surface area (107.2 m2 g−1), and conductive network throughout the NCNWs/rGO substrate, the deposited Ni(OH)2 can not only realize an ultra-high loading ratio, but also exposes more active surfaces (221.3 m2 g−1). After a comprehensive electrochemical test, it was found that the Ni(OH)2/NCNWs/rGO positive materials have a high specific capacitance of 2016.6 F g−1 at a scan rate of 1 mV s−1, and exhibit significantly better stability. The assembled Ni(OH)2/NCNWs/rGO//AC asymmetric supercapacitor could achieve a high energy density of 85.2 Wh kg−1 at power densities of 381 W kg−1. In addition, the asymmetric supercapacitor has excellent stability and could retain 70.1% of initial capacitance after 10,000 cycles. These results demonstrate the feasibility of using NCNWs/rGO substrate to construct high-performance supercapacitor electrode materials, and it is also expected to be promoted in other active composite materials. Full article
(This article belongs to the Section Electrochemistry)
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41 pages, 5611 KiB  
Article
An Annular Conductive Membrane-Based Hollow Capacitive Wind Pressure Sensor: Analytical Solution and Numerical Design and Calibration
by Jun-Yi Sun, Zhi-Qiang Yan, He-Hao Feng and Xiao-Ting He
Materials 2025, 18(5), 965; https://doi.org/10.3390/ma18050965 - 21 Feb 2025
Cited by 1 | Viewed by 375
Abstract
A novel hollow capacitive wind pressure sensor is for the first time proposed. The sensing element of the proposed sensor uses a non-parallel plate variable capacitor, whose movable electrode plate uses a transversely uniformly loaded annular conductive membrane with a fixed outer edge [...] Read more.
A novel hollow capacitive wind pressure sensor is for the first time proposed. The sensing element of the proposed sensor uses a non-parallel plate variable capacitor, whose movable electrode plate uses a transversely uniformly loaded annular conductive membrane with a fixed outer edge and a rigid inner edge (acting as the wind pressure sensitive element of the sensor). Due to the unique hollow configuration of the proposed sensor, it can be used alone to detect the pressure exerted by fast-moving air in the atmosphere or by fast-moving air or gas, etc., in pipes, but it also can be used in pairs to measure the flow rate of fast-moving air or gas, etc., in pipes. The analytical solution of the large deflection elastic behavior of the transversely uniformly loaded annular conductive membrane is derived by using a new set of membrane governing equations. The effectiveness of the new analytical solution is analyzed. The new membrane governing equations are compared with the previous ones to show the differences between them. The superiority of the new analytical solution over the existing ones is analyzed. An example is given to demonstrate the numerical design and calibration of the proposed sensor and the effect of changing design parameters on the important capacitance–pressure (Cq) analytical relationship of the proposed sensor is investigated comprehensively. Finally, an experimental verification of the analytical solution derived is carried out. Full article
(This article belongs to the Special Issue Materials and Machine Learning-Related Challenges for Sensors)
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12 pages, 7388 KiB  
Article
Piezoresistive, Piezocapacitive and Memcapacitive Silk Fibroin-Based Cement Mortars
by Daniel A. Triana-Camacho, Antonella D’Alessandro, Silvia Bittolo Bon, Rocco Malaspina, Filippo Ubertini and Luca Valentini
Sensors 2024, 24(22), 7357; https://doi.org/10.3390/s24227357 - 18 Nov 2024
Cited by 1 | Viewed by 988
Abstract
Water-stable proteins may offer a new field of applications in smart materials for buildings and infrastructures where hydraulic reactions are involved. In this study, cement mortars modified through water-soluble silk fibroin (SF) are proposed. Water-soluble SF obtained by redissolving SF films in phosphate [...] Read more.
Water-stable proteins may offer a new field of applications in smart materials for buildings and infrastructures where hydraulic reactions are involved. In this study, cement mortars modified through water-soluble silk fibroin (SF) are proposed. Water-soluble SF obtained by redissolving SF films in phosphate buffer solution (PBS) showed the formation of a gel with the β sheet features of silk II. Electrical measurements of SF indicate that calcium ions are primarily involved in the conductivity mechanism. By exploiting the water solubility properties of silk II and Ca2+ ion transport phenomena as well as their trapping effect on water molecules, SF provides piezoresistive and piezocapacitive properties to cement mortars, thus enabling self-sensing of mechanical strain, which is quite attractive in structural health monitoring applications. The SF/cement-based composite introduces a capacitive gauge factor which surpasses the traditional resistive gauge factor reported in the literature by threefold. Cyclic voltammetry measurements demonstrated that the SF/cement mortars possessed memcapacitive behavior for positive potentials near +5 V, which was attributed to an interfacial charge build-up modulated by the SF concentration and the working electrode. Electrical square-biphasic excitation combined with cyclic compressive loads revealed memristive behavior during the unloading stages. These findings, along with the availability and sustainability of SF, pave the way for the design of novel multifunctional materials, particularly for applications in masonry and concrete structures. Full article
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21 pages, 4318 KiB  
Article
Shear Force of Interior Beam–Column Joints under Symmetrical Loading with Two Transverse Forces on the Beam
by Albena Doicheva
Buildings 2024, 14(9), 3028; https://doi.org/10.3390/buildings14093028 - 23 Sep 2024
Cited by 2 | Viewed by 10009
Abstract
The beam-to-column connection is a particularly vulnerable element in frame structures under seismic action and is often responsible for building damages. Experimental investigations carried out over the past six decades on shear strength in frame joints have not led to the establishment of [...] Read more.
The beam-to-column connection is a particularly vulnerable element in frame structures under seismic action and is often responsible for building damages. Experimental investigations carried out over the past six decades on shear strength in frame joints have not led to the establishment of a uniform procedure in the design codes of different countries. The reason lies probably in the varied nature of the investigated parameters and in the varied configurations of beam–column connections. A good knowledge of the forces passing through the frame joints in the beam–beam and column–column direction would allow both their adequate computation in new buildings and the verification of existing ones without requiring experimental studies. In the design codes of the leading countries in seismic engineering, the shear force is determined by the capacitive method, considering only the area of the longitudinal reinforcement of the beam passing through the column. This method shows us how much shear force the beam reinforcement can take, but not what the magnitude of the resulting forces actually is as a result of the acting loads. In addition, the method of the codes does not indicate the contribution of the concrete to the total magnitude of the shear force in the beam–column connection. In the proposed mathematical model for calculating the forces that leave the beam, the full dimensions of the cross-section of the beam were taken into account. The material properties and cross-sectional shape were also taken into account. A determining factor for the magnitude of forces entering the beam–column joint is the acting load on the beam. In this paper, the load of two transverse forces was considered. The forces are applied in different possible positions, while remaining symmetrically located on the beam. The calculations are based on Menabrea’s theorem to determine the hyperstatic unknowns. The results of the proposed method for the considered beam show that the magnitude of the shear force differs from that accepted in the literature and the norms by 2% to 27%, depending on the stage of development of the crack. In comparison, the Eurocode-recommended method shows differences in the order of 27% to 40% for the adopted beam under static loads. Full article
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16 pages, 12492 KiB  
Article
The Development of a Novel Transient Signal Analysis: A Wavelet Transform Approach
by Eduardo Gómez-Luna, Dixon E. Cuadros-Orta, John E. Candelo-Becerra and Juan C. Vasquez
Computation 2024, 12(9), 178; https://doi.org/10.3390/computation12090178 - 3 Sep 2024
Cited by 3 | Viewed by 1790
Abstract
This paper presents a new method for the analysis of transient signals in the frequency domain based on the Continuous Wavelet Transform (CWT). The proposed case study involves test signals measured from an electronic switch considering open and close operations. The source is [...] Read more.
This paper presents a new method for the analysis of transient signals in the frequency domain based on the Continuous Wavelet Transform (CWT). The proposed case study involves test signals measured from an electronic switch considering open and close operations. The source is connected to inductive, resistive, and capacitive loads. Resonance behaviors are introduced and compared with the Discrete Fourier Transform (DFT). Multiple factors, such as reliability, repeatability, high noise attenuation, and the smoothing of the analyzed spectrum, are considered in this study. This proposed study highlights the effectiveness of CWT in signal processing, especially in obtaining a detailed spectrum that reveals the behavior of electrical circuits. Resonance behaviors were analyzed, demonstrating that the signal processing performed by CWT is better for spectrum analysis than DFT. This study shows the potential of CWT to analyze transient electrical signals, specifically for identifying and characterizing the behavior of load connections and disconnections. Full article
(This article belongs to the Section Computational Engineering)
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30 pages, 22313 KiB  
Article
Laplace Transform-Based Modelling, Surge Energy Distribution, and Experimental Validation of a Supercapacitor Transient Suppressor
by Sadeeshvara Silva Thotabaddadurage
Technologies 2023, 11(6), 173; https://doi.org/10.3390/technologies11060173 - 6 Dec 2023
Cited by 1 | Viewed by 3335
Abstract
The discovery of the transient-surge-withstanding capability of electrochemical dual-layer capacitors (EDLCs) led to the development of a unique, commercially beneficial circuit topology known as a supercapacitor transient suppressor (STS). Despite its low component count, the new design consists of a transient-absorbing magnetic core [...] Read more.
The discovery of the transient-surge-withstanding capability of electrochemical dual-layer capacitors (EDLCs) led to the development of a unique, commercially beneficial circuit topology known as a supercapacitor transient suppressor (STS). Despite its low component count, the new design consists of a transient-absorbing magnetic core which takes the form of a coupled inductor placed between the AC-main- and load-side varistors. With an introduction to the structural features of metal oxide varistors (MOVs), gas tubes, thyristors, and EDLCs, this research presents a frequency (S)-domain analysis of an STS circuit to accurately model the surge propagation through its coupled inductor. Transient energy distribution trends among STS components are estimated in this paper, with an emphasis on peak energies absorbed and dissipated by the various inductive, capacitive, and resistive circuit elements. Moreover, this study reveals STS transient-mode test waveforms validated by a standard lightning surge simulator with supporting simulation plots based on LTSpice numerical techniques. Both experimental and simulation results are consistent, with the analytical findings showing 90% of the peak transient propagating through the primary coil, whereas only 10% is shared into the secondary coil of the coupled inductor. In addition, it is proven that the two STS MOVs dissipate over 50% of the transient energy for a standard 6 kV/3 kA combinational surge, while the magnetic core absorbs over 20% of the energy. All test procedures conducted during this research adhere to IEEE C62.41/IEC 61000-4-5 standards. Full article
(This article belongs to the Collection Electrical Technologies)
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14 pages, 6451 KiB  
Article
Hierarchical Porous Activated Carbon Derived from Coconut Shell for Ultrahigh-Performance Supercapacitors
by Yawei Wang, Yuhui Duan, Xia Liang, Liang Tang, Lei Sun, Ruirui Wang, Shunhang Wei, Huanan Huang, Pinghua Yang and Huanan Hu
Molecules 2023, 28(20), 7187; https://doi.org/10.3390/molecules28207187 - 20 Oct 2023
Cited by 11 | Viewed by 4506
Abstract
In this research, we successfully produced hierarchical porous activated carbon from biowaste employing one-step KOH activation and applied as ultrahigh-performance supercapacitor electrode materials. The coconut shell-derived activated carbon (CSAC) features a hierarchical porous structure in a honeycomb-like morphology, leading to a high specific [...] Read more.
In this research, we successfully produced hierarchical porous activated carbon from biowaste employing one-step KOH activation and applied as ultrahigh-performance supercapacitor electrode materials. The coconut shell-derived activated carbon (CSAC) features a hierarchical porous structure in a honeycomb-like morphology, leading to a high specific surface area (2228 m2 g−1) as well as a significant pore volume (1.07 cm3 g−1). The initial test with the CSAC electrode, conducted in a 6 M KOH loaded symmetric supercapacitor, demonstrated an ultrahigh capacitance of 367 F g−1 at a current density of 0.2 A g−1 together with 92.09% retention after 10,000 cycles at 10 A g−1. More impressively, the zinc–ion hybrid supercapacitor using CSAC as a cathode achieves a high-rate capability (153 mAh g−1 at 0.2 A g−1 and 75 mAh g−1 at 10 A g−1), high energy density (134.9 Wh kg−1 at 175 W kg−1), as well as exceptional cycling stability (93.81% capacity retention after 10,000 cycles at 10 A g−1). Such work thus illuminates a new pathway for converting biowaste-derived carbons into materials for ultrahigh-performance energy storge applications. Full article
(This article belongs to the Special Issue Modern Materials in Energy Storage and Conversion)
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15 pages, 7663 KiB  
Article
Multifunctional MXene–Fe3O4–Carbon Nanotube Composite Electrodes for High Active Mass Asymmetric Supercapacitors
by Wenyu Liang, Rui Xu, Mohamed Nawwar and Igor Zhitomirsky
Batteries 2023, 9(6), 327; https://doi.org/10.3390/batteries9060327 - 16 Jun 2023
Cited by 3 | Viewed by 2336
Abstract
Ti3C2Tx–Fe3O4–carbon nanotube composites were prepared for electrochemical energy storage in the negative electrodes of supercapacitors. The electrodes show a remarkably high areal capacitance of 6.59 F cm−2 in a neutral Na2 [...] Read more.
Ti3C2Tx–Fe3O4–carbon nanotube composites were prepared for electrochemical energy storage in the negative electrodes of supercapacitors. The electrodes show a remarkably high areal capacitance of 6.59 F cm−2 in a neutral Na2SO4 electrolyte, which was obtained by the development of advanced nanofabrication strategies and due to the synergistic effect of the individual components. Enhanced capacitance was achieved using the in-situ synthesis method for the Fe3O4 nanoparticles. The superparamagnetic behavior of the Fe3O4 nanoparticles facilitated the fabrication of electrodes with a reduced binder content. Good mixing of the components was achieved using a celestine blue co-dispersant, which adsorbed on the inorganic components and carbon nanotubes and facilitated their co-dispersion and mixing. The capacitive behavior was optimized by the variation of the electrode composition and mass loading in a range of 30–45 mg cm−2. An asymmetric device was proposed and fabricated, which contained a Ti3C2Tx–Fe3O4–carbon nanotube negative electrode and a polypyrrole–carbon nanotube positive electrode for operation in an Na2SO4 electrolyte. The asymmetric supercapacitor device demonstrated high areal capacitance and excellent power-density characteristics in an enlarged voltage window of 1.6 V. This investigation opens a new avenue for the synthesis and design of MXene-based asymmetric supercapacitors for future energy storage devices. Full article
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12 pages, 3294 KiB  
Article
Effect of High-Energy Ball Milling, Capping Agents and Alkalizer on Capacitance of Nanostructured FeOOH Anodes
by Chengwei Zhang and Igor Zhitomirsky
Nanomaterials 2023, 13(10), 1693; https://doi.org/10.3390/nano13101693 - 21 May 2023
Cited by 1 | Viewed by 1987
Abstract
This investigation is motivated by interest in nanostructured FeOOH anodes for aqueous asymmetric supercapacitors operating in Na2SO4 electrolyte. The research goal is the fabrication of anodes with high active mass loading of 40 mg cm−2, high capacitance and [...] Read more.
This investigation is motivated by interest in nanostructured FeOOH anodes for aqueous asymmetric supercapacitors operating in Na2SO4 electrolyte. The research goal is the fabrication of anodes with high active mass loading of 40 mg cm−2, high capacitance and low resistance. The influence of high-energy ball milling (HEBM), capping agents and alkalizer on the nanostructure and capacitive properties is investigated. HEBM promotes the crystallization of FeOOH, which results in capacitance reduction. Capping agents from the catechol family, such as tetrahydroxy-1,4-benzoquinone (THB) and gallocyanine (GC), facilitate the fabrication of FeOOH nanoparticles, eliminate the formation of micron size particles and allow the fabrication of anodes with enhanced capacitance. The analysis of testing results provided insight into the influence of the chemical structure of the capping agents on nanoparticle synthesis and dispersion. The feasibility of a conceptually new strategy for the synthesis of FeOOH nanoparticles is demonstrated, which is based on the use of polyethylenimine as an organic alkalizer-dispersant. The capacitances of materials prepared using different nanotechnology strategies are compared. The highest capacitance of 6.54 F cm−2 is obtained using GC as a capping agent. The obtained electrodes are promising for applications as anodes for asymmetric supercapacitors. Full article
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18 pages, 7110 KiB  
Article
Research on Non-Invasive Floating Ground Voltage Measurement and Calibration Method
by Chunguang Suo, Mingxing He, Guoqiong Zhou, Xinghua Shi, Xiangyu Tan and Wenbin Zhang
Electronics 2023, 12(8), 1858; https://doi.org/10.3390/electronics12081858 - 14 Apr 2023
Cited by 4 | Viewed by 2820
Abstract
Voltage measurement is an important part of power system operation, and non-intrusive voltage sensors have the advantages of low insulation difficulty, simple structure, easy loading and unloading, and high construction safety, which have become a new direction for voltage measurement. Based on the [...] Read more.
Voltage measurement is an important part of power system operation, and non-intrusive voltage sensors have the advantages of low insulation difficulty, simple structure, easy loading and unloading, and high construction safety, which have become a new direction for voltage measurement. Based on the principle of electric field coupling, this paper constructs a non-intrusive floating ground three-capacitance voltage measurement model, which can complete the accurate measurement of voltage without connecting with the line to be measured and the earth in the measurement process. In non-intrusive voltage measurement, the change of the object to be measured or the measurement environment will cause the change of the coupling capacitance, which leads to the uncertainty of the transmission relationship of the sensor and the large error of measurement results. In order to solve this problem, a new method of sensor calibration is proposed in this paper. By sampling capacitance in parallel between two electrodes of the sensor, changing the capacitance value, and establishing an input output equation, the coupling capacitance value and the voltage value to be measured under different operating conditions are solved. In addition, the sampling capacitance is often several orders of magnitude larger than the sensor’s own capacitance, making the sensor’s voltage division ratio significantly higher and more conducive to the measurement of high voltages. The experimental results show that the measurement error is less than 2%, which verifies the feasibility of the method and the accuracy of the voltage measurement. Full article
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